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Saharanpur clash: End politics of hatred, says Rahul; Congress slams BJP



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Signs of thaw: Amar Singh to share stage with Mulayam today



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Express investigation part-I: Over 600 ‘communal incidents’ in UP since LS results, 60% near bypoll seats



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Four years after he was sacked from SP, Amar Singh shares stage with Mulayam Singh Yadav



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Ramgopal Yadav rules out Amar Singh’s return to SP



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BJP playing ‘dangerous games’, says Mulayam



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Nitish dismisses speculation about Manjhi’s removal



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Shailesh’s family does not suspect any foul play in his death



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Dawood Ibrahim not in Pak, says Abdul Basit country’s High Commissioner to India



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Girls outshine boys as UP Board 2015 results come out



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Dress code for UP Imambaras: ‘Head covered, no short dresses’ while framing rules for tourists



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‘Nothing wrong’ in Mulayam scolding IPS officer: Akhilesh Yadav



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SP supremo Mulayam Singh takes party office bearers to task



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Shiksha Mitras’ regularisation illegal: UP govt to move SC against Allahabad High Court order



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Akhilesh meets Ghulam Ali, says art and artists should not be linked to politics



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Characterization of aerosolized particles from nanoclay-enabled composites during manipulation processes

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01211G, Paper
Eun Gyung Lee, Lorenzo Cena, Jiwoon Kwon, Ali Afshari, HaeDong Park, Gary Casuccio, Kristin Bunker, Traci Lersch, Ashley Gall, Huy Pham, Alixandra Wagner, Sushant Agarwal, Cerasela Zoica Dinu, Rakesh Gupta, Sherri A. Friend, Todd A. Stueckle
Manufacturing, processing, use, and disposal of nanoclay-enabled composites potentially lead to the release of nanoclay particles from the polymer matrix in which they are embedded; however, exposures to airborne particles are poorly understood.
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Rapid organic solvent extraction coupled with surface enhanced Raman spectroscopic mapping for ultrasensitive quantification of foliarly applied silver nanoparticles in plant leaves

Environ. Sci.: Nano, 2020, 7,1061-1067
DOI: 10.1039/C9EN01246J, Communication
Zhiyun Zhang, Ming Xia, Chuanxin Ma, Huiyuan Guo, Wenhao Wu, Jason C. White, Baoshan Xing, Lili He
An organic solvent-based extraction approach coupled with surface enhanced Raman spectroscopic mapping technique to quantify silver nanoparticles in spinach leaf.
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The adsorption and oxidation of SO2 on MgO surface: experimental and DFT calculation studies

Environ. Sci.: Nano, 2020, 7,1092-1101
DOI: 10.1039/C9EN01474H, Paper
Honghong Wang, Cheng Zhong, Qingxin Ma, Jinzhu Ma, Hong He
The reaction mechanisms and synergistic effects of NO2/O2 on the heterogeneous oxidation of SO2 to sulfate on a MgO surface.
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Mass cytometric study on the heterogeneity in cellular association and cytotoxicity of silver nanoparticles in primary human immune cells

Environ. Sci.: Nano, 2020, 7,1102-1114
DOI: 10.1039/C9EN01104H, Paper
My Kieu Ha, Jang-Sik Choi, Sook Jin Kwon, Jaewoo Song, Yangsoon Lee, Young-Eun Kim, Tae Hyun Yoon
Between-population and within-population heterogeneity in the uptake and toxicity of silver nanoparticles in primary human immune cells revealed by mass cytometry.
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Trophic transfer and biomagnification of fullerenol nanoparticles in an aquatic food chain

Environ. Sci.: Nano, 2020, 7,1240-1251
DOI: 10.1039/C9EN01277J, Paper
Qiuyue Shi, Cheng Long Wang, Han Zhang, Chunying Chen, Xian Zhang, Xue-Ling Chang
Understanding the trophic transfer and biomagnification potential of nanomaterials in aquatic food chains is crucial for assessing the environmental risks of such materials.
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Immobilization of mercury by nano-elemental selenium and the underlying mechanisms in hydroponic-cultured garlic plant

Environ. Sci.: Nano, 2020, 7,1115-1125
DOI: 10.1039/C9EN01294J, Paper
Jiating Zhao, Xujun Liang, Nali Zhu, Liming Wang, Yunyun Li, Yu-Feng Li, Lirong Zheng, Zhiyong Zhang, Yuxi Gao, Zhifang Chai
Naturally and anthropogenic selenium nanoparticles highly work on mercury immobilization and inactivation in aquatic-plant systems.
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Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments enhances DNA damage and stress gene expression in freshwater Asian clam Corbicula fluminea

Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper
Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Exposure medium and particle ageing moderate the toxicological effects of nanomaterials to Daphnia magna over multiple generations: a case for standard test review?

