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Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01641F, Research Article
Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai Li
An FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.
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Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01879F, Research Article
Yuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin Fan
Oxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...
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Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01828A, Review Article
Kazutaka Shoyama, Frank Wuerthner
Polycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...
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Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
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π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01592D, Research Article
Bin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao He
The development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...
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Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01734J, Research Article
Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing Li
Transition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...
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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
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At Via Milano in Hyderabad, the pizza can wait, go for the chops




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Woman arrested after kidnap attempt in Koti Government Maternity Hospital

The accused was a habitual offender and had made a vain bid on Tuesday night, before being caught by the hospital staff and police on Wednesday




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Cong. govt cheating paddy farmers on procurement: Kishan Reddy




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Two from Hyderabad, including government employee, lose ₹50 lakh in separate scams




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Mahabubnagar District Education Officer in ACB net




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TGSRTC Karimnagar region to operate special buses to Arunachala Hill in Tamil Nadu on November 13




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Thousands gather for Chhath Puja at Bathukamma ghats

In addition to Hussainsagar, Chhath Puja is being celebrated at 49 other locations across the twin cities of Hyderabad and Secunderabad.




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₹4.8 crore loan fraud scheme unearthed at SBI Sanathnagar, eight more arrested




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HYDRAA created fear among encroachers and big builders and not common people: Telangana CM




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75th anniversary of Bharat Scouts and Guides celebrated




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Cyberabad | Four arrested for vandalising Gandhi statue




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Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad

Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika




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‘Rahasyam Idham Jagath’ movie review: Earnest but far from engrossing

Director Komal R Bharadwaj’s Telugu indie ‘Rahasyam Idham Jagath’ is ambitious in using science, technology and stories from the Indian epics for an adventure drama, but falls short in its execution




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Owaisi hails Supreme Court ruling on AMU’s minority status

The Modi government should take this judgement in its stride, says Asad




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Home guard injured after engineering student attempts to flee vehicle checking in Panjagutta




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Varun Tej: ‘Matka’ entertains but does not glorify the gambler

Actor Varun Tej discusses his new Telugu film ‘Matka’, a fictional tale inspired by Ratan Khatri, set in Visakhapatnam of the 1960s and 70s




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Cockroach infestation found at CCMB canteen; hygiene violations flagged at Nacharam restaurants




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Charitable trust donates furniture to flood-affected residential school in Khammam




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U.S. doctors explore institutional collaboration with NIMS




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Commotion at BRS dharna in Huzurabad, vehicular traffic disrupted on highway




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Mental health and resilience in higher education institutions as a mission 

A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing




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Man, friend killed in car-bus collision after attending sister’s wedding reception




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Telangana delegation to embark on 3-day study tour in Karnataka for fisheries development




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Guru Nanak’s 555th birth anniversary celebrations to begin in Hyderabad on November 11




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Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months

45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data




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Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe

Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice




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Explosion at restaurant injures four in Hyderabad’s Jubilee Hills




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Lorry ferrying EV cars to Hyderabad catches fire




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Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana




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Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief

He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore




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Man held for damaging idol at temple in Shamshabad




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Man arrested for shooting at father of woman he liked




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Agitated villagers chase govt officials over proposed pharma plant in Vikarabad

The villagers have been protesting for several weeks against the proposed pharma company




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Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat

The new order comes into effect from November 11 until further notice, said the commissioner




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VHP flays State govt. for temple vandalism




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Nodal officers appointed for the caste survey in Greater Hyderabad




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Watch: ‘I am prepared to face political repercussions’: Revanth Reddy on HYDRAA

Telangana Chief Minister A. Revanth Reddy made it clear that the government is not going to spare encroachers and that HYDRAA has been given full powers 




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Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy




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Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village




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Maamaas studio inaugurated in Kukatpally




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GHMC’s claims for budget allocations delayed due to absence of full time commissioner




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Letters to the Editor dated June 24, 2024




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Letters to Editor dated June 25, 2024