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[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




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[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




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[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00021




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] C5 Metalation of Imidazole-Based Monothiolates en Route to Selenothiolates

Organometallics
DOI: 10.1021/acs.organomet.0c00201




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[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

Organometallics
DOI: 10.1021/acs.organomet.0c00102




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[ASAP] Catalytic Dimerization of Alkynes via C–H Bond Cleavage by a Platinum–Silylene Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00195




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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No word in Rail Budget on track conversion in Tripura:Minister

have sought clarification on plans of converting the meter gauge railway lines into broad gauge:Transport minister Manik Dey




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The Difficult First Episode

In our very first episode we discuss the difficulty of writing your own online biography, the pros and cons of co-working, the move towards flat file site generation, the upcoming New Adventures in Web Design conference, the shiny new Rode iXY microphone and end with bespoke fixed gear bikes.




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All Things Startup

Skype wasn’t kind to us this week so sincere apologies for the sound quality. We are instigating new audio fiedlity procedure moving forward! This week we discuss Teux Deux moving to a payment model, the demise of Google Reader, startup media icons and Kieran manages to top all previous “and finally” items.




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Online Collaboration

But for pesky technical gremlins, this would certainly be our best episode yet. Apologies in advance for the background noise. Pre-recording testing was good, however it appears that an intermittent issue with a USB connector has caused us a few problems that can’t be edited out. Now we know we’ll do better next time.

Moving on this week’s show focuses on online document collaboration, discusses GMail’s 9th birthday, a new JS gem from Dave Rupert and much more.




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Celebrities on KickStarter

This weeks show is kindly supported by Insites: ConfShop — A unique one day event for web workers focused on openness, sharing and learning taking place in London on Friday July 5th. Tickets are limited to 100 and are available for £125.

In this episode we tell you about our new “studio”, discuss the route to inner nirvana (no really), the “problem” of celebrities on KickStarter and ask whether Ghost is the future of blogging as we know it.

Thanks again to Insites: ConfShop for supporting this weeks episode.




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New Flickr, New Digg!

We are back behind the Yeti’s to discuss Keir’s trip to Beyond Tellerrand, the new Flickr subscription model, Digg Reader, Prism and our recent Mac email client woes. We round out the show with quite possibly the best use of technology we have come across – intrigued? You should be!




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The Problem of Overfunding on KickStarter

As the web appears to have gone on holiday we present a mixed bag of goodness on Episode 010. We lament the loss of one of our zero’s, Kieran brings forth the news and the funny and we engage in a almost academic level of discourse on the issues associated with overfunding on crowdfunding platforms. Also included – a bit of Startup talk, a new Mac code editor, the new Royal baby and our first ever competition.

Lunchbox Competition

To enter the Back to Front Show lunchbox giveaway simply tweet the answer to the following question before Friday 2nd August 2013. All correct answers will be entered into the draw. If nobody guesses correctly the closest response will win.

Question: What is the height difference in inches between Kieran and Keir?




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How Not to Run a Competition

In the 11th instalment of our artisanal hand-crafted high-fidelity podcast we prove that despite being able to bring up a LAMP stack in under 12 minutes we are utterly incapable of running a competition. Listen in and find out who the two, yes two, winners of Keir’s lunchbox are! We also discuss Keir’s (and Elliot’s) latest publication called Digest, chat about a new design trend, shine a light on a new screencasting service and ask if online comments are dead.




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Six Choice Cuts

Episode #013 is brought to you in association with Squarespace, the all-in-one platform that makes it fast and easy to create your own professional website or online portfolio. For a free trial and 10% off, go to squarespace.com and use offer code Backtofront8.

This week there’s a change to our format as we strive to go weekly. In our new “8bit-minified-compressed” format we discuss six choice cuts found around the web including Google and Uber, Local Tunnel and the trend of coffee cups in web marketing.

Thanks again to Squarespace for supporting the show




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Proving your App

Episode #015 is brought to you in partnership with Squarespace, the all-in-one platform that makes it fast and easy to create your own professional website or online portfolio. For a free trial and a massive 20% off (valid for September 2013), go to squarespace.com and use offer code Backtofront9.

