Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01321K, Critical Review

Botao Liu, Kumar Vikrant, Ki-Hyun Kim, Vanish Kumar, Suresh Kumar Kailasa
Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).
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Environ. Sci.: Nano, 2020, 7,1102-1114
DOI: 10.1039/C9EN01104H, Paper

My Kieu Ha, Jang-Sik Choi, Sook Jin Kwon, Jaewoo Song, Yangsoon Lee, Young-Eun Kim, Tae Hyun Yoon
Between-population and within-population heterogeneity in the uptake and toxicity of silver nanoparticles in primary human immune cells revealed by mass cytometry.
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Environ. Sci.: Nano, 2020, 7,1068-1081
DOI: 10.1039/C9EN01382B, Paper

Quin R. S. Miller, John P. Kaszuba, Sebastien N. Kerisit, H. Todd Schaef, Mark E. Bowden, B. Peter McGrail, Kevin M. Rosso
Mineral carbonation reactivity trends and thresholds in nanoconfined water films delineated with in situ X-ray diffraction and molecular simulations.
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Environ. Sci.: Nano, 2020, 7,1041-1060
DOI: 10.1039/C9EN00938H, Critical Review

Open Access

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Andrew J. Chetwynd, Iseult Lynch
Metabolites present in the corona may play a key role in biological recognition of nanomaterials yet remain a much-overlooked aspect of the corona.
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Environ. Sci.: Nano, 2020, 7,1008-1040
DOI: 10.1039/C9EN01341E, Critical Review

Xiaoyuan Zhang, Yu Liu
Nanomaterials have been demonstrated to be an effective adsorbent or an ion exchanger for selectively removing various radioactive species present in contaminated water while preventing radionuclides from entering and interacting with the biosphere.
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Environ. Sci.: Nano, 2020, 7,1205-1213
DOI: 10.1039/C9EN01408J, Paper

Dezhi Chen, Shoujun Wang, Zhiming Zhang, Hongying Quan, Yachao Wang, Yijie Jiang, Matthew J. Hurlock, Qiang Zhang
The efficient removal of endocrine-disrupting pollutants (EDCs) from water is a crucial issue for improving the quality of drinking water.
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Environ. Sci.: Nano, 2020, 7,1194-1204
DOI: 10.1039/C9EN01453E, Paper

Zhuanxi Luo, Zhenhong Wang, Baoshan Xing
This study provides new insights into the “Trojan horse” effects of nano-TiO₂ on arsenite (As(III)) bioaccumulation in Daphnia magna.
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Environ. Sci.: Nano, 2020, 7,1126-1135
DOI: 10.1039/D0EN00016G, Paper

Qiuju Shi, Weina Zhang, Yuemeng Ji, Jiaxin Wang, Dandan Qin, Jiangyao Chen, Yanpeng Gao, Guiying Li, Taicheng An
Glyoxal (GL) exhibits a preferential tendency to the acidic nanoparticle interface, and sulfuric acid (SA) has a catalytic effect on hydration reaction of glyoxal in the aqueous phase.
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Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper

Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Environ. Sci.: Nano, 2020, 7,1136-1149
DOI: 10.1039/D0EN00049C, Paper

Open Access

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Laura-Jayne A. Ellis, Eugenia Valsami-Jones, Iseult Lynch
Pristine engineered nanomaterials (NMs) entering the aquatic environment become ‘aged’ during their lifetime via chemical, physical and/or biological process.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00023J, Paper

Joana Figueiredo, Susana Loureiro, Roberto Martins
Biocides encapsulation appears to be a promising solution to develop a new generation of efficient anti-fouling additives (e.g. SiNC–DCOIT; SiNC–DCOIT–Ag) for maritime coatings with lower environmental hazard than the current state-of-the-art biocides (e.g. DCOIT).
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00174K, Critical Review

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Meike van der Zande, Anita Jemec Kokalj, David Spurgeon, Susana Loureiro, Patricia Silva, Zahra Khodaparast, Damjana Drobne, Nathaniel J. Clark, Nico van den Brink, Marta Baccaro, Kees van Gestel, Hans Bouwmeester, Richard D. Handy
The structure of the gut barrier and luminal chemistry in non-mammalian vertebrates and invertebrates has been given little attention with respect to the dietary uptake of engineered nanomaterials (ENMs). This...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper

Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper

Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00115E, Paper

Zachary J. Shepard, Elizabeth M. Lux, Vinka A. Oyanedel-Craver
This work presents the first performance evaluation of ovoid CWFs designed by Potters without Borders. Performance analysis and characterization data are presented here to inform manufacturing decisions and research methods.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper

Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01427F, Paper

Vincent Noel, Naresh Kumar, Kristin Boye, Lilia barragan, Juan Lezama-Pacheco, Rosalie K. Chu, Nikola Tolic, Gordon Brown, John Bargar
We have used synchrotron-based X-ray absorption spectroscopy (structure of Fe-S clusters), transmission electron microscopy (solid-phase crystallinity), Fourier-transform ion-cyclotron-resonance mass spectrometry (identity and composition of natural organic carbon compounds), inductively coupled...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper

Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper

Open Access

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Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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CrystEngComm, 2020, 22,2756-2765
DOI: 10.1039/C9CE01885A, Paper

Yaser Balmohammadi, Hamid Reza Khavasi, S. Shahab Naghavi
There is a common perception by the scientific community that a halogen-involving interaction forms when the distance between the donor atom and the acceptor atom is less than the sum of their van der Waals (vdW) radii.
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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication

Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a Rh^III₄Zn^II₄ polycarboxylate is reported.
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CrystEngComm, 2020, 22,2788-2794
DOI: 10.1039/C9CE01228A, Paper

Zsolt Dallos, Viktória Kovács Kis, Ferenc Kristály, István Dódony
Bioapatite, the main inorganic component of bone, is similar to hydroxyapatite (HAp, Ca₅[PO₄]₃(OH)) having some [CO₃]²⁻ content which plays an important role in leaching/precipitation processes in many biological lesions.
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CrystEngComm, 2020, 22,2827-2836
DOI: 10.1039/D0CE00171F, Paper

Binghui Xu, Xin Dai, Qingke Tan, Yuan Wei, Gonggang Liu, Guanglei Wu
In this work, a nano-sized goethite and zinc oxide hetero-structure (FeOOH@ZnO) dispersed on reduced graphene oxide (RGO) sheets was synthesized for the first time to construct a ternary composite (FeOOH@ZnO/RGO) via a stepped graphene oxide (GO) deoxygenation process.
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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper

Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between Fe^III/Cr^I ion and Cu^II ion.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00370K, Paper

Corrado Di Nicola, Alessia Tombesi, Marco Moroni, Rebecca Vismara, Fabio Marchetti, Riccardo Pettinari, Luca Nardo, Guglielmo Vesco, Simona Galli, Silvia Casassa, Luciano Pandolfo, Claudio Pettinari
Enlarging the family of CPs with the {Cu(μ-pz)₂} building unit: synthesis, thermal behaviour, crystal structure and spectroscopic properties of [Cu(μ-4-Xpz)₂(μ-DMF)]_n (4-Xpz = 4-Xpyrazolate, X = H, Cl, Br, I) and the non-solvated counterparts.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00489H, Highlight

Zhonghua Pan, chenglong deng, zhi wang , Jin-Qing Lin, Geng-Geng Luo, Di Sun
Silver clusters with atomic precision have garnered immense attention owing to their aesthetic structures and fascinating properties. Assembly of silver clusters involves organizing positively charged silver ions into an intricate...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper

Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction

Open Access

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Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00026D, Paper

Open Access

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Thai T. H. Nguyen, Robert B. Hammond, Ioanna D. Styliari, Darragh Murnane, Kevin J. Roberts
A detailed inter-molecular (synthonic) analysis of terbutaline sulfate, an ionic addition salt for inhalation drug formulation, is related to its crystal morphology, the surface chemistry of the habit faces and hence to its crystal surface energy.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00084A, Paper

Yang Wang, Mengjia Luo, pei Zhao, Xiangli Che, Yunzhen Cao, Fu Qiang Huang
A new mid-infrared nonlinear optical oxyselenide, Sr₄Pb_1.5Sb₅O₅Se₈, was successfully synthesized by traditional solid-state reaction. It crystallizes in the noncentrosymmetric space group Cm (No. 8) of the monoclinic system. The crystal...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper

Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(D_xH_1-x)₂PO₄ (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
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CrystEngComm, 2020, 22,2904-2913
DOI: 10.1039/C9CE01157A, Paper

Edurne S. Larrea, Roberto Fernández de Luis, Arkaitz Fidalgo-Marijuan, Eva M. Maya, Marta Iglesias, Maria I. Arriortua
The versatility of CuBTC (HKUST-1) MOF materials to be functionalized to improve their catalytic activity performance was evaluated. CuBTC@IL catalysts are selective for the cycloaddition of CO₂ to epoxides, giving rise to value-added products.
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CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper

Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
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CrystEngComm, 2020, 22,2953-2963
DOI: 10.1039/D0CE00268B, Paper

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
2D porous nickel oxalate thin sheets constructed by ultrathin nanosheets were first synthesized by using a simple hydrothermal method. The resulting porous thin sheets exhibited superior supercapacitor performance.
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CrystEngComm, 2020, 22,2889-2894
DOI: 10.1039/D0CE00397B, Communication

