an

Form II to form I transition in solution-crystallized isotactic polybutene-1

Soft Matter, 2024, 20,3191-3202
DOI: 10.1039/D4SM00152D, Paper
Peng Fu, Jiaxin Huo, Jingqing Li, Claudio De Rosa, Shichun Jiang
Different polymer chains in a solution or melt have different conformations with corresponding entropy at each moment, which would be confined after crystallization.
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an

Destructive effect of fluctuations on the performance of a Brownian gyrator

Soft Matter, 2024, 20,3154-3160
DOI: 10.1039/D3SM01606D, Paper
Pascal Viot, Aykut Argun, Giovanni Volpe, Alberto Imparato, Lamberto Rondoni, Gleb Oshanin
The Brownian gyrator is often called a minimal model of a nano-engine performing a rotational motion, because in non-equilibrium conditions its torque, specific angular momentum  and specific angular velocity  have non-zero mean values.
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an

Steering droplets on substrates with plane-wave wettability patterns and deformations

Soft Matter, 2024, 20,3161-3174
DOI: 10.1039/D4SM00213J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Josua Grawitter, Holger Stark
Motivated by strategies for targeted microfluidic transport of droplets, we investigate how sessile droplets can be steered toward a preferred direction using travelling waves in substrate wettability or deformations of the substrate.
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an

Fabric-based jamming phase diagram for frictional granular materials

Soft Matter, 2024, 20,3175-3190
DOI: 10.1039/D3SM01277H, Paper
Yuxuan Wen, Yida Zhang
Fabric-based jamming phase diagram, where Ft and Zt are the fabric anisotropy (deviatoric invariant of the 2nd order fabric tensor) and the coordination number (mean invariant of the 2nd order fabric tensor) of the total-contact network, respectively.
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an

Mechanical guidance to self-organization and pattern formation of stem cells

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00172A, Paper
Wei-Hua Zhou, Lin-Ru Qiao, She-Juan Xie, Zhuo Chang, Xu Yin, Guang-Kui Xu
We introduce a mechanical model based on the dynamic balance between cell-ECM-culture environment, and demonstrate that it can capture specific phenomena in stem cell pattern formation experiments guided by geometric constraints.
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an

Can self-propelled objects escape from compression stimulation?

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00288A, Paper
Open Access
Masaki Yoshikai, Muneyuki Matsuo, Nobuhiko J. Suematsu, Hiraku Nishimori, Satoshi Nakata
We studied circular papers impregnated with camphor (CPs) and CPs with magnets (MCPs) as self-propelled objects floating on water under the compression of the water surface as an inanimate system for evacuation in an emergency.
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A microrheological examination of insulin-secreting β-cells in healthy and diabetic-like conditions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01141K, Paper
Open Access
Lukas Woolley, Adam Burbidge, Jan Vermant, Fotis Christakopoulos
We provide an insight into the compliance of β-cells and explore structural changes in conditions relevant to type-2 diabetes, showing an altered transport behavior and hindering the effective control of insulin secretion.
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A computational study of cell membrane damage and intracellular delivery in a cross-slot microchannel

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00047A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruixin Lu, Peng Yu, Yi Sui
The inertial effect increases the cell deformation and membrane damage in the channel cross-slot; however, the enhancement can be reversed by the cell membrane viscosity.
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an

Divergent self-assembly propensity of enantiomeric phenylalanine amphiphiles that undergo pH-induced nanofiber-to-nanoglobule conversion

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00117F, Paper
Manas Kumar Pradhan, Nayanika Misra, Fathima Sahala, Nyaya Prakash Pradhan, Aasheesh Srivastava
Enantiomeric single phenylalanine derivatives demonstrate very different self-assembling propensity and thermodynamic parameters associated with self-assembly.
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an

Adsorption of semiflexible wormlike polymers to a bar and their double-chain complex formation

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper
Open Access
A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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an

Measuring mechanical cues for modeling the stromal matrix in 3D cell cultures

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01425H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Linda Srbova, Ossi Arasalo, Arttu J. Lehtonen, Juho Pokki
An approach to quantify microscale viscoelasticity in breast-cancer-associated stromal tissues was developed for cell-scale analyses of physiologically stiff 3D cell cultures.
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an

Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00216D, Paper
Yuting Wan, Yuening Qiu, Jin Zhou, Jinbo Liu, Martien A. Cohen Stuart, Yangfeng Peng, Junyou Wang
Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors.
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an

Enzymatic functionalization of decellularized tilapia skin scaffolds with enhanced skin regeneration

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01742G, Paper
Cuixia Chen, Wenwen Tao, Di Jiang, Yanyan Yang, Tiantian Liang, Qilong Gu, Yuran Xu, Junjuan Zhao, Xing Zhou, Xinglong Fan
The enzymatic dTS/RGD scaffolds, possessing medium mechanical strength, a rapid degradation rate and enough cell responsive motifs, provide a suitable microenvironment for wound healing, which make them potential in skin regeneration engineering.
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an

Spatiotemporal Mapping of Nanotopography and Thickness Transitions of Ultrathin Foam Films

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00048J, Tutorial Review
Chenxian Xu, Yiran Zhang, Vivek Sharma
Freshly formed soap films, soap bubbles, or foam films display iridescent colors due to thin film interference that changes as squeeze flow drives drainage and a steady decrease in film...
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an

Pinning–depinning transition of droplets on inclined substrates with a three-dimensional topographical defect

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00081A, Paper
Ninad V. Mhatre, Satish Kumar
The influence of defect geometry on the critical inclination angle required for droplet depinning on inclined substrates is studied.
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an

Dynamic compaction of cohesive granular materials: scaling behavior and bonding structures

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01116J, Paper
Open Access
Max Sonzogni, Jean-Mathieu Vanson, Katerina Ioannidou, Yvan Reynier, Sébastien Martinet, Farhang Radjai
The compaction of cohesive granular materials is a common operation in powder-based manufacture of many products.
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an

Avalanche properties at the yielding transition: from externally deformed glasses to active systems

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01354E, Paper
Open Access
Carlos Villarroel, Gustavo Düring
We investigated the yielding phenomenon under different scenarios of deformation in the quasistatic limit using numerical simulations of soft particles.
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an

Hydrogen bonding enhanced drug–polymer interaction for efficient drug loading and delivery

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00003J, Communication
Xiaotian Qu, Junran Li, Yishu Yu, Jie Yang
A carrier design strategy of hydrogen bonding enhanced drug–carrier interaction is developed to prepare a polymeric nanomedicine with high drug loading content and superb loading efficiency as well as tunable nanostructures.
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an

Self-healing polyacrylates based on dynamic disulfide and quadruple hydrogen bonds

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00257A, Paper
Longjin Du, Yuting Zhong, Linying Zhao, Chengzhen Hu, Liang Shen, Yuping Yang, Jiang Zhong
Herein, a self-healing polyacrylate system was successfully prepared by introducing crosslinking agents containing disulfide bonds and monomers capable of forming quadruple hydrogen bonds through free radical copolymerization.
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an

Novel turbulence and coarsening arrest in active-scalar fluids

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00163J, Paper
Nadia Bihari Padhan, Kolluru Venkata Kiran, Rahul Pandit
We uncover a new type of turbulence – activity-induced homogeneous and isotropic turbulence – in a model that has been employed to investigate motility-induced phase separation (MIPS) in a system of microswimmers.
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The effect of structural changes on the self-assembly of novel green pyridinium-carboxylate gemini surfactants in Langmuir and Langmuir–Blodgett films

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01671D, Paper
Ala’a F. Eftaiha, Abdussalam K. Qaroush, Dina M. Foudeh, Ahmad S. Abo-shunnar, Suhad B. Hammad, Khaleel I. Assaf, Matthew F. Paige
The synthesis and interfacial characterization of a series of gemini surfactants based on pyridine-n-carboxylic acids, including picolinic, nicotinic, and isonicotinic acids, in Langmuir and Langmuir–Blodgett films have been reported.
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an

Temperature dependence of micelle shape transitions in copolymer solutions: the role of inter-block incompatibility

