Dalton Trans., 2020, 49,5396-5405
DOI: 10.1039/D0DT00587H, Perspective

Yajing Du, Hongzhi Liu
This Perspective reviews recent advances in cage-like silsesquioxanes-based hybrid materials, ranging from monomer functionalization and materials preparation to application.
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Dalton Trans., 2020, 49,5503-5512
DOI: 10.1039/D0DT00615G, Paper

Magdalena Rok, Marcin Moskwa, Andrzej Pawlukojć, Rafał Janicki, Iga Zuba, Piotr Zieliński, Paweł Sobieszczyk, Grażyna Bator
The single-crystals of mixed (C₃H₅N₂)₂[KFe_xCo_1−x(CN)₆] crystals, with different ratios of x = 0, 0.29, 0.42, 0.51, 0.63, 0.70, 0.85, and 1, have been grown from aqueous solutions.
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Dalton Trans., 2020, 49,5493-5502
DOI: 10.1039/D0DT00297F, Paper

Guoqiang Guan, Bo Li, Wenlong Zhang, Zhe Cui, Shu-Ang He, Rujia Zou, Xinwu Lu, Junqing Hu
Highly efficient body-clearance sulfur-doped iron oxides were developed for magnetic resonance imaging-guided photo-magnetic hyperthermia therapy.
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Dalton Trans., 2020, 49,5416-5419
DOI: 10.1039/D0DT00725K, Communication

S. Azpeitia, A. J. Martínez-Martínez, M. A. Garralda, A. S. Weller, M. A. Huertos
Rhodium promoted a fast, quantitative and room temperature Si–CH₃ bond activation.
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Dalton Trans., 2020, 49,5573-5580
DOI: 10.1039/C9DT04664J, Paper

Yunjing Shi, Hairui Bai, Fei Yan, Rui Hu, Kaikai Chen, Bo Shen, Jiwei Zhai
The component with the R–T phase coexistence near MPB affords an optimal piezoelectric coefficient (d₃₃) of 130 pC N⁻¹.
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Dalton Trans., 2020, 49,5531-5538
DOI: 10.1039/C9DT04614C, Paper

Wenzhu Zhang, Xiuyan Xi, Yong-Lei Wang, Zhongbo Du, Chaolong Liu, Jianping Liu, Bo Song, Jingli Yuan, Run Zhang
We report the design, synthesis, and characterization of a responsive Ru(II) complex probe for background-free time-gated luminescence detection of bisulfite.
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Dalton Trans., 2020, 49,5513-5522
DOI: 10.1039/D0DT00337A, Paper

Beatrice Berti, Cristiana Cesari, Cristina Femoni, Tiziana Funaioli, Maria Carmela Iapalucci, Stefano Zacchini
Redox active molecular Ni–Pd alloy nanoclusters were obtained by redox condensation, their total structures and metal distribution were determined by X-ray crystallography, and their electron-sink behavior was ascertained by electrochemical studies.
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Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper

Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
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Dalton Trans., 2020, 49,5420-5423
DOI: 10.1039/D0DT00842G, Communication

Luis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La Pierre
The synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.
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Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication

Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BO_xF_4−x] (x = 1,2,3) like [BO₄] and triangular elements [BO_xF_3−x] (x = 1,2) like [BO₃].
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Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper

Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper

Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)₄] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)₃(N₂)].
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Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper

Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Dalton Trans., 2020, 49,5730-5735
DOI: 10.1039/D0DT00976H, Paper

Yao Xiao, Beibei Guo, Jing Zhang, Chun Hu, Ruguang Ma, Deyi Wang, Jiacheng Wang
A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.
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Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment

Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
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Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment

Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00908C, Paper

Carlos Ángel-Jijón, David Rendón-Nava, Jose M. Vazques-Pérez, Alejandro Álvarez-Hernández, Daniel Mendoza-Espinosa, Verónica Salazar-Pereda
Treatment of NHC–AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTp^R2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3–6 with the general formula NHC–Au–Tp^R2.
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Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
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Dalton Trans., 2020, 49,5742-5742
DOI: 10.1039/D0DT90075C, Retraction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Yubing Sun, Changlun Chen, Xiaoli Tan, Dadong Shao, Jiaxing Li, Guixia Zhao, Shubin Yang, Qi Wang, Xiangke Wang
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper

Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper

Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η²:η²-peroxido)Cu^IICu^II complex 1 and the bis(μ-oxido)Cu^IIICu^III complex 2.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00156B, Paper

Cheng-Chang Chiu, Ming-Chuan Cheng, Sheng-Hsiang Lin, Cheng-Wei Yan, Gene-Hsiang Lee, Mu-Chieh Chang, Tien-Sung Lin, Shie-Ming Peng
A novel heteroheptanuclear metal string complex was synthesized by using nickel and ruthenium metal ions to explore the electronic structure and magnetic property.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper

Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH₄ hydrogens are shown for clarity).
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper

Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO₃.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper

Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper

Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication

Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00824A, Paper

Mengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin Li
Owing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper

Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru₂(μ-κ₂N,N’:κ₂N’,N’’-dpp)2(μ-X)(X)₂]^q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru₂(OAc)₄Cl] paddlewheel starting material. The neutral...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication

Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper

Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper

Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper

María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper

Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper

Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper

Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper

Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper

Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper

Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper

Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper

Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO₄^3-/ CrO₄^2- was...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper

Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy₂)Pt(μ-PCy₂){κ²P,O-μ-P(O)Cy₂}Pt(PHCy₂)] (Pt–Pt) affords the η¹-alkenyl-μ,η¹:η²-alkynyl complex [(η¹-trans-(Ph)HCCH)(PHCy₂)Pt(μ-PCy₂)(μ,η¹:η²-PhCC)Pt{κP-P(O)Cy₂}(PHCy₂)].
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper

Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper

Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication

Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper

Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper

Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper

Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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