Environ. Sci.: Nano, 2020, 7,1136-1149
DOI: 10.1039/D0EN00049C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laura-Jayne A. Ellis, Eugenia Valsami-Jones, Iseult Lynch
Pristine engineered nanomaterials (NMs) entering the aquatic environment become ‘aged’ during their lifetime via chemical, physical and/or biological process.
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Effect of NOM on copper sulfide nanoparticle growth, stability, and oxidative dissolution

Environ. Sci.: Nano, 2020, 7,1163-1178
DOI: 10.1039/C9EN01448A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin Hoffmann, Sylvain Bouchet, Iso Christl, Ralf Kaegi, Ruben Kretzschmar
Natural organic matter (NOM) impedes the growth of colloidally stable CuxS nanoparticles and slows down their morphological development, but also drives their oxidative dissolution.
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Retraction: Mutual effect of Cs(I) and Sr(II) sorption on nano-talc investigated by EXAFS, modeling and theoretical calculations

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90021D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Wencheng Song, Yang Liu, Tasawar Hayat, Ahmed Alsaedi, Yuejie Ai, Virender K. Sharma, Xiangke Wang
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Retraction: Influence of aqueous sulfide on speciation of U(VI) adsorbed to nanomagnetite

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90018D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Jianhui Lan, Mengxue Li, Wei Hu, Haibo Liu, Gang Song, Diyun Chen, Weiqun Shi, Xiangke Wang
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Retraction: Mutual effect of U(VI) and Sr(II) on graphene oxides: evidence from EXAFS and theoretical calculations

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90022B, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wencai Cheng, Congcong Ding, Qunyan Wu, Xiangxue Wang, Yubing Sun, Weiqun Shi, Tasawar Hayat, Ahmed Alsaedi, Zhifang Chai, Xiangke Wang
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Peroxymonosulfate (PMS) activation on cobalt-doped TiO2 nanotubes: degradation of organics under dark and solar light irradiation conditions

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00131G, Paper
Jonghun Lim, Michael R. Hoffmann
The Co-TNT/PMS system enables the continuous degradation of organic pollutants under dark and solar light-irradiation conditions.
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Hazard of novel anti-fouling nanomaterials and biocides DCOIT and silver to marine organisms

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00023J, Paper
Joana Figueiredo, Susana Loureiro, Roberto Martins
Biocides encapsulation appears to be a promising solution to develop a new generation of efficient anti-fouling additives (e.g. SiNC–DCOIT; SiNC–DCOIT–Ag) for maritime coatings with lower environmental hazard than the current state-of-the-art biocides (e.g. DCOIT).
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Formation of Fe(III)–As(V) complexes: effect on the solubility of ferric hydroxide precipitates and molecular structural identification

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00024H, Paper
Qiantao Shi, George E. Sterbinsky, Shujuan Zhang, Christos Christodoulatos, George P. Korfiatis, Xiaoguang Meng
Soluble Fe(III)–As(V) complexes were found at both acidic and neutral conditions, which significantly change the solubility of ferric oxides.
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Nanoparticulate zero valent iron interaction with dissolved organic matter impacts iron transformation and organic carbon stability

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper
Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
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Multivariate analysis of the exposure and hazard of ceria nanomaterials in indoor aquatic mesocosms

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper
Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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Sulfidation attenuates the adverse impacts of metallic nanoparticles on anammox from the perspective of chronic exposure

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper
Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Environmental fate of sulfidated nZVI particles: the interplay of nanoparticle corrosion and toxicity during aging

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper
Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Fragmentation of polymer nanocomposites: modulation by dry and wet weathering, fractionation, and nanomaterial filler

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper
Open Access
Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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Chalcone single crystals with red emission and photodimerization-triggered hopping behavior: the substituent effect and molecular packing effect

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00404A, Communication
Xinrui He, Jian Zhao, Zeqing Tan, Jiaxin Zhao, Xiao Cheng, Chuanjian Zhou
Chalcone single crystals with distinctively different emission color and photoinduced mechanical response are designed and fabricated via fine-tuning the donor substituents.
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Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
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Realization of rocksalt Zn1−xCdxO thin films with an optical band gap above 3.0 eV by molecular beam epitaxy

CrystEngComm, 2020, 22,2781-2787
DOI: 10.1039/C9CE02018G, Paper
Hyo Chang Jang, Katsuhiko Saito, Qixin Guo, Kin Man Yu, Wladek Walukiewicz, Tooru Tanaka
We have grown Zn1−xCdxO (ZnCdO) thin films by molecular beam epitaxy on α-Al2O3 (0001) substrates across the full composition range of 0 ≤ x ≤ 1. A large optical gap of 3.0 eV is obtained in rocksalt-ZnCdO with a low resistivity and high mobility.
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Different effects in the selective detection of aniline and Fe3+ by lanthanide-based coordination polymers containing multiple reactive sites

