mp

Importance of Portraying African American History

Stephen Seals joins to discuss some of the powerful African American programming available during Black History Month and beyond in 2016. Hear some of his favorites and why it’s so important to tell the stories of half of the population of Williamsburg in the 18th century.




mp

Journey to Redemption

The cast and crew of Colonial Williamsburg’s groundbreaking program Journey to Redemption join to talk about how the piece was developed and why it’s so important to be having conversations surrounding racism and the history of slavery in our nation. Learn more




mp

JD(U) MP detained,prevented from visiting riot-hit Muzaffarnagar



  • DO NOT USE Uttar Pradesh
  • India

mp

Weeks after Muzaffarnagar violence,women allege rape in written complaints



  • Cities
  • DO NOT USE Uttar Pradesh

mp

Muzaffarnagar violence: Homeless riot victims buy plots next to relief camps




mp

MHA awaits Akhilesh reply on children’s deaths in Muzaffarnagar relief camps



  • DO NOT USE Uttar Pradesh
  • India

mp

In temple town, Kejriwal seeks, finds support in minorities



  • DO NOT USE Uttar Pradesh
  • India

mp

Youths claiming to be Varun’s supporters protest outside BJP MP’s house



  • DO NOT USE Uttar Pradesh
  • India

mp

UP government to felicitate Muslim village head who built temple



  • DO NOT USE Uttar Pradesh
  • India

mp

2013 Muzaffarnagar riots: SIT completes probe in 503 cases; case pending against BJP MLA



  • DO NOT USE Uttar Pradesh
  • India

mp

Rampur: ‘SP worker’ wants police to find who stole his hens



  • DO NOT USE Uttar Pradesh
  • India

mp

Cop murder case: Congress MP’s son held, accuses father of hatching conspiracy



  • DO NOT USE Uttar Pradesh
  • India

mp

Characterization of aerosolized particles from nanoclay-enabled composites during manipulation processes

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01211G, Paper
Eun Gyung Lee, Lorenzo Cena, Jiwoon Kwon, Ali Afshari, HaeDong Park, Gary Casuccio, Kristin Bunker, Traci Lersch, Ashley Gall, Huy Pham, Alixandra Wagner, Sushant Agarwal, Cerasela Zoica Dinu, Rakesh Gupta, Sherri A. Friend, Todd A. Stueckle
Manufacturing, processing, use, and disposal of nanoclay-enabled composites potentially lead to the release of nanoclay particles from the polymer matrix in which they are embedded; however, exposures to airborne particles are poorly understood.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Nuclear translocation of silver ions and hepatocyte nuclear receptor impairment upon exposure to silver nanoparticles

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01348B, Paper
Open Access
Vanessa Tardillo Suárez, Elizaveta Karepina, Mireille Chevallet, Benoit Gallet, Cécile Cottet-Rousselle, Peggy Charbonnier, Christine Moriscot, Isabelle Michaud-Soret, Wojciech Bal, Alexandra Fuchs, Rémi Tucoulou, Pierre-Henri Jouneau, Giulia Veronesi, Aurélien Deniaud
Upon exposure to non-toxic concentration of silver nanoparticles, only the ionic form of silver is found in the nucleus leading to an endocrine disruptor-like effect.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Release of silver from nanoparticle-based filter paper and the impacts to mouse gut microbiota

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01387C, Paper
Jingtao Wu, Cui Li, Jie Zhang, Neal W. Menzies, Paul M. Bertsch, Peng Wang, Peter M. Kopittke
The high antibacterial properties of the filter paper containing silver nanoparticles (Ag-NPs) and subsequent impacts on mice.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Emerging investigator series: synthesis of magnesium oxide nanoparticles fabricated on a graphene oxide nanocomposite for CO2 sequestration at elevated temperatures

Environ. Sci.: Nano, 2020, 7,1225-1239
DOI: 10.1039/C9EN01442J, Paper
C. A. Gunathilake, G. G. T. A. Ranathunge, R. S. Dassanayake, S. D. Illesinghe, Amanpreet S. Manchanda, C. S. Kalpage, R. M. G. Rajapakse, D. G. G. P. Karunaratne
MONP and MONP–GO sorbents exhibited relatively high CO2 sorption capacity (2.79–3.34 mmol g−1) under elevated temperature conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

