en

Sattva Group plans ₹14,000-crore investment to build 80 m sft of residential, commercial projects

Co-living space a focus area for Sattva Group, eyes co-living capacity of 15-16,000 beds by year-end




en

Biz families of Tier-II cities drive-up ultra luxury residential demand in North & West India

‘The Dahlias’ – realty major DLF’s upcoming super-luxury residential project in Gurgaon with units priced upwards of ₹80 crore – is witnessing active buyer interest from some of these Tier-II city-based business families




en

Brigade to invest ₹800 crore to develop 1 million sq ft residential apartments in West Chennai

West Chennai is one of the fastest growing parts of the city




en

IBBI pushes for land authorities to join CoC meetings in real estate insolvency cases

Releases discussion paper to revamp real estate insolvency, addressing seven key areas




en

Non-IT services tenants, SEZ conversions aid occupancies in REITs

Brookfield India Real Estate Trust, which was hit by exits by tenants in the IT and IT services segments, has only 26 per cent of its tenant base in the technology sector




en

Exquisiteness that holds charm




en

Heavenly aromas

This new fragrance boutique offers you scented candles, fragrances and accessories




en

Earnest show of talent




en

Arundhati Menon: The rich weave of Madras




en

When destroyers proved to be the saviours

Forensic expert P. Chandrasekaran credits termites as unifiers of Pathur Nataraja with his consort




en

Woven with care




en

How China came to Chennai

Anusha Parthasarathy peeps into the oldest crockery shops and finds how they have changed to suit changing times



  • History & Culture

en

Wooden toys for Navaratri at Tanirikaa




en

Showcasing authentic Tamil art




en

Experimenting with beads

IT professional Anitha Sanju makes customised jewellery under the brand Glitter n’ Hues




en

Odds, ends and more

OFFBEAT Here’s a Potti Kadai that stocks a variety of things, including eco-friendly products




en

Persian influence abounds in Bidri ware




en

Catch up with the latest trends




en

Renowned sculptor Jasuben Shilpi passes away in Gujarat




en

A threadbare existence

Artisans and their indigenous crafts are being pushed to the brink due to fierce competition and lack of cohesive government support




en

ART of investment

London-based Anders Petterson, who was in city to launch the Chennai Art Club recently, shared his views on art investment in the global market




en

Students develop skills at handicrafts-training camp




en

Channapatna dolls come a-knocking: Karthik Vaidyanathan brings his store, Varnam, to Chennai

At Varnam, entrepreneur Karthik Vaidyanathan brings innovative creations by Karnataka’s Channapatna artisans to Chennai, from traditional toys to home decor pieces



  • Life & Style

en

Label Erode’s debut collection blends the GI-tagged jamakkalam with Jimi Hendrix’s music

How a Mumbai-based fashion label is reviving the GI-tagged Bhavani jamakkalam through its debut collection




en

An efficient approach to AviCys analogues via regio- and stereoselective hydrosulfuration of ynamides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01572J, Research Article
Zhenjia Zhang, Zhe Ding, Jinhua Yang, Yongli Zhao, Zhenguang Zhao, Can Liu, Norman Metanis, Junfeng Zhao
A novel synthetic strategy for the construction of AviCys analogues via a highly efficient regio- and stereoselective hydrosulfuration of ynamides was reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Synthesis of C-glycosides enabled by palladium-catalyzed glycosylation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01619J, Review Article
Wenli Tong, Jie-Ping Wan, Jianchao Liu
This review highlights the recent progress in palladium-catalyzed C-glycosylation reactions for the synthesis of C-glycosides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

All-thiophene dendrimers based on cyclooctatetrathiophene: synthesis and aggregation-induced emission (AIE) features

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01525H, Research Article
Pengfei Wang, Chunmei Zhao, Shuai Qiu, Wan Xu, Chunli Li, Zhiying Ma, Wei Cao, Li Xu, Hua Wang
A novel class of all-thiophene dendrimers with obvious AIE emissions was designed and synthesized based on saddle-shaped cyclooctatetrathiophene (COTh) as building blocks.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Isomeric diazapyrene–thiophene conjugated systems: synthesis, characterization, and transport properties

