s:

Maharashtra Assembly polls: 202 persons cast votes from home in 18 seats in Thane district

Nearly 202 citizens above 85 and with disabilities ‘home voted’ in Thane for Maharashtra Assembly polls, increasing voter turnout




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Maharashtra Assembly polls: Uddhav Thackeray siding with those who insulted Balasaheb and Savarkar, says Amit Shah

After releasing the BJP’s manifesto for the November 20 Maharashtra Assembly polls, Mr Shah also said his party will not allow religion-based reservation in the country.




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Maharashtra Assembly polls: Supriya Sule accuses Mahayuti of corruption, distorting history

The NCP (SP) leader said the BJP and its allies avoided discussions on corruption in this elections as they themselves were engulfed in corruption. Ms. Sule refuted Mahayuti’s claims that the Maha Vikas Aghadi had copied schemes such as Ladki Bahin in its manifesto.




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Sino-Russia Arctic Relations: The View from Singapore

Sino-Russia Arctic Relations: The View from Singapore Sino-Russia Arctic Relations: The View from Singapore

jacksonl




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Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia

Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia Understated and Sometimes Contentious: A Perspective on the US-Australia Alliance in Southeast Asia

jacksonl





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K'taka's economy outpaces national growth despite global headwinds: CM Siddaramaiah�




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Bengaluru rains: Three bodies recovered, 17 feared trapped as under-construction building collapses




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Baku climate talks: India not attending World Leaders Climate Action Summit




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No longer one-sided beneficiary of alliance with US: South Korean National Security Advisor




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Nominated posts filled after screening 30,000 applications: Chandrababu Naidu




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Kerala bypolls: Voting date for Palakkad Assembly seat shifted to Nov 20




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Drones to emerge as a game changer in fisheries: MoS George Kurian




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Thoughts on Streaming Services: 2024 Edition

Streaming services have revolutionized content delivery, sending linear media companies into a panic as they watch traditional cable services decay. “Cutting the cord” is a common practice these days, but the streaming landscape isn’t perfect. We’re a decade into streaming so I wanted to share my thoughts on the state of new media: first impressions, […]

The post Thoughts on Streaming Services: 2024 Edition appeared first on David Walsh Blog.




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PHOTOS: Man City dominate Slovan; Arsenal stun PSG

IMAGES from the Champions League matches played on Tuesday.




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Soccer PICS: Juventus drop points; Musiala tricks

All the action from football matches played in Europe on Wednesday




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India will be one of the biggest intelligence markets: Mukesh Ambani

Reliance would like to build AI infrastructure in the country that would make a similar impact like Jio did for telecom infrastructure, says Mukesh Ambani, speaking at the Nvidia AI summit in Mumbai




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India should manufacture its own AI systems: Nvidia’s Jensen Huang

In an interaction with media in Mumbai, Huang said, “Manufacture your own AI. You should not outsource, you should not export data to import intelligence. Don’t wait to jump into this one 20 years later. Enter this one at Ground Zero.”




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Having a data backup is not enough. You should store it at multiple places: Veeam

This rule involves maintaining three copies of data, stored on two different types of storage media, with one copy located offsite




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The rise of digital arrest scams: What you need to know

Cybercriminals generally initiate contact through phone calls or emails sometimes. One or two audio calls will be followed by a video call from multiple locations – from an ‘airport’, from the police station, or even from a court




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Four semiconductor projects in Gujarat to create 53,000 new jobs: Govt

The statement from the government pointed out that the foundation stone for Micron’s advanced semiconductor ATMP plant was laid in Sanand, marking an investment of over ₹22,500 crore




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This is naked greed, nothing less: Zoho’s Sridhar Vembu on Freshworks layoff

‘This is why choose to remain private. We put our customers and employees first. Shareholders should come last,’ Vembu




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Exploring the self-assembly dynamics of novel steroid–coumarin conjugates: a comprehensive spectroscopic and solid-state investigation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00192C, Paper
Open Access
Claudia M. Ramírez-Lozano, Ma. Eugenia Ochoa, Pablo Labra-Vázquez, Arturo Jiménez-Sánchez, Norberto Farfán, Rosa Santillan
The design, synthesis, and characterization of seven novel steroid–coumarin conjugates with diverse steroidal nuclei as lipophilic fluorescent materials for bioimaging applications are presented.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New 2-pyridone-based donor–acceptor dyes: the effect of the donor group position, type of π-linker and acid–base characteristics of the medium on the photophysical properties