The rise of the nanomaterial metabolite corona, and emergence of the complete corona

Environ. Sci.: Nano, 2020, 7,1041-1060
DOI: 10.1039/C9EN00938H, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrew J. Chetwynd, Iseult Lynch
Metabolites present in the corona may play a key role in biological recognition of nanomaterials yet remain a much-overlooked aspect of the corona.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Impact of nano-TiO2 on horizontal transfer of resistance genes mediated by filamentous phage transduction

Environ. Sci.: Nano, 2020, 7,1214-1224
DOI: 10.1039/C9EN01279F, Paper
Xue Han, Peng Lv, Lu-Guang Wang, Fei Long, Xiao-Lin Ma, Chang Liu, Yu-Jie Feng, Ming-Feng Yang, Xiang Xiao
The spread of antibiotic resistance genes (ARGs) in the environment has aroused growing concern for human health and ecological safety.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Enhanced uptake of glyoxal at the acidic nanoparticle interface: implications for secondary organic aerosol formation

Environ. Sci.: Nano, 2020, 7,1126-1135
DOI: 10.1039/D0EN00016G, Paper
Qiuju Shi, Weina Zhang, Yuemeng Ji, Jiaxin Wang, Dandan Qin, Jiangyao Chen, Yanpeng Gao, Guiying Li, Taicheng An
Glyoxal (GL) exhibits a preferential tendency to the acidic nanoparticle interface, and sulfuric acid (SA) has a catalytic effect on hydration reaction of glyoxal in the aqueous phase.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Retraction: Mechanistic insights into the decontamination of Th(IV) on graphene oxide-based composites by EXAFS and modeling techniques

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90019B, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Xiangxue Wang, Wencheng Song, Songhua Lu, Changlun Chen, Xiangke Wang
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Retraction: Plasma-grafted amidoxime/metal–organic framework composites for the selective sequestration of U(VI)

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90017F, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fengbo Li, Xiaoyu Li, Pu Cui, Yubing Sun
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Formation of Fe(III)–As(V) complexes: effect on the solubility of ferric hydroxide precipitates and molecular structural identification

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00024H, Paper
Qiantao Shi, George E. Sterbinsky, Shujuan Zhang, Christos Christodoulatos, George P. Korfiatis, Xiaoguang Meng
Soluble Fe(III)–As(V) complexes were found at both acidic and neutral conditions, which significantly change the solubility of ferric oxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

The Gut Barrier and the Fate of Engineered Nanomaterials: A View from Comparative Physiology

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00174K, Critical Review
Open Access
Meike van der Zande, Anita Jemec Kokalj, David Spurgeon, Susana Loureiro, Patricia Silva, Zahra Khodaparast, Damjana Drobne, Nathaniel J. Clark, Nico van den Brink, Marta Baccaro, Kees van Gestel, Hans Bouwmeester, Richard D. Handy
The structure of the gut barrier and luminal chemistry in non-mammalian vertebrates and invertebrates has been given little attention with respect to the dietary uptake of engineered nanomaterials (ENMs). This...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Nanoparticulate zero valent iron interaction with dissolved organic matter impacts iron transformation and organic carbon stability

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper
Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Integrating an Ag0-Ag+ mediated Ag2Ta4O11/Ag8(Nb0.5Ta0.5)26O69 Heterojunction to Timely Decontaminate Indoor Gaseous Formaldehyde under Natural Temperature, Humidity and Sunlight Irradiation

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper
Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Performance of silver nanoparticle-impregnated ovoid ceramic water filters

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00115E, Paper
Zachary J. Shepard, Elizabeth M. Lux, Vinka A. Oyanedel-Craver
This work presents the first performance evaluation of ovoid CWFs designed by Potters without Borders. Performance analysis and characterization data are presented here to inform manufacturing decisions and research methods.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Sulfidation attenuates the adverse impacts of metallic nanoparticles on anammox from the perspective of chronic exposure

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper
Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Fragmentation of polymer nanocomposites: modulation by dry and wet weathering, fractionation, and nanomaterial filler

Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper
Open Access
Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Susceptible CoSnO3 nanoboxes with p-type response for triethylamine detection at low temperature

CrystEngComm, 2020, 22,2795-2805
DOI: 10.1039/D0CE00170H, Paper
Lingli Zheng, Yingqiang Zhao, Yongshan Xu, Chen Yang, Jun Zhang, Xianghong Liu
CoSnO3 nanoboxes exhibit a p-type response to detect triethylamine at 100 °C with a limit of detection of 134 ppb.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Heterobimetallic complexes from 0D clusters to 3D networks based on various polycyanometallates and [Cu(dmpn)2]2+ (dmpn = 2,2-dimethyl-1,3-diaminopropane): synthesis, crystal structures and magnetic properties

CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper
Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between FeIII/CrI ion and CuII ion.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Synthesis and investigation alkaline energetic coordination polymers based on 1,2,3-triazole-4,5-dicarboxylic acid for green component of pyrotechnic

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper
Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Silver clusters templated by homo- and hetero-anions

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00489H, Highlight
Zhonghua Pan, chenglong deng, zhi wang , Jin-Qing Lin, Geng-Geng Luo, Di Sun
Silver clusters with atomic precision have garnered immense attention owing to their aesthetic structures and fascinating properties. Assembly of silver clusters involves organizing positively charged silver ions into an intricate...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Synthesis of the finger-like MoS2@VS2 micro-nano composite with enhanced field emission performance

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00347F, Paper
Yu Feng, Erwei Du, Shijing Gong, Ke Yu, Xiaofan Chen, Ziqiang Zhu
The MoS2@VS2 micro-nano composite was synthesized via a two-step hydrothermal method. The field emission properties of MoS2@VS2 micro-nano composite were investigated for the first time. The finger-like VS2 has a...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Crystal nucleation of salicylamide and a comparison with salicylic acid

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00168F, Paper
Shubhangi Kakkar, K. Renuka Devi, Michael Svärd, Åke Rasmuson
Nucleation behaviour of salicylamide in different solvents was determined and compared with salicylic acid, attempting to progress the rationalization of the influence of the solvent and solute on crystal nucleation of organic compounds in solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

The effect of deuteration-levels in solution and temperature on the segregation coefficient of deuterium content in rapid-grown K(DxH1-x)2PO4 crystals using Raman spectroscopy

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper
Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(DxH1-x)2PO4 (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Syntheses of Nymphaea-like BiOCl with oxygen vacancies for effectively remove tetracycline hydrochloride

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00417K, Paper
Weidong Hou, Jia Yang, Haiming Xu, Dongya Li, Zhongwei Zou, Dongsheng Xia
Nymphaea-like BiOCl with oxygen vacancies (OVs) was successfully prepared by adjusting the pH of the precursor and using aspartic acid as surfactant. The as-fabricated samples were investigated by XRD, SEM,...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Diminishing accessibility of electrophilic nickel(II) centres due to incorporation of a methylene spacer in the pendant side arm of a series of heterotrinuclear nickel(II)/sodium complexes: a DFT study using a homodesmotic equation

CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper
Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Influence of lamellar thickness on the transformation of isotactic polybutylene-1/carbon nanotube nanocomposites

CrystEngComm, 2020, 22,2990-2997
DOI: 10.1039/D0CE00112K, Paper
Yan-Kai Li, Yu-Ge Wang, Cui-Liu Fu, You-Liang Zhu, Zhan-Wei Li, Zhao-Yan Sun
The crystallization transformation from form II to form I in PB-1/CNT materials is mainly influenced by the lamellar thickness.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Step-by-step: uncommon SCSC transformation accompanied by stepwise change in the binding of a particular ligand within a mononuclear complex upon stepwise desolvation

CrystEngComm, 2020, 22,2895-2899
DOI: 10.1039/D0CE00379D, Communication
Andrey V. Gavrikov, Andrey B. Ilyukhin, Pavel S. Koroteev
Uncommon SCSC transformation when desolvation induces subtle changes within a mononuclear complex, namely a stepwise change in the binding of a particular ligand.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Enhanced near-infrared luminescence in Ln2Cd2 (Ln = Nd, Yb) heterotetranuclear complexes

