nat Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02496F, PaperSergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena ShubinaOctahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02274B, PaperEmilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-ŻyrekHistatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02467B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank VanhaeckeThis study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02848A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi ShimojimaWell-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02131B, PaperGuo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming RenFour multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02713B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie C. Corner, Gemma K. Gransbury, David P. MillsWe present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat In the abode of lovely nature By www.thehindu.com Published On :: Sun, 13 Oct 2024 02:58:00 +0530 There is a gentle breeze that blows ever so often from the Kunda Betta and the old trees sway gently, as if in sheer delight Full Article Open Page
nat Foreign fascination By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:00:00 +0530 Exploring the dream of crossing the borders brought on by inquisitiveness and curiosity Full Article Open Page
nat Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur By www.thehindu.com Published On :: Sun, 10 Nov 2024 08:01:00 +0530 Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign Full Article Karnataka
nat Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru By www.thehindu.com Published On :: Sun, 10 Nov 2024 09:46:15 +0530 There were more than 15 delays, and six flights diverted Full Article Bengaluru
nat Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 17:22:47 +0530 Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy Full Article Karnataka
nat Karnataka makes online applications mandatory for private aided school teacher recruitment By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:03:16 +0530 DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently Full Article Karnataka
nat Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:39:36 +0530 The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka Full Article Karnataka
nat Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha By www.thehindu.com Published On :: Mon, 11 Nov 2024 17:14:22 +0530 The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process Full Article Karnataka
nat Here are the big stories from Karnataka today By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:10:43 +0530 Welcome to the Karnataka Today newsletter, your guide from The Hindu on the major news stories to follow today. Curated and written by Nalme Nachiyar. Full Article Karnataka Today
nat Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument By www.thehindu.com Published On :: Mon, 11 Nov 2024 22:47:38 +0530 The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year Full Article Karnataka
nat Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year By www.thehindu.com Published On :: Mon, 11 Nov 2024 23:28:30 +0530 Full Article Karnataka
nat Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:00:00 +0530 Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign. Full Article Karnataka
nat Karnataka’s KSRTC introduces UPI payments for cashless ticketing By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:07:00 +0530 As part of this initiative, KSRTC has equipped its buses with advanced Electronic Ticketing Machines, which are designed to accept UPI payments, along with debit and credit cards, making transactions quick and convenien Full Article Karnataka
nat I apologise if my remark about H.D. Kumaraswamy has hurt JD(S) workers: Karnataka Housing Minister B Z Zameer Ahmed Khan By www.thehindu.com Published On :: Tue, 12 Nov 2024 16:22:44 +0530 Housing Minister’s remarks about colour of skin of Union Minister H. D. Kumaraswamy had drawn criticism from BJP and JD(S) Full Article Karnataka
nat Here are the big stories from Karnataka today By www.thehindu.com Published On :: Tue, 12 Nov 2024 18:22:46 +0530 Welcome to the Karnataka Today newsletter, your guide from The Hindu on the major news stories to follow today. Curated and written by Nalme Nachiyar. Full Article Karnataka Today
nat Karnataka: AEE throws away cash bundle during Lokayukta raid By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:43:45 +0530 Full Article Karnataka
nat JD(S) demands Zameer’s resignation for his remarks against HDK By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:11:01 +0530 Full Article Karnataka
nat Karnataka byelections: All set for polling today after weeks of high-decibel campaign By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:33:21 +0530 Though the results have little consequence in the number game for the government, the stakes are high for individual leaders Full Article Karnataka
nat Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen. By darius.uleth.ca Published On :: Washington, DC : American Psychiatric Association Publishing, [2024] Full Article
nat Nov 20 Maharashtra election: 4,140 candidates in fray; 2,938 withdraw nominations By www.newkerala.com Published On :: Tue, 05 Nov 2024 10:48:03 +0530 Full Article
nat Ranji Trophy | Sudip’s unbeaten ton, the silver-lining in Karnataka-Bengal stalemate By www.thehindu.com Published On :: Sun, 10 Nov 2024 01:02:16 +0530 Saha’s fifty quashes hopes of a comeback by the hosts; Smaran, Shreyas and Manish take their side to safety after a shaky start; Mayank puts the onus on the batters to iron out their flaws Full Article Cricket
nat Messi and Miami eliminated from MLS Cup playoffs in first round By www.thehindu.com Published On :: Sun, 10 Nov 2024 12:31:34 +0530 Inter Miami, led by Lionel Messi, suffers a shocking playoff elimination after a 3-2 defeat to Atlanta United Full Article Football
nat ICC continues discussion on Champions Trophy schedule with participating nations By www.thehindu.com Published On :: Tue, 12 Nov 2024 22:15:41 +0530 Meanwhile, it was not a surprise that ICC has also put on hold the prestigious ODI tournament's launch event, which was scheduled to be held in Lahore on November 11. Full Article Cricket
