science and technology

Fungal diversity and key functional gene abundance in Iowa bioretention cells: implications for stormwater remediation potential

Environ. Sci.: Processes Impacts, 2024, 26,1796-1810
DOI: 10.1039/D4EM00275J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Erica A. Wiener, Jessica M. Ewald, Gregory H. LeFevre
Fungal communities within bioretention cells were diverse, including taxa capable of biodegrading recalcitrant contaminants, and influenced by plant type. Fungal functional genes demonstrate bioremediation potential in stormwater infrastructure.
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science and technology

Experimental assessment of low temperature plasma devices for bacterial aerosol inactivation in the air duct of HVAC systems

Environ. Sci.: Processes Impacts, 2024, 26,1836-1846
DOI: 10.1039/D4EM00158C, Paper
Yang Lv, Xiaodong Wang, Beibei Wang, Wenjie Yuan
This study evaluates the effectiveness of low temperature plasma (LTP) devices in the air duct of HVAC systems, achieving 82% bacterial aerosol inactivation under optimal conditions, advocating their use in public buildings to improve air quality.
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science and technology

Microplastics are effective carriers of bisphenol A and facilitate its escape from wastewater treatment systems

Environ. Sci.: Processes Impacts, 2024, 26,1811-1820
DOI: 10.1039/D4EM00297K, Paper
Wang Li, Bo zu, Lei Li, Jian Li, Jiawen Li, Qiujie Xiang
Microplastics (MPs) pollution is a major issue in aquatic environments.
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science and technology

Impact of particle size separation on the stabilisation efficiency of heavy-metal-contaminated soil: a meta-analysis

Environ. Sci.: Processes Impacts, 2024, 26,1821-1835
DOI: 10.1039/D4EM00308J, Paper
Lixia Sun, Yunlong Zhang, Bo Wu, Enzhu Hu, Linlin Li, Longlong Qu, Shuqi Li
The meta-method was used to analyze the impact of soil sieving particle size on the unit stabilisation efficiency of heavy metals.
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science and technology

Depletion rates of O2-naphthenic acids from oil sands process-affected water in wetland microcosms

Environ. Sci.: Processes Impacts, 2024, 26,1859-1867
DOI: 10.1039/D4EM00227J, Paper
Alexander M. Cancelli, Frank A. P. C. Gobas
Depuration in OSPW occurs by mechanisms of natural attenuation, sorption and microbial degradation, and plant-mediated uptake and biotransformation.
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science and technology

A 150 years record of polycyclic aromatic compounds in the Sihailongwan Maar Lake, Northeast China: impacts of socio-economic developments and pollution control

Environ. Sci.: Processes Impacts, 2024, 26,1748-1759
DOI: 10.1039/D4EM00309H, Paper
Jianing Zhang, Chong Wei, Yongming Han, Benjamin A. Musa Bandowe, Dewen Lei, Wolfgang Wilcke
The geochemical composition of sediment cores can serve as a proxy for reconstructing past human and nature-driven environmental and climatic changes.
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science and technology

Combining a tunable pinhole with synchronous fluorescence spectrometry for visualization and quantification of benzo[a]pyrene at the root epidermis microstructure of Kandelia obovata

Environ. Sci.: Processes Impacts, 2024, 26,1879-1886
DOI: 10.1039/D4EM00443D, Paper
Bingman Lei, Yaxian Zhu, Yong Zhang
Establishing a method to reveal the distribution and retention of benzo[a]pyrene at the root epidermis microstructure of Kandelia obovata.
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science and technology

Influence of tritium exposure route on vegetation types at the Savannah River Site

Environ. Sci.: Processes Impacts, 2024, 26,1736-1747
DOI: 10.1039/D4EM00311J, Paper
Martine C. Duff, Elizabeth A. Pettitt, Holly VerMeulen
This study shows a relationship between total T content and the OBT:HTO in plants. These results give information on environmental management options if an aqueous or atmospheric T release event from a fusion reactor occurs and reaches a water body.
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science and technology

