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Comparative techno-economic and life cycle assessment of electrocatalytic processes for lignin valorization

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Published On ::

Green Chem., 2024, 26,11303-11315
DOI: 10.1039/D4GC01963F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zahra Ebrahimpourboura, Manish Mosalpuri, Cheng Yang, Aditya Ponukumati, Corey Stephenson, Marcus Foston, Mark Mba Wright
This study explores the potential of using electrochemical (EC) methods for valorizing lignin, a lignocellulosic biomass cell wall component, into biofuels and high-value compounds.
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Substrate-controlled regioselective hydrophosphorylation of allenes to enable photocatalytic synthesis of alkenylphosphoryl compounds

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Green Chem., 2024, 26,11272-11279
DOI: 10.1039/D4GC03588G, Paper
Tian-Ming Yang, Xin-Lu Fan, Wei Shi, Xuefei Zhao, Xu-Hong Hu
A visible-light-induced hydrophosphorylation of allenes with H-phosphine oxides is demonstrated to give a diverse range of alkenylphosphoryl compounds in a highly stereoselective and regioselective manner.
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Iron/photoredox dual-catalyzed redox-neutral double decarboxylative C(sp3)–C(sp3) cross-coupling

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Green Chem., 2024, 26,11334-11339
DOI: 10.1039/D4GC04523H, Paper
Qi Zhang, Shanghui Wu, Xuesong Wu
An efficient iron porphyrin/photoredox dual catalytic system for the double decarboxylative radical C(sp3)–C(sp3) cross-coupling under redox-neutral and mild conditions.
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Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
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A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts

By pubs.rsc.org
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Green Chem., 2024, 26,11351-11363
DOI: 10.1039/D4GC04447A, Paper
Open Access
Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen Li
A paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.
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Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)

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Green Chem., 2024, 26,11125-11131
DOI: 10.1039/D4GC05070C, Communication
Open Access
Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin, Stephen J. Connon
The evaluation of a library of phase transfer catalysts in the alkaline hydrolysis of polyethylene terephthalate revealed the key interplay between catalyst structure/properties and the reaction conditions.
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Biomass-derived polyol esters as sustainable phase change materials for renewable energy storage

By pubs.rsc.org
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Green Chem., 2024, 26,11259-11271
DOI: 10.1039/D4GC03460K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Magdalena Gwóźdź, Marta Markiewicz, Stefan Stolte, Anna Chrobok, David R. Turner, Karolina Matuszek, Alina Brzęczek-Szafran
Innovative thermal battery technology has the capability to revolutionize the renewable energy storage market.
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Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide

By pubs.rsc.org
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Green Chem., 2024, 26,11106-11124
DOI: 10.1039/D4GC04094E, Tutorial Review
Qiang Yuan, Xiao Cai, Weiping Ding, Yan Zhu
The homogeneous and heterogeneous catalyst systems applied in N-formylation reaction of amines and CO2 reaction from both homogeneous and heterogeneous systems are summarized.
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Correction: Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11364-11364
DOI: 10.1039/D4GC90117G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu Hwang
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Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

By pubs.rsc.org
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Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
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Converting waste PET into dimethyl terephthalate and diverse boronic esters under metal-free conditions

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Green Chem., 2024, 26,11132-11139
DOI: 10.1039/D4GC03358B, Communication
Minghao Zhang, Yunkai Yu, Zhuo Wang, Shaoyu Zhang, Xiong Gao, Jiaming Liu, Jing Li, Weixiang Wu, Qingqing Mei
An ionic liquid-catalyzed metal-free approach was proposed to upcycle waste PET into dimethyl terephthalate and boronic esters, facilitated by multiple hydrogen bonds.
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Reusable Co-catalysts for general and selective α-alkylation of nitriles with alcohols

By pubs.rsc.org
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Green Chem., 2024, 26,11140-11146
DOI: 10.1039/D3GC04436J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhuang Ma, Zechen Wu, Carsten Kreyenschulte, Stephan Bartling, Henrik Lund, Matthias Beller, Rajenahally V. Jagadeesh
A general cobalt-catalyzed α-alkylation of nitriles with alcohols is reported.
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Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode

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Green Chem., 2024, 26,11328-11333
DOI: 10.1039/D4GC04617J, Paper
Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi, Toshio Fuchigami
A novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds and dehalogenation of various aromatic halides.
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Formaldehyde dehydrogenase SzFaldDH: an indispensable bridge for relaying CO2 bioactivation and conversion

