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Fabrication and evaluation of a flexible antenna device composed of a compatible iron-oxide clay in a PDMS graphene matrix

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React. Chem. Eng., 2024, 9,901-909
DOI: 10.1039/D2RE00352J, Paper
Ameen Abdelrahman, Fouad Erchiqui, Mourad Nedil
We create a flexible and robust conductive polymer composite based on iron oxide and a thin film of clay doped with graphene nanoparticles, and test its application as a wearable device for underground workers.
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Mediated electron transfer in a photo-bioreactor: continuous flow hydroxylation using cytochrome P450 BM3 in NADPH-free conditions

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React. Chem. Eng., 2024, 9,803-815
DOI: 10.1039/D3RE00569K, Paper
Ali Fendri, Donya Valikhani, Joelle N. Pelletier
We designed a proof-of-concept photo-bioreactor enabling continuous flow NADPH-free activation of cytochrome P450 BM3 via mediated electron transfer.
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Dominant role of zeolite in coordination between metal and acid sites on an industrial catalyst for tetralin hydrocracking

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React. Chem. Eng., 2024, 9,940-949
DOI: 10.1039/D3RE00605K, Paper
Jiayao Qi, Hanqiong Jia, Fei Wang, Hang Gao, Bo Qin, Xinwei Zhang, Jinghong Ma, Yanze Du, Ruifeng Li
An effective approach for upgrading light cycle oil (LCO) is the targeted conversion of poly-aromatic hydrocarbons to valuable monoaromatic hydrocarbons.
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Synthesis of hollow sphere structured TiO2 loaded with Ag2O and its photocatalytic activity

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React. Chem. Eng., 2024, 9,861-871
DOI: 10.1039/D3RE00473B, Paper
Hejin Liu, Ying Liu, Xueqin Wang, Peng Qiao, Wenyi Wang, Mei Zhang, Yanxiu Liu, Hua Song
Owing to its high stability and catalytic activity, TiO2 has been widely used as a photocatalyst where its photocatalytic performance can be significantly improved by microstructure regulation and semiconductor loading.
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Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification

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React. Chem. Eng., 2024, 9,950-958
DOI: 10.1039/D3RE00606A, Paper
Xianming Li, Yi Wang, Qiao Yuan, Xintai Chen, Xiaoling Mou, Xiangen Song, Li Yan, Ronghe Lin, Yunjie Ding
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
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Experimental study of CO2 capture from air via steam-assisted temperature-vacuum swing adsorption with a compact kg-scale pilot unit

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React. Chem. Eng., 2024, 9,910-924
DOI: 10.1039/D3RE00460K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
H. M. Schellevis, D. W. F. Brilman
Reactor design and process performance evaluation.
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Temperature effect on the steric and polar Taft substituent parameter values

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React. Chem. Eng., 2024, 9,833-841
DOI: 10.1039/D3RE00500C, Paper
Sindi Baco, Marcel Klinksiek, Mélanie Mignot, Christoph Held, Julien Legros, Sébastien Leveneur
We investigate the influence of temperature by re-evaluating the substituent parameters of the Taft equation applied to the esterification of levulinic acid by methanol and ethanol, and the saponification of methyl and ethyl levulinates.
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A robust data analytical method to investigate sequence dependence in flow-based peptide synthesis

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React. Chem. Eng., 2024, 9,825-832
DOI: 10.1039/D3RE00494E, Paper
Open Access
Bálint Tamás, Pietro Luigi Willi, Héloïse Bürgisser, Nina Hartrampf
A new data analytical method for flow-based peptide synthesis enables robust and quantitative analysis of sequence-dependent difficult couplings.
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General synthesis of secondary imines via reductive coupling of carbonyl and nitro compounds employing a reusable cobalt catalyst

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React. Chem. Eng., 2024, 9,925-929
DOI: 10.1039/D3RE00509G, Paper
Chaochong Zhang, Yurong He, Peng Zhou, Yuandie Ma, Ziliang Yuan, Guoqiang She, Zhe Zheng, Juncheng Hu, Qingqing Jiang, Jason Chun-Ho Lam, Bo Han, Zehui Zhang, Bing Liu
Reusable nitrogen-doped carbon-encapsulated Co nanoparticle catalysts are found robust for the synthesis of secondary imines via the reductive amination of carbonyl compounds with NH3 or directly with nitro compounds.
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The electrochemical oxidation of a thioether to form an API intermediate and the effects of substrate electronics on impurity formation

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React. Chem. Eng., 2024, 9,883-887
DOI: 10.1039/D3RE00632H, Paper
Hamish R. Stephen, Holly Longhurst, Michael Nunn, Christopher D. Parsons, Matthew Burns
Electrochemistry was explored as a means of oxidising a thioether to form a sulfone API intermediate.
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A safe and new strategy for N-arylation of 2,4-thiazolidinediones via microwave irradiation using base catalyst K2CO3 in DMF

