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Web Directions Code ’20 session spotlight–Know Your HTML

By www.webdirections.org
Published On :: Wed, 18 Mar 2020 23:57:53 +0000

Know Your HTML Chris Lienert, Front End Technical Lead Iress HTML didn’t stop at version 5 and it continues to evolve. Chris Lienert will review a number of HTML elements and attributes that are new and (somewhat!) ready to be used. About Chris Lienert Chris started out as a web developer when Netscape ruled the […]

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Web Directions Code ’20 session spotlight–The State of the DOM

By www.webdirections.org
Published On :: Fri, 20 Mar 2020 02:58:00 +0000

The State of the DOM Marcos Caceres, Standards Engineer Mozilla The DOM, while not quite as old as the Web itself, has been with us for the entire professional lifetime of almost every web developer. But its far from fixed in stone. Now the responsibility of the WHATWG it continues to evolve in response to […]

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Web Directions Code ’20 session spotlight–Evolving Web APIs for everyday developers

By www.webdirections.org
Published On :: Mon, 23 Mar 2020 01:17:00 +0000

Evolving Web APIs for everyday developers Michael Mifsud, Senior platforms engineer Redbubble JavaScript is evolving quickly, and with it so the Web APIs. In just a few years it’s grown from humble callbacks to include generators, async iterations, and async functions. With this growth has come fragmentation not just in the availability of APIs but […]

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Web Directions Code ’20 session spotlight–Tuning web performance with just browser APIs

By www.webdirections.org
Published On :: Mon, 23 Mar 2020 22:08:00 +0000

Tuning web performance with just browser APIs Yaser Adel Mehraban, Lead Consultant Telstra Purple As web applications become more complex, with a corresponding increase in required bandwidth and bundle sizes, to meet users’ expectations the need to consider web performance has never been more important. Yes, there are third-party tools that can help with performance […]

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Web Directions Code ’20 session spotlight–Web Assembly at the Edge

By www.webdirections.org
Published On :: Mon, 30 Mar 2020 22:10:00 +0000

Web Assembly at the Edge Mark Nottingham, Principal Engineer Fastly Full session details coming soon About Mark Nottingham Mark Nottingham has helped develop the Web and the Internet since the late 90’s. He has written, edited or substantially contributed to more than twenty IETF RFCs and W3C Recommendations about topics like HTTP, caching, linking, Web […]

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Characterization of aerosolized particles from nanoclay-enabled composites during manipulation processes

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01211G, Paper
Eun Gyung Lee, Lorenzo Cena, Jiwoon Kwon, Ali Afshari, HaeDong Park, Gary Casuccio, Kristin Bunker, Traci Lersch, Ashley Gall, Huy Pham, Alixandra Wagner, Sushant Agarwal, Cerasela Zoica Dinu, Rakesh Gupta, Sherri A. Friend, Todd A. Stueckle
Manufacturing, processing, use, and disposal of nanoclay-enabled composites potentially lead to the release of nanoclay particles from the polymer matrix in which they are embedded; however, exposures to airborne particles are poorly understood.
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Nuclear translocation of silver ions and hepatocyte nuclear receptor impairment upon exposure to silver nanoparticles

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01348B, Paper
Open Access
Vanessa Tardillo Suárez, Elizaveta Karepina, Mireille Chevallet, Benoit Gallet, Cécile Cottet-Rousselle, Peggy Charbonnier, Christine Moriscot, Isabelle Michaud-Soret, Wojciech Bal, Alexandra Fuchs, Rémi Tucoulou, Pierre-Henri Jouneau, Giulia Veronesi, Aurélien Deniaud
Upon exposure to non-toxic concentration of silver nanoparticles, only the ionic form of silver is found in the nucleus leading to an endocrine disruptor-like effect.
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Surface coating and particle size are main factors explaining the transcriptome-wide responses of the earthworm Lumbricus rubellus to silver nanoparticles

