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West Bengal Governor, HC seek report from State govt. on ‘vandalism’ during pujas

While the counsels appearing for the Leader Of Opposition alleged that vandalism took place during Durga Puja and Kali Puja, Advocate General Kishore Datta strongly refuted allegations of communal clashes




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Not in favour of genetically modified tea, says Asia Tea Alliance

With saturation of European and American markets, Asian tea producers are eyeing untapped African market for exports




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West Bengal bypolls: Campaign picks up as political barbs fly thick and fast

BJP president Sukanta Majumdar targets police whereas Trinamool leader Firhad Hakim apologises  for comment on woman BJP leader




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West Bengal junior doctors bring out rally to demand justice for R.G. Kar victim

The protesting doctors have also come up with a gallery highlighting their protests for the past 90 days




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Trinamool moves ECI against State BJP president, misuse of Central forces

The Trinamool Congress delegation also expressed dissatisfaction that the Election Commissioners were not available to meet the party delegation at ECI headquarters




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Jadavpur University professor from West Bengal found dead in Uttarakhand hotel room

Colleagues and students expressed shock over his untimely and mysterious demise




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Veteran Bengali actor Manoj Mitra no more

The 85-year-old thespian was known for his performances as an actor, his work as a director, and as the author of several plays numbering in the hundreds




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Art festival to remind Kolkata of one of Bengal’s biggest mass movements

This year’s festival features nine events including walks, installations, talks and performances, presented at historic sites and archives across Kolkata




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Halide-free and metal-free allylic thiolation/selenation of P(O)H compounds with sulfur/selenium and allylic alcohols

Green Chem., 2024, 26,10886-10892
DOI: 10.1039/D4GC03960B, Paper
Longzhi Zhu, Weiwei Luo, Furong Guo, Lin Chen, Ying Tang, Biquan Xiong, Yu Liu, Ke-Wen Tang, Renhua Qiu
A halide- and metal-free method for forming C–S/Se–P(O) bonds using allylic alcohols, P(O)H compounds, and elemental sulfur/selenium is reported, eliminating the need for toxic, odorous, and moisture-sensitive starting materials.
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One-pot synthesis of conjugated vinylene-extended viologen ionic radical polyacetylenes for visible light-promoted photocatalytic CO2 cycloaddition

Green Chem., 2024, 26,10876-10885
DOI: 10.1039/D4GC03683B, Paper
Yanan Chang, Shuo Wang, Juan Chen, Zixuan Xu, Qing Shi, Yunjie Mao, Yanli Gai, Zhouyang Long, Guojian Chen
In situ synthesis of a conjugated vinylene-extended viologen ionic radical polyacetylene (VIRP-2) for visible light-promoted photocatalytic CO2 cycloaddition under ambient conditions.
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What to do with polyurethane waste? The environmental potential of chemically recycling polyurethane rigid foam

Green Chem., 2024, 26,10893-10906
DOI: 10.1039/D4GC02594F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Pillich, Johannes Schilling, Luca Bosetti, André Bardow
The environmental potential guides through the maze of chemical recycling of polyurethane rigid foams highlighting promising options.
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Self-supported FeCoNiCuP high-entropy alloy nanosheet arrays for efficient glycerol oxidation and hydrogen evolution in seawater electrolytes

Green Chem., 2024, 26,10921-10928
DOI: 10.1039/D4GC02517B, Paper
Leyang Song, Chaoqun Ma, Peidong Shi, Xiaojuan Zhu, Kaiyu Qu, Lijie Zhu, Qipeng Lu, An-Liang Wang
Self-supported FeCoNiCuP high entropy alloy nanosheet arrays electrocatalyst was developed for highly efficient glycerol oxidation to formate and hydrogen evolution in seawater electrolytes.
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Solid phase peptide synthesis using side-chain unprotected arginine and histidine with Oxyma Pure/TBEC in green solvents