Exploring the variability of PFAS in urban sewage: a comparison of emissions in commercial versus municipal urban areas

Environ. Sci.: Processes Impacts, 2024, 26,1868-1878
DOI: 10.1039/D4EM00415A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Krlovic N., Saracevic E., Derx J., Gundacker C., Krampe J., Kreuzinger N., Zessner M., Zoboli O.
PFAS in an urban environment can come from various sources. The main activity in the area, i.e. commercial versus municipal, can influence the overall loads and speciation of PFAS in the examined wastewater.
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science and technology

Storms mobilize organophosphate esters, bisphenols, PFASs, and vehicle-derived contaminants to San Francisco Bay watersheds

Environ. Sci.: Processes Impacts, 2024, 26,1760-1779
DOI: 10.1039/D4EM00117F, Paper
Open Access
Katherine T. Peter, Alicia Gilbreath, Melissa Gonzalez, Zhenyu Tian, Adam Wong, Don Yee, Ezra L. Miller, Pedro M. Avellaneda, Da Chen, Andrew Patterson, Nicole Fitzgerald, Christopher P. Higgins, Edward P. Kolodziej, Rebecca Sutton
We evaluated the occurrence of 154 organic contaminants from multiple chemical/use classes in San Francisco Bay watersheds during storm events, revealing complex mixtures and high concentrations transported to receiving waters.
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science and technology

Assessment of occurrence, source appointment, and ecological risks of pharmaceuticals and personal care products in the water–sediment interface of Qiantang River in the Hangzhou region

Environ. Sci.: Processes Impacts, 2024, 26,1887-1897
DOI: 10.1039/D4EM00355A, Paper
Yang Wan, Ziming Wang, Kaiping Xu, Wei Wang, Pengcheng Yao, Aiju You
TCS exhibited the highest concentration across different phases and seasons in QTR, and TCS posed high risks in surface water and low risks in sediment across all sampling sites.
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science and technology

Pollution characteristics and risk assessment of endocrine-disrupting chemicals in surface water of national (freshwater) aquatic germplasm resource reserves in Guangdong Province

Environ. Sci.: Processes Impacts, 2024, 26,1898-1911
DOI: 10.1039/D4EM00425F, Paper
Tao Zhou, Jie Li, Weizhen Zhang, Yanyi Zeng, Yuan Gao, Haiyan Li, Wanling Yang, Yongzhan Mai, Qianfu Liu, Caiqin Hu, Chao Wang
EE2, E1, BPA, NP, and E2 were identified as high-risk substances based on comprehensive ecological risk evaluation and fish are the most sensitive organisms.
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science and technology

Critical insights into data curation and label noise for accurate prediction of aerobic biodegradability of organic chemicals

Environ. Sci.: Processes Impacts, 2024, 26,1780-1795
DOI: 10.1039/D4EM00431K, Paper
Open Access
Paulina Körner, Juliane Glüge, Stefan Glüge, Martin Scheringer
The newly developed classifier has a balanced accuracy of 94.2%, better than any other classification model for aerobic biodegradability so far. During the model development, some data points needed to be excluded due to a very high variance.
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science and technology

Assessment of extracellular polymeric substances production and antioxidant defences in periphytic communities exposed to effluent contaminants

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00446A, Paper
Carlos Silva, Etelvina Figueira, Diana Matos, Carina Sá, Tânia Vidal, Fernando José Mendes Gonçalves, Nelson Abrantes, Joana Luísa Pereira
Periphyton is frequently used in the evaluation of the ecological status of aquatic ecosystems using diatoms as a proxy.
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science and technology

Assessment of the cytotoxicity micro- and nano-plastic on human intestinal Caco-2 cells and the protective effects of catechin

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00408F, Paper
Xiaoxia Wang, Zhongneng Yang, Xiao-Min Ren, Zhenghuan Zhang, Huan He, Xuejun Pan
This study found that PS-M/NPs have a size-dependent cytotoxic effect on the human intestinal epithelial cell line Caco-2, mediated by the production of reactive oxygen species. Additionally, catechins were shown to mitigate these adverse effects.
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science and technology

Organic aerosol formation from 222 nm germicidal light: ozone-initiated vs. non-ozone pathways

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00384E, Paper
Open Access
Matthew B. Goss, Jesse H. Kroll
Ozone production can explain most indoor air quality impacts of 222 nm germicidal ultraviolet light (GUV222). However, GUV222 causes more new particle formation than is explained by ozone chemistry.
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science and technology

Experimental and theoretical investigation of benzothiazole oxidation by OH in air and the role of O2

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00461B, Paper
Natalia V. Karimova, Weihong Wang, R. Benny Gerber, Barbara J. Finlayson-Pitts
Products of the oxidation of BTH by OH in air.
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science and technology

Longevity of size-dependent particle removal performance of do-it-yourself box fan air filters

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00406J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Theresa Pistochini, Graham Jaeger, Christopher D. Cappa, Richard L. Corsi
Filtration performance of do-it-yourself (DIY) box fan air filters deployed across a university campus was assessed over an academic year.
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science and technology

Degradation of norfloxacin by the synergistic effect of micro–nano bubbles and sodium hypochlorite: kinetics, influencing factors and pathways

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00490F, Paper
Guijuan Li, Yan Cheng, Mengyao Jing, Dan Zhang, Yufei Ma, Shengke Yang
The degradation reaction process and influencing factors of norfloxacin in the sodium hypochlorite and micro–nano bubble composite system.
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science and technology

The gas phase ozonolysis and secondary OH production of cashmeran, a musk compound from fragrant volatile chemical products

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00452C, Paper
Ayomide A. Akande, Nadine Borduas-Dedekind
We quantified the lifetime of cashmeran, a musk compound, against 20 ppbv of O3 to be 85 days. In the presence of O2, cashmeran may influence the oxidative capacity indoors via production of secondary OH radicals (up to 5.1 × 105 molec cm−3).
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science and technology

How do ecosystem service functions affect ecological health? Evidence from the Yangtze River Economic Belt in China

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00296B, Paper
Wei Wang, Jun Yang, Guishan Yang, Chao Wu, Jie Yu
Ecosystem services serve as a bridge between social and economic impacts and ecological health.
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science and technology

Commercial kitchen operations produce a diverse range of gas-phase reactive nitrogen species

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00491D, Paper
Leigh R. Crilley, Jenna C. Ditto, Melodie Lao, Zilin Zhou, Jonathan P. D. Abbatt, Arthur W. H. Chan, Trevor C. VandenBoer
Gas phase reactive nitrogen (Nr) species in a commercial kitchen are mainly composed of expected species with many additional species completing the budget.
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science and technology

Polyethylene microplastics affect behavioural, oxidative stress, and molecular responses in the Drosophila model

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00537F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Himanshu Ranjan, Swetha Senthil Kumar, Sharine Priscilla, Subhashini Swaminathan, Masakazu Umezawa, Sahabudeen Sheik Mohideen
The study highlights the negative effects of PE MPs on motor functions, oxidative stress, and cellular stress responses in Drosophila, emphasizing the broader ecological risks associated with microplastic pollution.
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science and technology

Quantitative read-across structure–property relationship (q-RASPR): a novel approach to estimate the bioaccumulative potential for diverse classes of industrial chemicals in aquatic organisms

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00374H, Paper
Prodipta Bhattacharyya, Pabitra Samanta, Ankur Kumar, Shubha Das, Probir Kumar Ojha
The Bioconcentration Factor (BCF) is used to evaluate the bioaccumulation potential of chemical substances in reference organisms, and it directly correlates with ecotoxicity.
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science and technology

A methodology for estimating indoor sources contribution to PM2.5

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00538D, Paper
Open Access
Shiva Nourani, Ana María Villalobos, Hector Jorquera
Quantifying source contributions to indoor PM2.5 brought by indoor PM2.5 sources has been limited by the costs associated to chemical speciation analyses of indoor PM2.5 samples. Here we propose a...
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science and technology

