Chem. Soc. Rev., 2024, 53,3829-3895
DOI: 10.1039/D3CS01043K, Review Article

Yao-Jie Lei, Lingfei Zhao, Wei-Hong Lai, Zefu Huang, Bing Sun, Pauline Jaumaux, Kening Sun, Yun-Xiao Wang, Guoxiu Wang
This review categorizes subnanometer pores/channels (SNPCs) from structural perspective and demonstrates electrochemical couplings in SNPCs for batteries while proposing corresponding challenges and future research directions.
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Chem. Soc. Rev., 2024, 53,3896-3951
DOI: 10.1039/D3CS00784G, Review Article

Mian He, Chaopeng Hu, Rui Wei, Xin-Feng Wang, Liu Leo Liu
This review provides an overview of main group carbene analogues, covering recent advancements, synthesis strategies, and the diverse reactivity of elements in groups 13–15 based on their structural characteristics.
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Chem. Soc. Rev., 2024, 53,4020-4044
DOI: 10.1039/D3CS00944K, Review Article

Ya Wang, Yamin Xiong, Kangqi Shi, Clement Yaw Effah, Lulu Song, Leiliang He, Jianbo Liu
This review is dedicated to offering a new perspective on using DNA nanostructures to explore the progress of cell–cell communication.
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Chem. Soc. Rev., 2024, 53,4045-4085
DOI: 10.1039/D3CS00431G, Review Article

Mobina Bayat, Hanieh Mardani, Hossein Roghani-Mamaqani, Richard Hoogenboom
Self-indicating polymers undergo detectable variations in response to stimuli. Important mechanisms of self-indication are aggregation, phase transition, covalent and non-covalent bond cleavage, isomerization, charge transfer, and energy transfer.
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Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review

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Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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Chem. Soc. Rev., 2024, 53,3976-4019
DOI: 10.1039/D3CS00456B, Review Article

Sisi Wang, Lizhi Gai, Yuncong Chen, Xiaobo Ji, Hua Lu, Zijian Guo
This review focuses on the design strategy, spectroscopic characteristics, and functionalization of mitochondrion-targeted BODIPY dyes, providing an overview of these dyes for mitochondrion-targeted bioimaging and photodynamic therapy.
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Chem. Soc. Rev., 2024, 53,3714-3773
DOI: 10.1039/D3CS00921A, Review Article

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Carlos Redondo-Gómez, Paula Parreira, M. Cristina L. Martins, Helena S. Azevedo
Self-assembled monolayers (SAMs) based on peptides represent a reproducible platform for screening and studying peptide functions and facilitating their translation into multidisciplinary applications.
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Chem. Soc. Rev., 2024, 53,4086-4153
DOI: 10.1039/D3CS00923H, Review Article

Ben Jia, Heyuan Huang, Zhicheng Dong, Xiaoyang Ren, Yanyan Lu, Wenzhi Wang, Shaowen Zhou, Xin Zhao, Baolin Guo
This review critically analyzes degradable biomedical elastomers, focusing on their degradation, synthesis, microstructure, and role in tissue repair. It guides experts in balancing degradation with tissue repair for improved applications.
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Chem. Soc. Rev., 2024, 53,3952-3975
DOI: 10.1039/D3CS01165H, Review Article

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Giacomo Picci, Riccardo Montis, Vito Lippolis, Claudia Caltagirone
Squaramides are a class of extremely versatile receptors for anion recognition, sensing, transport and extraction.
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Chem. Soc. Rev., 2024, 53,4154-4229
DOI: 10.1039/D3CS00819C, Review Article

Junzhe Li, Chao Wang, Rui Wang, Chaofeng Zhang, Guanjie Li, Kenneth Davey, Shilin Zhang, Zaiping Guo
This review critically evaluates recent advances in iron-based electrode materials and applications in alkali metal ion batteries, covering chemical synthesis, structural design, and modification strategies, with insights into future directions.
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Chem. Soc. Rev., 2024, 53,4230-4301
DOI: 10.1039/D3CS00929G, Review Article

Jingqiang Wang, Yan-Fang Zhu, Yu Su, Jun-Xu Guo, Shuangqiang Chen, Hua-Kun Liu, Shi-Xue Dou, Shu-Lei Chou, Yao Xiao
Various optimization strategies are reviewed and summarized to formulate design principles for layered oxide cathodes for sodium-ion batteries.
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Chem. Soc. Rev., 2024, 53,3656-3686
DOI: 10.1039/D3CS00894K, Review Article