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00177J, Paper
Saveliy P. Sorokin, Mikhail Yu. Ievlev, Oleg V. Ershov
Synthesis of a series of new donor–acceptor dyes based on 2-pyridone and the study of the effect of the position of the donor group, the type of π-linker and the acid–base characteristics of the medium on their photophysical properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical and photochemical reaction of isatins: a decade update

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00202D, Review Article
Nandini M. Gotgi, J. Saurab Jain, Rita Pal, Debashis Ghosh
This review presents all the recent reports on electro- and photochemical reactions of isatins over the last decade.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Recent progress of core-substituted naphthalenediimides: highlights from 2010

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB90045F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sheshanath V. Bhosale, Sidhanath V. Bhosale, Suresh K. Bhargava
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rh(III)-catalysed C-H annulation of cis-stilbene acids with 2-diazo-1,3-diketones: A facile access to 6,7-dihydrobenzofuran-4(5H)-one and α-pyrone scaffolds

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00151F, Paper
Shankaraiah Nagula, Mary Sravani Galla, Nandini B. Kale, Akshay Kumawat, Darshana Bora
An efficient Rh(III)-catalysed C-H functionalization, tandem annulation of cis-stilbene acids using 2-diazo-1,3-diketones was devised. The protocol has solely afforded 6,7-dihydrobenzofuran-4(5H)-ones using alicyclic diazocarbonyls via decarbonylation and α-pyrones with aliphatic diazo...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural flexibility of favipiravir and its structural analogues in solutions: experimental and computational insight

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00404C, Paper
Tatiana P. Gerasimova, Almaz A. Zagidullin, Anastasiia N. Nikolaeva, Robert R. Fayzullin, Aliya M. Saitova, Vasili A. Miluykov, Stefan Grimme, Sergey A. Katsyuba
Keto-enol transformations of 6-R-3-hydroxy-2-pyrazinecarboxamides in solutions are accompanied by deprotonation of enol tautomers and the formation of corresponding anionic species. The key factors determining these processes have been identified.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Covalently linked thieno[2,3-b]thiophene-fullerene dimers: synthesis and physical characterization

Org. Biomol. Chem., 2024, 22,2978-2984
DOI: 10.1039/D4OB00027G, Paper
Abdulrahman M. Alazemi, Mohammad H. BinSabt, Hamad M. Al-Matar, Alan L. Balch, Mona A. Shalaby
Linked thieno[2,3-b]thiophene-fullerene Dimers.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Expanding the scope of the successive ring expansion strategy for macrocycle and medium-sized ring synthesis: unreactive and reactive lactams

Org. Biomol. Chem., 2024, 22,2985-2991
DOI: 10.1039/D4OB00285G, Paper
Open Access
Zhongzhen Yang, Marion Arnoux, Damien Hazelard, Owen R. Hughes, Joe Nabarro, Adrian C. Whitwood, Martin A. Fascione, Christopher D. Spicer, Philippe Compain, William P. Unsworth
New Successive Ring Expansion (SuRE) protocols are described for use on unreactive lactams, as well as iminosugar derived lactams.
The content of this RSS Feed (c) The Royal Society of Chemistry




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BBr3-mediated dearomative spirocyclization of biaryl ynones: facile access to spiro[5.5]dienones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00274A, Communication
Gaurav Jaiswal, Subhas Chandra Pan
BBr3 mediated dearomative spirocyclization of biaryl ynones has been reported for the direct synthesis of spiro[5.5]dienones with a tri-substituted double bond.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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3-Halo-5,6-dihydro-4H-1,2-oxazine N-oxides as synthetic equivalents of unsaturated nitrile oxides in the [3 + 2]-cycloaddition with arynes: synthesis of substituted 3-vinyl-1,2-benzisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00391H, Communication
Alexander A. Lukoyanov, Svetlana A. Aksenova, Andrey A. Tabolin, Alexey Yu. Sukhorukov
3-Halo-1,2-oxazine N-oxide derivatives act as surrogates of vinyl nitrile oxides in tandem [3 + 2]-cycloaddition/[3 + 2]-cyclofragmentation with arynes leading to benzisoxazoles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Revisiting Biginelli-like Reactions: Solvent Effects, Mechanisms, Biological Applications and Correction of Several Literature Reports