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Environ. Sci.: Nano, 2020, 7,1179-1193
DOI: 10.1039/C9EN01144G, Paper
Dick Roelofs, Sunday Makama, Tjalf E. de Boer, Riet Vooijs, Cornelis A. M. van Gestel, Nico W. van den Brink
We present transcriptome responses of earthworms exposed to differently sized and coated silver nanoparticles (AgNPs), which are used in important industrial and biomedical applications.
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Emerging investigator series: synthesis of magnesium oxide nanoparticles fabricated on a graphene oxide nanocomposite for CO2 sequestration at elevated temperatures

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Environ. Sci.: Nano, 2020, 7,1225-1239
DOI: 10.1039/C9EN01442J, Paper
C. A. Gunathilake, G. G. T. A. Ranathunge, R. S. Dassanayake, S. D. Illesinghe, Amanpreet S. Manchanda, C. S. Kalpage, R. M. G. Rajapakse, D. G. G. P. Karunaratne
MONP and MONP–GO sorbents exhibited relatively high CO2 sorption capacity (2.79–3.34 mmol g−1) under elevated temperature conditions.
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Molten NaCl-induced MOF-derived carbon-polyhedron decorated carbon-nanosheet with high defects and high N-doping for boosting the removal of carbamazepine from water

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Environ. Sci.: Nano, 2020, 7,1205-1213
DOI: 10.1039/C9EN01408J, Paper
Dezhi Chen, Shoujun Wang, Zhiming Zhang, Hongying Quan, Yachao Wang, Yijie Jiang, Matthew J. Hurlock, Qiang Zhang
The efficient removal of endocrine-disrupting pollutants (EDCs) from water is a crucial issue for improving the quality of drinking water.
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Immobilization of mercury by nano-elemental selenium and the underlying mechanisms in hydroponic-cultured garlic plant

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Environ. Sci.: Nano, 2020, 7,1115-1125
DOI: 10.1039/C9EN01294J, Paper
Jiating Zhao, Xujun Liang, Nali Zhu, Liming Wang, Yunyun Li, Yu-Feng Li, Lirong Zheng, Zhiyong Zhang, Yuxi Gao, Zhifang Chai
Naturally and anthropogenic selenium nanoparticles highly work on mercury immobilization and inactivation in aquatic-plant systems.
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Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments enhances DNA damage and stress gene expression in freshwater Asian clam Corbicula fluminea

By pubs.rsc.org
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Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper
Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Exposure medium and particle ageing moderate the toxicological effects of nanomaterials to Daphnia magna over multiple generations: a case for standard test review?

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Environ. Sci.: Nano, 2020, 7,1136-1149
DOI: 10.1039/D0EN00049C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laura-Jayne A. Ellis, Eugenia Valsami-Jones, Iseult Lynch
Pristine engineered nanomaterials (NMs) entering the aquatic environment become ‘aged’ during their lifetime via chemical, physical and/or biological process.
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Efficacy of chitosan/double-stranded RNA polyplex nanoparticles for gene silencing under variable environmental conditions

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00137F, Paper
Stuart S. Lichtenberg, Kanthi Nuti, Jason DeRouchey, Olga V. Tsyusko, Jason M. Unrine
Chitosan/dsRNA polyplex nanoparticles have shown great potential as insect biocontrol agents. Here, we show that polyplex nanoparticles have their gene silencing capacity altered by environmental variables.
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Retraction: Mechanistic insights into the decontamination of Th(IV) on graphene oxide-based composites by EXAFS and modeling techniques

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90019B, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Xiangxue Wang, Wencheng Song, Songhua Lu, Changlun Chen, Xiangke Wang
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Retraction: Plasma-grafted amidoxime/metal–organic framework composites for the selective sequestration of U(VI)

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90017F, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fengbo Li, Xiaoyu Li, Pu Cui, Yubing Sun
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Potentiation of polycyclic aromatic hydrocarbon uptake in zebrafish embryos by nanoplastics

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00163E, Paper
Yueyang Zhang, Greg G. Goss
The presence of microplastics in the environment and their potential effects on the health of organisms are a subject of great concern.
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Multivariate analysis of the exposure and hazard of ceria nanomaterials in indoor aquatic mesocosms

