an

Improved photovoltaic performance and stability of perovskite solar cells by adoption of an n-type zwitterionic cathode interlayer

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00253A, Communication
Young Wook Noh, Jung Min Ha, Jung Geon Son, Jongmin Han, Heunjeong Lee, Dae Woo Kim, Min Hun Jee, Woo Gyeong Shin, Shinuk Cho, Jin Young Kim, Myoung Hoon Song, Han Young Woo
Integration of NDI-ZI as a cathode interlayer in perovskite solar cells improves both device efficiency and stability, mitigating halide and Ag ion migration by chemically capturing ions via electrostatic Coulombic interactions.
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N-Type polymeric mixed conductors for all-in-one aqueous electrolyte gated photoelectrochemical transistors

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00267A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Latifah Almulla, Victor Druet, Christopher E. Petoukhoff, Wentao Shan, Nisreen Alshehri, Sophie Griggs, Yazhou Wang, Maryam Alsufyani, Wan Yue, Iain McCulloch, Frédéric Laquai, Sahika Inal
An n-type organic photoelectrochemical transistor produces large and reversible current changes in response to light-intensity variations in aqueous electrolytes. A long exciton lifetime of the n-type gate ensures a high photovoltage response.
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A mechanochemical process to capture and separate carbon dioxide from natural gas using boron nitride nanosheets

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00188E, Communication
Srikanth Mateti, Ying (Ian) Chen, Gautham Sathikumar, Qi Han, Shiva Prasad, Reza Ghandehari Ferdowsi, Amrito Battacharjee
A mechanochemical process to store and separate CO2 gas using boron nitride nanosheets.
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Better nanoscience through open, collaborative, and critical discussions

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01781H, Opinion
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nathanne Cristina Vilela Rost, Maha Said, Mustafa Gharib, Raphaël Lévy, Federico Boem
Material science publications are the outcome of research, but they can contain errors. We advocate for post publication peer review as a way to collectively improve self-correction of science.
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Triplet–triplet annihilation-based photon upconversion using nanoparticles and nanoclusters

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00117F, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yoshiki Niihori, Taiga Kosaka, Yuichi Negishi
We introduce the triplet sensitizabilities of semiconductor nanoparticles and metal nanoclusters for triple–triplet annihilation-based photon upconversion. This review aims to explore the potential of new applications for inorganic nanomaterials.
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A bioactive calcium silicate nanowire-containing hydrogel for organoid formation and functionalization

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00228H, Communication
Wenping Ma, Yi Zheng, Guangzhen Yang, Hongjian Zhang, Mingxia Lu, Hongshi Ma, Chengtie Wu, Hongxu Lu
An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
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Excellent thermomagnetic power generation for harvesting waste heat via a second-order ferromagnetic transition

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02225K, Communication
Haodong Chen, Xianliang Liu, Yao Liu, Longlong Xie, Ziyuan Yu, Kaiming Qiao, Mingze Liu, Fengxia Hu, Baogen Shen, R. V. Ramanujan, Ke Chu, Hu Zhang
NiMnIn Heusler alloys with second-order ferromagnetic transition show good thermomagnetic generation (TMG) performance with zero hysteresis and a long-term service life, enabling them to be better candidates for practical applications of TMG.
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Heterointerface regulation of covalent organic framework-anchored graphene via a solvent-free strategy for high-performance supercapacitor and hybrid capacitive deionization electrodes

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication
Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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Intelligent micro/nanorobots based on biotemplates

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00114A, Review Article
Open Access
Ting Chen, Yuepeng Cai, Biye Ren, Beatriz Jurado Sánchez, Renfeng Dong
Micromotors based on biotemplates: nature meets controlled motion. Cutting edge advances and recent developments are described.
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Photo-induced synthesis of polymeric nanoparticles and chemiluminescent degradable materials via flow chemistry

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00106K, Communication
Joshua O. Holloway, Laura Delafresnaye, Emily M. Cameron, Jochen A. Kammerer, Christopher Barner-Kowollik
Polymeric nanospheres can be synthesised within minutes using photo-flow chemistry, without the need for initiators, additives, or surfactants. The particles can be selectively degraded on demand, emitting light in the process.
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Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
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Differential-targeting core-shell microneedle patch with coordinated and prolonged releases of mangiferin and MSC-derived exosomes for scarless skin regeneration

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH01910A, Communication
Shang LYU, Qi Liu, Ho-Yin Yuen, Huizhi Xie, Yuhe Yang, Kelvin Yeung, Chak-Yin Tang, Shuqi Wang, Yaxiong Liu, Bin Li, Yong He, Xin Zhao
Microneedles for skin regeneration are conventionally restricted by uncontrollable multi-drug release, limited types of drugs, and poor wound adhesion. Here, a novel core-shell microneedle patch is developed for scarless skin...
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Polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00322E, Communication
Zixiong Sun, Yuhan Bai, Hongmei Jing, Tian-Yi Hu, Kang Du, Qing Guo, Pan Gao, Ye Tian, Chunrui Ma, Ming Liu, Yongping Pu
Due to dielectric capacitors’ already-obtained fast charge-discharge speed, research has been focused on improving their Wrec. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher...
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Time-averaged atomic volume spectrum: locating and identifying vacancies

