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Sunshine Music Tours and Travels: Ain’t no sunshine at all

A film about a motley crew on a road trip is actually an overt promotion for an EDM fest




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Trolls: Pursuit of happiness

A moderately entertaining albeit predictable story in a novel universe




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Bengaluru residential property micromarkets witness record hike in prices: Report

Prices in Bagaluru in North Bengaluru have surged by nearly 90 per cent in the past five years, while Whitefield has seen an 80 per cent rise in prices




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Positive response to Small and Medium REITs: SEBI Chief

There is an imbalance of power between large institutions and small investors, and regulations have helped foster trust in the system, Says Madhabi Puri Buch




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Housing sales dipped 11% in Jul-Sept, average prices up by 23% in top 7 cities: Anarock

Among the top 7 cities, Hyderabad saw the highest jump of 32 per cent in average residential property prices




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Brookfield India REIT Q2 results: NOI up 40% YoY

Brookfield REIT gross leased 1 million square feet with a spread of 19 per cent driven by a strong revival in SEZ demand




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Manganese(III) acetate in organic synthesis: a review of the past decade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01499E, Review Article
Jian Wang, Yan Zhang, Ying Zhou, Xin Gu, Bingxu Han, Xuelu Ding, Shuai Liang
In this review, we summarize the latest developments and applications of Mn(OAc)3 in organic synthesis over the past decade, focusing on efforts to achieve milder reaction conditions while expanding the scope of synthesis possibilities.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pyrrolylsulfonium salts: stable, accessible and versatile pseudohalides for Stille couplings

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01793E, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jodie L. Hann, Catherine L. Lyall, Gabriele Kociok-Köhn, Simon E. Lewis
Pyrroles functionalised with a thianthrenium or diphenylsulfonium group undergo Stille couplings with aryl or alkynyl stannanes in good yields, avoiding the issues of instability that can hamper the use of the analogous pyrrolyl halides.
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Isomeric diazapyrene–thiophene conjugated systems: synthesis, characterization, and transport properties

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01305K, Research Article
Open Access
Honglei Li, Guodong Zhao, Qingxin Tang, Hongkun Tian, Lixiang Wang
Three key dihalogenated diazapyrene intermediates were synthesized and the corresponding isomeric co-oligomers with bithiophene demonstrated distinct position-dependence in the crystal structures, and optoelectronic and charge transport properties.
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The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article
Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects

Org. Chem. Front., 2024, 11,6393-6410
DOI: 10.1039/D4QO01451K, Research Article
Jiaoyang Liu, Li-juan Huang, Zeang Sun, Juan Li
DFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.
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Activation of donor–acceptor cyclopropanes under basic conditions: ring opening of 2-(p-siloxyaryl)cyclopropane 1,1-dicarboxylates with nitro compounds and other C-nucleophiles

Org. Chem. Front., 2024, 11,6483-6494
DOI: 10.1039/D4QO01472C, Research Article
Yulia A. Antonova, Andrey A. Tabolin
A new activation mode for donor–acceptor cyclopropanes was proposed and implemented in their reaction with nitro compounds and other common C-nucleophiles.
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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
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Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis

Org. Chem. Front., 2024, 11,6573-6588
DOI: 10.1039/D4QO01644K, Review Article
Zhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You Huang
Recent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.
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Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
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DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01512F, Research Article
Rahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez Khan
A new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...
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Regio- and stereoselective azidation of activated N-allenamides: an entry to α, β, γ and δ-amido-azides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01802H, Research Article
Dorian Schutz, Maxime Hourtoule, Laurence Miesch
A totally controlled regiodivergent azidation of activated N-allenamides is described, offering a broad range of diverse functionalized amido-azide derivatives.
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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01810A, Research Article
Ángel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-Castells
Cyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...
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π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01592D, Research Article
Bin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao He
The development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...
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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
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When hope meets hurdles: stark reality of Telangana’s job market

The State’s job crisis has come back to haunt the Congress party, which rode to power last year on promises of employment. While local youth wait, worry, and exchange dreams about securing government jobs, short-term opportunities are drawing people from other States. This dynamic has transformed Telangana into a job magnet for outsiders but a desert for its own aspirants, reports Serish Nanisetti




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66% of gamers in India are from non-metro cities: Lumikai annual report

Average weekly time spent on gaming increased by 30% to 13 hours




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Women’s ODI rankings: Harmanpreet Kaur rises to ninth, Smriti Mandhana remains fourth

India are placed in third position in the ICC Women’s Championship standings with 25 points while New Zealand are sixth with 20 from 21.




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Indian students can even work in UK after studies: UK minister




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Newly synthesized sulfonamide derivatives explored for DNA binding, enzyme inhibitory, and cytotoxicity activities: a mixed computational and experimental analyses

RSC Adv., 2024, 14,35047-35063
DOI: 10.1039/D4RA06412G, Paper
Open Access
Nasima Arshad, Yasir Mehmood, Hammad Ismail, Fouzia Perveen, Aneela Javed, Pervaiz Ali Channar, Aamer Saeed, Sadia Naseem, Fatima Naseer
This work reports synthesis, characterization, DNA, enzyme binding and cytotoxicity activity of three 4-((3-arylthiazolo[3,4-d]isoxazol-5-yl)amino)benzene sulfonamide derivatives with a thaizaole(3,4-d)isoxazole-based fused ring heterocyclic system.
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Design, synthesis, and evaluation of novel thiadiazole derivatives as potent VEGFR-2 inhibitors: a comprehensive in vitro and in silico study