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper
Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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A tribo-positive Fe@MoS2 piezocatalyst for durably degradation of tetracycline: Degradation mechanism and toxicity assessment

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00284D, Paper
Fanqing Meng, wei Ma, Yinglong Wang, Zhaoyou Zhu, zhen chen, gung Lu
The elimination of antibiotics by piezo-catalysis method has recently drawn great attention for its benefits in engineering application. However, the risk assessment of the target antibiotics and its degradation intermediates...
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Sulfidation attenuates the adverse impacts of metallic nanoparticles on anammox from the perspective of chronic exposure

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper
Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Effect of freeze/thaw on aggregation and transport of nano-TiO2 in saturated porous media

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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00008F, Paper
Jeffrey M. Farner, Jacopo De Tommaso, Heather Mantel, Rachel S. Cheong, Nathalie Tufenkji
Research has focused on nanoparticle (NP) aggregation and transport behavior in saturated granular porous media, but few studies have looked at the effect that temperature variability associated with winter conditions will have on engineered NPs.
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Fragmentation of polymer nanocomposites: modulation by dry and wet weathering, fractionation, and nanomaterial filler

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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper
Open Access
Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
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Defective crystal plane-oriented induced lattice polarization for the photocatalytic enhancement of ZnO

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CrystEngComm, 2020, 22,2709-2717
DOI: 10.1039/C9CE01966A, Paper
Xiaojuan Bai, Boxuan Sun, Xuyu Wang, Tianshuo Zhang, Qiang Hao, Bing-Jie Ni, Ruilong Zong, Ziyang Zhang, Xiaoran Zhang, Haiyan Li
The mechanism of the photocatalytic reaction of defective ZnO systems was determined.
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Susceptible CoSnO3 nanoboxes with p-type response for triethylamine detection at low temperature

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CrystEngComm, 2020, 22,2795-2805
DOI: 10.1039/D0CE00170H, Paper
Lingli Zheng, Yingqiang Zhao, Yongshan Xu, Chen Yang, Jun Zhang, Xianghong Liu
CoSnO3 nanoboxes exhibit a p-type response to detect triethylamine at 100 °C with a limit of detection of 134 ppb.
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Different effects in the selective detection of aniline and Fe3+ by lanthanide-based coordination polymers containing multiple reactive sites

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CrystEngComm, 2020, 22,2837-2844
DOI: 10.1039/D0CE00238K, Paper
Xinfang Liu, Liyong Du, Rongfang Li, Ningning Ma, Mengdi You, Xun Feng
Isostructural Ln-CPs (1-Eu and 2-Tb) show almost the same high detection ability for Fe3+ and different detection abilities for aniline. The detection difference was studied through PXRD, UV-vis, luminescence lifetimes and Hirshfeld surface analysis.
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Heterobimetallic complexes from 0D clusters to 3D networks based on various polycyanometallates and [Cu(dmpn)2]2+ (dmpn = 2,2-dimethyl-1,3-diaminopropane): synthesis, crystal structures and magnetic properties

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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper
Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between FeIII/CrI ion and CuII ion.
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Melting point–solubility–structure correlations in chiral and racemic model cocrystals

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CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper
Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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Discovery of new polymorphs of the tuberculosis drug isoniazid

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CrystEngComm, 2020, 22,2705-2708
DOI: 10.1039/D0CE00440E, Communication
Keke Zhang, Noalle Fellah, Alexander G. Shtukenberg, Xiaoyan Fu, Chunhua Hu, Michael D. Ward
Two new metastable polymorphs of the tuberculosis drug isoniazid, considered monomorphic for sixty years, were discovered using melt crystallization and nanoscale confinement.
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Investigation on the interconversion from DMF-solvated to unsolvated copper(II) pyrazolate coordination polymers

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00370K, Paper
Corrado Di Nicola, Alessia Tombesi, Marco Moroni, Rebecca Vismara, Fabio Marchetti, Riccardo Pettinari, Luca Nardo, Guglielmo Vesco, Simona Galli, Silvia Casassa, Luciano Pandolfo, Claudio Pettinari
Enlarging the family of CPs with the {Cu(μ-pz)2} building unit: synthesis, thermal behaviour, crystal structure and spectroscopic properties of [Cu(μ-4-Xpz)2(μ-DMF)]n (4-Xpz = 4-Xpyrazolate, X = H, Cl, Br, I) and the non-solvated counterparts.
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Synthesis and investigation alkaline energetic coordination polymers based on 1,2,3-triazole-4,5-dicarboxylic acid for green component of pyrotechnic

