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Redox-inactive ions control the redox-activity of molecular vanadium oxides

Chem. Sci., 2020, 11,4450-4455
DOI: 10.1039/D0SC01401J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simon Greiner, Benjamin Schwarz, Mark Ringenberg, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Maximilian Fichtner, Montaha Anjass, Carsten Streb
The enhanced redox-activity of a molecular vanadium oxide cluster upon functionalization with redox-inert Ca2+ ions is reported together with initial insights into its performance as a lithium ion battery cathode.
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Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

Chem. Sci., 2020, 11,4297-4304
DOI: 10.1039/D0SC00735H, Minireview
Open Access
Eike Brunner, Marcus Rauche
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
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Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
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N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
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Bihar gears up to screen all returnees from abroad

The state government is gearing up to facilitate the arrival of state residents stranded abroad, including in the Middle-East, after the Centre on Thursday kicked off the evacuation exercise to bring back Indian stranded due to the Covid-19 lockdown.




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Wife dead, man held on dowry charges in Patna

A 30-year-old man was arrested in Patna after his wife was found dead at their home in Shivpuri under Shastri Nagar police station area on Thursday. The couple, Manish Kumar and Anita Devi, were marred in 2017.




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What is IPO grading?

It is not mandatory for the issuer to get its issue graded.




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NCDEX gets Sebi go-ahead for Rs 500 crore IPO

The offering comprises a fresh issue aggregating up to Rs 100 crore and an offer for sale of up to 1.44 crore shares.




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Half of FY20 IPOs hold head above water in this selloff, some remain multibaggers

Out of the 15 stocks that got listed in FY 2019-20, seven are still trading above issue prices.




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Academic culture : a student's guide to studying at university / Jean Brick, Maria Herke, Deanna Wong ; editor: Laura Davies

Brick, Jean, author




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The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling




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Corporate humanities in higher education : moving beyond the neoliberal academy / Jeffrey R. Di Leo

Di Leo, Jeffrey R., author




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International handbook of research on conceptual change / edited by Stella Vosniadou




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The Giroux reader / by Henry A. Giroux ; edited and introduced by Christopher G. Robbins

Giroux, Henry A., author




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Pedagogy and the politics of hope : theory, culture, and schooling : a critical reader / Henry A. Giroux

Giroux, Henry A




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The university in chains : confronting the military-industrial-academic complex / Henry A. Giroux

Giroux, Henry A




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Situation models and children's reading comprehension : what role does visual imagery play? / by Maroulia Katsipis

Katsipis, Maroulia, author




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Teaching for social justice : a Democracy and education reader / edited by William Ayers, Jean Ann Hunt, and Therese Quinn




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Engaging the six cultures of the academy : revised and expanded edition of the Four cultures of the academy / William H. Bergquist, Kenneth Pawlak

Bergquist, William H




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Research methods for education in the digital age / Maggi Savin-Baden and Gemma Tombs

Savin-Baden, Maggi, 1960- author




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Geoffrey Bolton introduces 'It had better be a good one' [videorecording] : the first ten years of Murdoch University

Bolton, G. C. (Geoffrey Curgenven), 1931-2015




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Learning English as a second language in the early years : hundreds of ideas for supporting children with English as an additional language / Anita Soni & Liz Rouse

Soni, Anita, (Educational psychologist), author




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How colleges work : the cybernetics of academic organization and leadership / Robert Birnbaum

Birnbaum, Robert




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Video-conferencing in rural and remote secondary education in Canada : a mixed-method collective case study of teachers' perceptions around presence, process and professional learning / Nicole A. Rehn

Rehn, Nicole A., author




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The toxic university : zombie leadership, academic rock stars and neoliberal ideology / John Smyth

Smyth, W. J. (William John), 1944- author




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Liberating praxis : Paulo Freire's legacy for radical education and politics / by Peter Mayo (University of Malta)

Mayo, Peter, 1955- author




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Developing the curriculum : improved outcomes through systems approaches / William R. Gordon II, Ed.D. (Chief Operations Officer, Retired, Florida virtual School, Orlando, Florida), Rosemarye T. Taylor, Ph.D. (Professor, Educational Leadership, University

Gordon, William, II, author




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Leading the academy : distributed leadership in higher education / Sandra Jones

Jones, Sandra, author




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Reaching all by creating tribes learning communities / Jeanne Gibbs ; in collaboration with Teachers and Administrators Extraordinaire

Gibbs, Jeanne, 1924- author




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Adult education and lifelong learning : theory and practice / Peter Jarvis

Jarvis, Peter, 1937- author




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Reading and learning difficulties : approaches to teaching and assessment / Peter Westwood

Westwood, Peter S. (Peter Stuart), 1936- author




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Building research design in education : theoretically informed advanced methods / edited by Lorna Hamilton and John Ravenscroft




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Unique individuals, broad skills : inquiry into school to work transition / House of Representatives. Standing Committee on Employment, Education and Training

Australia. Parliament. House of Representatives. Standing Committee on Employment, Education and Training, author, issuing body




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Hands on : trade & technical careers for girls & women - things you should know & places to go / [writer Jenny Pausacker]

Pausacker, Jenny




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Planning your PhD : all the tools and advice you need to finish your PhD in three years / authors: Hugh Kearns & Maria Gardiner

Kearns, Hugh, author




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Assessment and reporting : celebrating student achievement / Laurie Brady ; Kerry Kennedy

Brady, Laurie, 1947- author




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Fundamentals of statistical reasoning in education / Theodore Coladarci (University of Maine), Casey D. Cobb (University of Connecticut)

Coladarci, Theodore, author




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Higher education and the future of graduate employability : a connectedness learning approach / edited by Ruth Bridgstock, Neil Tippett




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Practical planning and assessment / Kylie Readman and Bill Allen

Readman, Kylie, author




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Teaching : dilemmas, challenges and opportunities / Robyn Ewing, Lisa Kervin, Christine Glass, Brad Gobby, Rosie Le Cornu, Susan Groundwater-Smith

Ewing, Robyn (Robyn Ann), 1955- author




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Literacy : reading, writing and children's literature / Gordon Winch, Rosemary Ross Johnston, Paul March, Lesley Ljungdahl, Marcelle Holliday

Winch, Gordon, 1930- author




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Implementing change : patterns, principles, and potholes / Gene E Hall, President, Concerns Based Systems, Inc., Professor Emeritus, University of Nevada, Las Vegas, Shirley M. Hord, Scholar Laureate, Learning Forward ; forewords by Bruce Joyce, Barrie Be

Hall, Gene E., 1941- author




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No-No Boy, John Okada

The first Japanese American novel: a powerful, radical testament to the experiences of Japanese American draft resisters in the wake of World War II. --Recommended by Paul




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The Nickel Boys, Colson Whitehead

In this bravura follow-up to the Pulitzer Prize, and National Book Award-winning #1 New York Times bestseller The Underground Railroad, Colson Whitehead brilliantly dramatizes another strand of American history through the story of two boys sentenced to a hellish reform school in Jim Crow-era Florida.




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The Berge equilibrium: a game-theoretic framework for the golden rule of ethics / Mindia E. Salukvadze, Vladislav I. Zhukovskiy

Online Resource




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Binary code fingerprinting for cybersecurity: application to malicious code fingerprinting / Saed Alrabaee, Mourad Debbabi, Paria Shirani, Lingyu Wang, Amr Youssef, Ashkan Rahimian, Lina Nouh, Djedjiga Mouheb, He Huang, Aiman Hanna

Online Resource