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03745F, Communication
Boxia Guo, Xiuling Ji, Yaju Xue, Yuhong Huang
A novel formaldehyde dehydrogenase with outstanding reductive activity and kinetic properties was discovered for CO2 bioactivation and conversion.
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Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
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Utilize rather than create: transforming phthalonitrile resin into N-rich hierarchical porous carbon for supercapacitor materials

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04103H, Paper
Yi Li, Qiancheng Liu, Qian Zhang, Xiaoxiao Li, Yang Yang, Pan Wang, Kui Li, Ying Li, Fei Zhong, Qi Liu, Yun Zheng, Xulin Yang, Peng Zhao
The “utilize rather than create” strategy employs the reaction product (RPH) as the precursor and the by-product (KCl) as the template for the synthesis of N-rich hierarchical porous carbon for high performance supercapacitor materials.
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CdS/Mg–Fe layered double hydroxide: a versatile heterogeneous photocatalyst for the acylation of indoles with α-keto acids

By pubs.rsc.org
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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05239K, Paper
Jun-Bo Wang, Tong Yue, Ling Xu, Zhi-Qiang Hao, Zhan-Hui Zhang
The composite CdS/Mg–Fe layered double hydroxide was constructed and confirmed as an efficient recyclable heterogeneous photocatalyst for C-3 acylation of indoles with α-keto acids under light irradiation at room temperature.
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Bio-derived solvent-based automated dispersive liquid–liquid microextraction for pretreatment of diamide insecticides in environmental water samples

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04467C, Paper
Jin Liu, Yuxin Wang, Rui Song, Yukun Yang, Li Li, Xu Jing
The automatic dispersive liquid–liquid microextraction based on bio-derived solvents achieved great environmental greenness, high-throughput operation, and low human error compared to the present sample pretreatment methods for diamide insecticides.
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Ball milling-promoting difunctionalization of alkynyl sulfonium salts with sulfinic acids towards (Z)-1,2-disulfonylethenes

By pubs.rsc.org
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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04895D, Paper
Li-Hua Yang, Bei Li, Lin Chen, Wen-Shi Yao, Han-Yue Peng, Sha Peng, Long-Yong Xie
A simple ball milling-mediated disulfonylation of alkynyl sulfonium salts with sulfinic acids for the stereoselective synthesis of various (Z)-1,2-disulfonylethenes has been developed under catalyst-, additive- and solvent-free conditions.
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1D/3D hierarchical carbon skeleton confined NiFe nanoparticles with optimized three-phase interfaces as tri-functional electrocatalysts

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04466E, Paper
Yuqing Chen, Binyang Liu, Xuesong Liu, Jiahui Ye, Kuan Deng, Chengjie Wu, Qiang Niu, Tao Yang, Wen Tian, Junyi Ji
Multilevel 1D/3D CNTs/carbon spheres with hydrophilicity can promote the infiltration of an electrolyte into the interior and guide bubble diffusion, thus constructing an optimal gas–solid–liquid interface to enhance the electrocatalytic process.
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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
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Comparison of microbial strains as candidate hosts and genetic reservoirs for the valorization of lignin streams

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03876B, Paper
Open Access
Rebecca A. Wilkes, Andrew J. Borchert, Valentina E. Garcia, Gina M. Geiselman, Sarah Liu, Adam M. Guss, Joshua K. Michener, Daniel R. Noguera, Eiji Masai, John M. Gladden, John Ralph, Gregg T. Beckham
Comparison of microbial strains for tolerance to and catabolism of lignin stream constituents toward evaluating microbial hosts for lignin bioconversion.
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CO2 switchable solvents for sustainable dissolution, modification, and processing of cellulose materials: a critical review

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04032E, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peter McNeice, Ben L. Feringa
CO2 switchable solvents provide a convenient and environmental method to dissolve and process cellulose.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

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Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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Mechanoenzymatic Hydrolysis of Cotton to Cellulose Nanocrystals

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Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05113K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sandra Kaabel, Inge Schlapp-Hackl, Eero Kontturi, Mauri A. Kostiainen
Solid-state mechanoenzymatic approaches for the production of cellulose nanocrystals from cotton were examined using three commercially available cellulase systems from Trichoderma reesei, Aspergillus niger and a Cellic CTec2 cellulase blend....
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Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05207B, Paper
Yao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming Zhang
The direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.
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Of corporates and newsrooms​

By www.thehindubusinessline.com
Published On :: Mon, 23 Feb 2015 15:21:47 +0530


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Education vs HRD

By www.thehindubusinessline.com
Published On :: Fri, 04 Nov 2016 16:32:44 +0530

​The nomenclature ​has changed but has it made a difference big enough to change things?


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The battle over Chengalpet

By www.thehindu.com
Published On :: Sat, 23 Apr 2016 17:38:17 +0530

Vijay starrer Theri not releasing in the theatres of Chengalpet has spurred a war or words that threatens to divide the industry


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Athlete to actress

By www.thehindu.com
Published On :: Sat, 21 May 2016 15:32:58 +0530

In this column, the photographer tells us how this picture came to be. This week, we feature actress Lakshmi Priyaa


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Thaai Sollai Thattathe(1961)

By www.thehindu.com
Published On :: Sat, 28 May 2016 13:56:02 +0530


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A tale of two tattoos

By www.thehindu.com
Published On :: Sat, 04 Jun 2016 16:57:27 +0530

The tough choice of choosing a book or its cinematic adaptation


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Innovations... and collections

By www.thehindu.com
Published On :: Sat, 11 Jun 2016 15:57:21 +0530

Only a professional approach can extend the careers of new-age directors and producers


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Athisaya Thirudan (1958)

By www.thehindu.com
Published On :: Sat, 18 Jun 2016 15:22:27 +0530

Gemini Ganesan, Savithri, T. S. Balaiah, K. A. Thangavelu, T. P. Muthulakshmi, Baby Rajakumari, K. Natarajan, V. N. Elumalai


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Kabali fever grips the nation

By www.thehindu.com
Published On :: Sat, 16 Jul 2016 15:37:16 +0530

Press, TV, theatre owners, distributors and audiences prepare for the arrival of the biggest film of the year


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'Magizhchi' at the box-office

By www.thehindu.com
Published On :: Sat, 30 Jul 2016 15:54:34 +0530

Kabali has had the biggest-ever opening for a Tamil film


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Neengatha Ninaivu (1963)

By www.thehindu.com
Published On :: Sat, 20 Aug 2016 15:18:44 +0530

Star Cast: S.S. Rajendran, Kalyankumar, R. Vijayakumari, Pushpalatha, V.K. Ramasami, T.V. Kumudhini, C.K. Nagesh, C.R. Manorama, S. Ramarao, ‘Master’ Mohan, ‘Baby’ Savithri


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Return of the native

By www.thehindu.com
Published On :: Sat, 03 Sep 2016 15:40:01 +0530

Tamil Nadu’s B and C centres are experiencing a revival with films like Thirunaal, Dhilluku Dhuddu and Dharma Durai becoming hits


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Feasting at festivals

By www.thehindu.com
Published On :: Sat, 22 Oct 2016 18:48:21 +0530

The recent film festivals at Busan and London had a number of interesting films


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How Rang De Basanti created a challenging storyboard for future filmmakers

By www.thehindu.com
Published On :: Thu, 15 Sep 2022 17:28:02 +0530

Rang De Basanti set a trend in filmmaking with its unconventional narrative style


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Virat-AB like Batman-Superman, says Chris Gayle

By www.thehindu.com
Published On :: Tue, 17 May 2016 11:13:33 +0530


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Unglamorous Green Park’s shot at big-ticket cricket

By www.thehindu.com
Published On :: Tue, 17 May 2016 22:50:08 +0530


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‘They are Batman and Superman’

By www.thehindu.com
Published On :: Tue, 17 May 2016 22:53:08 +0530


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Supergiants prevail in a rain-hit match

By www.thehindu.com
Published On :: Wed, 18 May 2016 01:20:48 +0530

Dhoni’s men score 76 for one in 11 overs, well ahead of the D/L requirement of 57, when play is called off.


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A run-feast anticipated as race hots up

By www.thehindu.com
Published On :: Wed, 18 May 2016 23:22:14 +0530

Gujarat Lions has stayed on course by resorting to percentage cricket.


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Daredevils face Sunrisers in do-or-die IPL match

By www.thehindu.com
Published On :: Thu, 19 May 2016 17:14:56 +0530

The Sunrisers, on the other hand, are virtually through to the play-offs and they are on top of the table with 16 points from 12 games.


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Virat and AB are playing a different game: Watson

By www.thehindu.com
Published On :: Thu, 19 May 2016 23:12:20 +0530


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Pune vs Punjab: Cellar-dwellers battle to avoid wooden spoon

By www.thehindu.com
Published On :: Sat, 21 May 2016 01:08:54 +0530


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Lions win will seal MI’s fate

By www.thehindu.com
Published On :: Sat, 21 May 2016 01:12:56 +0530

Raina’s side could opt for a spinner-friendly track to counter the defending champion's strengths.


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Captain Dhoni at his belligerent best

By www.thehindu.com
Published On :: Sun, 22 May 2016 03:10:04 +0530

Final-ball finish helps Supergiants consign Kings XI to last spot


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