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Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02496F, Paper
Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena Shubina
Octahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...
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Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
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Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02467B, Paper
Open Access
Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank Vanhaecke
This study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.
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Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02848A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02713B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sophie C. Corner, Gemma K. Gransbury, David P. Mills
We present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.
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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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In the abode of lovely nature

There is a gentle breeze that blows ever so often from the Kunda Betta and the old trees sway gently, as if in sheer delight




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Foreign fascination

Exploring the dream of crossing the borders brought on by inquisitiveness and curiosity




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’

Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy

The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka




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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process




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Here are the big stories from Karnataka today

Welcome to the Karnataka Today newsletter, your guide from The Hindu on the major news stories to follow today. Curated and written by Nalme Nachiyar.




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Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument  

The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year




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Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year




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Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister

Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign.




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Karnataka’s KSRTC introduces UPI payments for cashless ticketing

As part of this initiative, KSRTC has equipped its buses with advanced Electronic Ticketing Machines, which are designed to accept UPI payments, along with debit and credit cards, making transactions quick and convenien




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I apologise if my remark about H.D. Kumaraswamy has hurt JD(S) workers: Karnataka Housing Minister B Z Zameer Ahmed Khan

Housing Minister’s remarks about colour of skin of Union Minister H. D. Kumaraswamy had drawn criticism from BJP and JD(S)




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Here are the big stories from Karnataka today

Welcome to the Karnataka Today newsletter, your guide from The Hindu on the major news stories to follow today. Curated and written by Nalme Nachiyar.




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Karnataka: AEE throws away cash bundle during Lokayukta raid




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JD(S) demands Zameer’s resignation for his remarks against HDK




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Karnataka byelections: All set for polling today after weeks of high-decibel campaign

Though the results have little consequence in the number game for the government, the stakes are high for individual leaders




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Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen.

Washington, DC : American Psychiatric Association Publishing, [2024]




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Nov 20 Maharashtra election: 4,140 candidates in fray; 2,938 withdraw nominations




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Ranji Trophy | Sudip’s unbeaten ton, the silver-lining in Karnataka-Bengal stalemate

Saha’s fifty quashes hopes of a comeback by the hosts; Smaran, Shreyas and Manish take their side to safety after a shaky start; Mayank puts the onus on the batters to iron out their flaws




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Messi and Miami eliminated from MLS Cup playoffs in first round

Inter Miami, led by Lionel Messi, suffers a shocking playoff elimination after a 3-2 defeat to Atlanta United




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ICC continues discussion on Champions Trophy schedule with participating nations

Meanwhile, it was not a surprise that ICC has also put on hold the prestigious ODI tournament's launch event, which was scheduled to be held in Lahore on November 11.




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Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
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A novel graphene oxide–microalgae hybrid material for the removal of pentavalent arsenic from natural water and industrial wastewater

Environ. Sci.: Water Res. Technol., 2024, 10,2796-2808
DOI: 10.1039/D4EW00308J, Paper
Eliana S. Lemos, Evelyn M. Valdés Rodríguez, Adrián Bonilla Petriciolet, Andrea M. Ray, Leticia B. Escudero
The adsorption process using bionanomaterials based on graphene oxide and green microalgae for the removal of arsenic from complex samples of natural water and industrial wastewater.
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Degradation of benzylamines during chlorination and chloramination

Environ. Sci.: Water Res. Technol., 2024, 10,2655-2664
DOI: 10.1039/D4EW00556B, Paper
Chih-Hsien Lin, Wei-Hsiang Chen, William A. Mitch
This study characterized the degradation pathways of benzylamine, N-methylbenzylamine and N,N-dimethylbenzylamine during chlorination and chloramination.
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Effects of chloride transport on the bioelectrochemical remediation of nitrate-contaminated groundwater

Environ. Sci.: Water Res. Technol., 2024, 10,2776-2786
DOI: 10.1039/D4EW00335G, Paper
Hanyu Tang, McKenzie Burns, Mohan Qin
The impact of ion competition on nitrate removal from contaminated groundwater using membrane-based bioelectrochemical systems is investigated.
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Environmental and private property contamination following the Norfolk Southern chemical spill and chemical fires in Ohio