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01305K, Research Article
Open Access
Honglei Li, Guodong Zhao, Qingxin Tang, Hongkun Tian, Lixiang Wang
Three key dihalogenated diazapyrene intermediates were synthesized and the corresponding isomeric co-oligomers with bithiophene demonstrated distinct position-dependence in the crystal structures, and optoelectronic and charge transport properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01496K, Research Article
Dawei Gong, Caiyu Gao, Qixuan Li, Yufei Li, Lina Zhao, Degong Kong
Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Multi-step chirality transfer and racemization kinetics of pillar [5]arenes by tuning the halogen substituents on the rims

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01799D, Research Article
Lizhi Fang, Xiaowen Guan, Yanling Shen, Dayang Zhou, Long Chen, Xiaochuan Chen, Wanhua Wu, Leyong Wang, Cheng Yang
Halogen-substituted pillar[5]arenes exhibited hindered hydroquinone subunit flipping, enabling enantioseparation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

C–H acylation as an enabling tool to tag phenolic drugs

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01505C, Research Article
Open Access
Carlota Girón-Elola, Arkaitz Correa
A Pd-catalyzed directed C–H acylation of a collection of intricate phenol-containing compounds with ethanol and other alcohols and aldehydes is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Shaping cycles with light: a regiodivergent approach to tetracyclic aza-aromatic compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01606H, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Mañas, Belén Ibarra, Estíbaliz Merino
We present a novel visible light-promoted regiodivergent cyclization, enabling the selective synthesis of distinct azapolyaromatic regioisomers from 2-alkynlazobenzenes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01609B, Research Article
Rongrong Yu, Song-Zhou Cai, Xianjie Fang
We report a Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes. In the absence of Al Lewis acid, the reaction predominantly yields ring-opened allylic nitrile products while the addition of Lewis acid favors the formation of cyano-substituted cyclopropane products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01312C, Research Article
Yi Chen, Jianing Wu, Yongzheng Ding, Hanmin Huang
Transition metal-catalyzed hydrocarbonylation of alkenes has been widely studied; however, the hydrocarbonylation reaction that took place between two alkenes has been largely unexplored.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01628A, Research Article
Feng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min Lin
A novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01767F, Research Article
Gui-Xiang Zhou, Cheng Hou
This study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01702A, Research Article
Yiting Zhou, Bin Liu
We present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01570C, Research Article
Fei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing Wu
A novel palladium-catalyzed cascade reaction of o-iodostyrenes, internal alkynes and formates to access various indene-1-acetates through sequential double carbopalladation and aryloxycarbonylation under a palladium/air system was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Synthesis of bambusurils with perfluoroalkylthiobenzyl groups as highly potent halide receptors

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01746C, Research Article
Open Access
Matúš Chvojka, Hennie Valkenier, Vladimír Šindelář
Four new fluorinated bambusuril macrocycles were prepared to show exceptional high binding affinity towards halide anions in acetonitrile.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01562B, Research Article
Xinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin Fan
A versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01841A, Research Article
Xunhua Wang, Jianhua Wang, Xiaoxun Li
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01638F, Research Article
Aijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei Ding
A highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article
Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Towards the total synthesis of mandelalide B: construction of the tetrahydrofuran/α-hydroxyl lactone fragment

Org. Chem. Front., 2024, 11,6353-6357
DOI: 10.1039/D4QO01433B, Research Article
Jia-Lei Yan, Jie Yu, Yingying Cheng, Mingze Yang, Zhengshuang Xu, Tao Ye
A stereocontrolled synthesis of the tetrahydrofuran/α-hydroxy lactone fragment of mandelalide B has been accomplished. The synthesis features a Horner-Wadsworth-Emmons fragment assembly strategy and a highly stereospecific iodine-induced cyclization.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H

Org. Chem. Front., 2024, 11,6333-6339
DOI: 10.1039/D4QO01147C, Research Article
Jia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian Hu
The first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Org. Chem. Front., 2024, 11,6340-6346
DOI: 10.1039/D4QO01376J, Research Article
Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong Lian
We developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry