J. Mater. Chem. A, 2024, 12,30279-30288
DOI: 10.1039/D4TA04014G, Paper

Kotaro Ishihara, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Shunsuke Nozawa, Akinori Saeki, Ryu Abe
Function-/site-selective hybridisation of two specific Ru(II) complex catalysts on donor–acceptor conjugated polymers enables bifunctional visible-light water oxidation and CO₂ reduction.
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J. Mater. Chem. A, 2024, 12,30768-30782
DOI: 10.1039/D4TA03416C, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Lion Schumacher, Jana Timm, Roland Marschall
Hydrothermal treatment of mesoporous photocatalysts in diluted NaOH solution or H₂O might be a simple and promising strategy to improve photocatalytic activities in general, as we show for TiO₂ and SrTiO₃/TiO₂ composites.
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J. Mater. Chem. A, 2024, 12,30783-30797
DOI: 10.1039/D4TA05336B, Paper

Debasish Ghosh, Dimple K. Bora, Asit Baran Panda
Mn₃O₄@CeO₂/γ-FeOOH hetero-structure showed interfacial electron coupling induced superior bifunctional electrocatalytic activity suitable for AEM electrolyser.
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J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper

Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
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J. Mater. Chem. A, 2024, 12,30729-30742
DOI: 10.1039/D4TA04079A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Mohamed I. Helal, Alessandro Sinopoli, Ivan Gladich, Yongfeng Tong, Radwan Alfahel, Tricia Gomez, Khaled A. Mahmoud
Two-dimensional (2D) lamellar MXene membranes have demonstrated ultrafast water permeance and outstanding ion rejection performance, thus showing great potential for water purification.
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J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co₉S₈ (pre)catalyst derived from a novel {Co^IIS₄} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co₉S₈ reconstructs completely into a CoOOH active phase via S-leaching.
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J. Mater. Chem. A, 2024, 12,30601-30610
DOI: 10.1039/D4TA05955G, Paper

Song-Bai Xiang, Xiyu Zhang, Yue Hou, Wenjing Li, Chengri Yin, Zhenxing Yin
A 3D soft current collector with excellent lithiophilicity was obtained by constructing a conductive Ag-CuNW/MWCNT network on a melamine foam, which can effectively reduce the local current density and guide the uniform Li deposition.
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J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper

Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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J. Mater. Chem. A, 2024, 12,30862-30871
DOI: 10.1039/D4TA04729J, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Li-Chung Kin, Andreas Distler, Oleksandr Astakhov, Bakary Kone, Hans Kungl, André Karl, Tsvetelina Merdzhanova, Rüdiger-A. Eichel, Christoph J. Brabec, Uwe Rau
Generalized framework for the design of indoor power units for autonomous Internet of Things (IOT) devices results in record efficiency combination of organic PV and sodium ion battery.
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J. Mater. Chem. A, 2024, 12,30798-30809
DOI: 10.1039/D4TA04194A, Paper

Manigandan Ramadoss, Hesheng Yu, Anand Rajkamal, Gun Jin Yun, Ziheng Zhang, Chengtao Yang, Fei Ma, Yu Wu, Chen Daiqian, Yuanfu Chen
Fe-single-atom-coupled Fe₃C multifunctional catalysts on P-, F-, N-doped CNT deliver comparable OER behavior to RuO₂, better ORR performance than Pt/C, and better ZAB performance than Pt/C–RuO₂, due to the nanoarchitecture and abundant active sites.
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J. Mater. Chem. A, 2024, 12,30534-30547
DOI: 10.1039/D4TA06163B, Paper

Yang Xu, Gang Li, Jiangtao Hai, Hewei Yuan, Haotian Weng, Kun Li, Xiaolu Huang, Yanjie Su, Nantao Hu, Yafei Zhang
A free-standing 3D scaffold of nickel nanowires decorated with lithiophilic Ni₃S₂ nanosheets was successfully constructed for stable Li anodes.
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J. Mater. Chem. A, 2024, 12,30121-30168
DOI: 10.1039/D4TA05097E, Review Article