Environ. Sci.: Water Res. Technol., 2024, 10,3007-3023
DOI: 10.1039/D4EW00456F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paula B. Coelho, Gracie Fitzgerald, Kristofer Isaacson, Rasul Diop, Gouri Prabhakar, Stephanie Heffner, Akshat Verma, Jeffrey P. Youngblood, Youn Jeong Choi, Stefanie Surdyka, Samuel A. Spears, Marty D. Frisbee, Katherine R. Del Real, Lauren A. Gustafson, Ana María Núñez-Torres, Caitlin R. Proctor, Linda S. Lee, Heather D. Whitehead, Kyle Doudrick, Brock A. Harpur, Andrew J. Whelton
In February 2023, a train derailment in Ohio caused a chemical spill and fires releasing contaminants into the air, soil, waterways, and buildings.
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Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654
DOI: 10.1039/D4EW00496E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. Pearce
Removal of pertechnetate 99TcO4 and perrhenate ReO4 during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.
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Concurrent boron removal from reverse osmosis concentrate and energy production using a microbial desalination cell-Donnan dialysis hybrid system

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00621F, Paper
A. Yagmur Goren, H. Eser Okten
The removal of boron from aqueous solutions offers an important opportunity to improve the management of sustainable resources.
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Removal of Cu2+ from AMD by goethite modified biochar combined with sodium alginate: characterization, performance and mechanisms

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00664J, Paper
Hong Yang, Ruixue Zhang, Li An, Pan Wu, Yuran Fu, Jiajun Zou, Min Yu
An innovative method for resource utilization of agricultural waste crops.
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Sorption and biodegradation of stormwater trace organic contaminants via composite alginate bead geomedia with encapsulated microorganisms

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00600C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Debojit S. Tanmoy, Gregory H. LeFevre
We quantified sorption of stormwater relevant trace organic contaminants and dissolved phosphorus to a novel composite-alginate geomedia. We demonstrated coupled sorption and biodegradation of a representative tirewear compound via the geomedia.
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AIBEA warns of nationwide strike, but says date not decided yet

The bank employees union demands filling ‘more than a lakh vacancies’ at banks across India; says customer service has been badly hit 




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India’s IT services market grew 6.1% in 2023, reaching a size of $14.5 bn: International Data Corporation

While IT investments showed a slower recovery compared to the previous year, digital transformation (DX) initiatives and IT environments would continue to drive market growth




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Natco Pharma Q2 net surges 83% to ₹677 crore on robust growth in formulation exports

Natco Pharma said that the company has shown continued strong growth during the second quarter driven by exports formulation business and stable domestic pharma business




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Kerala bypolls: Arguments about civility in electoral politics dominate Palakkad byelection narrative

Electoral battle turned rather unsightly in public after expelled Congress leader-turned-LDF Independent candidate P. Sarin ran into his former compatriot and poll rival in Palakkad, Rahul Mamkootathil of UDF, at a wedding on Sunday




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School of drama to host third International Festival of Theatre Schools in February

Three research chairs, named after G. Shankara Pillai, Vayala Vasudevan Pillai and Ramachandran Mokeri, to be established at the institution




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UP Bypolls: Yogi Adityanath Slams SP At Mirzapur Rally, Dubs It 'Production House Of Criminals And Mafia'

UP CM Yogi alleged that the INDIA bloc led by the SP and the Congress has nothing to do with the development of the country or state.




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Jharkhand Converted Into 'Dharmashala' For Rohingyas, Bangladeshi Infiltrators: Yogi Adityanath

Uttar Pradesh Yogi Adityanath alleged that the JMM-led government in Jharkhand fuelled corruption, anarchy and looting of natural resources.




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Ahead Of Uttar Pradesh Bypolls, Yogi Adityanath Faces A 'Youth' Challenge

UPPCS Protest: Amid the bypolls contest, the Yogi Adityanath government is facing a challenge which the BJP was not anticipating at this time.