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper
Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
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Mesoporogen-free synthesis of hierarchical HZSM-5 for LDPE catalytic cracking

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper
Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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Synthesis of the finger-like MoS2@VS2 micro-nano composite with enhanced field emission performance

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00347F, Paper
Yu Feng, Erwei Du, Shijing Gong, Ke Yu, Xiaofan Chen, Ziqiang Zhu
The MoS2@VS2 micro-nano composite was synthesized via a two-step hydrothermal method. The field emission properties of MoS2@VS2 micro-nano composite were investigated for the first time. The finger-like VS2 has a...
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Correction: Two-dimensional porous nickel oxalate thin sheets constructed by ultrathin nanosheets as electrode materials for high-performance aqueous supercapacitors

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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A novel synthesis of YVO4:Ln3+ (Ln = Eu, Sm, and Dy) porous/hollow submicro-ellipsoids and their luminescence properties

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00526F, Paper
Shuang Zhao, Baiqi Shao, Yang Feng, Senwen Yuan, Langping Dong, Liang Zhang, Hongpeng You
A novel synthesis strategy of porous/hollow YVO4 submicro-ellipsoids with multicolor emissions has been developed based on the high structural matching of LYH and YVO4.
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Sr4Pb1.5Sb5O5Se8: a new mid-infrared nonlinear optical material with a moderate SHG response

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00084A, Paper
Yang Wang, Mengjia Luo, pei Zhao, Xiangli Che, Yunzhen Cao, Fu Qiang Huang
A new mid-infrared nonlinear optical oxyselenide, Sr4Pb1.5Sb5O5Se8, was successfully synthesized by traditional solid-state reaction. It crystallizes in the noncentrosymmetric space group Cm (No. 8) of the monoclinic system. The crystal...
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The effect of deuteration-levels in solution and temperature on the segregation coefficient of deuterium content in rapid-grown K(DxH1-x)2PO4 crystals using Raman spectroscopy

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper
Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(DxH1-x)2PO4 (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
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Polymorph induced diversity of photomechanical motions of molecular crystals

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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00311E, Paper
Lei Gao, Yunhui Hao, Xiunan Zhang, Xin Huang, Ting Wang, Hongxun Hao
Photomechanical motions of the polymorphs of trans-4,4'-azopyridine are distinct under the influence of different molecular packing and intermolecular interactions.
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First Preparation of Microporous AFY-type MeAPO by Topotactic Pillaring of Lamellar Aluminophosphate Precursor

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00644K, Communication
Kazuyuki Maeda, Kentaro Wakui, Kyosuke Arakawa, Atsushi Kondo
Topotactic pillaring of lamellar aluminophosphate (ALPO) layers with zinc cations is used to prepare microporous zincoaluminophosphate (ZnAPO) with AFY-type framework for the first time. This approach should be promising for...
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Diminishing accessibility of electrophilic nickel(II) centres due to incorporation of a methylene spacer in the pendant side arm of a series of heterotrinuclear nickel(II)/sodium complexes: a DFT study using a homodesmotic equation

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CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper
Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
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Effect of dilution in a hydrothermal process and post-synthetic annealing on the tailoring of hierarchical ZnO nanostructures

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CrystEngComm, 2020, 22,3059-3069
DOI: 10.1039/D0CE00310G, Paper
Smriti Thakur, Sanjay K. Mandal
Morphology transformation and dimensionality change as a result of dilution and post-synthetic annealing are reported.
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Formation mechanism of porous rose-like WO3 and its photoresponse and stability study

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CrystEngComm, 2020, 22,2945-2952
DOI: 10.1039/D0CE00185F, Paper
Jiacheng Yao, Min Zhang, Hongfei Yin, Muhammad Arif, Xiaoheng Liu
Fabrication of rose-like WO3 by chemical bath method.
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Influence of lamellar thickness on the transformation of isotactic polybutylene-1/carbon nanotube nanocomposites