nat Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830DOI: 10.1039/D4EW00538D, PaperJun Li, Salma Tabassum, Hüseyin AltundagDenitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat A novel graphene oxide–microalgae hybrid material for the removal of pentavalent arsenic from natural water and industrial wastewater By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2796-2808DOI: 10.1039/D4EW00308J, PaperEliana S. Lemos, Evelyn M. Valdés Rodríguez, Adrián Bonilla Petriciolet, Andrea M. Ray, Leticia B. EscuderoThe adsorption process using bionanomaterials based on graphene oxide and green microalgae for the removal of arsenic from complex samples of natural water and industrial wastewater.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Degradation of benzylamines during chlorination and chloramination By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2655-2664DOI: 10.1039/D4EW00556B, PaperChih-Hsien Lin, Wei-Hsiang Chen, William A. MitchThis study characterized the degradation pathways of benzylamine, N-methylbenzylamine and N,N-dimethylbenzylamine during chlorination and chloramination.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Effects of chloride transport on the bioelectrochemical remediation of nitrate-contaminated groundwater By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2776-2786DOI: 10.1039/D4EW00335G, PaperHanyu Tang, McKenzie Burns, Mohan QinThe impact of ion competition on nitrate removal from contaminated groundwater using membrane-based bioelectrochemical systems is investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Environmental and private property contamination following the Norfolk Southern chemical spill and chemical fires in Ohio By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,3007-3023DOI: 10.1039/D4EW00456F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paula B. Coelho, Gracie Fitzgerald, Kristofer Isaacson, Rasul Diop, Gouri Prabhakar, Stephanie Heffner, Akshat Verma, Jeffrey P. Youngblood, Youn Jeong Choi, Stefanie Surdyka, Samuel A. Spears, Marty D. Frisbee, Katherine R. Del Real, Lauren A. Gustafson, Ana María Núñez-Torres, Caitlin R. Proctor, Linda S. Lee, Heather D. Whitehead, Kyle Doudrick, Brock A. Harpur, Andrew J. WheltonIn February 2023, a train derailment in Ohio caused a chemical spill and fires releasing contaminants into the air, soil, waterways, and buildings.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654DOI: 10.1039/D4EW00496E, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. PearceRemoval of pertechnetate 99TcO4− and perrhenate ReO4− during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Concurrent boron removal from reverse osmosis concentrate and energy production using a microbial desalination cell-Donnan dialysis hybrid system By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, Advance ArticleDOI: 10.1039/D4EW00621F, PaperA. Yagmur Goren, H. Eser OktenThe removal of boron from aqueous solutions offers an important opportunity to improve the management of sustainable resources.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Removal of Cu2+ from AMD by goethite modified biochar combined with sodium alginate: characterization, performance and mechanisms By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, Advance ArticleDOI: 10.1039/D4EW00664J, PaperHong Yang, Ruixue Zhang, Li An, Pan Wu, Yuran Fu, Jiajun Zou, Min YuAn innovative method for resource utilization of agricultural waste crops.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat Sorption and biodegradation of stormwater trace organic contaminants via composite alginate bead geomedia with encapsulated microorganisms By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, Advance ArticleDOI: 10.1039/D4EW00600C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Debojit S. Tanmoy, Gregory H. LeFevreWe quantified sorption of stormwater relevant trace organic contaminants and dissolved phosphorus to a novel composite-alginate geomedia. We demonstrated coupled sorption and biodegradation of a representative tirewear compound via the geomedia.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
nat AIBEA warns of nationwide strike, but says date not decided yet By www.thehindu.com Published On :: Mon, 21 Oct 2024 14:44:21 +0530 The bank employees union demands filling ‘more than a lakh vacancies’ at banks across India; says customer service has been badly hit Full Article Industry
nat India’s IT services market grew 6.1% in 2023, reaching a size of $14.5 bn: International Data Corporation By www.thehindu.com Published On :: Mon, 28 Oct 2024 22:32:07 +0530 While IT investments showed a slower recovery compared to the previous year, digital transformation (DX) initiatives and IT environments would continue to drive market growth Full Article Business
nat Natco Pharma Q2 net surges 83% to ₹677 crore on robust growth in formulation exports By www.thehindu.com Published On :: Tue, 12 Nov 2024 17:34:43 +0530 Natco Pharma said that the company has shown continued strong growth during the second quarter driven by exports formulation business and stable domestic pharma business Full Article Industry
nat Kerala bypolls: Arguments about civility in electoral politics dominate Palakkad byelection narrative By www.thehindu.com Published On :: Mon, 04 Nov 2024 13:47:28 +0530 Electoral battle turned rather unsightly in public after expelled Congress leader-turned-LDF Independent candidate P. Sarin ran into his former compatriot and poll rival in Palakkad, Rahul Mamkootathil of UDF, at a wedding on Sunday Full Article Kerala
nat School of drama to host third International Festival of Theatre Schools in February By www.thehindu.com Published On :: Tue, 05 Nov 2024 18:46:32 +0530 Three research chairs, named after G. Shankara Pillai, Vayala Vasudevan Pillai and Ramachandran Mokeri, to be established at the institution Full Article Kerala
nat UP Bypolls: Yogi Adityanath Slams SP At Mirzapur Rally, Dubs It 'Production House Of Criminals And Mafia' By Published On :: Sunday, November 10, 2024, 23:32 +0530 UP CM Yogi alleged that the INDIA bloc led by the SP and the Congress has nothing to do with the development of the country or state. Full Article
nat Jharkhand Converted Into 'Dharmashala' For Rohingyas, Bangladeshi Infiltrators: Yogi Adityanath By Published On :: Monday, November 11, 2024, 22:44 +0530 Uttar Pradesh Yogi Adityanath alleged that the JMM-led government in Jharkhand fuelled corruption, anarchy and looting of natural resources. Full Article
nat Ahead Of Uttar Pradesh Bypolls, Yogi Adityanath Faces A 'Youth' Challenge By Published On :: Tuesday, November 12, 2024, 21:43 +0530 UPPCS Protest: Amid the bypolls contest, the Yogi Adityanath government is facing a challenge which the BJP was not anticipating at this time. Full Article