Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article

Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [Fe^II(L^H-OR)(NCBH₃)₂] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00023J, Research Article

Yao Yuan, Xiaoyu Chen, Xing Zhang, Zumin Wang, Ranbo Yu
A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00261E, Research Article

Kok-Giap Haw, Simona Moldovan, Lingxue Tang, Zhengxing Qin, Qianrong Fang, Shilun Qiu, Valentin Valtchev
The accessibility of SSZ-13 is enhanced by having a sponge-like structure after etching under neutral pH conditions.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article

Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln₆₀. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00146E, Review Article

Hui Chen, Xiaoxin Zou
This review summarizes structural features and recent synthesis methods of structurally ordered intermetallic borides, and the theoretical–experimental advances in the emerging boride-catalyzed reactions.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00365D, Research Article

Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu
The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00259C, Research Article

Ping He, Jiehua Ding, Zhengxing Qin, Lingxue Tang, Kok-Giap Haw, Yiying Zhang, Qianrong Fang, Shilun Qiu, Valentin Valtchev
Organic structure directing agent (OSDA)- and binder-free preparation of ZSM-5@silica beads and their use for aniline removal.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article

Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00316F, Research Article

Qing Li, Nan Li, Jing An, Huan Pang
Mesoporous rod-like structured composites of NiO/Ni have been successfully prepared via a low temperature heat treatment of the precursor NiC₂O₄·2H₂O in N₂.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article

Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article

Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00319K, Research Article

Fabrice Pointillart, Jessica Flores-Gonzalez, Vincent Montigaud, Lorenzo Tesi, Vladimir Kuz'mich Cherkasov, Boris Le Guennic, Olivier Cador, Lahcene Ouahab, Roberta Sessoli, Viacheslav Kuropatov
The first simultaneous redox and solvato-magnetic switching was achieved. The dinuclear complex [Dy2(hfac)6(H2SQ)]CH2Cl2 (Dy2H2SQ) (where hfac = 1,1,1,5,5,5-hexafluoroacethylacetonate and H2SQ = 2,2’-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate) was reversibly oxidized into the dinuclear complex [Dy2(hfac)6(H2O)2(Q)]...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01691K, Research Article

Liang Chen, Xuefang Xie, Zhian Zhang, Xiangzhong Kong, Shuquan Liang, Anqiang Pan
Graphene decorated with hetero-Co₉S₈–NiS sheets have abundant active sites, which can efficiently catalyze the electrochemical conversion of lithium polysulfides in Li–S battery.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article

Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO₂ to C₂H₄, and exhibit a maximum Faraday Efficiency 41.3%.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00276C, Research Article

Shuang Lü, Hongli Huang, Ru-Fen Zhang, Chunlin Ma, Qianli Li, Jiao He, Ting Li, jun yang, Yulong Li
In order to enrich the chemistry of the Fe/Te cluster compounds related to the active site of [FeFe]-hydrogenase, the reactions of compound Fe2(μ-TeAr)2(CO)6 with tertiary phosphines were described. Three types...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00228C, Research Article

Youngkwan Yoon, Jin Young Koo, Jongwon Oh, Soyoung Kim, Hee Cheul Choi, Seok Min Yoon
Polymorphism control of the titanyl-phthalocyanine (TiOPc) single crystals by molecule-surface interactions and their effects of crystallographic structural differences on photo-electronics.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article

Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00232A, Research Article

Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Minguez Espallargas, Lauro J. Q. Maia, Gisane Gasparotto, Ricardo Costa de Santana, Walter Cañón-Mancisidor
A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu₄]₃[LnH(PW₁₁O₃₉)(phen)₂]·H₂O, denoted as LM⁴-1-Ln^† (Ln = Dy^III, Tb^III, Eu^III, Nd^III, Er^III, Ho^III and Gd^III), were synthesized via hydrothermal synthesis and were structurally...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article

Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO₂/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm⁻² for electrocatalytic water splitting.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article

Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Inorg. Chem. Front., 2020, 7,1845-1850
DOI: 10.1039/C9QI01431D, Research Article

Jonghoon Choi, Yunho Lee
Catalytic hydrogenation of CO₂ occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.
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Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article

Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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Inorg. Chem. Front., 2020, 7,1900-1908
DOI: 10.1039/C9QI01674K, Research Article

Xiaoxia Xu, Lingjie Li, Huiqing Chen, XiaoSong Guo, Zhonghua Zhang, Jing Liu, Changming Mao, Guicun Li
Heterostructured porous FeS₂/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.
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Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article

Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)₄]²⁻ complexes within π-acidic cavities.
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Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article

Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO₂ nanosheets.
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Inorg. Chem. Front., 2020, 7,1872-1879
DOI: 10.1039/D0QI00120A, Research Article

Yue Song, Risheng Bai, Yongcun Zou, Zhaochi Feng, Jihong Yu
A temperature-regulated method was developed to construct anatase-free hierarchical TS-1 zeolite catalysts by utilizing a two-step hydrothermal crystallization strategy with tetrabutylammonium hydroxide as the sole organic template.
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Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article

Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article

Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe₂O₄–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article

Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article

Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl₂ cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl₂ during discharging in acidic AlCl₃-based electrolyte.
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Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article

Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Inorg. Chem. Front., 2020, 7,1801-1821
DOI: 10.1039/D0QI00167H, Review Article

Partha Samanta, Sumanta Let, Writakshi Mandal, Subhajit Dutta, Sujit K. Ghosh
This review aims to provide an overview regarding the development of luminescent metal–organic frameworks (LMOFs) based sensory materials for the detection of cationic inorganic and organic water pollutants.
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Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article

Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO₂-philic acylamide groups exhibits high performance for CO₂ capture, separation and chemical conversion.
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Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article

Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO₂/CH₄, C₂H₂/CO₂, C₂H₂/CH₄ and benzene/cyclohexane, and catalytic conversion of CO₂ with epoxides.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article

Genlei Zhang, Zhenxi Zhang
Porous Ir₃Pb nanodendrites exhibit excellent activity and superior CO₂ selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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Inorg. Chem. Front., 2020, 7,1864-1871
DOI: 10.1039/D0QI00224K, Research Article

Cheng Zhang, Ruilin Guan, Xinxing Liao, Cheng Ouyang, Jiangping Liu, Liangnian Ji, Hui Chao
A dinuclear complex [(ppy)Ir(tpy)PtCl]²⁺ (Ir–Pt) can exhibit strong antitumor activity towards cisplatin-resistant cancer cells and induce cell necrosis via mtDNA damage and mitochondrial dysfunction.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article

Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article

Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00359J, Research Article

Juan Zhang, Yueying Chu, Feng Deng, Zhaochi Feng, Xiangju Meng, Feng-Shou Xiao
The formation and evolution of building units for zeolites play an important role during crystallization.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article

Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article

Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo₂S₄ are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article

Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg₂Cl₃]⁺ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article

Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article

Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article

Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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