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Scuttling people’s right to information

There is a severe backlash against the RTI Act, which has just entered its 20th year, and against those who use it




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Spotlighting the work of the Economics Nobel winners

AJR have emphasised the role of institutions in development but there has been criticism of this approach as privileging western liberal institutions




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Methodology of the MIT-SOG-Lokniti-CSDS pre-poll survey on Maharashtra




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Maharashtra Assembly elections 2024: A mixed assessment

It is quite clear that voters in Maharashtra are not swayed by either of the two coalitions yet. While a greater share of voters are satisfied rather than dissatisfied with the incumbent government, they expressed concerns about unemployment, inflation, and corruption, which are likely to dominate the electoral discourse




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Maharashtra elections 2024: Unemployment and inflation are main concerns of voters

With public sentiment leaning towards addressing immediate economic challenges, the effectiveness with which each coalition communicates its vision will be crucial in determining its success.




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Maharashtra elections 2024: On Maratha reservation, there is near social consensus

There is no battle between the Marathas and the OBCs on the issue of reservation to Marathas, as of now




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Maharashtra elections 2024: Comparing the governments led by Thackeray and Shinde

While the previous MVA govt. has a higher rating in terms of overall development of Maharashtra and social harmony, the incumbent Mahayuti govt. has edge in the areas of condition of hospitals, supply of electricity, drinking water, and roads.




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Maharashtra elections 2024: Six in 10 Maharashtrians relate more to the national identity than the regional

Two in 10 believe that they are Maharashtrian first, Indian later. A little over one-sixth of the respondents favoured both identities equally.




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Maharashtra elections 2024: Keen contest on the cards as caste equations shape up ahead of polls

While the Mahayuti is popular among the upper castes, Marathas, and those who are economically well-off, the MVA seems to be the first choice among Muslims, Buddhists, Adivasis, and farmers.




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Maharashtra elections 2024: Shinde-led Mahayuti government perceived as high on corruption, not bad on performance

Two in five (42%) voters believed that corruption had increased under the Mahayuti government.




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Fighting high-stakes bypolls

Wayanad, Palakkad, and Chelakkara will all witness tough three-way contests




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Probability, choice, and reason [electronic resource] / Leighton Vaughan Williams.

Boca Raton, FL : CRC Press, 2022.




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History of Banach spaces and linear operators [electronic resource] / Albrecht Pietsch

Boston, Mass. : Birkhäuser ; 2007




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Kudla Samskrutika Prathishtana to hold ‘Mangaluru Street Food Festival’ from January 15 to 19




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MRPL receives awards in eight categories in the PRCI conclave




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Collective action can promote culture of honesty, Maharashtra Upa Lokayukta




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Wine merchants deny allegations of giving money for Maharashtra polls




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Air India flight from Mangaluru to Mumbai departs after over-three-hour delay

An Air India official attributed the delay to ‘technical issues’




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Those snatching central university teachers' right of reservation lecturing others: Kharge

RTI query has revealed that of the 18,940 sanctioned posts in 46 central universities, 27% teaching posts are vacant; 38% seats for the Scheduled Castes (SCs), Scheduled Tribes (STs) and Other Backward Classes (OBC) are not filled




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NEET-UG irregularities: CBI registers fresh case, books student caught taking test for aspirant

Nishika Premprakash Yadav, a second-year medical student, allegedly appeared at the D.Y. Patil (deemed to be) University centre in Navi Mumbai on May 5 on behalf of one Mayuri Manohar Patil




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Vistara to make last flight today before Air India merger

Vistara, a joint venture between Tata Group and Singapore Airlines, will fully merge with Air India, also owned by Tata Group




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Carl Zeiss to help 1,00,000 persons with nearsightedness in rural Karnataka

The German company inaugurated its maiden Global Capability Centre (GCC) in India in Bengaluru




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'Kutrame Thandanai' review: thoughtfully made, but something’s missing




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Aanandam: a light-hearted, ‘college days’ drama




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Ajoy Mehta leaves behind a more compliant real estate sector in Maharashtra