Yifan He, Shanshan Guo, Xueji Zhang, Lijun Qu, Tingting Fan, Jinlei Miao
Ultrathin 2D membranes were assembled by graphene and MXene nanosheets for separation to overcome the “trade-off” limitation between permeability and selectivity.
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J. Mater. Chem. A, 2024, 12,30558-30566
DOI: 10.1039/D4TA06146B, Paper

Qingya Wei, Yuanyuan Li, Weikun Chen, Qinhao Shi, Shaofeng Zhu, Wensheng Yan, Yingping Zou
A low-cost pentacyclic fused-ring SMA, BZ4F-ch1, was designed with a cyclohexyl side-chain, which achieved a high device efficiency over 16% with an FF over 80%. Besides, the highest PCE/MOC value of 3.56 revealed remarkable cost-effectiveness.
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J. Mater. Chem. A, 2024, 12,30298-30308
DOI: 10.1039/D4TA05825A, Paper

Fan Chen, Xian Song, Jingjing Fu, Jiaheng Liang, Junhua Zhou, Jiehua Cai, Yufei Zhang, Mengjia Zhu, Yichun Ding, Jinxing Jiang, Zijian Chen, Youchao Qi, Zhihao Zhou, Qiyao Huang, Yingying Zhang, Zijian Zheng
An all-fibrous self-powered electronic skin that offers textile-like breathability, intrinsic stretchability, skin adhesion, biocompatibility, and good sensing performance for real-time gesture recognition assisted by machine learning.
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J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper

Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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J. Mater. Chem. A, 2024, 12,30351-30361
DOI: 10.1039/D4TA05869K, Paper

Jiawei Huang, Weifeng Chen, Qiyan Kuang, Ting Xiao, Lihua Jiang, Xinyu Tan, Yizhu Lei
This study develops a state-of-the-art passive radiative cooling emitter with 95.5% reflectance and 97.9% emissivity, achieving an average temperature reduction of 20.1 °C and a cooling power of 121.0 W m⁻² under intense sunlight.
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J. Mater. Chem. A, 2024, 12,30743-30756
DOI: 10.1039/D4TA05082G, Paper

Niranjanmurthi Lingappan, Sandhiya Lakshmanan, Wonoh Lee
Designing an efficient and durable electrocatalyst is central to hydrogen production technologies such as hydrogen evolution reaction, oxygen evolution reaction, and urea oxidation reaction.
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J. Mater. Chem. A, 2024, 12,30486-30497
DOI: 10.1039/D4TA06543C, Paper

Jingyi Zhu, Yukun Chen, Patrick C. Lee, Shuidong Zhang
Developing recyclable microcellular rubber foams with excellent photothermal conversion ability can reduce resource waste and harvest solar energy to alleviate environmental pollution and the energy crisis simultaneously.
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J. Mater. Chem. A, 2024, 12,30371-30379
DOI: 10.1039/D4TA05290K, Paper

Xiaofei Gu, Jianyu Han, Zhi Wang, Yixin Hong, Tianyi Huang, Yafeng Wu, Yuanjian Zhang, Songqin Liu
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
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J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper

Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
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J. Mater. Chem. A, 2024, 12,30707-30721
DOI: 10.1039/D4TA04495A, Paper

Zhengyu Sun, Weiwei Sun, Shaohan Li, Zening Yang, Mutian Zhang, Yang Yang, Huayun Geng, Jin Yu
We propose an innovative GNN model, CrysGraphFormer, which accurately predicts lattice thermal conductivity and enhances insights for material discovery.
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J. Mater. Chem. A, 2024, 12,30190-30248
DOI: 10.1039/D4TA05386A, Review Article

Elmira Kohan, Roushan Khoshnavazi, Mir Ghasem Hosseini, Abdollah Salimi, Mehdi Salami-Kalajahi
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
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J. Mater. Chem. A, 2024, 12,30567-30581
DOI: 10.1039/D4TA04574B, Paper

