Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper

Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication

Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C₂H₂/C₂H₄ at room temperature.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02831G, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntosh
A switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02861A, Paper

Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda
Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02616K, Paper

Jiali Chen, Guihua Yang, Feng Gao, Rui Wang
The ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper

Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper

Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication

Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper

Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]₃ 1, [Ga(BHA-H]₃ 2,...
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Dalton Trans., 2024, 53,17819-17828
DOI: 10.1039/D4DT01625D, Paper

Songhan Hu, Kai Wang, Xinxin Xu, Qiang Wang
Two Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H₂O₂ production.
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Dalton Trans., 2024, 53,17803-17818
DOI: 10.1039/D4DT01490A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. Vila
The study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC₅₀ values.
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Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective

Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper

Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al³⁺ ions and ESIPT-off for Ag⁺ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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Dalton Trans., 2024, 53,17766-17771
DOI: 10.1039/D4DT02505A, Frontier

John Mack, Gugu Kubheka, Aviwe May, Bokolombe P. Ngoy, Tebello Nyokong
Recent research at the Institute for Nanotechnology Innovation at Rhodes University exploring the utility of BODIPY and azaBODIPY dyes for optical limiting of incident nanosecond laser pulses in the visible region is described.
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Dalton Trans., 2024, 53,17829-17840
DOI: 10.1039/D4DT01571A, Paper

Ajay Gupta, Pijus K. Sasmal
Herein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.
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Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper

Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper

Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO₂/mesoporous TiO₂ framework structures with different morphologies and efficient photocatalytic CO₂ reduction performance.
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Dalton Trans., 2024, 53,17852-17863
DOI: 10.1039/D4DT02538E, Paper

Kelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. Toledo
A structural and functional biomimetic Ni(II)N₃O complex, capable of O₂ mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
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Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper

Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe₃O₄@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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Dalton Trans., 2024, 53,17880-17892
DOI: 10.1039/D4DT02544J, Paper

Zhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing Cui
Three novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.
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Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper

Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
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Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper

Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp²)–C(sp³) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper

Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper

Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)₂(imphen)]⁺ is a ³MLLCT emitter, while [Ir(pybzth)₂(imphen)]⁺ has a predominant ³LC_N∩C character.
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Dalton Trans., 2024, 53,17772-17776
DOI: 10.1039/D4DT02595D, Communication

Zaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi Yi
Neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO₂ reduction.
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Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined Pd^II complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper

Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La_9.33Si₆O₂₆ with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
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Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper

Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper

The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication

Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
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Dalton Trans., 2024, 53,17783-17788
DOI: 10.1039/D4DT02336F, Communication

Danijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. Swiegers
Ca-doped birnessite MnO_x on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper

Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper

Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol⁻¹, leading to (S)-hydroxylated products.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02589J, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef Holub
The objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper

Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO₂⁻) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper

Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h⁻¹ and the l/b ratio reaches 2.6).
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper

Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper

Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier

Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper

Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic Co^II complexes exhibiting field-induced single-ion magnetism.
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