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00341G, Paper
Yue Qi, Ou Sun, Yanyan Zhou, Yuan Yao, Zhenyu Cheng, Ting Gao, Hongfeng Li
Due to the effect of the combination of the rigid structure and synergistic interactions of two ligands on energy transfer, the Cd–Ln complexes show excellent NIR luminescence properties with the QYs reaching 0.34% for Nd3+ and 2.13% for Yb3+.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

The different magnetic relaxation behaviors in [Fe(CN)6]3− or [Co(CN)6]3− bridged 3d–4f heterometallic compounds

CrystEngComm, 2020, 22,2998-3004
DOI: 10.1039/D0CE00039F, Paper
Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qinglun Wang, Bin Zhao, Peng Cheng
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)6]3− linking LnIII-Schiff-base units, the diamagnetic CoIII ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

A theoretical insight on the rigid hydrogen-bonded network in the solid state structure of two zinc(II) complexes and their strong fluorescence behaviors

CrystEngComm, 2020, 22,3005-3019
DOI: 10.1039/D0CE00125B, Paper
Ipsita Mondal, Tanmoy Basak, Snehasis Banerjee, Shouvik Chattopadhyay
A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(II). Strong fluorescence behaviors of two zinc(II) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Lanthanide doped bismuth-based fluoride nanoparticles: controlled synthesis and ratiometric temperature sensing

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00435A, Paper
Pengpeng Lei, Ran An, Chengyu Li, Jing Feng, Hongjie Zhang
Bismuth-based nanoparticles, especially NaBiF4, have attracted extensive attention as hosts of lanthanides (Ln3+) ions and other luminescent ions in recent years. However, controllable synthesis of NaBiF4 nanoparticles remains a challenge....
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

3C–, 4H–, and 6H–SiC crystal habitus and interfacial behaviours in high temperature Si-based solvents

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00521E, Paper
Taka Narumi, Didier Chaussende, Takashi Yoshikawa
Solution growth of SiC is a promising process for producing high-quality SiC crystals; however, control over the morphology of the growth interface under rapid growth conditions is a critical issue....
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

The impact of positional isomerism on electronic and photochromic properties of 1D zinc-based naphthalene diimide coordination polymers

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00025F, Paper
Pengfei Hao, Huihui Zhu, Yue Pang, Junju Shen, Yunlong Fu
The positional isomeric DPNDI ligands can effectively modulate the interfacial contacts of electron donors/acceptors and the efficiency of electronic/photochromic properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Mining the Cambridge Database for theoretical chemistry. Mi-LJC: a new set of Lennard-Jones–Coulomb atom–atom potentials for the computer simulation of organic condensed matter

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00334D, Paper
Angelo Gavezzotti, Leonardo Lo Presti, Silvia Rizzato
A novel, universal Lennard-Jones–Coulomb (LJC) atom–atom force field parametrization reproduces the experimental sublimation enthalpies of 377 molecular crystals drawn from the CSD.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Phase transformations in a double complex salt of ruthenium nitrosyl anion with tetraamine-palladium cation

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00441C, Paper
Gennadiy Kostin, Evgeny Filatov, Denis P Pishchur, Natalia Kuratieva, Sergey Korenev
Second-order phase transformation in double complex salt (DCS) [Pd(NH3)4][RuNO(NO2)4OH] was examined by DSC, single-crystal diffraction and powder diffraction. All data confirms the reversible “order-disorder” phase transition without sharp volume changes...
The content of this RSS Feed (c) The Royal Society of Chemistry




mp

Conductive zigzag Pd(III)–Br chain complex realized by multiple-hydrogen-bond approach

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00332H, Paper
Mohammad Rasel Mian, Unjila Afrin, Hiroaki Iguchi, Shinya Takaishi, Takefumi Yoshida, Tatsuya Miyamoto, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Masahiro Yamashita
Coexistence of zigzag structure and uncommon Pd(III) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)2Br]SO4·3H2O (2), for the first time. Intra-...
The content of this RSS Feed (c) The Royal Society of Chemistry