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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Ultrasensitive DNA Electrochemical Biosensor Based on MnTBAP Biomimetic Catalyzed AGET ATRP Signal Amplification Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication
Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Surfactant-free synthesis of ultralong silver nanowires for endurable transparent conducting electrodes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01915A, Communication
Sian-Hong Tseng, Lian-Ming Lyu, Kai-Yuan Hsiao, Wan-Hua Ho, Ming-Yen Lu
The present study employed the surfactant-free growth of ultralong (~50 μm) silver nanowires (AgNWs) with high aspect ratio (up to 500) by galvanic replacement. AgNW conducting film were fabricated as...
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Bimolecular Vinylation of Arenes by Vinyl Cations

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication
ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF3)3)4] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Host-guest interaction based supramolecular photodynamic therapy system: a promising candidate in the battle against cancer

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02001J, Feature Article
Kui Yang, Zhihua Zhang, Jie Du, Wei Li, Zhichao Pei
Owing to its spatiotemporal selectivity and noninvasive nature, photodynamic therapy (PDT) has become a promising approach for the treatment of cancer. However, the non-targeting capability and the accompanying side effects...
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Fluorescent Molecular Logic Gates based on Photoinduced Electron Transfer (PET) Driven by a Combination of Atomic and Biomolecular Inputs

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication
Open Access
Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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A DNA logic gate with dual-anchored proximity aptamers for accurate identification of circulating tumor cells

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication
Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Intra-mitochondrial self-assembly to overcome the intracellular enzymatic degradation of L-peptides

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication
M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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An ultrasensitive electrochemical biosensor for Pseudomonas aeruginosa assay based on a rolling circle amplification-assisted multipedal DNA walker

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication
Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Smart azobenzene-containing tubular polymersomes: fabrication and multiple morphological tuning

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication
Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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3D spongy nanofiber structure Fe–NC catalysts built by a graphene regulated electrospinning method

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication
Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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A radical-mediated 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite: facile access to sulfonyl isoxazoles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication
Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Enzyme-mimicking accelerated signal enhancement for visually multiplexed quantitation of telomerase activity

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01951H, Communication
Lu Sun, Qiao Zhao, Xinli Liu, Yongchun Pan, Yanfeng Gao, Jingjing Yang, Yuzhen Wang, Yujun Song
Here, we propose an amplification strategy of enzyme-mimicking accelerated signal enhancement integrated with triple-channel volumetric bar-chart chip for visually multiplexed quantitation of telomerase activity. This platform was used for evaluating...
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Highly dispersed nickel anchored on N-doped carbon molecular sieve derived from metal-organic frameworks for efficient hydrodeoxygenation in aqueous-phase

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication
Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication
Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Nitrosoarene-catalyzed regioselective aromatic C–H sulfinylation with thiols under aerobic conditions

Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication
Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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1,6-Conjugate addition initiated formal [4+2] annulation of p-quinone methides with sulfonyl allenols: a unique access to spiro[5.5]undeca-1,4-dien-3-one scaffolds

Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication
Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling

Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication
Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Live cell fluorescent stain of bacterial curli and biofilm through supramolecular recognition between bromophenol blue and CsgA

Chem. Commun., 2020, 56,5014-5017
DOI: 10.1039/D0CC01643H, Communication
Lixia Zhang, Zhenhua Li, Zhijun Chen
A curli fluorescent light-up probe called bromophenol blue, which binds to curli via recognizing CsgA.
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Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction

Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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A multipedal DNA walker for amplified detection of tumor exosomes

Chem. Commun., 2020, 56,4982-4985
DOI: 10.1039/D0CC01817A, Communication
Peng Miao, Yuguo Tang
A novel electrochemical biosensor for exosomes is proposed based on a multipedal DNA walking strategy. A limit of detection down to 6/μL is obtained with excellent selectivity.
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Halogen bonding for molecular recognition: new developments in materials and biological sciences

Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight
Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Facile construction of double network cross-linked luminescent supramolecular elastomer from hydrosilylation and pillar[5]arene host–guest recognition

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication
Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Photo-regulated supramolecular star with a pillar[6]arene-coated metal-organic polyhedron (MOP) core

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication
Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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A combined viscosity-restricted intramolecular motion and mitochondrial targeting leads to selective tumor visualization