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00331D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. J. Greenall, M. J. Derry
The incompatibility of the blocks in a copolymer strongly affects the temperature dependence of the micelle shape transitions in solution.
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an

Spontaneous crumpling of active spherical shells

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00015C, Paper
Open Access
M. C. Gandikota, Shibananda Das, A. Cacciuto
The existence of a crumpled Flory phase for equilibrated self-avoiding elastic surfaces has remained contentious. Here, we show that a crumpled phase develops reliably upon subjecting a thin spherical self-avoiding shell to active fluctuations.
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an

The interplay of chirality and restricted rotation: stabilisation of chiral, frustrated mesophases over a wide thermal range

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00126E, Paper
Sachin A. Bhat, Channabasaveshwara V. Yelamaggad
Chiral dimers formed by linking cholesterol to phenyl 3-(4-(n-alkoxy)phenyl)propiolate via ω-oxyalkanoyloxy spacer exhibit odd–even effect, stabilizing SmA, N*, BPI/II, & TGBC* phases. TGBC* phase width increases with longer terminal tails.
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an

Multiple physical crosslinked highly adhesive and conductive hydrogels for human motion and electrophysiological signal monitoring

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00195H, Paper
Qirui Wu, Anbang Chen, Yidan Xu, Songjiu Han, Jiayu Zhang, Yujia Chen, Jianren Hang, Xiaoxiang Yang, Lunhui Guan
Ionic conducting hydrogel (ICHgel) was synthesized by doping fumed SiO2, which exhibited superior stretchability, conductivity, and adhesiveness, making it a promising bridge for effective communication between electronic devices and human tissues.
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an

Improved ionic current rectification utilizing cylindrical nanochannels coated with polyelectrolyte layers of non-uniform thickness

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00123K, Paper
Nader Nekoubin, Steffen Hardt, Arman Sadeghi
We show that a cylindrical nanochannel coated with a polyelectrolyte layer of non-uniform thickness can be a good alternative to the widely-used conical nanochannels in creating ionic current rectification.
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an

Deformation-dependent gel surface topography due to the elastocapillary and osmocapillary effects

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00139G, Paper
Open Access
Luochang Wang, Qihan Liu
Elastocapillary and osmocapillary effects can roughen a stretched surface although the elastic Poisson’s effect always flattens a stretched surface.
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an

Morphology of Impact Polypropylene Copolymer Extruded Cast Film Revealed by Confocal Raman Imaging

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00156G, Paper
Chunbo Zhang, Meng Xu, Minqiao Ren, Hongwei Shi, Guoming Liu, Juan Li, Xuanbo Liu, Longgui Zhang, Dali Gao
An impact polypropylene copolymer (IPC), composed of polypropylene (PP) and ethylene-propylene copolymer (EPC), was synthesized through two-stage in-reactor polymerization. A systematic investigation of the crystalline structure, thermal behavior, morphology, and...
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an

Lock-Key Microfluidics: Simulating Nematic Colloid Advection along Wavy-Walled Channels

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D3SM01536J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Karolina Wamsler, Louise C Head, Tyler Nathan Shendruk
Liquid crystalline media mediate interactions between suspended particles and confining geometries, which not only has potential to guide patterning and bottom-up colloidal assembly, but can also control colloidal migration in...
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Dynamics and phase behavior of metallo-dielectric rod-shaped microswimmers driven by Alternating Current electric field

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00206G, Paper
Suvendu Kumar Panda, Srikanta Debata, Nomaan Alam Kherani, Dhruv Pratap Singh
The ability to move and self-organize in response to external stimuli is a fascinating feature of living active matter. Here, the metallo-dielectric rod-shaped microswimmers are shown to have a similar...
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A mean-field theory for predicting single polymer collapse induced by neutral crowders

Soft Matter, 2024, 20,3271-3282
DOI: 10.1039/D3SM01522J, Paper
Quentin Chaboche, Gerardo Campos-Villalobos, Giuliana Giunta, Marjolein Dijkstra, Marco Cosentino Lagomarsino, Vittore F. Scolari
Depletion forces arising from molecular crowding compact single polymers. Simulations lead to a unified description. Collapse is governed by the packing fraction of crowders and the ratio of crowder to monomer size, and can be hindered by jamming.
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Bending creep behaviour of various polymer films analysed by surface strain measurement

Soft Matter, 2024, 20,3248-3255
DOI: 10.1039/D3SM01566A, Paper
Jiayi Yu, Masayuki Kishino, Kyohei Hisano, Atsushi Shishido
Polymer films subjected to a static bending state exhibit temporal strain increase due to their viscoelastic nature. We quantitatively measured the surface strain change in various polymer films in real time and gained insights into the occurrence of this phenomenon.
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In silico design of misfolding resistant proteins: the role of structural similarity of a competing conformational ensemble in the optimization of frustration

Soft Matter, 2024, 20,3283-3298
DOI: 10.1039/D4SM00171K, Paper
Bondeepa Saikia, Anupaul Baruah
The degree of similarity of the non-native conformations to the target plays a prominent role in designing misfolding resistant protein sequences.
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Achieving controllable and reversible snap-through in pre-strained strips of liquid crystalline elastomers

Soft Matter, 2024, 20,3256-3270
DOI: 10.1039/D4SM00037D, Paper
Open Access
James T. Waters, Anna C. Balazs
Deformable, elastic materials that buckle in response to external stimuli can display “snap-through”, which involves a transition between different, stable buckled states.
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Effects of shear-induced crystallization on the complex viscosity of lamellar-structured concentrated surfactant solutions

Soft Matter, 2024, 20,3299-3312
DOI: 10.1039/D3SM01198D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Parth U. Kelkar, Matthew Kaboolian, Ria D. Corder, Marco Caggioni, Seth Lindberg, Kendra A. Erk
Material relationships at low temperatures were determined for concentrated surfactant solutions using a combination of rheological experiments, cross-polarized microscopy, calorimetry, and small angle X-ray scattering.
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Cosolvent incorporation modulates the thermal and structural response of PNIPAM/silyl methacrylate copolymers

Soft Matter, 2024, 20,3322-3336
DOI: 10.1039/D4SM00246F, Paper
Jason D. Linn, Fabian A. Rodriguez, Michelle A. Calabrese
The nanoscale structure formation and optical response of aqueous thermoresponsive polymers with reactive silane groups can be widely tuned via polymer architecture and organic cosolvent incorporation.
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Interaction between stabilized droplets of different phases in the same continuous phase of an aqueous three-phase system

Soft Matter, 2024, 20,3359-3366
DOI: 10.1039/D3SM01688A, Paper
Do-Nhu-Trang Nguyen, Léa Waldmann, Valérie Ravaine, Taco Nicolai, Lazhar Benyahia
Janus-like droplets, covered with microgel, formed after the fusion of gelatin and dextran droplets in a common poly(ethylene oxide) phase.
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Braiding, twisting, and weaving microscale fibers with capillary forces

Soft Matter, 2024, 20,3337-3348
DOI: 10.1039/D3SM01732J, Paper
Ahmed Sherif, Maya Winters Faaborg, Cheng Zeng, Michael P. Brenner, Vinothan N. Manoharan
We present a 3D-printed machine that uses repulsive capillary forces to programmably braid, twist, and weave micrometer-scale fibers.
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Pure elongation flow of an electrorheological fluid: insights on wall slip from electrorheology

Soft Matter, 2024, 20,3313-3321
DOI: 10.1039/D3SM01448G, Paper
Ishu Chaudhary, Manish Kaushal
We study the pure elongation flow behavior of an electrorheological fluid as a model soft-jammed system, wherein the extent of jamming is controlled by an externally applied electric-field. Additionally, this study offers general insight into how jamming affects slip dynamics.
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Strong, tough and conductive single-network hydrogels based on deswelling and the salting-out effect

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00298A, Paper
Xingyue Sun, Haiyi Liang, Lina Ye
By comparing the mechanical properties between salt-treated hydrogels and air-dried hydrogels, the synergistic effect in energy transfer and dissipation arising from increases in polymer fraction and cross-linking plays an indispensable role in toughening SN hydrogels.
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an