Green Chem., 2024, 26,10929-10939
DOI: 10.1039/D4GC03209H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tommaso Fantoni, Andrea Orlandin, Ilaria Di Stefano, Marco Macis, Alessandra Tolomelli, Antonio Ricci, Walter Cabri, Lucia Ferrazzano
Oxyma Pure/TBEC coupling protocol in green solid phase peptide synthesis (GSPPS) eliminates protective groups on Arg and His, enhancing atom economy and reducing impurities during cleavage. The technology was extended to side-chain-free Tyr and Trp.
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Light-driven ultrafast dual C–C cleavage and coupling of dihydroxyacetone into high-purity carbon monoxide and ethylene glycol

Green Chem., 2024, 26,10859-10866
DOI: 10.1039/D4GC04180A, Paper
Fanhao Kong, Hongru Zhou, Zhiwei Chen, Zhaolin Dou, Min Wang
Reforming of biomass-based dihydroxyacetone to produce high-purity CO and ethylene glycol is achieved via a distinctive photochemical process under ambient conditions.
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Evaluation on the recovery of lignin from basic [Ch][Lys] systems using low-cost alcohols as anti-solvents under acid-free conditions

Green Chem., 2024, 26,10950-10959
DOI: 10.1039/D4GC03898C, Paper
Yichen Liu, Wanting Zhao, Qizhen Luo, Jipeng Yan, Jian Sun
An acid-free, high efficiency, and mild method of precipitating and separating lignin from basic ionic liquids (BIL) such as choline lysinate ([Ch][Lys]) by using alchohols (such as tert-butanol) as anti--solvents.
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Green and controllable synthesis of symmetrical and unsymmetrical difluoromethylated diarylmethanes via a direct bisarylation strategy enabled by an HFIP–B(C6F5)3 adduct

Green Chem., 2024, 26,10969-10974
DOI: 10.1039/D4GC03917C, Paper
Xindi Li, Yiping Zhu, Zhina Gong, Jinshan Li, Jialin Xie, Zhendong Zhao, Jianwei Li, Chunman Jia
An efficient and environmentally friendly for the synthesis of symmetrical and unsymmetrical difluoromethylated diarylmethanes via direct bisarylation of difluoroacetaldehyde hemiacetal with aniline enabled by HFIP–B(C6F5)3 adduct is described.
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A sequential flow process of CO2 capture and conversion using cost-effective porous organic polymers

Green Chem., 2024, 26,10960-10968
DOI: 10.1039/D4GC03494E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhongqi Wu, Zhong Li, Lei Hu, Samson Afewerki, Maria Strømme, Qian-Feng Zhang, Chao Xu
A sequential flow process utilizing cost-effective porous organic materials to capture CO2 and directly convert it into fine chemicals has been achieved, which could improve the practical applicability of CO2 capture and utilization technologies.
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Straightforward solid-phase modification of TiO2 with propylphosphonic acid via manual grinding and shaker mixing: enhancing modification degree by thermal control while improving atom economy

Green Chem., 2024, 26,10907-10920
DOI: 10.1039/D4GC03330B, Paper
Open Access
Kaimin Zhang, Jinxin Wang, Nick Gys, Elien Derveaux, Nahal Ghanemnia, Wouter Marchal, Peter Adriaensens, Vera Meynen
The straightforward manual grinding method achieves controllable grafting of organophosphonic acid onto TiO2, demonstrating its atom economy and greenness.
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Monoliths enabling biocatalysis in flow chemistry

Green Chem., 2024, 26,10718-10738
DOI: 10.1039/D4GC03535F, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Aleksandra Lambarska, Katarzyna Szymańska, Ulf Hanefeld
Biocatalysis in flow improves space time yields and enables straightforward downstream processing. The underlying principles of monolithic flow reactors and their application in mono- and bi-phasic biocatalytic systems are discussed.
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Lipase-entrapped colloidosomes with light-responsive wettability for efficient and recyclable Pickering interfacial biocatalysis