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00140K, Communication
YongQuan Wu, Hao Wang, JiaHao Fu, BoYang Zhang, Xu Zhao, Kai Zhang
We developed the TAVS method to accurately locate and fully identify vacancies based on a new concept of the atomic cage enwrapping vacancies. This flexible method is believed to be applicable to any type of vacancy in any type of material.
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Advancing Lithium-Sulfur Battery Efficiency: Utilizing a 2D/2D g-C3N4@MXene Heterostructure to Enhance Sulfur Evolution Reactions and Regulate Polysulfides in Lean Electrolyte Conditions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00200H, Communication
Vijay Kumar, Otavio Augusto Titton Dias, Abdelaziz Gouda, Ritu Malik, Mohini M. Sain
Lithium–sulfur batteries (LSBs) show promise for achieving a high energy density of 500 Wh/kg, despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics...
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Composited silk fibroins ensured adhesion stability and magnetic controllability of Fe3O4-nanoparticle coating on implant for biofilm treatment

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00097H, Communication
Kecheng Quan, Zhinan Mao, Yupu Lu, Yu Qin, Shuren Wang, Chunhao Yu, Xuewei Bi, Hao Tang, Xiaoxiang Ren, Dafu Chen, Yan Cheng, Yong Wang, Yufeng Zheng, Dandan Xia
Magnetic propulsion of nano-/micro-robots is an effective way to treat implant-associated infections by physically destroying biofilm structures to enhance antibiotic killing.
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Intelligent anti-impact elastomers by precisely tailoring the topology of modular polymer networks

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00002A, Communication
Jianfeng Cheng, Xianhua Yao, Zhipeng Zhang, Yizhong Tan, Nan Hu, Chunfeng Ma, Guangzhao Zhang
Utilizing the modular construction strategy, intelligent anti-impact elastomers with varying topology network structures have been prepared by tailoring the stereoscopic and linear building blocks as independent modules.
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Biphenyl Tetracarboxylic Acid based Metal-Organic Frameworks: A Case of Topology-Dependent Thermal Expansion

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication
Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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High-Entropy Materials for Thermoelectric Applications: Towards Performance and Reliability

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02181E, Review Article
NOUREDINE OUELDNA, Noha Sabi, Hasna Aziam, Vera Trabadelo, Hicham Ben youcef
High-entropy materials (HEMs), including alloys, ceramics and other entropy-stabilized compounds, have attracted considerable attention in different application fields. This is due to their intrinsically unique concept and properties, such as...
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Giant auxetic behavior in remote-plasma synthesized few-layer tungsten semicarbide

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02193A, Communication
Noah B. Stocek, Farman Ullah, Giovanni Fanchini
We show how remote-plasma synthesis far from thermodynamic equilibrium yields unprecedented 2D crystals and demonstrates the first synthesis of 2D tungsten semicarbide, which was known from theoretical predictions to exhibit giant auxetic behavior.
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Aggregation-induced emission organic metal halide complex for X-ray scintillation

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication
Open Access
Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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Atomic Scale Quantum Anomalous Hall Effect in Monolayer Graphene/MnBi2Te4 Heterostructure

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00165F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yueh-Ting Yao, Su-Yang Xu, Tay-Rong Chang
The two-dimensional quantum anomalous Hall (QAH) effect is direct evidence of non-trivial Berry curvature topology in condensed matter physics. Searching for QAH in 2D materials, particularly with simplified fabrication methods,...
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Transforming Patterned Defects into Dynamic Poly-Regional Topographies in Liquid Crystal Oligomers

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00131A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuxin You, Youssef Golestani, Dirk J. Broer, Tinghong Yang, Guofu Zhou, Robin L. B. Selinger, Dong Yuan, Danqing Liu
We create high-aspect-ratio dynamic poly-regional surface topographies in a coating of a main-chain liquid crystal oligomer network (LCON). The topographies form at the topological defects in the director pattern organized...
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Photochemical engineering unsaturated Pt islands on supported Pd nanocrystals for a robust pH-universal hydrogen evolution reaction

Mater. Horiz., 2024, 11,1964-1974
DOI: 10.1039/D3MH02041J, Communication
Yidan Liu, Nuttapon Yodsin, Ting Li, Haocheng Wu, Rongrong Jia, Liyi Shi, Zhuangchai Lai, Supawadee Namuangruk, Lei Huang
Novel core–shell Pd7@Ptx heterostructured nanocrystals with Pt-islands shell of unsaturated coordination edges could be directly photodeposited on a reduced graphene oxide support as a highly efficient HER electrocatalyst in a wide pH range.
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Engineering a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis

Mater. Horiz., 2024, 11,2032-2040
DOI: 10.1039/D3MH01909H, Communication
Jialei Yang, Zhenyu Yang, Jiafu Li, Hao Gang, Donghai Mei, Dongming Yin, Ruiping Deng, Yifeng Zhu, Xingyun Li, Ning Wang, Sameh M. Osman, Yusuke Yamauchi
A sub-nano interfacial catalytic structure is orchestrated by tailor-designing a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis.
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Injectable extracellular matrix-mimetic hydrogel based on electrospun Janus fibers