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02943B, Communication
Le Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung Kim
We report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...
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Efficient generation of sulfate radicals in Fe (II)/S (IV) system induced by WS2 nanosheets and examined by its intrinsic chemiluminescence

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01999B, Communication
Tong Sun, Yingying Su, Houjing Liu, Hongjie Song, Yi Lv
In this study, more 〖SO〗_4^( ∙-) and strong intrinsic chemiluminescence (CL) can be achieved through activating sulphite (〖SO〗_3^( 2-)) with ferrous ions (Fe2+) on the WS2 nanosheets with the thickness...
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Rh(III)-catalyzed sequential ortho- C–H oxidative arylation/cyclization of sulfoxonium ylides with quinones toward 2-hydroxy-dibenzo[b,d]pyran-6-ones

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication
Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
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Electrospray Ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01906B, Communication
Amina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezec
Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...
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Engineering of Decameric D-fructose-6-phosphate Aldolase A by Combinatorial Modulation of Inter- and Intra-subunit Interactions

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02437F, Communication
Xiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei Yu
Combinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...
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Integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02329A, Communication
Lijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun Cai
We report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...
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Single molecule magnet behaviour in a square planar S = 1/2 Co(II) complex and spin-state assignment of multiple relaxation modes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01854F, Communication
Indrani Bhowmick, David Washburn Shaffer, Jenny Y Yang, Matthew Shores
We report the first example of field-induced single molecule magnet (SMM) behaviour in a square-planar S = ½ Co(II) pincer complex [(PNNNP)CoBr]Br (2). The related five-coordinate complexes [(PCNCP)CoBr2] (1) and...
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Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02506B, Communication
Takehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINO
Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.
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Bulk and Surface Structural Changes in High Nickel Cathodes Subjected to Fast Charging Conditions

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02579H, Communication
Zhijia Du, Tianyi Liu, Xianyang Wu, Muhammad Mominur Rahman, Dennis Nordlund, Kejie Zhao, Michael D Schulz, Feng Lin, David L. Wood III, Ilias Belharouak
Fast charging of Li-ion batteries emerges as a requirement for the widespread of electric vehicles (EVs). The challenge is that the active materials inside the cells may undergo significant interfacial...
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Scalability rules : 50 principles for scaling Web sites / Martin L. Abbott, Michael T. Fisher

Abbott, Martin L




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The enigma of web interfaces : cultural aspects of web site design / by Linda Lim Mei Luan

Lim, Linda Mei Luan




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Multimedia security : watermarking, steganography, and forensics / edited by Frank Y. Shih




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Researching virtual worlds : methodologies for studying emergent practices / edited by Ursula Plesner and Louise Phillips




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Application of graphic processing unit in process modelling and simulation tools / Arash Dadrieh

Sadrieh, Arash




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The culture of design / Guy Julier

Julier, Guy, author




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Burn your portfolio : stuff they don't teach you in design school, but should / Michael Janda

Janda, Michael, author




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Lemon poppy seed : multitasking creativity / [edited by Robert Klanten, Hendrik Hellige, Adeline Mollard]




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Minimalist graphics / Julia Schonlau

Schonlau, Julia




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Women in graphic design 1890-2012 = Frauen und Grafik-Design [1890-2012] / edited by/herausgegeben von Gerda Breuer, Julia Meer ; [übersetzung/translation, Barbara Fitton Hauss, Julia Taylor Thorson]




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The principles of beautiful web design / by Jason Beaird & James George

Beaird, Jason, author




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Adobe Photoshop CC : 2014 release / Andrew Faulkner & Brie Gyncild

Faulkner, Andrew, author




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Illustration now!. 5 / edited by Julius Wiedemann




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Dynamic identities : how to create a living brand / by Irene van Nes ; texts, Paul Hughes, Ghislaine van Drunen & Irene van Nes

Nes, Irene van, author




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Beautiful users : designing for people / Ellen Lupton with contributions by Thomas Carpentier and Tiffany Lambert

Lupton, Ellen, author




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Algorithmic life : calculative devices in the age of big data / edited by Louise Amoore and Volha Piotukh




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Big data analytics with Spark : a practitioner's guide to using Spark for large-scale data processing, machine learning, and graph analytics, and high-velocity data stream processing / Mohammed Guller

Guller, Mohammed, author