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React. Chem. Eng., 2024, 9,842-848
DOI: 10.1039/D3RE00641G, Paper
Ragini C. Patil, Nita M. Khiratkar, Sumeer Ahmed, Joazaizulfazli Jamalis, Aso Hameed Hasan, Malika Berredjem, Sarkar M. A. Kawsar, Ajmal R. Bhat
Green efforts as an alternative to existing conventional methods for providing new tools, knowledge and design of organic synthesis, will contribute to the economy and protecting the environment and health.
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Encapsulation of TixFeyLamOz nanoparticles into NH2-MIL-125(Ti) to fabricate a promising photocatalyst for the C–N coupling reaction

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React. Chem. Eng., 2024, 9,849-860
DOI: 10.1039/D3RE00457K, Paper
Yahya Absalan, Mohammad Rafsanjani Dehghazi, Reza Samavati, Kambiz Souri, Mostafa Gholizadeh
An array of organic compounds and natural products can be synthesized through carbon–nitrogen coupling reactions.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

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React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption

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React. Chem. Eng., 2024, 9,816-824
DOI: 10.1039/D3RE00513E, Paper
Pariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta Chareonpanich
In this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.
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Selective aerobic oxidative C–C bond cleavage using a high-entropy oxide-derived multimetallic catalyst

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React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper
Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O2.
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From microkinetic model to process: understanding the role of the boron nitride surface and gas phase chemistry in the oxidative dehydrogenation of propane

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React. Chem. Eng., 2024, 9,795-802
DOI: 10.1039/D3RE00600J, Paper
Unni Kurumbail, William P. McDermott, Edgard A. Lebrón-Rodríguez, Ive Hermans
In the oxidative dehydrogenation of propane over boron nitride, propylene selectivity is lost due to unselective gas-phase chemistry.
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Biomass-based graphene aerogel for the removal of emerging pollutants from wastewater

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React. Chem. Eng., 2024, 9,753-776
DOI: 10.1039/D3RE00526G, Review Article
Vijayendra Kumar Tripathi, Manish Shrivastava, Jaya Dwivedi, Raju Kumar Gupta, Lokesh Kumar Jangir, Kumud Malika Tripathi
This review article provides a detailed overview of the synthesis techniques of biomass-based graphene aerogels and highlights the influence of fabrication parameters on the performance of the resulting aerogels for wastewater treatment applications.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

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React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Digital Pareto-front mapping of homogeneous catalytic reactions

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React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Surface treatment of magnetite nanoparticle thin films with potassium phosphate for calcium phosphate precipitation

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React. Chem. Eng., 2024, 9,782-786
DOI: 10.1039/D4RE00048J, Communication
Reo Kimura, Kazuto Sugimoto, Iori Yamada, Motohiro Tagaya
The treatment of magnetite nanoparticle thin films with potassium phosphate and their surface reaction with simulated body fluid were in situ monitored by the QCM-D technique, which is suitable for the precipitation of calcium phosphate.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Determination of intermediates and products of the uranyl aerosol formation in UF6 hydrolysis in the gas phase

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian Mark Salvador, Jason M. Richards, Shannon M. Mahurin, Meng-Dawn Cheng, Joshua A. Hubbard
A graphical representation of the uranyl aerosol formation.
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Comprehensive Study of Lumped Kinetic Models and Bio-Oil Characterization in Microwave-Assisted Pyrolysis of Sargassum sp.

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00674C, Paper
Teta Fathya Widawati, Muhammad Fuad Refki, Rochmadi Rochmadi, Arief Budiman
Indonesia, renowned for its tropical marine environments, boasts a rich diversity of macroalgae, with Sargassum being a major contributor. Currently, Sargassum's primary application revolves around alginate extraction, prompting a systematic...
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Automated kinetic model identification via cloud services using model-based design of experiments

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00047A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emmanuel Agunloye, Panagiotis Petsagkourakis, Muhammad Yusuf, Ricardo Labes, Thomas Chamberlain, Frans L. Muller, Richard A. Bourne, Federico Galvanin
Industry 4.0 has birthed a new era for the chemical manufacturing sector, transforming reactor design and integrating digital twin into process control.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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On a seamlessly replicable circular photoreactor for lab-scale continuous flow applications

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00109E, Paper
Yi-Hsuan Tsai, Martin Cattoen, Guillaume Masson, Gabrielle Christen, Lisa Traber, Morgan Donnard, Frederic R. Leroux, Guillaume Bentzinger, Sylvain Guizzetti, Jean-Christophe M. Monbaliu
A cost effective and replicable continuous flow circular photoreactor system is introduced. All body parts of the reactor are 3D-printed and the electronics are purchased from various mainstream suppliers. The...
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A sequential lumped kinetic modelling approach for the co-pyrolysis of plastic mixtures with a heavy refinery intermediate product in a tubular reactor

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00075G, Paper
Open Access
Sebastian-Mark Lorbach, Andreas E. Lechleitner, Teresa Schubert, Markus Lehner
A novel sequential approach for the lumped kinetic modelling of a plastic pyrolysis process in a tubular reactor.
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Hydrogenolysis of furfuryl alcohol over CuCeMgAl mixed metal oxide catalysts derived from layered double hydroxides

