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Advancing energy safety via stepwise nucleophilic substitution on tetrazine

J. Mater. Chem. A, 2024, 12,30548-30557
DOI: 10.1039/D4TA06039C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jatinder Singh, Richard J. Staples, Jean'ne M. Shreeve
This study presents a feasible approach to synthesizing hydrazine/nitroamine and amino/nitroamine substituted tetrazine derivatives.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
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Understanding the crucial roles of natural clinochlore in reinforcing Li–S batteries

J. Mater. Chem. A, 2024, 12,30655-30666
DOI: 10.1039/D4TA05849F, Paper
Yumei Qin, Yashuai Pang, Chujie Zeng, Xue Li, Pengfei Wang, Yan Meng, Guangfeng Zeng, Yunchen Ge, Xiang-Long Huang
Random dendrite growth and the severe shuttle effect of lithium polysulfides are major obstacles to exploiting dependable high-capacity Li–S batteries.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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A C8P monolayer with cross-sp-hybridized phosphorus atoms and ultrahigh energy density as a K-ion battery anode

J. Mater. Chem. A, 2024, 12,30842-30849
DOI: 10.1039/D4TA04961F, Paper
Xu Yan, Sheng Wang, Shicong Ding, Javed Rehman, Yong Liu, Guochun Yang
The proposed C8P monolayer and its derivatives are promising candidates as anode materials for high performance K-ion batteries.
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Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics

J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper
Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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Room-temperature thermochemical water splitting: efficient mechanocatalytic hydrogen production

J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H2 (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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Development and application of Few-shot learning methods in materials science under data scarcity

J. Mater. Chem. A, 2024, 12,30249-30268
DOI: 10.1039/D4TA06452F, Review Article
Yongxing Chen, Peng Long, Bin Liu, Yi Wang, Junlong Wang, Tian Ma, Huilin Wei, Yue Kang, Haining Ji
Machine learning, as a significant branch of artificial intelligence, shortens the cycle of material discovery and synthesis by exploring the characteristics of data.
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Electrode–electrolyte interphases in lithium-based rechargeable batteries with ionic liquid electrolytes: recent advances and future perspectives

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06184E, Review Article
Taohong He, Yushan Han, Bofang Shi, Jianan Wang, Honghui Yang
The characteristics of interphase formation between ionic liquid-based electrolytes and various electrodes are reviewed to support the development of improved electrolyte designs for lithium-based batteries.
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Review of electro-spun carbon nanofiber electrode materials for electrochemical capacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06221C, Review Article
Yutian Peng, Xingyu Zhang, Ruiling Sun, Xunlong Zhang, Can Ge, Yuqing Liu
Schematic illustration demonstrating various approaches to enhance the electrochemical performance of carbon nanofiber electrode materials.
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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Dually encapsulated LiMn0.6Fe0.4PO4 architecture with MXenes and amorphous carbon to achieve high-performance and ultra-stable lithium batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06323F, Paper
Yang Song, Haidong Zhong, Tingting Hu, Qizhi Chen, Lei Shi, Jun Du, Changyuan Tao, Qian Zhang
An LMFP@MXene@C cathode material was fabricated by electrostatic adsorption and in situ graphitization, providing optimized Li+ transmission and a stable structure featuring ultrahigh average capacity and cycle stability.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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Enhanced oxygen exchange kinetics and long-term stability of Ruddlesden-Popper phase Pr4Ni3O10+δ cathode for solid oxide fuel cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01845A, Paper
Saim Saher, Affaq Qamar, Chou Yong Tan, Singh Ramesh, Walied Alfraidi
This research explores the intricacies of oxygen exchange kinetics in Pr4Ni3O10+δ (PNO), aiming to assess its potential as a viable cathode material for solid oxide fuel cell applications. Utilizing a...
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PEO/cysteine composite nanofiber-based triboelectric nanogenerator for tiny mechanical energy harvesting