Open Access

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Peng Yang, Buthainah Alshankiti, Niveen M. Khashab
Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00341G, Paper

Yue Qi, Ou Sun, Yanyan Zhou, Yuan Yao, Zhenyu Cheng, Ting Gao, Hongfeng Li
Due to the effect of the combination of the rigid structure and synergistic interactions of two ligands on energy transfer, the Cd–Ln complexes show excellent NIR luminescence properties with the QYs reaching 0.34% for Nd³⁺ and 2.13% for Yb³⁺.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00359J, Communication

Zhenfeng Zhang
An X-shaped CN⋯CO interaction, which plays a critical role in dictating the molecule conformation and crystal packing patterns, has been found to occur on the polar surface of (cyanoacetyl)hydrazones, and is rationalized by density functional theory calculations.
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CrystEngComm, 2020, 22,2998-3004
DOI: 10.1039/D0CE00039F, Paper

Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qinglun Wang, Bin Zhao, Peng Cheng
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)₆]³⁻ linking Ln^III-Schiff-base units, the diamagnetic Co^III ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00521E, Paper

Taka Narumi, Didier Chaussende, Takashi Yoshikawa
Solution growth of SiC is a promising process for producing high-quality SiC crystals; however, control over the morphology of the growth interface under rapid growth conditions is a critical issue....
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00334D, Paper

Angelo Gavezzotti, Leonardo Lo Presti, Silvia Rizzato
A novel, universal Lennard-Jones–Coulomb (LJC) atom–atom force field parametrization reproduces the experimental sublimation enthalpies of 377 molecular crystals drawn from the CSD.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00312C, Paper

Stefan Neumann, Cristina Menter, Ahmed Salaheldin Mahmoud, Doris Segets, David Rafaja
Although the concept of quantum confinement was introduced more than thirty years ago, a wide application of the quantum dots is still limited by the fact that monodisperse quantum dots...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00226G, Paper

Nida Tabassum, Panayiotis C. Varras, Fiza Arshad, Muhammad I. Choudhary, Sammer Yousuf
Urotropine (1) is a synthetic heterocyclic antibacterial agent.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00325E, Paper

Guijin Yang, Botao Zhu, Daqiang Gao, Yujun Fu, Jing Zhao, Jinyun Li
For water electrolysis and metal-air batteries, rational design and preparation of highly efficient and environmentally friendly catalysts for oxygen evolution reactions (OER) is urgently required. Here, abundant Co3O4/MnCO3 heterointerfaces supported...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00403K, Paper

Open Access

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Eline Grothe, hugo meekes, Rene de Gelder
With the current interest in multicomponent crystals containing chiral residues, a wide variety of studies could benefit from a comprehensive inventory of chirality in multicomponent crystals. We combined computational approaches...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00495B, Paper

John D. Wallis, Alun Christopher Garner, Songjie Yang
Methyl 2,6-diaminobenzoate and its bis-triphenylboron complex show hydrogen bonding from NH2 groups to both oxygen atoms of the carboxylic ester, and there is little difference in the lengths of these...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00136H, Paper

Guoshun Zhang, xiaoqing shang, wei han, lifeng zhang, guolian ren, Shuqiu Zhang
As a quinazolinocarboline alkaloid, dehydroevodiamine (DHED) derived from Evodia rutaecarpa has recently gained attention because it improves memory failure in Alzheimer's mice. However, its solid forms, which have not yet...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00368A, Paper

Ling-Yang Wang, Yueming Yu, Ming-Chao Yu, Yan-Tuan Li, Zhi-Yong Wu, Cui-Wei Yan
The first molecular salt concurrently combining antibacterial drug sulfathiazole (SFZ) and antiviral constituent amantadine (ATD) is designed and successfully synthesized via salification strategy. The precise structure of the newly obtained...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00501K, Paper

Dusan P Malenov, Snezana D Zaric
Cambrigde Structural Database search was performed in order to study stacking interactions of 7-membered tropylium ring and 8-membered cyclooctatetraenide (COT) ring, coordinated to transition metals via their π-electrons. The search...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00423E, Paper

Abraham Colin-Molina, Diego Velazquez-Chavez, Marcus Jellen, Lizbeth A. Rodríguez-Cortés, Miguel Eduardo Cifuentes Quintal, Gabriel Merino, Braulio Rodríguez-Molina
Two new compounds 2 and 3 and their deuterated analogues 2-d4 and 3-d4 have been prepared from Ullmann-type coupling reactions. Both showed good emissive properties in solution ΦF = 0.13...
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