The Maharashtra Real Estate Regulatory Authority’s outgoing chairman did not shy away from wielding the regulatory whip, ensuring that builders realised that homebuyers have the right to expect timely delivery of their houses, with all the promised amenities




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Pune’s home sales value surges 19% in Q3 2024 despite a slight dip in transactions

Based on data from the Inspector General of Registration (IGR), the city’s home sales value jumped 19 per cent year-on-year (YoY), reaching ₹13,865 crore




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The texture of thoughts



  • Life & Style

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Artisans steal the limelight




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Shaping cycles with light: a regiodivergent approach to tetracyclic aza-aromatic compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01606H, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Mañas, Belén Ibarra, Estíbaliz Merino
We present a novel visible light-promoted regiodivergent cyclization, enabling the selective synthesis of distinct azapolyaromatic regioisomers from 2-alkynlazobenzenes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01767F, Research Article
Gui-Xiang Zhou, Cheng Hou
This study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01702A, Research Article
Yiting Zhou, Bin Liu
We present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light mediated selective phosphonylation modification of tryptophan residues in oligopeptides

Org. Chem. Front., 2024, 11,6287-6292
DOI: 10.1039/D4QO01028K, Research Article
Wenfang Xiong, Junye He, Jinyao Liu, Peiru Chen, Shiqi Xu, Yipeng Liu, Shiting Chen, Yuanyuan You, Zhenyu Chen, Jinwu Zhao
A direct C2-H phosphonylation strategy driven by visible light for specific modification of tryptophan-containing peptides has been reported, providing a plethora of phosphorylated tryptophan-containing peptides
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives

Org. Chem. Front., 2024, 11,6380-6384
DOI: 10.1039/D4QO01329H, Research Article
Hang Luo, Fangnian Yu, Luqing Lin
The photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A cucurbit[8]uril-mediated host–guest complex for red-light photocatalysis

Org. Chem. Front., 2024, 11,6327-6332
DOI: 10.1039/D4QO01492H, Research Article
Weiquan Xu, Yinghao Du, He Ma, Xingchen Tang, Jiang-Fei Xu, Xi Zhang
Two-step host–guest complexation can occur between an elongated dye and CB[8], leading to the formation of CB[8]@2TPP and 3CB[8]@2TPP sequentially. Of these species, 3CB[8]@2TPP in particular can act as an efficient red-light photocatalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects

Org. Chem. Front., 2024, 11,6393-6410
DOI: 10.1039/D4QO01451K, Research Article
Jiaoyang Liu, Li-juan Huang, Zeang Sun, Juan Li
DFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis

Org. Chem. Front., 2024, 11,6573-6588
DOI: 10.1039/D4QO01644K, Review Article
Zhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You Huang
Recent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01870B, Research Article
Lijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng Yu
We developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01734J, Research Article
Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing Li
Transition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Usha Rk on the visual splendour of Adi Shankaracharya’s Ashtakams

Usha Rk, former director of Jawaharlal Nehru Cultural Center (JNCC) of the Embassy of India in Moscow, shares her vision of bringing Adi Shankaracharya’s Ashtakams to life through a dance form




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Moneylenders push family to end life, man his daughter die, wife survives

Head of the family was being harassed and intimidated by two Nizamabad-based moneylenders




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₹4.8 crore loan fraud scheme unearthed at SBI Sanathnagar, eight more arrested




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Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad

Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika




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Vigil mounted in erstwhile Adilabad district following ‘sighting’ of a tiger




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I will prove my that my retention was right decision: Shashank

Shashank established himself as a fine finisher for Punjab Kings in the last season where he was their top run-getter with 354 runs at a strike rate of 164.65. He averaged 44.25.




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NZ series whitewash might awaken sleeping giant India: Josh Hazlewood

“The results are obviously good for us in a way,” said the Aussie fast bowler.




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Denish leads Assam’s fightback against Tamil Nadu

The skipper compiles a patient unbeaten 54 and forges an unbroken 71-run stand with southpaw Sibsankar Roy, denying the opposition bowlers a breakthrough till close of play