Green Chem., 2024, 26,10824-10828
DOI: 10.1039/D4GC03982C, Communication
Dingyi Yang, Qi Zeng, Kaiwen Tan, Haoyue Hou, Xingyuan Fang, Chenlong Guo, Hao Yuan, Tao Meng
We prepared lipase-entrapped TiO2 colloidosomes with excellent recyclability for light-responsive Pickering interfacial biocatalysis, providing a green, recyclable and efficient Pickering interfacial biocatalysis platform.
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Metal-free photoinduced-radical hydrocyclization of 2-isocyanides: a unified synthetic approach to facilely assemble diverse N-heteroarenes

Green Chem., 2024, 26,10804-10810
DOI: 10.1039/D4GC03774J, Communication
Ziyi Wang, Haonan Wei, Jinrong Du, Zhijun Zuo
We present an efficient and sustainable protocol for the photoinduced-radical hydrocyclization of isocyanides, providing a united route to assemble diverse α-unsubstituted N-heteroarenes.
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Electroreductive deoxygenative carboxylation of alkyl oxalates with CO2

Green Chem., 2024, 26,10811-10817
DOI: 10.1039/D4GC03452J, Communication
Yong Yuan, Hangfei Jiang, Ya-Nan Zhang, Yuyan Tao, Xincong Liu, Congde Huo
An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated.
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Electrochemistry-enabled Rh-catalyzed regioselective [4 + 1] and [4 + 2] cycloaddition of benzoic acid with alkynyl esters/amides

Green Chem., 2024, 26,10996-11002
DOI: 10.1039/D4GC03753G, Paper
Wei-Jung Chiu, Chung-Ming Sun
The reaction of benzoic acids with alkynyl esters/amides in the presence of a Rh-catalyst and AcOH as an additive to give phthalides by [4 + 1] annulation. In contrast, the additive NaOAc exclusively affords isocoumarins through the [4 + 2] pathway.
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Electroreductive deuteration of N-propynylamides to enamides

Green Chem., 2024, 26,10975-10981
DOI: 10.1039/D4GC03790A, Paper
Qiansong Gao, Mingchun Wang, Lianyou Zheng, Lingling Shi, Cheng Wu, He Li, Jinbao Xiang
A migratory reductive deuteration of terminal alkynes to access enamides with more than 3 deuteriums incorporated per molecule was realized.
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Visible light-driven α-sulfonylation of ketone-derived silyl enol ethers via an electron donor–acceptor complex

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04554H, Paper
Barakha Saxena, Roshan I. Patel, Anuj Sharma
We herein describe a versatile electron donor–acceptor complex (EDA) mediated α-sulfonylation of ketone-derived silyl enol ethers using thiosulfonates (acceptor) with DABCO (donor) under visible light irradiation.
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Postliminary treatment of food-waste digestate via combined hydrothermal carbonization and microbial fuel cell for bio-energy recovery: a comparative life cycle impact assessment

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04081C, Paper
Shraddha Yadav, Manikanta M. Doki, Makarand M. Ghangrekar, Brajesh K. Dubey
Multiple resource recovery from food-waste digestate by deploying hydrothermal carbonisation and microbial fuel cells. A green route for environmental sustainability and economic gains.
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A solvent-free, self-emulsified and heat-responsive polyester coating enables chemically-recyclable and fire-safe PET foam

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04531A, Paper
Bei-Bei Zhang, Li-Xia Fan, Lin Chen, Xiu-Li Wang, Yu-Zhong Wang
This work implements a state-of-the-art strategy to simultaneously achieve use performance and future recycling, which will greatly benefit the green sustainable circular economy for wind turbine blades.
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Does enzymatic catalysis lead to more sustainable chemicals production? A life cycle sustainability assessment of isopropyl palmitate

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04514A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pieter Nachtergaele, Ozan Kocak, Yblin Roman Escobar, Jordy Motte, Dries Gabriels, Leopold Mottet, Jo Dewulf
A methodology is presented for assessing the life cycle sustainability of enzymatic catalysis for chemicals production. For IPP, lower environmental impacts, but higher costs and social risks were found for switching to enzymatic catalysis.
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Valorization of pomegranate waste through green solvent extraction and biochar production: a zero-waste biorefinery approach

