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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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In a state of urgency




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Of govt departments and RTI




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Looking for the hidden logic




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The highs and lows of plant parenthood

It helps one realise the value of soil and look at the sun with deep reverence




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Samen delen across the fence

Striking a rapport with neighbours in the Netherlands




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Pencilled in

The writing stick has all but disappeared, flaunted only by a few sections




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Achieving gender parity is still a dream

Antiquated stereotypes about the roles and responsibilities of women are a pain




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The dark side of digital dependence

The dreaded blue screen can throw life out gear in the most unlikeliest of places




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Women at the receiving end

They are the worst affected by alcoholism among men




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When homes turn hell

Domestic violence takes a psychological, emotional, financial and physical toll




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When influencers call the shots

They act as symbols of beauty, success, and happiness, and their posts, stories, and videos are vehicles of meaning for the audiences




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Nothing has changed for women in India

From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country




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Parenting parents

A role reversal wrought by time




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The bird in a patch of green

A pigeon becomes a regular visitor to a terrace with lush foliage




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Talking about menopause

Media explore gender disparity largely, but it has failed to explicitly probe this transformative stage in a woman’s life




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Reimagining parenting

Stringent discipline and control may fail to address the deeper emotional needs of children these days




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Making sense of death

Untimely death is scary because it may shatter the lives of the living




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Building mental reserves

Treat mental health like an “account” with regular deposits of nurturing habits, thoughts, and actions




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A women-only conversation, but for all

Why do we descend to the misogynistic use of ‘girlish’ and ‘womanly’ as labels to demean some of the complex disciplines?




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Celebrate menopause

Recognise it as the beginning of a new chapter in a woman’s life




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Women and travel

Whether working or not working, during daytime or at night, indoors or outdoors, they have the right to life and dignity




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Rising stars: Chani Nava and Will Chen

Interview with early-career scientists in astronomy and quantitative ecology




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




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Enhancing radiotherapy with MRI

Bas Raaymakers describes how MRI can help target tumours with improved accuracy




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J&K students in Holenarasipur complain against nursing college; HIMS director says issue resolved




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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Channapatna bypolls: Micro-management of OBCs and MBCs might hold the key

BJP leaders from various backward class communities are entrusted with the task of micro-managing voters, since JD (S) lacks many such leaders in its ranks




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Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’

Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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Digital drive soon to encourage passengers to make QR code-based payments for railway tickets

The drive will entail establishing special ‘May I Help You’ counters manned by railway staff near ticket booking counters




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Art camp in support of cancer patients in Mysuru soon




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BJP should sack BSY and Vijayendra from party posts over irregularities in purchases during pandemic, demands Congress




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Dalit family assaulted for entering temple in Arakalgud village




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Tension erupts in Mandya over entry of Dalits into temple

Former MLA M. Srinivas took the initiative in leading the entry of Dalits into the temple. However, a small group of persons opposed the move, took away the processional deity and tore down the temple plaque and board.




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Public campaigning for bypolls to end on November 11

The final day of public canvassing will see the Chief Minister and the Deputy Chief Minister besides top leaders of JD(S) and BJP seeking votes in Channapatna




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Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’

After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy




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Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra




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KSRTC plans to launch Ashwamedha AC buses within 100-km radius of Bengaluru

In contrast to regular Ashwamedha buses, the AC version will be smaller, fully air-conditioned, and equipped with comfortable seating, and amenities like charging ports 




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Model rocketry workshop launched to inspire young innovators in Bengaluru

The workshop is aimed at promoting innovation and technical expertise