Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article

Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article

Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti₃C₂T_x lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01947D, Research Article

Hyeonggeun Choi, Seunghwan Jo, Ki Hoon Shin, HeeYoung Lim, Liting Zhang, Keon Beom Lee, Young-Woo Lee, Jung Inn Sohn
A charge valence state and surface-electronegativity-modulated NiMoCuCo composite is proposed as an active and durable alkaline hydrogen evolution reaction electrocatalyst with moderated hydroxide adsorption energy.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article

Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02311K, Research Article

Jingyi Ma, Zhihan Chang, Xue Xi, Juju Liang, Yuchun Lin, Yaling Zhu, Xiuli Wang
Electrocatalytic water cracking for hydrogen evolution has drawn the concern from researchers owing to its high efficiency. Polymolybdate has excellent redox behaviors and O-rich surface, becoming attractive electrocatalytic materials. In...
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Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article

Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe₃O₄ decorated MXenes in the removal of highly toxic ¹³³Ba and ¹³⁷Cs using a radioactive indicator method.
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Inorg. Chem. Front., 2024, 11,7812-7821
DOI: 10.1039/D4QI02131B, Research Article

Oshan J. Jinarathne, Malkanthi K. Karunananda
Metal–metal bonds facilitate a red-shift in the maximum absorption wavelength and an enhancement of the oscillator strength in photosensitizers.
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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru₂Cl(D-p-CNPhF)(O₂CCH₃)₃]_n (D-p-CNPhF⁻ = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Inorg. Chem. Front., 2024, 11,7872-7885
DOI: 10.1039/D4QI01874E, Research Article

Open Access

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Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo Busico
The stability and reactivity of {[iBu₂(L)Al]₂(μ-H)}⁺[B(C₆F₅)₄]⁻ (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).
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Inorg. Chem. Front., 2024, 11,7886-7897
DOI: 10.1039/D4QI02020K, Research Article

Zhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping Zhao
Complete conversion of MgCo₂O₄ with excellent electrochemical performance has been successfully achieved.
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Inorg. Chem. Front., 2024, 11,7991-8002
DOI: 10.1039/D4QI01976H, Research Article

Linjian Zhan, Junyi Zhang, Boyuan Ning, Yunhui He, Guangcan Xiao, Zhixin Chen, Fang-Xing Xiao
Ag₂₅(SR)₁₈ nanocluster is utilized to couple with transition metal chalcogenides for constructing TMC/Ag₂₅(SR)₁₈ heterostructures, which demonstrate boosted photoactivities toward selective organic transformation and heavy metal reduction.
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Inorg. Chem. Front., 2024, 11,7947-7954
DOI: 10.1039/D4QI01685H, Research Article

Meng Feng, Jiantang Li, Xirong Wang, Jingyu Wang, Dongmei Wang, Banglin Chen
Benefitting from reticular chemistry, the newly developed MOF material ZJNU-400 establishes a low-polarity environment that enables reversed ethane adsorption and facilitates the efficient separation of C₂H₆/C₂H₄.
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Inorg. Chem. Front., 2024, 11,7930-7935
DOI: 10.1039/D4QI01965B, Research Article

Dipanwita Palit, Debasish Manna
TET enzymes play a key role in epigenetic regulation by oxidizing 5-methylcytosine, impacting gene expression and DNA methylation. Here, we report a chemical model of the TET enzyme which selectively and catalytically oxidize 5-hydroxymethylcytosine.
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Inorg. Chem. Front., 2024, 11,8003-8015
DOI: 10.1039/D4QI02005G, Research Article

Jiawei Liu, Xin Liu, Chunhui Dai, Chao Zeng, Sajjad Ali, Mohamed Bououdina, Yushuai Jia
Bi₂MoO₆ catalysts doped by monovalence Cu with self-adapting O vacancies (Ov) are prepared. The optimal Bi₂MoO₆–10% Cu exhibits an outstanding CO evolution rate of 11.40 μmol g⁻¹ h⁻¹, about 6 times higher than that of Bi₂MoO₆ (1.94 μmol g⁻¹ h⁻¹).
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Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article

Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb³⁺-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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Inorg. Chem. Front., 2024, 11,8016-8024
DOI: 10.1039/D4QI01661K, Research Article

Yan Li, Fei Zhang, Miaomiao Wu, Yong Guo, Yuanyuan Liang, Reyihanguli Ababaikeri, Luyang Wang, Qiao Liu, Xingchao Wang
δ-MnO₂ anchored in N-doped carbon fibers, derived from coal, was prepared using an electrospinning method, demonstrating enhanced performance in AZIBs.
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Inorg. Chem. Front., 2024, 11,7910-7920
DOI: 10.1039/D4QI01808G, Research Article

Xinxuan Yang, Lexin Wang, Meihan Liu, Jiahui Jin, Lili Yang, Lin Fan, Maobin Wei, Huilian Liu, Haoran Chen, Jinghai Yang, Yulei Chang, Fengyou Wang
A reconstruction strategy is designed to manipulate the surface microstructure of a CBD SnO₂ ETL, yielding PSCs with a high PCE >24%.
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Inorg. Chem. Front., 2024, 11,7936-7946
DOI: 10.1039/D4QI01835D, Research Article

Xinxin Guo, Mengmeng Zhou, Ziwu Liu, Shiheng Mu, Kaijia Wang, Huanqiang Shi, Fang Wang, Shijian Lu, Zhonghai Ni, Guiqing Liu
A self-standing high-entropy FeCoMnCuNiSe₂ electrode exhibited superior HER activity and OWS performance due to high entropy, lattice distortion and tip-enhancement effects.
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Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article

Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH₄Ce₃F₁₃ is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Inorg. Chem. Front., 2024, 11,8078-8092
DOI: 10.1039/D4QI01704H, Research Article

Zhengzheng Xu, Yanjiao Li, Shiqi Li, Yingying Chen, Majid Farahmandjou, Guoxiu Wang, Hongxun Yang, Hao Tian
A facile and general strategy is developed for constructing graphene aerogels with in situ encapsulated bimetallic selenide heterostructure materials exhibiting high rate-capabilities and long cycling stabilities in sodium-ion batteries.
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article

Open Access

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Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Inorg. Chem. Front., 2024, 11,8037-8046
DOI: 10.1039/D4QI01580K, Research Article

Liang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu Lin
Two-dimensional chiral bismuth–porphyrin metal–organic frameworks featuring mesoscopic square spiral terrace morphology significantly enhance H₂O₂ photosynthesis.
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Inorg. Chem. Front., 2024, 11,8047-8069
DOI: 10.1039/D4QI01943A, Research Article

Michal Liberka, Mikolaj Zychowicz, Laurine Vasseur, James Hooper, Szymon Chorazy
Modification of an organic linker bonding two cyanido-nitrido Re(V) complexes enables the tuning of the emission mechanism that non-trivially modulates the photoluminescence and its applicability for temperature sensing.
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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article

Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H₂] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k²-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h⁻¹.
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Inorg. Chem. Front., 2024, 11,7831-7842
DOI: 10.1039/D4QI02064B, Research Article

Ao Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli Zhou
Limited by the poor electronic conductivity and strong interaction between Mg²⁺ and MoS₂, the 2H phase of MoS₂ as a cathode material exhibits low capacity and poor rate capability.
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Inorg. Chem. Front., 2024, 11,7756-7774
DOI: 10.1039/D4QI02232G, Review Article

Hangwei Jia, Xueling Hou, Shilie Pan
The calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.
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Inorg. Chem. Front., 2024, 11,7822-7830
DOI: 10.1039/D4QI02027H, Research Article

Haisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing Ren
Benefiting from the long-range synergistic effect between Pt_n clusters and Zn₁ single atoms, Pt_n@Zn₁-N–C displays superior catalytic performance in selective hydrogenations.
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Inorg. Chem. Front., 2024, 11,8025-8036
DOI: 10.1039/D4QI01804D, Research Article

Fangyuan Yu, Qifa Lin, Xiangfu Zeng, Ping Zhou, Xiao Wu, Cong Lin, Chunlin Zhao, Min Gao, Tengfei Lin, Xingan Jiang, Laihui Luo, Qiwei Zhang
Sr/Er was codoped in KNN ceramics to induce the coexistence of O and T phases, resulting in improving optical transparency, maintaining moderate ferroelectricity, inducing excellent PC behavior and fluorescence temperature sensing performance.
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Inorg. Chem. Front., 2024, 11,8093-8100
DOI: 10.1039/D4QI02276A, Research Article

Qing Ma, Sen Yin, Ziye Song, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng Li
The dinuclear helicate Eu₂(L^R)₄ exhibits a solvent-regulated metal stereocenter Δ/Λ configurational inversion, independent of P/M helical conformational conversion. This reversal process is accompanied by an inversion of the CPL.
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Inorg. Chem. Front., 2024, 11,8123-8129
DOI: 10.1039/D4QI02019G, Research Article

Xiaojia Wang, Wei Zheng, Xiangzhou Zhang, Xiangxiang Chen, Yuhai Zhang
Cs₂NaScCl₆ crystals exhibit a pure blue emission originating from self-trapped excitons, which is significantly boosted by Mn²⁺/Sb³⁺ doping. The doped crystals shows not only a PL QY up to 62.4% but also a long afterglow after X-ray excitation.
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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article

Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article

Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)_n@CNT materials effectively boost OER catalysis.
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Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article

Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article

Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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Inorg. Chem. Front., 2024, 11,7682-7755
DOI: 10.1039/D4QI01363H, Review Article

Open Access

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Subrata Mandal, Sahar Yoosefi, Alexander K. Mengele, Sven Rau, Andrea Pannwitz
Metal–organic frameworks (MOFs) integrate photoactive and catalytic entities within a 3D structure. This review classifies photocatalytic MOFs by photosensitizer and catalyst localization and their roles in artificial photosynthesis.
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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article

Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co₃O₄ nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article

Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Inorg. Chem. Front., 2024, 11,8146-8146
DOI: 10.1039/D4QI90072C, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Ru-Ling Tang, Gang-Xiang Liu, Wen-Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng-Ping Guo
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Inorg. Chem. Front., 2024, 11,8147-8147
DOI: 10.1039/D4QI90073A, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Maddalena Paolillo, Giarita Ferraro, Irene Cipollone, Eugenio Garribba, Maria Monti, Antonello Merlino
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02324B, Research Article

Xiya Du, Lei Sun
Reducing the spin concentration, spin-orbit coupling strength, and ground spin state of lanthanide ions embedded in metal–organic frameworks improves their spin qubit performance.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02333A, Research Article

Weiwei Bao, Mameng Yang, Taotao Ai, Jie Han, Zhifeng Deng, Xiangyu Zou, Peng Jiang, Junjun Zhang
The oxygen-containing anion formed by electrooxidation and leaching on the electrode surface can effectively improve the catalytic activity of UOR and provide an accurate way for the energy saving hydrogen production assisted by urea.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02162B, Research Article

Ni-Ya Li, Xin-Yu Wang, Pei-Xuan Zhang, Ning-Ning Zou, Wen Qiu, Yu-Fei Xing, Yun-Jian Wang, Xiao-Yan Tang, Dong Liu
A unique coordination polymer can transform between comb-like and ladder-like bistable structures through reversible single-crystal-to-single-crystal photoreaction and exhibit photo-switchable fluorescence.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02383H, Review Article

Maiyong Zhu
Ionic liquids (ILs) as emerging solvents have demonstrated a significant prospective in green chemistry, which can be used as green solvent, high efficiency catalyst, electrolyte, and so on. Metal–organic frameworks...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02343A, Research Article

Yu-Xuan Zhang, Yi-Jie Ma, Yu-Jia Zhao, Zi-Yan Wang, Cai-Xia Yu, Xiaoqiang Li, Lei-Lei Liu
Exploration of non-noble-metal-based catalysts with high catalytic activity and selectivity is significant for driving innovation in green chemistry and technology. Herein, we report a facile synthesis of two-dimensional (2D) NiCo-MOF...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article

Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01942C, Research Article

Zhou Fang, Yi Tong, Yue Yang, Anjun Hu, Jianping Long, Yan Zhao, Xin Lai, Daojiang Gao, Mengjiao Liu
The present work simultaneously addresses the structural instability and poor diffusion kinetics of NH₄V₄O₁₀ cathodes using Ag⁺ intercalation, providing a new perspective on transition metal ion intercalation towards high-performance cathodes for AZIBs.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02143F, Research Article

Tongzheng Zhang, Zhaohui Huang, Guanshun Xie, Le Liao, Changqiang Yu, Xiuqiang Xie, Nan Zhang
La/Ni-MOF with oxygen vacancies and regulated electronic structures is prepared and exhibits enhanced visible-light photocatalytic activity for CO₂-to-CO conversion.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02135E, Research Article

Tao Shao, Xianmeng Song, Zongnan Wei, Shuaibing Yang, Siying Zhang, Rong Cao, Minna Cao
Pd NP modification with Me₁₀CB[5]–M capsules boosted CO₂RR by enhancing CO₂ adsorption, tuning Pd's electronic structure, and optimizing *COOH/*CO binding.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02325K, Research Article

Weijie Fang, Chaofan Liu, Jiang Wu, Weikai Fan, Le Chen, Zaiguo Fu, Lin Peng, Ping He, Jia Lin, Zhongwei Chen
The moss-like amorphous CoB/crystalline CeO₂ heterojunction nanosheets synthesized in this study have excellent OER activity and stability.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02016B, Research Article

Xiaoyu Jiang, Boran Tao, Hongda Li
A multistage construction of the Gd-doped g-C₃N₄/Mo₁₅S₁₉ catalyst, with Gd³⁺ as redox centers and Mo₁₅S₁₉ as N₂ activation sites, synergistically enhances its photocatalytic NRR performance.
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