Emerging investigator series: open dumping and burning: an overlooked source of terrestrial microplastics in underserved communities

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00439F, Paper
Open Access
Kendra Z. Hess, Kyle R. Forsythe, Xuewen Wang, Andrea Arredondo-Navarro, Gwen Tipling, Jesse Jones, Melissa Mata, Victoria Hughes, Christine Martin, John Doyle, Justin Scott, Matteo Minghetti, Andrea Jilling, José M. Cerrato, Eliane El Hayek, Jorge Gonzalez-Estrella
Open dumping and burning of solid waste are widely practiced in underserved communities lacking access to solid waste management facilities. The generation of microplastics from these sites has been overlooked.
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science and technology

Validation of a laboratory spray generation system and its use in a comparative study of hexamethylene diisocyanate (HDI) evaluation methods

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00513A, Paper
Hugues Ahientio, Loïc Wingert, Sébastien Gagné, Jacques Lesage, Livain Breau, Simon Aubin
Isocyanates are well-known irritants and sensitizers, and measuring their occupational airborne exposure is challenging due to their high chemical reactivity and semi-volatile nature. This study builds on a previous publication...
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science and technology

Systematic characterization of selenium speciation in coal fly ash

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00398E, Paper
Open Access
Estefania Garcia, Pan Liu, Sharon E. Bone, Yinghao Wen, Yuanzhi Tang
A survey study of Se speciation in coal fly ash samples representative of coal source and combustion conditions.
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science and technology

Leachability of per- and poly-fluoroalkyl substances from contaminated concrete

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00482E, Paper
Open Access
Prashant Srivastava, Grant Douglas, Greg B. Davis, Rai S. Kookana, Canh Tien Trinh Nguyen, Mike Williams, Karl Bowles, Jason K. Kirby
This study examines PFAS leaching behavior from concrete contaminated by the historical use of aqueous film-forming foams at an Australian Defence site, highlighting the long-term environmental implications of contaminated infrastructure.
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science and technology

Domestic groundwater wells in Appalachia show evidence of low-dose, complex mixtures of legacy pollutants

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00364K, Paper
Open Access
Nicolette A. Bugher, Boya Xiong, Runako I. Gentles, Lukas D. Glist, Helen G. Siegel, Nicholaus P. Johnson, Cassandra J. Clark, Nicole C. Deziel, James E. Saiers, Desiree L. Plata
Private groundwater wells in communities co-located with historically contaminated sites and ongoing industrial activity contain complex mixtures of low-dose organic chemicals.
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science and technology

Mobility of biochar-derived dissolved organic matter and its effects on sulfamerazine transport through saturated soil porous media

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00143E, Paper
Mengya Liu, Xiaochen Liu, Yalu Hu, Qiang Zhang, Usman Farooq, Zhichong Qi, Laotao Lu
Dissolved organic matter (DOM) released from biochar may impact antibiotic mobility and environmental fate in subsurface environments.
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science and technology

Kinetic multilayer models for surface chemistry in indoor environments

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00549J, Paper
Pascale S. J. Lakey, Manabu Shiraiwa
Multiphase interactions and chemical reactions at indoor surfaces are of particular importance due to their impact on air quality in indoor environments with high surface to volume ratios.
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science and technology

Exposure to per- and polyfluoroalkyl substances (PFAS) in North Carolina homes: results from the indoor PFAS assessment (IPA) campaign

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00525B, Paper
Naomi Y. Chang, Clara M. A. Eichler, Elaine A. Cohen Hubal, Jason D. Surratt, Glenn C. Morrison, Barbara J. Turpin
Per and polyfluoroalkyl substances (PFAS) are ubiquitous in the indoor environment, resulting in indoor exposure. Inhalation and ingestion dominate.
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science and technology

Mobile monitoring reveals the importance of non-vehicular particulate matter sources in London