CrystEngComm, 2020, 22,2837-2844
DOI: 10.1039/D0CE00238K, Paper
Xinfang Liu, Liyong Du, Rongfang Li, Ningning Ma, Mengdi You, Xun Feng
Isostructural Ln-CPs (1-Eu and 2-Tb) show almost the same high detection ability for Fe3+ and different detection abilities for aniline. The detection difference was studied through PXRD, UV-vis, luminescence lifetimes and Hirshfeld surface analysis.
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Machine learning methods to predict the crystallization propensity of small organic molecules

CrystEngComm, 2020, 22,2817-2826
DOI: 10.1039/D0CE00070A, Paper
Florbela Pereira
Machine learning algorithms were explored for the prediction of the crystallization propensity based on molecular descriptors and fingerprints generated from 2D chemical structures and 3D chemical structures optimized with empirical methods.
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Discovery of new polymorphs of the tuberculosis drug isoniazid

CrystEngComm, 2020, 22,2705-2708
DOI: 10.1039/D0CE00440E, Communication
Keke Zhang, Noalle Fellah, Alexander G. Shtukenberg, Xiaoyan Fu, Chunhua Hu, Michael D. Ward
Two new metastable polymorphs of the tuberculosis drug isoniazid, considered monomorphic for sixty years, were discovered using melt crystallization and nanoscale confinement.
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Agglomeration enhancement of AlN surface diffusion fluxes on a (0 0 0 1)-sapphire substrate grown by pulsed atomic-layer epitaxy techniques via MOCVD

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00113A, Paper
Mohd Nazri Abd Rahman, Yusnizam Yusuf, Afiq Anuar, Mohamad Raqif Mahat, Narong Chanlek, Noor Azrina Talik, Muhammad I. M. Abdul Khudus, Norzaini Zainal, Wan Haliza Abd Majid, Ahmad Shuhaimi
An atomically flat covering with a dense and crack-free surface of aluminium nitride films was successfully deposited on a sapphire-(0 0 0 1) substrate through a pulsed atomic-layer epitaxy technique via horizontal metalorganic chemical vapour deposition.
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Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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Role of Surface Phenomena on the Reaction of Molecular Solids: the Diels-Alder Reaction on Pentacene

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00269K, Paper
Selma Piranej, Michael A. W. Shelhart Sayers, Gregory J. Deye, Sergey N. Maximoff, Jonathan P. Hopwood, Haejun Park, Jean G. Slavsky, Jacob Ciszek
Reactivity trends for molecular solids cannot be explained exclusively through topochemical phenomenon (i.e. diffusivity, reaction cavities) or electronic structure of the molecules. As an example of this class, Diels-Alder reactions...
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Correction: Two-dimensional porous nickel oxalate thin sheets constructed by ultrathin nanosheets as electrode materials for high-performance aqueous supercapacitors

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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A digital workflow from crystallographic structure to single crystal particle attributes for predicting the formulation properties of terbutaline sulfate

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00026D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thai T. H. Nguyen, Robert B. Hammond, Ioanna D. Styliari, Darragh Murnane, Kevin J. Roberts
A detailed inter-molecular (synthonic) analysis of terbutaline sulfate, an ionic addition salt for inhalation drug formulation, is related to its crystal morphology, the surface chemistry of the habit faces and hence to its crystal surface energy.
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Polymorph induced diversity of photomechanical motions of molecular crystals

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00311E, Paper
Lei Gao, Yunhui Hao, Xiunan Zhang, Xin Huang, Ting Wang, Hongxun Hao
Photomechanical motions of the polymorphs of trans-4,4'-azopyridine are distinct under the influence of different molecular packing and intermolecular interactions.
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Cocrystals/salt of 1-naphthaleneacetic acid and utilizing Hirshfeld surface calculations for acid–aminopyrimidine synthons

CrystEngComm, 2020, 22,2978-2989
DOI: 10.1039/D0CE00106F, Paper
Utsav Garg, Yasser Azim, Aranya Kar, Chullikkattil P. Pradeep
Revisit of acid–aminopyrimidine synthons to explore the robustness in presence of linear hetrotetramer and heterotrimer synthon.
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Two-dimensional porous nickel oxalate thin sheets constructed by ultrathin nanosheets as electrode materials for high-performance aqueous supercapacitors

CrystEngComm, 2020, 22,2953-2963
DOI: 10.1039/D0CE00268B, Paper
Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
2D porous nickel oxalate thin sheets constructed by ultrathin nanosheets were first synthesized by using a simple hydrothermal method. The resulting porous thin sheets exhibited superior supercapacitor performance.
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Step-by-step: uncommon SCSC transformation accompanied by stepwise change in the binding of a particular ligand within a mononuclear complex upon stepwise desolvation

CrystEngComm, 2020, 22,2895-2899
DOI: 10.1039/D0CE00379D, Communication
Andrey V. Gavrikov, Andrey B. Ilyukhin, Pavel S. Koroteev
Uncommon SCSC transformation when desolvation induces subtle changes within a mononuclear complex, namely a stepwise change in the binding of a particular ligand.
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