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03707C, Paper
Leonardo M. de Souza Mesquita, Letícia S. Contieri, Bárbara M. C. Vaz, Vitor Sencadas, Filipe H. B. Sosa, João A. P. Coutinho, Maurício A. Rostagno, Sónia P. M. Ventura
This study presents a zero-waste biorefinery for pomegranate waste, extracting anthocyanins and ellagic acid with green solvents and converting leftovers to biochar.
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Modular access to multi-substituted allenones via environmentally friendly organocatalytic C–H allenylation of aldehydes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04550E, Paper
Xinying Hu, Ayisenbati Jialingbieke, Yuzhi Ren, Yifan Yang, Donghui Wei, Jian Gao, Ding Du
Organocatalytic direct C–H allenylation of aldehydes with propargyl bromides has provided a straightforward and step-economical strategy for allenone modular synthesis.
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Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
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Catalytic hydrodeoxygenation and C–C coupling of lignin and its derivatives into renewable jet-fuel-range cycloalkanes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC02051K, Critical Review
Xinyong Diao, Ying Xiong, Yawen Shi, Longlong Ma, Chenglong Dong, Shengbo Zhang, Na Ji
This review provides an in-depth understanding of the synthesis pathways and corresponding catalytic systems for the production of jet-fuel-range cycloalkanes from lignin and its derivatives via catalytic hydrodeoxygenation and C–C coupling.
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Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
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Engineering high-valence nickel sites in Ni3S2/Ni3Se2 architectures enabling urea-assisted hydrogen evolution reactions

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04318A, Paper
Taotao Ai, Miaomiao Bai, Weiwei Bao, Jie Han, Xueling Wei, Xiangyu Zou, Jungang Hou, Lizhai Zhang, Zhifeng Deng, Yuxin Zhang
Bifunctional Ni3S2@Ni3Se2 electrocatalysts were constructed for urea-assisted hydrogen evolution. In the HER/UOR two-electrode system, the heterogeneous interface modulates the electronic structure and thus improves the catalytic performance.
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Engineering in situ: N-doped porous carbon-confined FeF3 for efficient lithium storage

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04097J, Paper
Open Access
Jinlong Hu, Weijun Xu, Lingzhi Zhang
Achieving N-doped porous carbon-confined FeF3 with enhanced lithium storage performance via an innovative in situ engineering approach.
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In silico modeling enables greener analytical and preparative chromatographic methods

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04300F, Paper
Troy T. Handlovic, Daipayan Roy, Muhammad Qamar Farooq, Gabriel Mazzi Leme, Kevin Crossley, Imad A. Haidar Ahmad
Environmental impact of chromatographic separation at both analytical and preparative scale can be significantly reduced using In Silico Modeling.
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Hypervalent iodine chemistry with a mechanochemical twist

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04903A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sayad Doobary, Miguel M. de Vries Ibáñez, Berit Olofsson
An assessment of mechanochemistry's utility with hypervalent iodine reagents highlighted its effectiveness, which showed better selectivity, reaction times and differing reactivity.
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Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
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Photo-Induced FeCl3-catalysed direct denitrative chlorination of (hetero)nitroarenes at room temperature

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04210G, Communication
Mingjing Deng, Ke Liu, Zhaolun Ma, Guanzhong Luo, Longyang Dian
We present herein an iron-catalyzed denitrative chlorination of (hetero)nitroarenes at room temperature under visible light irradiation. In this study, FeCl3 catalyzed direct chlorination was achieved through denitrative chlorination under light...
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Rational modulation of cellulose for zinc ion-based energy storage devices