In this week’s micro edition we look at six great articles including a Medium post on proving your app idea with existing technology, the art of great support, Grunt, advances in wi-fi technology, Kieran’s latest bling accessory and a great post by our Texan friend Mr. Trent walton.




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Mixed Bag

Episode #016 sees us discussing the recent Generate Conference in London, Shopify’s amazing Build a Business annual contest, faces for apps, Happy Cog giving us insights into their workflow and a couple of revisits including Editorially and Draft.




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Frost on Speaking

This weeks episode is kindly supported by Squarespace, the all-in-one platform that makes it fast and easy to create your own professional website or online portfolio. For a free trial and a massive 10% off, go to squarespace.com and use offer code Backtofront10.

In this episode we discuss Google’s foray into the IDE land, Brad Frost’s great post on speaking, Ace Hotel’s unique approach to web marketing and finish with the first use of the word p**n on the show. Rest assured it’s 100% SFW.




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Annual Awards Special

It’s the end of year Back to Front Show awards special. An opinonated, and occasionally tongue in cheek, look back over the last year in which we celebrate the events, the trends, the people, the apps, the podcasts, the magazines and the books that have made 2013 a great year. We also have details of our first ever guest co-host who will be joining Keir in December!

Award Categories

Winners will be linked up in a few weeks time *

  • Conference/event of the year
  • Side project of the year
  • Podcast of the year
  • Magazine of the year
  • Book of the year
  • “Blogger who you wished blogged more” of the year
  • Hipster Web Site of the year (AKA the moustache wax award for web ingenuity)
  • Dog related tech product of the year
  • Team of the year
  • Man of the year
  • Woman of the year
  • Trend of the year
  • “And finally…” of the year

* We really want you to listen to find out!




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The One with Marc

In our first episode of 2014 I am joined by new guest co-host Marc Roberts of Neutron Creations. After a lengthy chat about his rather special coat we moved onto more web related links and finished up with a discussion on node.js. Big thanks for Marc for taking the time to come on the show.




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Transitioning

Just when you thought you could delete us from your podcatcher we are back and with a distinct lack of excuses for our absence. This week we discuss our new weekly formats and chat extensively about “transitioning”.

Over the last few months both of us have found our main focuses shifting and as a result the way we present ourselves online has changed, or had to change, too. We revisit our discussion on “flowery Twitter bios” and look at ways in which our friends, colleagues and heroes represent themselves online – through the blog posts they write, links they curate and share and other output including podcasts and videos. We touch on expectations, schedules and much more in our first episode back behind the Yeti’s.

We’d love to hear about your experiences of transitioning. Get in touch on Twitter and Facebook.




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Domains

Behind every great idea lies a great domain, or is it the other way round? This week we discuss the domains we keep renewing in the hope of one day using, the original ideas behind them and whether or not they will ever see the light of day.

If you like our show please feel free to leave us a review on iTunes.




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So Entitled?

As we reach the ripe old age of 30 we sit back and chat about a topic we often come back to over an artisinal flat white – why do people think everything on the web “should” be free? We discuss some possible causes, the backlash against app developers charging for previously free tools and ponder if the rise of big VC has played it’s part too.

Oh and yes there’s yet more microphone drama. All will be explained next week. As always we do apologise for the disruption to the service.

If you like our show please feel free to leave us a review on iTunes.




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Live with a Flat White

This week Kieran joins us live via a pair of Apple headphones from Coffee #1. Complete with baristas creating flat whites and the chitter chatter of remote workers typing away we throw audio fidelity to the wind and freestyle over a few links from Keir’s web site.





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Back behind the Yeti&#8217;s

Back from our travels we retrun behind the Yeti’s to discuss everything from the hunt for the perfect email app to the sartorial elegance of modern tech CEO’s. This episode also features a rather spledid retreat venue only four hours from Spokane.