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00552J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Samuel Wilson, Naomi J. Farren, Shona E. Wilde, Rebecca L. Wagner, James D. Lee, Lauren E. Padilla, Greg Slater, Daniel Peters, David. C. Carslaw
A novel application of mobile monitoring to investigate the spatial distribution of vehicular and non-vehicular urban particulate matter sources in London, UK.
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science and technology

Combining sequential extractions with bulk and micro X-ray spectroscopy to elucidate iron and phosphorus speciation in sediments of an iron-treated peat lake

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00402G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Melanie Münch, Andreas Voegelin, Luis Carlos Colocho Hurtarte, Jörg Goettlicher, T. Behrends
In shallow lakes, mobilization of legacy phosphorus (P) from the sediments can be the main cause for persisting eutrophication after reduction of external P input. In-lake remediation measures can be...
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science and technology

Synergistic Fe,Ce doping of Ni3S2 for enhancing oxygen evolution reaction performance

Inorg. Chem. Front., 2024, 11,7623-7632
DOI: 10.1039/D4QI02187H, Research Article
Yu He, Kefan Shi, Xueqin Wang, Xingzi Zheng, Lanke Luo, Liu Lin, Zemin Sun, Genban Sun
Fe,Ce-Ni3S2@NF nanoneedle catalysts synthesised via a one-step hydrothermal route showed good OER performance.
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science and technology

MOF-derived Co–Mo bimetallic heterostructures for the selective trapping and conversion of polysulfides in lithium–sulfur batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01249F, Research Article
Rongmei Zhu, Yuxuan Jiang, Bingxin Sun, Wang Zhang, Huan Pang
Hollow CoSx/MoO3 derived from ZIF-67 shows preferred selective trapping and conversion of LiPSs as a modified separator material for LSBs.
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science and technology

A solvent-free neutral cobalt complex exhibiting macroscopic polarization switching induced by directional charge transfer

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01389A, Research Article
Zi-Qi Zhou, Shu-Qi Wu, Qi-Rui Shui, Wen-Wei Zheng, Akari Maeda, Xiao-Peng Zhang, Jing Chu, Shinji Kanegawa, Sheng-Qun Su, Osamu Sato
A solvent-free neutral cobalt complex featuring a non-centrosymmetric polar structure exhibits macroscopic polarization switching induced by charge transfer.
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science and technology

ZnIn2S4 nanosheets with tunable dual vacancies for efficient sacrificial-agent-free H2O2 photosynthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02030H, Research Article
Chen Zhang, Gao Xu, Qifeng Liang, Li Liang, Zebo Fang, Rong Wu, Shunhang Wei, Lei Wang, Xiaoxiang Xu
ZnIn2S4 nanosheets with tunable concentration of dual vacancies were prepared. Introducing dual vacancies effectively promotes photocarrier separation, facilitates O2 adsorption, and inhibits H2O2 decomposition by increasing hydrophilicity.
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science and technology

Multifunctional core–shell CaSnO3@N-doped carbon coaxial nanocables with excellent lithium storage performance and efficient microwave absorption

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02264E, Research Article
Xiaoqiang Li, Guangguang Guan, Siyi Tong, Xin Chen, Kaiyin Zhang, Jun Xiang
It is highly desirable but challenging to design multi-functional materials for energy storage and electromagnetic (EM) wave absorption.
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science and technology

Superior energy storage performance with a record high breakdown strength in bulk Ba0.85Ca0.15Zr0.1Ti0.9O3-based lead-free ceramics via multiple synergistic strategies

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02126F, Research Article
Changhao Wang, Jiaxi Hao, Longxiao Duan, Jianfan Zhang, Wenfeng Yue, Zhenhao Fan, Dandan Han, Raz Muhammad, Fanxu Meng, Dawei Wang
A composition and structure optimization strategy combined with a two-step sintering (TSS) process is proposed to design and fabricate (1−x)Ba0.85Ca0.15Zr0.1Ti0.9O3xBi(Mg1/2Sn1/2)O3 (BCZT-BMSx-TSS) lead-free ceramics.
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science and technology

