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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00513A, Research Article
Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong
The novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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ICRIER study explores untapped potential of India’s turmeric sector

Offers roadmap as the country dominates the global market with 70% market share




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Crude oil futures down due to profit-booking after recent surge

Market fears that the escalating tensions could disrupt crude oil supplies from West Asia as Iran is a major producer of crude oil in the world market




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Indian rice exports get delayed at ports as Customs officials hold up consignments

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice




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Crude oil futures dip amid easing Middle East tensions

Brent and WTI oil futures saw declines of over 3%, with MCX crude oil futures also experiencing significant drops.




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India’s oilmeal exports down by 8.5% in H1 of current fiscal

Shipments hit on lower rapeseed meal, castormeal consignments leaving the country




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Shift toward EVs could disrupt global oil market: International Energy Agency report

As China's rapid switch to electricity plays a significant role in disrupting the oil market, oil companies find they can sell more of their product to India




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Global Organic Textiles Standards bans 5 Indian cotton firms for faking documents

Two firms used non-existent shipping firms to show transactions, the others submitted fake transaction certificates




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Crude oil futures rise amid declining US inventories

December Brent oil futures rose to $74.37, while November WTI futures climbed to $70.59.




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India’s rice procurement drops by a half during October 1-15

Purchases for buffer stocks hit by storage and other issues in Punjab and Haryana




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Crude oil futures rise as US inventories decline 

Market players are also assessing the supply risks from West Asia following the tensions in the region




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Crude oil futures rise as China cuts key lending rates

In India, October crude oil futures traded slightly lower at ₹5,850




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Weather experts divided over emergence of La Nina

APEC Climate Centre predicts the weather event from December




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Crude oil futures slip as industry data shows increase in US inventory 

US crude oil inventories rose by 1.64 million barrels for the week ended October 18. Market estimates had earlier pegged increase at 0.7 million barrels




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Board to convene consumers meeting next week over falling natural rubber prices

Rubber Board officials said prices exceeded Rs₹200 on June 11 but plummeted 24 per cent to ₹187 per kg by October 21. The Board may ask consumers to proactively purchase in the domestic market




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Crude oil trades higher as market monitors developments in West Asia 

At 9.56 am on Friday, December Brent oil futures were at $74.50, up by 0.16 per cent, and December crude oil futures on WTI (West Texas Intermediate) were at $70.28, up by 0.13 per cent




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Easing West Asia tensions bring back overseas tea buyers to Kochi 

Sales percentage increases as Russian buyers turn active




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Crude oil trades higher as industry data shows decrease in US inventories 

Official data on crude oil inventory level in the US is expected later on Wednesday




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Praveena Rai takes charge as CEO of MCX

Praveena Rai succeeds P S Reddy, who completed his five-year tenure in May 2024




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Crude oil trades higher ahead of US Presidential poll

Market also focussed on outcome of US Federal Reserve meeting later in the week




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Crude oil futures fall as industry data shows inventory gain in US 

Market eyes results of the US presidential election




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Crude oil gains as market analyses Trump’s victory in US Presidential election

The Trump administration could stimulate economic growth in the US, which could help boost consumption demand in that country, say analysts




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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




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Coconut water, evening walks & meditation




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Golden morning, balanced diet & tennis




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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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Calisthenics, rock-climbing and laughter




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When patients are caught in the crossfire

The Executive Director of Doctors without Borders writes on MSF’s fight for healthcare and dignity for people in Gaza war




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Union Budget: Hopeful of an investment blueprint for healthcare

India’s healthcare sector needs government-private sector partnerships, funding for screening and diagnostics and lower taxes to enhance services




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A pitch to walk the fine line between innovation and access

 Ahead of USTR’s Special 301 report, India campaigns for flexibilities in international trade laws




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Funding healthcare: Stable investment in a volatile market

Investors are increasingly focusing on India’s healthcare sector for stable returns, with promising growth and investment opportunities




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Gen AI: Pharma’s new frontier

From clinical trials to cures, AI is set to transform lives faster with underutilized health data




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‘Yes! We can end TB’

Estimates say, 10.6 million people fell ill with TB in 2022 and 1.3 million people died from it




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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The rising global tide of genomics for public health

Genomics is advancing our understanding of the genetic basis of health and disease and shaping strategies to promote population health.




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MMA, Wim Hof breathing and intermittent fasting

Boost your day with Wim Hof breathing, meditation, MMA, fasting, and outdoor exercise for optimal health and wellness




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More than just a number: A call to improve adverse event reporting

Heal the hurt: Redressal and support are critical to keep the faith in the system from breaking down