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CrystEngComm, 2020, 22,2990-2997
DOI: 10.1039/D0CE00112K, Paper
Yan-Kai Li, Yu-Ge Wang, Cui-Liu Fu, You-Liang Zhu, Zhan-Wei Li, Zhao-Yan Sun
The crystallization transformation from form II to form I in PB-1/CNT materials is mainly influenced by the lamellar thickness.
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An Sc-based coordination polymer with concaved superstructures: preparation, formation mechanism, conversion, and their electrochemistry properties

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CrystEngComm, 2020, 22,2926-2932
DOI: 10.1039/D0CE00086H, Paper
Hualan Xu, Ran Liu, Yongmei Zhu, Jinjiang Li, Changfeng Wan, Hang Zhang, Chuying Ouyang, Shengliang Zhong
Scandium-based coordination polymer octahedrons with concaved surfaces have been fabricated. The formation mechanism was also investigated. Sc2O3 octahedrons were obtained after simple calcination in a N2 atmosphere.
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Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses

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CrystEngComm, 2020, 22,3070-3078
DOI: 10.1039/D0CE00075B, Paper
Yucheng Hao, Yang Pan, Yuan Lin, Linbo He, Guangjie Ge, Yu Ruan, Haida Zhou, Yang Xue, Kisan Koirala
Three novel highly porous aluminophosphates were synthesized through mild hydrothermal methods. Interestingly, among them, α-NaAlPO4(OH) is polar and exhibits moderate nonlinear optical properties with a short cutoff edge.
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Two-dimensional porous nickel oxalate thin sheets constructed by ultrathin nanosheets as electrode materials for high-performance aqueous supercapacitors

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CrystEngComm, 2020, 22,2953-2963
DOI: 10.1039/D0CE00268B, Paper
Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
2D porous nickel oxalate thin sheets constructed by ultrathin nanosheets were first synthesized by using a simple hydrothermal method. The resulting porous thin sheets exhibited superior supercapacitor performance.
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Flexible bifunctional monoethylphosphonate/carboxylates of Zn(II) and Co(II) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology

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CrystEngComm, 2020, 22,2933-2944
DOI: 10.1039/D0CE00275E, Paper
Anna Goldman, Beatriz Gil-Hernández, Simon Millan, Serkan Gökpinar, Christian Heering, Ishtvan Boldog, Christoph Janiak
The prototypal [M2(EtBCP)2(DABCO)0.5] MOFs, compliant with isoreticular expansion in two-dimensions, show flexibility manifested by a two-step CO2 adsorption isotherm, which might be associated to the “lever-action” of the metal-phosphonate moieties.
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A new Fourier transformation method for SAXS of polymer lamellar crystals

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CrystEngComm, 2020, 22,3042-3058
DOI: 10.1039/D0CE00157K, Paper
Xiangyang Li, Jianjun Ding, Pujing Chen, Kang Zheng, Lin Chen, Xingyou Tian
The interface distribution function is composed mainly of the self-interference item of the first interface F11, the interference term of the first and the second interfaces F12, and the interference term of the first and the third interfaces F13.
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Step-by-step: uncommon SCSC transformation accompanied by stepwise change in the binding of a particular ligand within a mononuclear complex upon stepwise desolvation

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CrystEngComm, 2020, 22,2895-2899
DOI: 10.1039/D0CE00379D, Communication
Andrey V. Gavrikov, Andrey B. Ilyukhin, Pavel S. Koroteev
Uncommon SCSC transformation when desolvation induces subtle changes within a mononuclear complex, namely a stepwise change in the binding of a particular ligand.
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Intrinsically porous molecular building blocks for metal organic frameworks tailored by the bridging effect of counter cations

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CrystEngComm, 2020, 22,2889-2894
DOI: 10.1039/D0CE00397B, Communication
Open Access
Peng Yang, Buthainah Alshankiti, Niveen M. Khashab
Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.
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