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00070F, Paper
Zhihui Wang, Wenbo Li, Xinyao Fu, Chen Zhang, Wei Zhang, Long Huang, Cuiqing Li
LDH-derived CuCeMgAl mixed metal oxide catalysts were synthesized. Ce addition promoted Cu dispersion and improved catalyst basicity, resulting in high activity in furfuryl alcohol hydrogenolysis and high selectivity toward 1,2-pentanediol.
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Scaling-up continuous production of mesoporous silica particles at kg scale: design & operational strategies

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00707C, Paper
Rajashri B. Jundale, Jayesh R. Sonawane, Anil V. Palghadmal, Hemant Kumar Jaiswal, Hital S. Deore, Amol A. Kulkarni
This paper demonstrates a continuous flow pilot-scale production of highly porous mesoporous silica particles (MSPs) via a soft template based technique.
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Correction: Applying quantum mechanics to deconvolute benchtop 1H NMR reaction data

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90015D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiayu Zhang, Tristan Maschmeyer, Ben Shapiro, Sunil Babu Paudel, Matthew C. Leclerc, Jason E. Hein
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Synthesis and kinetic study of 1,3,2-dioxathiolane 2,2-dioxide in microreactors

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00123K, Paper
Ting Wang, Junnan Wang, Chengxiang He, Zhongdong Wang, Yating Li, Chunying Zhu, Youguang Ma, Taotao Fu
1,3,2-dioxathiolane 2,2-dioxide (DTD) is an essential intermediate in organic synthesis and plays a vital role in improving the performance and service life of lithium-ion batteries. A large amount of heat...
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Generation of nitrogen by means of electrochemical oxygen depletion

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00104D, Paper
Open Access
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Dominik Sachse, Basil Noha Chelachottil, Andreas Glüsen, Martin Müller, Uwe Rau, Ralf Peters
Electrochemical oxygen reduction enables a high depletion of the oxygen content with very high Faraday efficiency at the same time.
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Efficient removal of dibutyl phthalate from aqueous solutions: recent advances in adsorption and oxidation approaches

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00055B, Review Article
Yaqi Wang, Jiawei Wu, Wenju Zhang, Linyun Zhong, Dan Zhang, Siqi Yan, Junyou Shi
Dibutyl phthalate (DBP), a recognized endocrine-disrupting contaminant, poses substantial environmental challenges due to its persistence, resistance to degradation, and potential for bioaccumulation.
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Experimental Investigation of Mass Transfer in NH3 SCR Over Self-Supporting Cu-ZSM-5 Foam

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00533J, Paper
Risha Raju, Kuruvilla Joseph, K. Prabhakaran, A. Salih
Selective catalytic reduction of NOx by NH3 is an emerging technology for emission control applications worldwide. The development of structured catalysts for process intensification is of growing interest in catalytic...
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Shoppers Stop aims to scale up beauty distribution, bring more international brands to India

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 15:38:48 +0530

Shoppers Stop expects Global SS Beauty to end this fiscal with revenues to the tune of ₹220-250 crore


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LatentView Analytics Q2FY25 net profit grows 17%

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 16:50:20 +0530

The acquisition of Decision Point Analytics has concluded and integration of the GTM and delivery teams is underway


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SIS Ltd eyes strategic acquisitions in India

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 19:19:36 +0530

Plans listing of cash logistics joint venture


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Create SECI-like entity for efficient long-term procurement of green hydrogen: TERI

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 19:35:48 +0530

The policy think tank also recommends creating an SPV for each industrial segment for development of pilot plants


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Tata Motors’ Q2 profit falls 11.18% due to weak performance

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 19:51:28 +0530

Lower sales volumes, supply constraints and underperformance of JLR, PVs resulted in the decline in profits


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Coca-Cola set to launch Vitaminwater in India

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 21:07:58 +0530

Company’s focus on premium hydration portfolio with an expected quick commerce first launch in top cities.


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Pantomath’s Bharat Value Fund invests ₹235 cr in Haldiram Bhujiawala

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 21:38:20 +0530

The company will use the funds to expand its manufacturing and markets outside East and North-East India


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India’s steel exports rise 11% in October; imports moderate for the first time this fiscal

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 18:04:10 +0530

Indian steel exports rose to 0.44 million tonnes in October, while imports moderated for the first time this year to 0.98 million tonnes as India tightened import norms


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Data Patterns reports 12% decline in PAT in Q2’25

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 18:50:59 +0530

Revenue for the quarter was impacted due to deferment of delivery schedule by the customer of completed products


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Debt at Vedanta Resources cut by $4.7 billion: Anil Agarwal

By www.thehindubusinessline.com
Published On :: Sun, 10 Nov 2024 15:24:00 +0530

Vedanta’s Agarwal says the company has delivered its highest-ever EBITDA of ₹Rs 20,639 crore in the first half of the current fiscal year


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Ashok Leyland sees a positive shift in the e-bus procurement market with reasonable bidding rates

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 09:02:07 +0530

Dheeraj Hinduja expressed confidence that these initiatives are helping establish a more stable and predictable framework for procuring electric vehicles, which will benefit the sector’s long-term growth


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