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06845A, Paper
Yijun Hao, Jia Yang, Xiaopeng Zhu, Keke Hong, Jiayu Su, Yong Qin, Wei Su, Hongke Zhang, Chuguo Zhang, Xiuhan Li
Triboelectric nanogenerator (TENG) has acted as a promising method for capturing mechanical energy. However, traditional polymer triboelectric materials result burden to environment, the natural/biodegradable tribo-materials have the disadvantages of poor...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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Recent Advances p-type Polymeric Electrode Materials towards High-Voltage 4.0 V-class Organic Lithium-ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06028H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Febri Baskoro, Santosh U. Sharma, Andre Lammiduk Lubis, Hung-Ju Yen
Lithium-ion batteries stand at the forefront of energy storage technologies, facilitating the transition towards sustainable and electrified systems. To meet the increasing demands for energy density, safety, and longevity, the...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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Machine learning aided design of high performance copper-based sulfide photocathodes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06128D, Paper
Yuxi Cao, Kaijie Shen, Yuanfei Li, Fumei Lan, Zeyu Guo, Kelu Zhang, Kang Wang, Feng Jiang
With the help of machine learning algorithms, we developed software that can predict the performance of copper-based sulfide photocathodes and this system shows excellent accuracy of up to 96%.
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Retraction: Thermally reduced graphene oxide/polymelamine formaldehyde nanocomposite as a high specific capacitance electrochemical supercapacitor electrode

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA90211D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali A. Ensafi, Hossein A. Alinajafi, B. Rezaei
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Advancing Paper-Based Sensors with MXenes and MOFs: Exploring the Cutting-Edge Innovations

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06561A, Review Article
Sepehr Larijani, Atefeh Zarepour, Arezoo Khosravi, Siavash Iravani, Mahnaz Eskandari, Ali Zarrabi
MXenes and metal-organic frameworks (MOFs) are emerging as promising materials for integration into paper-based sensors (PSs), offering unique properties that can enhance sensor performance in various applications. MXenes, with their...
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Vertical Macroporous Chitosan Aerogel Adsorbents for Simple and Efficient Enhancement of Atmospheric Water Harvesting and Air Dehumidification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07005D, Paper
Zhiguang Guo, Changhui Fu, Yuxuan He, Anhui Yu, Guangyi Tian, Danyan Zhan, Huimin Zhang
Adsorption-based atmospheric water harvesting (SAWH) has become one of the effective methods to extract water from the air in arid regions due to its high efficiency and low energy consumption....
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Pre-lithiation carbon anodes mitigating potassium loss toward for high-performance potassium-ion energy storage devices

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06451H, Paper
Danni Du, Qingyuan Liu, Jing Gao, Yuying Qin, Xiaobo Jiang, Yuanchang Shi, Minghao Hua, Xiaohang Lin, Zhiwei Zhang, Chengxiang Wang, Long-Wei Yin, Rutao Wang
Pre-potassiation technologies with the functions of providing additional potassium sources and/or mitigating potassium loss during cycling, make them capable of enhancing the energy density and cycling life of potassium-ion capacitors...
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Electrochemical PET recycling to formate through ethylene glycol oxidation on Ni-Co-S nanosheet arrays

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07156E, Paper
Yi Ma, Luming Li, Jialing Tang, Zongkun Hu, Yong Zhang, Ning Jian, Huan Ge, Jun Zhao, Andreu Cabot, Junshan Li
Plastics have become an integral part of modern society due to their excellent mechanical properties, lightweight, chemical stability and low cost. However, their continuous production and use worldwide have resulted...
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Radiofrequency-Triggered Surface-Heated Laser-Induced Graphene Membranes for Enhanced Membrane Distillation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA05611F, Paper
Md Hasib Al Mahbub, Fouzia Hasan Nowrin, Mohammad Saed, Mahdi Malmali
Membrane distillation (MD) has attracted significant research interest for desalinating hypersaline brine. However, the lack of robust hydrophobic membrane and lower energy efficiency requirements restrict its true potential. Designing and...
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Long-lasting, flexible and fully bioresorbable AZ31–tungsten batteries for transient, biodegradable electronics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06222A, Paper
Open Access
Gwan-Jin Ko, Tae-Min Jang, Daiha Shin, Heeseok Kang, Seung Min Yang, Sungkeun Han, Rajaram Kaveti, Chan-Hwi Eom, So Jeong Choi, Won Bae Han, Woon-Hong Yeo, Amay J. Bandodkar, Jiung Cho, Suk-Won Hwang
An eco-friendly, fully biodegradable magnesium alloy (AZ31)–tungsten (W) battery exhibits enhanced stability and corrosion resistance. The integration of alginate-based elastic electrolytes demonstrates a fully biodegradable solid-state battery.
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Flexible multifunctional MXene@Ag nanowires/cotton fabric inspired by transport of nutrients by roots for electromagnetic shielding, infrared stealth, Joule/solar heating and flame retardancy