Anju P. Veedu, Balasurendran Jeyakumar, Akhila Maheswari Mohan, Satheesh Kuppusamy, Pitchaiah K. Chinaraga, Manjula Muthurathinam, C. V. S. Brahmananda Rao, Sivaraman Nagarajan, Prabhakaran Deivasigamani
A solid-state naked-eye sensor composed of a mesoporous honeycomb structured silica monolith impregnated with a DMTHBD receptor offers a simple, rapid and eco-benign approach for the selective sensing of trace Cd²⁺, with brilliant color transitions.
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J. Mater. Chem. A, 2024, 12,30476-30485
DOI: 10.1039/D4TA04884A, Paper

Li-Bo Chen, Tong-Hui Wang, Xing-You Lang, Qing Jiang
The Lewis acid sites enhance N₂ adsorption and activation, while the flexible active center facilitates hydrogenation and NH₄⁺ formation, regenerating the catalyst.
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J. Mater. Chem. A, 2024, 12,30618-30628
DOI: 10.1039/D4TA04228J, Paper

Guang Zeng, Wenshuo Gao, Weicheng Qiu, Guanling Li, Shousen Chen, Xin He, Guoxing Sun, Weijia Yang, Yue Xin
A polyzwitterionic ionogel with a phase separation structure was designed to achieve a balance between mechanical robustness and ionic conductivity. This design holds immense potential for applications in wearable sensors.
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J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper

Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
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J. Mater. Chem. A, 2024, 12,30629-30641
DOI: 10.1039/D4TA05122J, Paper

Jianping Ma, Jinyi Guo, Weizheng Li, Xiaohan Yang, Chengde Huang
The introduction of a high-entropy structure into multi-metal sulfides has successfully mitigated volume expansion during the cycling process of sodium-ion batteries!
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J. Mater. Chem. A, 2024, 12,30420-30428
DOI: 10.1039/D4TA03949A, Paper

Jinyu Chen, Chao Chen, Chong Zhao, Na Tu, Yunjing Chen, Xin Nie, Xiaokun Huang, Jun-Ming Liu, Xiangping Jiang
The structural mechanism underlying the high piezoelectric activity of BF-BT was elucidated from the aspects of phase structure, domain dynamics, and octahedral torsion under an electric field.
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J. Mater. Chem. A, 2024, 12,30380-30387
DOI: 10.1039/D4TA05682E, Paper

Yahui Tian, Wenfang Zhai, Jie Su, Yuxin Zhao, Zhengfei Dai, Wei Gan, Hui Li
A black phosphorene-hosted NiO nanosheet heterostructure achieves enhanced surface Lewis basicity, delivering sensitive and selective sensor properties to trace H₂S gas.
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J. Mater. Chem. A, 2024, 12,30810-30820
DOI: 10.1039/D4TA05985A, Paper

Anubha Rajput, Ankita Kumari, Hirak Kumar Basak, Dibyajyoti Ghosh, Biswarup Chakraborty
MnMoO₄ is a barely explored material for the electrocatalytic oxygen evolution reaction (OER) and in situ tracking of the reactive intermediates and final active species during the OER in an alkaline pH lacks a sequential study.
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J. Mater. Chem. A, 2024, 12,30398-30408
DOI: 10.1039/D4TA05966B, Paper

Ning Ding, Yi Yang, Wei Zhou, Debora Puglia, Pengwu Xu, Deyu Niu, Weijun Yang, Piming Ma
Biobased polythiourethane/MXene nanocomposites with intrinsic flame-retardancy and remote ultrafast infrared “welding” performance.
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J. Mater. Chem. A, 2024, 12,30821-30830
DOI: 10.1039/D4TA05021E, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Jacqueline A. Penn, Wenting Hu, Ian S. Metcalfe, Greg A. Mutch
A H₂O driving force in the opposite direction to CO₂ permeation exerts control over CO₂ flux in a molten-salt membrane fabricated using hydroxides.
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J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper

Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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J. Mater. Chem. A, 2024, 12,30885-30891
DOI: 10.1039/D4TA03559C, Paper