Near-infrared-II photothermal conversion and magnetic dynamic regulation in [Ln3Rad2] aggregation by rigidity modification of nitronyl nitroxide

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01952K, Research Article
Hongdao Li, Chaoyi Jin, Jing Han, Jianke Tang, Xiaofeng Han, Zhenjun Song
Nitronyl nitroxide in Ln(III) multi-spin clusters has been utilized for realizing the regulation of NIR-II photothermal conversion and magnetic dynamics.
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science and technology

Water-stable zero-dimensional hybrid zinc halide modulated by π–π interactions: efficient blue light emission and third-order nonlinear optical response

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02194K, Research Article
Jia-Wei Li, Wenke Dong, Yanjie Liu, Yuhan Li, Lu-Yuan Qiao, Guang-Lu Liu, Hui Zhang, Chunjie Wang, Hui-Li Zheng, Jian-Qiang Zhao
Waterproof 0D hybrid Zn halide with highly efficient blue emission and third-order nonlinear optical response was constructed by the microregulating of π–π interactions, offering new insights for designing stable multifunctional halide materials.
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science and technology

Amorphous MoaZr0.8Ox-500 catalyzed selective oxidation of sulfides to sulfoxides mediated by 1O2 from direct heterolytic cleavage of H2O2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02008A, Research Article
Tong Li, Jiaheng Qin, Xueyao Zhang, Xiaoqi Tang, Mingzhe Lv, Weiwen Mao, Linkun Dong, Tongtong Fan, Yu Long, Jiantai Ma
Sulfoxides, a class of pharmaceuticals and fine chemicals of significant importance, are readily peroxidized to sulfones in the H2O2 system.
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science and technology

Significant adsorption enhancements driven by pore microenvironment tuning for efficient C2H2/C2H4 separation in a chemically stable Ni7-cluster-based framework

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01856G, Research Article
Yunli Wang, Rizhao Zhang, Jin-Peng Xue, Yuqiao Chai, Bao Li, Jia Li
This study presents a stable Ni7-cluster MOF with enhanced adsorption through pore microenvironment tuning. Two types of guest-free frameworks achieve C2H2/C2H4 separation, providing deep insights into separation mechanisms.
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science and technology

Vibrational analysis of auranofin complexes with cysteine and selenocysteine unveils distinct binding motifs and specific unimolecular reactivity

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02023E, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roberto Paciotti, Davide Corinti, Cecilia Coletti, Nazzareno Re, Giel Berden, Jos Oomens, Simonetta Fornarini, Maria Elisa Crestoni
The [(Et3P)AuCys]+ and [(Et3P)AuSec]+ ions and their deamination products were characterized using IRMPD spectroscopy backed by DFT calculations finding differences in binding motifs and reactivity.
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science and technology

Achieving high power density and stability in aqueous Mg–air batteries using taurine electrolyte additives

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01842G, Research Article
Sha Jianchun, Wang Qiang, Li Xue, Liu Zhoulin, Bao Jiaxin, Li Lianhui, Tian Jie, Chen Weilong, Liu Wenhong, Zhang Zhiqiang
Aqueous Mg–air batteries are promising candidates for large-scale energy storage, but their practical application is significantly hindered by water-induced parasitic reactions and the chunk effect.
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science and technology

Strategic pathway selection for photocatalytic degradation: roles of holes and radicals

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01635A, Review Article
Yixuan Li, Xu Gao, Yuxin Li
As global resources become scarce and environmental issues become increasingly severe, developing photocatalytic technology for efficiently and cleanly degrading pollutants has become a research trend.
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science and technology

Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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science and technology

Synthesis and structure of chlororuthenacyclopentatriene

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01833H, Research Article
Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi Chen, Guochen Jia
Chlororuthenacyclopentatriene, representing a new member of the ruthenaaromatic family, was successfully prepared using the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl.
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