Shuang Zhang, Na Kong, Zezheng Wang, Yangheng Zhang, Can Ni, Lingjun Li, Hongbin Wang, Min Yang, Wenrong Yang, Fuhua Yan
This review provides a comprehensive overview of the latest nanochemistry advancements in the design, synthesis, and utilization of engineered gold nanostructures (GNSs) for dental healthcare applications.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00898C, Review Article

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Basanta Kumar Biswal, Bei Zhang, Phuong Thi Minh Tran, Jingjing Zhang, Rajasekhar Balasubramanian
A critical review of the recent developments in the recycling of spent Li-ion batteries using five major technologies (direct recycling, pyrometallurgy, hydrometallurgy, bioleaching and electrometallurgy) and evaluation of their sustainability.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article

Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00662J, Tutorial Review

Paulo Roberto Bueno
The quantum rate concept v = E/h = c_*/L implies relativistic electrodynamics, permitting the transport of electrons in long-range paths of length L and explaining the respiration mechanism if a suitable Boltzmannian statistical setting of E is applied.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05035E, Communication

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Hiroyuki Tsutsumi, An Miura, Asuka Hanada, Rino Sonoda, Rie Nakashima, Tomonori Ohata, Hirohito Ikeda
The selective separation of cis-type gallated and non-gallated catechins in solution was achieved by utilizing the formation of outer-surface adducts between cis-type catechins and cucurbit[7]uril.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04789C, Communication

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Giorgia Toscano, Martina Rosati, Letizia Barbieri, Katharina Maier, Lucia Banci, Enrico Luchinat, Robert Konrat, Roman J. Lichtenecker
Combining multistep organic synthesis with mammalian cell based protein overexpression leads to isolated ¹³C–¹⁹F spin systems in tryptophan side chains, which represent ideal sensors to probe protein interaction and dynamics using NMR spectroscopy.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05361C, Communication

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Xin Qi, Yuanrui Wang, Xiao-Feng Wu
A carbonylative γ-C(sp³)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication

Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450_Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05344C, Communication

Fei Zheng, HongLuan Li, Jun Yang, Haiyan Wang, Guangle Qin, Dapeng Chen, Jingjie Sha
We show that PEG-induced macromolecular crowding enhances protein detection in nanopores by increasing capture rate and translocation frequency.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04037F, Communication

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Kazuki Inoue, Yosuke Nishiwaki, Mieko Kumasaki, Shinya Matsumoto, Ken Okada
Ammonium nitrate/glycine (2 : 1) energetic cocrystal was synthesized to address two drawbacks of ammonium nitrate: phase transitions and hygroscopicity. The cocrystal did not show phase transitions and exhibited decreased hygroscopicity.
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04976D, Communication

kang Wei, Zaitian Cheng, Xingyu Zhang, Qiang Huang, Pingwu Du
The π-extension of carbon nanorings towards ultrashort carbon nanotubes (CNTs) is a great challenge for synthetic chemists. Herein, we report the synthesis, characterization, and properties of a nanographene-embedded carbon nanoring...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication

Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05045B, Communication

Yijie Yang, Guorui Tang, Xiaoyun Liu, Liu Yang, Ruimin Gao, Cheng-Peng Li
The nitrate reduction represents a sustainable strategy for water denitrification. Herein we design ZIF-8 coated porous AuPt alloy composite film for electrocatalytic nitrate reduction with superior ammonia yield of (131.5...
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication

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Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N₂ and CO.
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04594G, Communication

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Masumi Taki, Masayasu Kuwahara, Chaohui Li, Naoko Tomoda, Naoyuki Miyashita, Tetsuo Kan, Jay Yang
A covalent binder for a target protein was obtained by a direct single-round screening of a latent-warhead-modified DNA library via affinity/reactivity-based co-selection of aptameric deoxyribonucleic acid (ARCaDia), followed by a...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04919E, Communication

Shuran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guangjuan Xu, Wei Xie, Na Xu, Yanhong Xu, Yaqian Lan
UiO-66-NH2 with different aggregation morphology are prepared to verify the morphology of photocatalysts could influence the charge transfer. Among them, UiO-66-NH2 with the poor aggregation exhibits superior performances over CO2...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04632C, Communication

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Akanksha Srivastava, Prarabdh Jain, Greeshma Gadikota, Prince Ochonma, Christopher Noe, Tianhe Yin
The aim is to probe the chemical mechanisms underlying the use of multifunctional solvents to simultaneously capture and convert CO2 into insoluble Rare Earth Element (REE)-carbonates, while forming soluble complexes...
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05088F, Communication