Vasilis Nikolaou, Deborah Romito, Clément Maheu, Jonathan Hamon, Eric Gautron, Florian Massuyeau, Pierre-Emmanuel Petit, Stéphane Jobic, Fabrice Odobel
The first use of the successive ionic layer adsorption and reaction (SILAR) method to grow CdS quantum dots on TiO₂ nanoparticles, achieving efficient photocatalytic alcohol oxidation and H₂ evolution without catalysts or sacrificial donors.
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J. Mater. Chem. A, 2024, 12,30831-30841
DOI: 10.1039/D4TA04698F, Paper

Adil Saleem, Leon L. Shaw, Mehwish Khalid Butt, Javed Rehman, Arshad Hussain, Zawar Hussain, Rashid Iqbal, Muhammad Kashif Majeed
The demand for high-energy-density lithium-ion batteries (LIBs) has driven intensive research into cathode materials that exhibit both superior performance and stability over multiple charge–discharge cycles.
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J. Mater. Chem. A, 2024, 12,30548-30557
DOI: 10.1039/D4TA06039C, Paper

Open Access

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Jatinder Singh, Richard J. Staples, Jean'ne M. Shreeve
This study presents a feasible approach to synthesizing hydrazine/nitroamine and amino/nitroamine substituted tetrazine derivatives.
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J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper

Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper

Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper

Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd_(2−x)Gd_xO₄ nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper

Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO₃⁻ and H₂O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH₃ yield.
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J. Mater. Chem. A, 2024, 12,30842-30849
DOI: 10.1039/D4TA04961F, Paper

Xu Yan, Sheng Wang, Shicong Ding, Javed Rehman, Yong Liu, Guochun Yang
The proposed C₈P monolayer and its derivatives are promising candidates as anode materials for high performance K-ion batteries.
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J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper

Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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J. Mater. Chem. A, 2024, 12,30892-30905
DOI: 10.1039/D4TA05332J, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Khasim Saheb Bayikadi, Safdar Imam, Wei-Shen Tee, Sugumaran Kavirajan, Chiao-Yu Chang, Amr Sabbah, Fang-Yu Fu, Ting-Ran Liu, Ching-Yu Chiang, Dinesh Shukla, Chien-Ting Wu, Li-Chyong Chen, Mei-Yin Chou, Kuei-Hsien Chen, Raman Sankar
Phonon scattering processes to κ_lat of Ge_0.85Sb_0.1W_0.05Te: Umklapp, boundary, point-defect, stacking faults, resonant scattering, nanoprecipitates & microstructural effects. (b) κ_lat reduction (inset: ZT enhancement).
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J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H₂ (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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J. Mater. Chem. A, 2024, 12,30249-30268
DOI: 10.1039/D4TA06452F, Review Article

Yongxing Chen, Peng Long, Bin Liu, Yi Wang, Junlong Wang, Tian Ma, Huilin Wei, Yue Kang, Haining Ji
Machine learning, as a significant branch of artificial intelligence, shortens the cycle of material discovery and synthesis by exploring the characteristics of data.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06184E, Review Article

Taohong He, Yushan Han, Bofang Shi, Jianan Wang, Honghui Yang
The characteristics of interphase formation between ionic liquid-based electrolytes and various electrodes are reviewed to support the development of improved electrolyte designs for lithium-based batteries.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06221C, Review Article

Yutian Peng, Xingyu Zhang, Ruiling Sun, Xunlong Zhang, Can Ge, Yuqing Liu
Schematic illustration demonstrating various approaches to enhance the electrochemical performance of carbon nanofiber electrode materials.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06323F, Paper

Yang Song, Haidong Zhong, Tingting Hu, Qizhi Chen, Lei Shi, Jun Du, Changyuan Tao, Qian Zhang
An LMFP@MXene@C cathode material was fabricated by electrostatic adsorption and in situ graphitization, providing optimized Li⁺ transmission and a stable structure featuring ultrahigh average capacity and cycle stability.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication

Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper

Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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