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06712F, Paper
Jiatong Yan, Meimei Chen, Rui Tan, Chuanxi Lin, Shan Jiang, Weijie Wang, Songyue Pan, Hongyan Xiao, Erhui Ren, Ronghui Guo
With the rapid development of 5G intelligent detection technology, electromagnetic shielding/infrared stealth fabrics with Joule/solar heating performance can meet the needs of wearable electronic devices for multi-application scenarios.
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Synergetic Effects from a High-Entropy NASICON-type Cathode for Advanced Sodium-Ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06950A, Paper
Shouyue Wang, Taiding Xu, Huitao Leng, Shengyu Liang, Wei Zhang, Yuheng Jin, Jingxia Qiu, Sheng Li
Na3V2(PO4)3 (NVP) is recognized as one of the most promising NASICON-type cathodes for sodium-ion storage. Enhancing electronic conductivity and further ensuring long-term structural stability when activating the high-voltage V⁴⁺/V⁵⁺ redox...
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Fantasy Football Week 11 Rankings: Tight ends (Half-PPR)

The fantasy football experts of Yahoo Fantasy reveal their Week 11 tight end rankings.




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Fantasy Football Week 11 Rankings: WRs (Half-PPR)

The fantasy football experts of Yahoo Fantasy reveal their Week 11 wide receiver rankings for half-PPR leagues.




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Fantasy Football Week 11 Rankings: RBs (Half-PPR)

The fantasy football experts of Yahoo Fantasy reveal their Week 11 running back rankings to kick off the 2024 season.




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Fantasy Football Week 11 Rankings: Tight Ends (Full-PPR)

The Yahoo Fantasy team reveals their Week 11 PPR tight end rankings.




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Fantasy Football Week 11 Rankings: WRs (Full-PPR)

The Yahoo Fantasy team reveals their Week 11 PPR wide receiver rankings.




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Fantasy Football Week 11 Rankings: RBs (Full-PPR)

The Yahoo Fantasy team reveals their Week 11 PPR running back rankings.




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Fantasy Football Week 11 Rankings (Full-PPR)

The Yahoo Fantasy team reveals their Week 11 PPR rankings for fantasy football.




an

Joe Schoen on Daniel Jones: QB decision will be based on football only

Jones has $23 million in injury guarantees on his contract for 2025.




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NFL news, injury updates: Cowboys' Dak Prescott to have surgery, Bears fire OC Shane Waldron

Are the Bears on the verge of reshaping their offensive braintrust around Caleb Williams?




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Where the Chiefs' unbeaten start to season ranks among best in NFL history

The Kansas City Chiefs fell to the Las Vegas Raiders at home in Week 16 of the 2023 NFL season -- and they haven't lost since.




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DeMeco Ryans: No setback for Nico Collins, game-time decision to sit him Sunday night

The Texans activated wide receiver Nico Collins from injured reserve last Saturday, but he wound up being on the inactive list for their loss to the Lions on Sunday night.




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Bears pivot to another potential location for Chicago stadium

The Bears can't get their effort to muster political support — and taxpayer money — for a new stadium off the ground.




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Jerry Jones continues to insist that the blinding sun at AT&T Stadium is a home-field advantage, doesn’t want a curtain

Jones doesn't appear to be willing to concede that opposing teams are also aware of when and where the sun sets.




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Chiefs' Isiah Pacheco and Charles Omenihu both returning to practice this week

The Chiefs are getting healthier.