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That VAT Thing

This week Keir tries to speak “Somerset” and no surprises for guessing the outcome of that one. Once that’s done and dusted we take a look at the rise in Markdown based writing apps, examine a new ebook service from Liberio, try and fail to work out the implications of the new EU VAT place of supply rule for digital services and finally round it out with a chat about at a new comms tool.




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The Joys &#038; Perils of Remote Working

In a change to the announced billing, an impromptu early morning phone call made us think a chat about remote working might be in order. As many of us fight the January blues, and inevitable bout of illness that the new year often brings, it felt a timely opportunity to discuss the good, and the bad, aspects of working from a distance.

Topics we discuss include:

  • How does working remotely affect us?
  • What we both like and dislike about it
  • How much real work you achieve per day
  • The importance of “banter”
  • Is the reality like the dream?
  • A typical day for remote working?
  • Do we put extra pressure on ourselves to output more as we are not in the office?
  • How to feel part of the company you work for

And finally for those Nabaztag doubters out there you can read the full history of the internet enabled rabbit on Wikipedia!

Five Simple Steps Giveaway

To be in with a chance of winning one of the two sets of Five Simple Step’s Pocket Guide Collection 3 all you have to do it answer one of the following two questions correctly. Kieran’s decision will be final (he’s a harsh judge):

  1. Q: What was Matthew Lillard’s handle in the cult-classic 1995 film Hackers?
  2. Q: In the same year Sandra Bullock played a Systems Analyst in the film The Net. During the course of the film her identity is changed by cyber criminals but what is the name they gave her?

To enter just send a tweet to @backtofrontshow with your answer. We’ll announce winners on the next episode.




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Moving Away from the Code Face

Like a phoenix from the flames, we have risen. Our year long retreat for slightly overweight tech men from the South West of England is officially over. We’ve eaten the kale, cleansed ourselves, got the glow and are now itching to get back behind the mics. It’s out with the Yeti’s and in with a spanking new steed for Kieran and a less than great “Madonna” mic for Keir.

In this week’s episode, we discuss where on earth we’ve been for the last 13 months, chat about how we’ve moved away from the code face and share experiences of a life away from daily development.

Finally, we announce the winner of the longest competition in Back to Front Show history!

It’s good to be back.




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The Big 40!

Three years ago we started this little adventure called The Back to Front Show. Since then we’ve somehow managed to record 39 shows. Not the best of averages but who’s counting?

In our milestone 40th show, we discuss the cake that never happened, Keir’s favourite new TV show, standing desks and end with a discussion that starts with Sarah Parmenter’s recent blog post and ends with thoughts on specialisation.

You may also be pleased to hear that our “and finally” section returns this week and features a great satire on our industry.




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The Gavin Ballard Special

This episode is dedicated to our favourite Australian Gavin Ballard — all round good guy, world traveller, bon viveur and last but by no means least Shopify Expert. Gavin is a long time listener (we still aren’t sure why) and friend of the show. If we had a pin badge and sticker “care package” he’d be the first recipient!

Topics covered in this mega-length show include the weather in the South West, Skype video, our favourite NYC diners, the use of technology in the bathroom, career paths for developers, and more.

If you would like a show dedicated to you please let us know via the comment link below and we’ll undoubtedly make it happen.




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Lost with Lindberg

This week we celebrate the internet’s very own Oliver Lindberg as we get #lostwithlindberg. Given our distinct lack of direction for this episode, it seemed only right and proper that our favourite editor of the internet takes this week’s naming rights. If you are ever lost, and if you can find him, maybe you can also get “lost with Lindberg”. Cue the music.

We might not be a crack commando unit but we did our best to highlight a few choice topics from the internet underground. In this week’s show, we speak out in favour of the new Instagram logo, welcome the Lord of the .io domain to the UK’s most hipster city, discuss a big man with a new big book, see the sunset on sunrise, and finally get all excited about our new startup!




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The Super Lit, Fam, Dope, En Flique Episode

It feels like only last week that the two “K Units” got behind the Samson CO1UPRO‘s and recorded episode #43. So close in fact, that we even manage to think we are still actually recording episode #43!