Mang Niu, Zongfan Zhu, Zhenkai Mou, Wenpei Kang
Yolk-shelled MoS₂/C@Void@C@MoS₂ exhibits superior high-rate sodium/potassium sodium storage capability, owing to the large inner void and ingenious shell.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05336B, Communication

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Adriana Sacristán-Martín, Nerea Álvarez-Llorente, Eric Masson, Alberto Diez-Varga, Héctor Barbero
The self-sorting process of homobimetallic Pt(II) terpyridyl acetylide dimers secured by a pair of Cucurbit[8]uril macrocycles with recognition motif mismatch can be quantified using a model comprising two coupled harmonic oscillators.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04963B, Communication

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Panward Prasongpholchai, Sam Tucker, Charles Burgess, Robert Jenkins, Ina Wilkening, Christophe Corre, Lijiang Song, Manuela Tosin
Investigations of the workings of a newly identified iterative polyketide synthase from Rhodococcus erythropolis PR4 reveal its ability to synthesise extended polyenes.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05059B, Communication

Sreelakshmi P., Soujanya H. Goudar, Soumyaranjan Behera, Kotagiri Venkata Rao, Ambika S., Narendra Kurra
MXene bonded perylene diimide redox electrode as a robust host for seawater electrolytes.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04488F, Communication

Dmitry A. Tatarinov, Elizaveta V. Sapozhnikova, Daria Khmelevskaia, Yangyang Ju, Dmitriy M. Dolgintsev, Elena V. Bodyago, Alexandr A. Marunchenko, Alexey E. Zhukov, Haizheng Zhong, Ivan G. Scheblykin, Anatoly P. Pushkarev
All-inorganic Cd-alloyed perovskite microdisks were synthesized by pressure-assisted high temperature recrystallization. The microdisks showed composition tunable and temporally stable photoluminescence.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04679J, Communication

Hao Van Bui, Anh Phan Nguyen, Manh Duc Dang, Truong Duc Dinh, Patricia J. Kooyman, J. Ruud Van Ommen
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO₂ nanopowder.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication

Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04651J, Communication

Vetrivelan Murugesan, Anagha Syam, Guru Vigknesh Anantharaj, Ramesh Rasappan
Hydroalkylation of terminal alkynes using unactivated alkanes under dual Co-TBADT catalysts is reported. Our cobalt-HAT catalysis achieves the desired Z alkene with excellent regio- and diastereoselectivity via C–H activation.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication

Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]⁻ acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P₄₄₄₂][1-MHy]-catalyzed reaction of atmospheric pressure CO₂ with MBY under metal- and solvent-free conditions.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight

Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp³)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05125D, Communication

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Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Javier García-Ben, Angel Ferradanes-Martínez, María Gelpi, Julian Walker, Charles James McMonagle, Socorro Castro-García, María Antonia Señarís-Rodríguez, Juan Manuel Bermúdez-García, Manuel Sánchez-Andújar
The hybrid metal halide [(CH₃)₃NOH]₂CoCl₄ exhibits a first-order phase transition at T ∼ 343 K.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05474A, Communication

Seungwon Lee, Byeung Ju Lee, Geunmoo Song, Kyu-Sung Jeong
A series of pyridinium–indolocarbazole oligomers has been synthesized, which fold into helical structures with tubular cavities capable of accommodating up to four iodide ions in a linear arrangement.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05493H, Communication

Yongxian Chen, Simin Jiang, Yang Wang, Fuxue Zhang, Liu Wang, Li Zhao, Siyu Liu, Junjun Tan, Staffan Persson, Bo Sun, Junsheng Chen, Andreas Blennow
Fluorescent starch nanoparticles used in live cell imaging in plants suggest that small-sized starch nanoparticles can efficiently penetrate plant cells, indicating great potential for applications in plant science and agriculture.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication

Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al³⁺ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05161K, Communication

Jessica M. López-Plá, Mohammed Obies, Georgia Zahariou, Michael Pissas, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis
The thermally assisted reaction of Cr(NO₃)₃·9H₂O, 4-Cl-pzH, and Et₃N yielded electrochemically active trinuclear Cr^III–oxo–pyrazolate complexes with formula (Ph₄P)₂[Cr₃(μ₃-O)(μ-4-Cl-pz)₆X₃], X = Cl (1) and Br (2).
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication

Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication

Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication

Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication

Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05486E, Communication

Martin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo Radius
The 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05214E, Communication

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JoLynn B. Giancola, Ronald T. Raines
Precision genetic medicine enlists antisense oligonucleotides (ASOs) to bind to nucleic acid targets important for human disease. Peptide nucleic acids (PNAs) have many desirable attributes as ASOs but lack cellular...
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