RSC Adv., 2024, 14,35505-35519
DOI: 10.1039/D4RA04158E, Paper
Open Access
Ibrahim H. Eissa, Walid E. Elgammal, Hazem A. Mahdy, Susi Zara, Simone Carradori, Dalal Z. Husein, Maymounah N. Alharthi, Ibrahim M. Ibrahim, Eslam B. Elkaeed, Hazem Elkady, Ahmed M. Metwaly
This study aims to investigate the potential of designed 2,3-dihydro-1,3,4-thiadiazole derivatives as anti-proliferative agents targeting VEGFR-2, utilizing a multidimensional approach combining in vitro and in silico analyses.
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Advances in quinoxaline derivatives: synthetic routes and antiviral efficacy against respiratory pathogens

RSC Adv., 2024, 14,35400-35423
DOI: 10.1039/D4RA04292A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fateme Dehnavi, Malihe Akhavan, Ahmadreza Bekhradnia
3D lung visualization showing COVID-19 infection areas alongside respiratory pathogens. The antiviral drug structure and comparison of healthy vs. infected lungs demonstrate how the drug could restore lung health.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
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Electromagnetic wave effects on Mn-doped superparamagnetic iron oxide nanofluids: applications in enhanced oil recovery

RSC Adv., 2024, 14,35671-35678
DOI: 10.1039/D4RA04500A, Paper
Open Access
Mohamad Amin Bin Hamid, Beh Hoe Guan, Chan Kar Tim, Hassan Soleimani
This study reveals that both direct current (DC) and alternating current (AC) electromagnetic fields can effectively reduce the interfacial tension (IFT) of Mn-doped Fe3O4 nanofluids, with AC fields showing more predictable and pronounced effects.
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Revolutionizing applications: the impact of controlled surface chemistry on marble powder

RSC Adv., 2024, 14,35727-35742
DOI: 10.1039/D4RA06342B, Review Article
Open Access
Ali Zia Noor, Sadia Bibi, Maryam Asrar, Muhammad Imran, Sadia Afzal, Sadiqa Abdal, Muhammad Atif
A large amount of marble powder is abundantly available as a byproduct and waste in the marble industry, and its reinforcement has been attempted in several applications through surface modification.
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From e-waste to eco-sensors: synthesis of reduced graphene oxide/ZnO from discarded batteries for a rapid electrochemical bisphenol A sensor

RSC Adv., 2024, 14,36073-36083
DOI: 10.1039/D4RA04046E, Paper
Open Access
Md Humayun Kabir, Md Yeasin Pabel, Nishat Tasnim Bristy, Md. Abdus Salam, Muhammad Shahriar Bashar, Sabina Yasmin
E-waste-derived reduced graphene oxide/ZnO forfast electrochemical detection of bisphenol A (BPA).
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Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation

RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
Open Access
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
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In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity

RSC Adv., 2024, 14,36209-36225
DOI: 10.1039/D4RA06890D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda Hakim
A facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.
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Assam floods: Six more dead as toll mounts to 52; over 21 lakh people affected

At least seven districts of Arunachal Pradesh cut off due to landslides; eight persons, including two children, killed in rain-induced landslides and floods in Manipur, Mizoram and Tripura




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After raping and murdering doctor, accused went to sleep, washed his clothes: Kolkata Police

West Bengal Chief Minister Mamata Banerjee vowed to seek death penalty for the perpetrator in the Kolkata doctor rape and murder case




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Asian Relays: Indian mixed 4x400m team sets National record

The timing puts India in the 21st place in the Road to Paris list of World Athletics while the aim was to be either in the 15th or 16th spot




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World Para Athletic Championships: Ekta wins gold with season's best effort in club throw

Reigning Paralympics champion Sumit Antil defended his F64 javelin throw world title while Thangavelu Mariyappan also grabbed gold medal.




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Asian Relay Championships: Indian men's and women's 4x400m teams win silver medals

Indian mixed 4x400 relay team set a national record while winning the gold medal but missed the target of entering the Paris Olympics qualification bracket.




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World Para Athletics Championships: Simran wins gold as India ends 6th with best-ever 17 medals 

Simran Sharma shaved off around one-fifth of a second from her earlier personal best of 25.16 seconds to win the gold.




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Athletics: Chebet breaks 10,000m record, Kerr beats Ingebrigtsen

Chebet clocked 28 minutes 54.14 seconds, taking nearly seven seconds off the previous world record set by Ethiopian Letesenbet Gidey three years ago to qualify for the event at the Paris Olympics.




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Paris Olympics: Afghan sprinter Yousoufi tells girls not to let others make decisions for them

Competing in her third Olympics — Rio de Janeiro and Tokyo — Yousofi finished with a time of 13.42 seconds, slower than the 13.29 three years ago.




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Paris Olympics: Men’s 4x400m relay team narrowly misses berth in final

The Indian campaign in athletics ended with the exit of the relay teams.




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Paris Olympics: Grant Holloway is now a relieved man after maiden Olympic title in 110m hurdles

The three-time World champion valued his maiden Olympic title after his feat at the Stade de France in Paris on Thursday (August 8, 2024) night.




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Paris Paralympics: Yogesh Kathuniya bags second consecutive silver in men's discus throw F-56 event

The 27-year-old hurled the discus to the podium-clinching distance in his very first attempt to add to the silver he won in the Tokyo Paralympics three years ago.




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‘Sweet’ sacrifice and sleepless nights: Sumit Antil on defending Paralympic gold despite back injury

On the advice of his physio, Sumit Antil grudgingly gave up sweets, followed a strict training regimen and shed around 12 kilograms in just two months.




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Paralympic Games: Praveen Kumar strikes gold in T64 high jump with Asian record

The country has so far won six gold, nine silver and 11 bronze medals to achieve its best-ever haul at a single edition of the Paralympic Games




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India Open under-23 athletics: Talented athletes eager to prove their worth

The athletes will look to perform well ahead of the Asian and World championships next year.