In this short 53 minute episode, we catch up on recent life goings on, learn that Kieran has been “tamping hard” in his role as “Digital Guy” at the bespoke artisanal coffee roasting company, discuss language used by people under the age of 30, announce our new club, and round out with a chat about Kickstarter. There may even be a mention of earphones!




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Back Stories with Marc Thiele

Welcome to Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

Each episode, unlike the usual show, will come in at 30 minutes and will attempt to delve into the interesting lives of people working in the web, design, tech, publishing, and creative industries.

In this first episode, Keir chats with Marc Thiele — long-time friend and the man behind the Beyond Tellerrand series of web conferences. There’s plenty of ground covered including the early 8 bit days, Flash, events, and more.

Marc Online




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Back Stories with Craig Lockwood

Welcome to the second episode of Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

In this episode, Keir is joined by Craig Lockwood — long time friend of the show and the man behind endeavours including software, events, co-working spaces, and more. In this very open and honest account of his work and life, Craig shares his experiences of working in the web and tech industry.

Craig Online




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Back Stories with Kurt Elster

In this episode of Back Stories, Keir chats with Kurt Elster — founder of ecommerce agency Ethercycle, host of the popular Ecommerce Hacks Weekly video series, author of Ecommerce Bootcamp, and the host of The Unofficial Shopify Podcast.

Topics include the benefits of the “peacock” jacket, naming your company, specialisation, automating inbound leads, productised consulting, and much more.

Kurt Online




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We Don&#8217;t Need no Education

I’ll say this — time off between episodes certainly gives us plenty to talk about. In our 45th, almost hour–long, outing behind the mics we welcome new members to “the club“, discuss Kieran’s move into the world of coffee capsule commerce, ponder on new forms of web education, and learn more what Kieran receives in the post!




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The Future of Medium?

Happy New Year to you all! Rather unsurprisingly we missed our end of year review but the outline was probably one of our best. Maybe we’ll do it next year!

This episode we catch up on Kieran’s move behind the camera, argue over what exactly constitutes a pair of Daps and delve into the future of Medium in light of Ev Williams recent announcement.

If you like the show don’t forget you can support our astronomical S3 costs by becoming an exclusive member of the Back to Front Show Club!




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Back Stories with Oliver Lindberg

In this episode of Back Stories, Keir chats with Oliver Lindberg— founder of the new Pixel Pioneers web conference series and all round content guru. Topics covered include how to find speakers for your conference, the role of a good editor, how to improve your writing skills, and how to pitch to an editor.

Oliver Online




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Kieran&#8217;s Big Red Button

It’s hard to believe it’s only been one week, no really, since our last confession. Where does the time go?

In this episode we catch up on what’s happened in our lives in the last seven days, discuss the latest goings on at Medium, ponder why the Guardian doesn’t write listicles and end on probably the best API in the world!




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Muppetry &amp; other Stories

Happy 2018! Eschewing a long-standing tradition of not actually releasing shows we are kicking off the year as we mean to go on (for now) with a brand spanking new edition!

Join us for 50 glorious high fidelity minutes (true for one of us) and celebrate five years of the show. We don’t dwell too long on our golden non-award winning archive and go on to indulge in some chat, review a book, have a moan about Kickstarter projects, and for once don’t end on dog tech!




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Kieran's Tiny House Dream

Tap tap, is this thing on? After eight months or working out how to plug in our USB microphones, we finally figured it out and are back with 45 glorious minutes of chat!

In this episode, we learn all about “New Kieran” — new job, new house, and a new laptop. We also discuss a great post on lessons learned running a subscription-based newsletter, discuss Hanno’s great online playbooks for remote working and end on a new Maus that neither of us wants.

Next up is our 50th episode — let us know what we should discuss via Twitter.




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25% jump in mental health cases in Gujarat

(This story originally appeared in AhmedabadMirror on May 8, 2020)




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Gujarat clears ordinance for labour reforms

In the wake of exodus of thousands of migrant workers who are leaving the state, the Gujarat cabinet has approved a new ordinance where existing stringent labour laws will be liberalised to ensure smooth functioning of industries in the post lockdown period.