Particle-based and continuum models for confined nematics in two dimensions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01684F, Paper
Humberto Híjar, Apala Majumdar
Particle-based mesoscopic simulations conduct 2D nematics confined in polygons through consistent defect annihilation dynamics and produce unstable structures that transform into equilibrium textures predicted by the Landau-de Gennes theory.
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Angle-resolved optical spectroscopy of photonic cellulose nanocrystal films reveals the influence of additives on the mechanism of kinetic arrest

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00155A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas G. Parton, Richard M. Parker, Sonja Osbild, Silvia Vignolini, Bruno Frka-Petesic
Photonic films produced by cellulose nanocrystal self-assembly offer a sustainable source of colouration. Their angular optical response reveals the suspension conditions at kinetic arrest and how common additives affect this liquid–solid transition.
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The sweetest polymer nanoparticles: opportunities ahead for glycogen in nanomedicine

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00261J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Quinn A. Besford
Glycogen is a biomaterial nanoparticle composed of sugar. In this perspective, the opportunities of glycogen in nanomedicine going forward is discussed.
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Effect of Aromatic Side Chain on the Dilational Rheological Properties of N-Acyltaurate Amphiphiles at Water-Decane Interfaces

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00269E, Paper
Yang-Wen Zhu, Zhicheng Xu, Li Zhang, Ping Liu, Yu Hou, Lei Zhang, Lu Zhang
To elucidate the effect of aromatic side chains on dilational rheological properties of N-acyltaurate amphiphiles at the decane-water interface, the interfacial rheological properties of sodium N-2-(2-naphthoxy)-tetradecanolytaurinate (12+N-T) and sodium N-2-(p-butylphenoxy)-...
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Surface charge density and induced currents by self-charging sliding drops

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00205A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pravash Bista, Aaron D. Ratschow, Amy Z. Stetten, Hans-Jürgen Butt, Stefan A.L. Weber
Sliding drops induce a bipolar current in subsurface electrodes beneath a hydrophobic substrate. We show how it depends on substrate properties and how it can be optimized for energy harvesting.
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an

Ligand-dependent folding and unfolding dynamics and free energy landscapes of acylphosphatase

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00131A, Paper
Li Yuan, Hao Sun, Xuening Ma, Yang Wang, Zilong Guo, Xingyu Qi, Shimin Le, Hu Chen
The free energy landscapes of AcP in the absence and presence of Pi are constructed by using stable magnetic tweezers.
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Capillary imbibition of confined monodisperse emulsions in microfluidic channels

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00179F, Paper
Masoud Norouzi Darabad, Sagnik Singha, Siva A. Vanapalli, Mark W. Vaughn, Jerzy Blawzdziewicz
Emulsion imbibition into flat capillaries is very complex. We show that formation of a clear-fluid or dense-emulsion region behind the meniscus, concentration and velocity fluctuations, and generation of ordered domains are confinement controlled.
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A versatile route for the fabrication of micro-patterned polylactic-acid (PLA)-based membranes with tailored morphology via breath figure imprinting

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00107A, Paper
Rayane Akoumeh, Manale Noun, Deepalekshmi Ponnamma, Maryam Al-Ejji, Khadija M. Zadeh, Alaa H. Hawari, Kenan Song, Mohammad K. Hassan
Breath figure imprinting, based on surface instabilities combined with fast polymer evaporation in a humid environment, enables the creation of micro-patterned membranes with tailored pore sizes.
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an

Energy dissipation of a contact line moving on a nanotopographical defect

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00161C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sylvain Franiatte, Germercy Paredes, Thierry Ondarçuhu, Philippe Tordjeman
We measure by dynamic atomic force microscopy the dissipated energy when a contact line moves on an individual nanotopographical defect.
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an

Structural interactions in polymer-stabilized magnetic nanocomposites

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00008K, Paper
Open Access
Gauri M. Nabar, Abhilasha V. Dehankar, Elizabeth Jergens, Benworth B. Hansen, Ezekiel Johnston-Halperin, Matthew Sheffield, Joshua Sangoro, Barbara E. Wyslouzil, Jessica O. Winter
Superparamagnetic iron oxide nanoparticles (SPIONs) can align in polymer-stabilized aggregates, changing their properties.
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