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00272E, Paper
Brenno A. D. Neto, Pedro Beck, Arthur Leitão, Yasmin Santana, Jose R. Correa, Carime Vitória da Silva Rodrigues, Daniel Machado, Guilherme Matos, Luciana Machado Ramos, Claudia Cristina Gatto, Carlos Kleber Z. Andrade, Sarah Caldas
This study critically reevaluates reported Biginelli-like reactions using a Kamlet-Abboud-Taft-based solvent effect model. Surprisingly, structural misassignments were discovered in certain multicomponent reactions, leading to the identification of pseudo three-component derivatives...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photoproperties of Favipiravir and their 6-Substituted Analogues: Fluorescence Controlled through Halogen Substitution and Tautomerism

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00397G, Paper
Angel H Romero, Marcos Couto, Ivan E Romero, German Fuentes, Matías N. Möller
Herein, we showed the photophysical properties of the favipiravir and their 6-substituted analogues. Also, we interpreted the origin of the fluorescence of the favipiravir and their 6-substituted analogues as function...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Isothiocyanates: Happy-Go-Lucky Reagents in Organic Synthesis

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00281D, Review Article
Bubul Das, Anjali Dahiya, Bhisma K Patel
: Owing to their unique structural features, isothiocyanates (ITCs) are a class of highly useful and inimitable reagents as the N=C=S group serves both as electrophile and nucleophile in organic...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Base- and sulfur-promoted oxidative lactonization of chalcone-acetate Michael adducts: access to pyran-2-ones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00479E, Communication
Cao Nguyen Nguyen, Duc Toan Nguyen, Ha An Tran, Dinh Hung Mac, Thi Thu Tram Nguyen, Pascal Retailleau, Thanh Binh Nguyen
A cost-effective, practical, straightforward and scalable synthesis of α-pyrones via base- and sulfur-promoted annulation of phenylacetates and chalcones is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00488D, Paper
Meng-Yang Chang, Chin-Huey Ho, Hsing-Yin Chen
The K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Getting Started with CSS Shapes: Wrapping content around custom paths

Using CSS Shapes we can create experiences that we have never been able to create on the web before.




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Redressing flaws: IndiGo needs to tweak its way

How the human element can help the airline appease passengers and employees




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Google to develop AI that takes over computers: Report

Google is developing AI technology that takes over a web browser to complete tasks such as research and shopping, The Information reported




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Dietary restriction or good genes: new study tries to unpack which has greater impact on lifespan

If we know that genetics and lifestyle affect how long you live, which one is more important? And how do they interact?




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Bridging the gap in mental healthcare services: NGOs launch dementia clinics in Hyderabad’s slums

India continues to grapple with a dearth of mental healthcare services, even as the number of persons with dementia is expected to rise over the next two decades




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Following WHO guidelines for sodium content in packaged food could prevent 3 lakh deaths in India in 10 years: study

Additionally, about 1.7 million new cardiovascular disease cases and 7,00,000 new chronic kidney disease cases could be prevented compared to current practices, the study said




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Tiruchi man with mpox symptoms: Sample has returned negative, says Tamil Nadu Health Minister

The man, who had returned from Sharjah on October 31, was found to have fever during screening on arriving at the Tiruchi airport.




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Understanding orphan drugs: what are they, how are they classified and what are their challenges in the Indian context

While orphan drugs are crucial to treating rare, sometimes debilitating conditions, the high cost of their research and development is a major barrier to their development in India




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60fps scrolling using pointer-events: none

Paul Lewis did an interesting article a while back about avoiding unnecessary paints through disabling hover effects as the user scrolls, which is a great approach. The down side being managing all your hover states through a parent class. UPDATE: I’ve done a follow up article which demonstrates a more robust technique. .hover .element:hover { … Continue reading "60fps scrolling using pointer-events: none"




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Review unlocking power of people analytics: Vibhu Verma's vision for data-driven workforce

People analytics focuses on leveraging employee data to identify patterns, assess performance, and understand the factors driving engagement and retention.




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Role of soft skills in industrial and product design career success: Preparing next generation of designers

Kushal Karwa, a thought leader in design education, emphasizes the need for integrating soft skills training into career preparation programs to help young designers thrive in real-world environments.




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Empowering Pharma with AI, Analytics: Accelerating Drug Discovery, Optimizing Healthcare Outcomes By Rajesh Munirathnam

While AI is making significant strides in healthcare, it is also transforming other industries, such as insurance.




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Shaping the Future of Web Apps: Full Stack Developer's Expertise in API Design and Cloud Deployment

Naga Lalitha has become visible as someone who is changing the face of technology for industry verticals like supply chain and manufacturing.