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC03525A, Tutorial Review
Penggao Liu, Chunrong He, Xinyue Chen, Ting Wang, Wei Song, Weifang Liu, Kaiyu Liu
Aqueous zinc-ion energy storage technology is currently undergoing intensive exploration. The construction of high-efficiency batteries remains a significant obstacle to the further advancement of novel battery types and enhanced electrochemical...
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Green dipolar aprotic solvents for the dynamic polycondensation of high-performance polyimide membranes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04279D, Paper
Open Access
E. San José, M. R. de la Viuda, F. J. Carmona, C. Soto, L. Palacio, P. Prádanos, A. Hernández, A. Tena
Guidelines for the evaluation of green solvents were revisited and integrated into a decision diagram. GVL, Cyrene™, DMC, NOP, DEC, DMI, GBL, NBP, Rhodiasolv® PolarClean, and DMSO showed the potential to substitute hazardous polar aprotic solvents.
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Crystalline/amorphous c-NiMo/a-NiMoOx nanoarrays for urea-assisted energy-saving H2 production in alkaline seawater

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05042H, Paper
Dongxue Guo, Yi Ping, Chuanjiao Wang, Changan Hou, Danhong Wang
Electrocatalytic seawater splitting is regarded as the most effective method for producing green hydrogen (H2), but it faces issues of high energy consumption and harmful chlorine evolution side reactions. Replacing...
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Photo-driven reduction/cyclization of nitroarenes via electron donor–acceptor complexes: a novel method for the acquisition of N-heterocycles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04082A, Communication
Bin Sun, Chun Lv, Xiaohui Zhuang, Yan Xu, Haijing Song, Jiayin Wang, Zhaokang Zhang, Jiayang Wang, Can Jin
An EDA complex-based method for the reduction/cyclization of nitroarenes to obtain N-heterocycles with H2O as a clean by-product is presented.
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Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
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High Efficiency Leaching of Valuable Metals from Waste Lithium-ion ternary Batteries under Mild Conditions Using Green Deep Eutectic Solvents

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04373A, Paper
Bo Li, Zhengfu Zhang, Chengping Li, Jinsong Wang, Rundong Wan, Jiangzhao Chen, Ying Liu, Yuejing Bin, xiaoping yang, Chongjun Bao, Shaohua Ju
Recently, the production and demand for lithium-ion batteries (LIBs) has increased owing to increasing number of electric vehicles and products. This surge has considerably increased spent LIBs, leading to environmental...
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Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
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Production of propyl 4-hydroxybenzoate via selective hydrogenolysis of lignin catalyzed by Ni/MFI-ns

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05260A, Paper
Lixia Li, Yinan Rao, Menghao Jiang, Jinxing Long
Selective conversion of lignin macromolecules into aromatic monomers is of great significance but remains a great challenge. Here, we present a metallic Ni supported on hierarchical multilamellar MFI nanosheets (MFI-ns)...
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Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts

Green Chem., 2024, 26,11164-11176
DOI: 10.1039/D4GC02757D, Paper
Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu Hwang
A bimetallic NiSn/ZnO catalyst converts biomass-derived furfuryl alcohol into 1,2-PDO continuously, yielding 91.0% over 400 hours.
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Catalyst free PET and PEF polyesters using a new traceless oxalate chain extender

Green Chem., 2024, 26,11182-11195
DOI: 10.1039/D4GC02791D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin van der Maas, Daniel H. Weinland, Robert-Jan van Putten, Bing Wang, Gert-Jan M. Gruter
When producing PET the metal catalyst (typically Sb) remains in the polymer. This raises concerns as our food and the air we breathe is contaminated with PET microplastics. Here we report the production of metal-free PET using a small amount of DGO.
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A spatially integrated electrochemical–thermal tandem reaction for continuous mild synthesis of propylene oxide

Green Chem., 2024, 26,11206-11215
DOI: 10.1039/D4GC03455D, Paper
Yuefeng Qiu, Peng Jiang, Wenkai Ye, Jiahao Hu, Bin Zhang, Tuo Ji, Liwen Mu, Xin Feng, Xiaohua Lu, Jiahua Zhu
A spatially integrated electrochemical–thermal tandem reaction generates propylene oxide at 1 atm using hydrogen, oxygen, and propylene as feedstock.
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