general Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general BODIPY dyes for optical limiting applications on the nanosecond timescale By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17766-17771DOI: 10.1039/D4DT02505A, FrontierJohn Mack, Gugu Kubheka, Aviwe May, Bokolombe P. Ngoy, Tebello NyokongRecent research at the Institute for Nanotechnology Innovation at Rhodes University exploring the utility of BODIPY and azaBODIPY dyes for optical limiting of incident nanosecond laser pulses in the visible region is described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Multi-functional biotinylated platinum(IV)–SAHA conjugate for tumor-targeted chemotherapy By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17829-17840DOI: 10.1039/D4DT01571A, PaperAjay Gupta, Pijus K. SasmalHerein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17963-17975DOI: 10.1039/D4DT02014F, PaperMorigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin ZhaoConstruction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general An insightful study on the reduction and extraction of neptunium assisted by molybdenum By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17909-17917DOI: 10.1039/D4DT02547D, PaperHuaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing ChenMo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Fluorescent molecular systems based on carborane-perylenediimide conjugates By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17841-17851DOI: 10.1039/D4DT02477J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ruben Rodriguez-Madrid, Sohini Sinha, Laura Parejo, Jordi Hernando, Rosario Núñezo-Carborane–perylenediimide conjugates exhibit exceptional fluorescence properties in solution, while red-light excimer emission is observed in their aggregated forms and in dispersible nanoparticles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17864-17879DOI: 10.1039/D4DT02425G, PaperJie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu XuanAn asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17880-17892DOI: 10.1039/D4DT02544J, PaperZhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing CuiThree novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17902-17908DOI: 10.1039/D4DT02609H, PaperXiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai YuanA series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18047-18053DOI: 10.1039/D4DT02567A, PaperHui Li, He ZhengInsights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18037-18046DOI: 10.1039/D4DT02755H, PaperJingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. ColebatchA new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17989-18002DOI: 10.1039/D4DT02195A, PaperJie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng FangA series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17772-17776DOI: 10.1039/D4DT02595D, CommunicationZaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi YiNeutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18013-18020DOI: 10.1039/D4DT02533D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. NolanDespite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17976-17988DOI: 10.1039/D4DT02355B, PaperThe Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang TranVarious 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17789-17793DOI: 10.1039/D4DT02791D, CommunicationGargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. SenThe reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02627F, PaperWenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie DingCage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02781G, PaperRuopei Sun, Erwan Dupuis, Jean Aupiais, Pascal ReillerThe formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Single-ion magnetism in novel Btp-based cobalt complexes of different charge By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02338B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez LópezBy deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
general Grow your own grub By www.thehindu.com Published On :: Mon, 26 Aug 2013 14:58:34 +0530 If the price of vegetables and concern about chemicals worries you, it’s time you turned an urban farmer and grew your own food. Your balcony, terrace, or your backyard can be your farm, says BHUMIKA K. August 25 is celebrated as World Kitchen Gardeners’ Day Full Article Gardens
general A bagful of joy By www.thehindu.com Published On :: Mon, 26 Aug 2013 19:20:10 +0530 Aashi Kitchen Garden’s Vegetable Grow Bags ensure that you get a consistent supply of vegetables Full Article Gardens
general Shrinking strategies By www.thehindu.com Published On :: Fri, 30 Aug 2013 15:47:41 +0530 Fascinated by bonsai and want to grow your own? Hema Vijay tells you how Full Article Gardens
general Where the grass is always green By www.thehindu.com Published On :: Fri, 13 Sep 2013 15:32:13 +0530 Always wanted a lawn, but didn’t know where to start? Navneeth Raghavan offers a few tips Full Article Gardens
general Treebay: Factory or farm? By www.thehindu.com Published On :: Fri, 13 Sep 2013 17:50:38 +0530 Nearly two thousand trees, 50 varieties of flowering plants and 20 varieties of hedge plants add colour to Jagannath Textile near Karumathampatti. Full Article Society
general Out of the planter By www.thehindu.com Published On :: Fri, 20 Sep 2013 15:42:45 +0530 Some unusual mediums for gardening from Rupa Gopal Full Article Gardens
general The glam girl among flowers By www.thehindu.com Published On :: Wed, 02 Oct 2013 18:29:21 +0530 Gardening: Welcome the sturdy anthuriums and be assured of splashes of colour Full Article Gardens
general Garden state By www.thehindu.com Published On :: Fri, 11 Oct 2013 12:34:55 +0530 In Singapore’s Hort Park, Rupa Gopal meets gardening enthusiasts at the annual fair Full Article Gardens
general The time to sow By www.thehindu.com Published On :: Fri, 11 Oct 2013 12:54:08 +0530 … is now, so start that garden today, says Hema Vijay Full Article Gardens