Mater. Horiz., 2024, 11,1944-1956
DOI: 10.1039/D3MH01789C, Communication
Jinzhong Zhang, Xiaolong Zha, Gengxin Liu, Huipeng Zhao, Xiaoyun Liu, Liusheng Zha
To date, the reported injectable hydrogels have failed to mimic the fibrous architecture of the extracellular matrix (ECM), limiting their biological effects on cell growth and phenotype.
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Seeding ductile nanophase in ceramic grains

Mater. Horiz., 2024, 11,1908-1922
DOI: 10.1039/D3MH02233A, Communication
Chong Zhao, Hao Lu, Haibin Wang, Xuemei Liu, Zhigang Zak Fang, Chao Hou, Xiaoyan Song
A novel strategy is proposed to achieve coordinated strengthening and toughening of brittle composites by introducing and tailoring ductile nanoparticles within ceramic grains. Transgranular fractures of the ceramic phase were remarkably reduced.
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Thermo-growing ion clusters enabled healing strengthening and tough adhesion for highly reliable skin electronics

Mater. Horiz., 2024, 11,1923-1933
DOI: 10.1039/D3MH01975F, Communication
Song Chen, Xinyu Chen, Kaiying Luo, Wenwei Yang, Xueling Yan, Lan Liu
A thermo-growing ion cluster-based elastomer was developed to achieve healing strengthening and tough adhesion features.
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An ultra-soft conductive elastomer for multifunctional tactile sensors with high range and sensitivity

Mater. Horiz., 2024, 11,1975-1988
DOI: 10.1039/D3MH02074F, Communication
Ao Yin, Ruiguang Chen, Rui Yin, Shiqiang Zhou, Yang Ye, Yuxin Wang, Peike Wang, Xue Qi, Haipeng Liu, Jiang Liu, Suzhu Yu, Jun Wei
Our study shows an ultra-soft conductive material with excellent adhesive ability to solve the mismatch of the interface. With coupled microstructures, our sensor demonstrates a remarkable sensitivity and a fast response time.
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Oxovanadium electronics for in-memory, neuromorphic, and quantum computing applications

Mater. Horiz., 2024, 11,1838-1842
DOI: 10.1039/D3MH01926H, Opinion
Kirill Yu. Monakhov
Redox- and spin-active macrocyclic vanadyl(IV) complexes and polyoxovanadates(V) have promising structural and physicochemical characteristics for innovative bottom-up hybrid electronics.
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Hierarchical surface-modification of nano-Cu toward one pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions

Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication
Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
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Electrochemical modulation of mechanical properties of glycolated polythiophenes

Mater. Horiz., 2024, 11,2021-2031
DOI: 10.1039/D3MH01827J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ilaria Abdel Aziz, Johannes Gladisch, Chiara Musumeci, Maximilian Moser, Sophie Griggs, Christina J. Kousseff, Magnus Berggren, Iain McCulloch, Eleni Stavrinidou
This work investigates the changes in the mechanical properties of glycolated polythiophenes induced by electrochemical addressing and by electrolyte concentration, due to its ability to stabilize water.
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Skin-adhesive and self-healing diagnostic wound dressings for diabetic wound healing recording and electrophysiological signal monitoring

Mater. Horiz., 2024, 11,1997-2009
DOI: 10.1039/D3MH02064A, Communication
Zishuo Hou, Tengjiao Wang, Lei Wang, Junjie Wang, Yong Zhang, Qian Zhou, Zhengheng Zhang, Peng Li, Wei Huang
A diagnostic wound dressing was fabricated, which could record the diabetic wounds healing and monitor electrophysiological signals. The flexible substrate of dressings shows excellent tissue adhesive, self-healing, and antibacterial properties.
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Microcage flame retardants with complete recyclability and durability via reversible interfacial locking engineering

Mater. Horiz., 2024, 11,1867-1876
DOI: 10.1039/D4MH00116H, Communication
Furong Zeng, Lei He, Jianwen Ma, Danxuan Fang, Zhiwei Zeng, Tongyu Bai, Rong Ding, Bowen Liu, Haibo Zhao, Yuzhong Wang
A new facile and scalable interfacial locking engineering strategy is exploited to endow reversible microcages with infinite chemical recyclability to starting monomers, exceptional durability, high flame-retardant efficiency, and extensive applicability across diverse polymers.
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Adaptive nanotube networks enabling omnidirectionally deformable electro-driven liquid crystal elastomers towards artificial muscles

Mater. Horiz., 2024, 11,1877-1888
DOI: 10.1039/D4MH00107A, Communication
Jiao Wang, Hao Zhou, Yangyang Fan, Wenhao Hou, Tonghui Zhao, Zhiming Hu, Enzheng Shi, Jiu-an Lv
Hierarchically structured electro-driven liquid crystal elastomers towards artificial muscles.
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A reflection on ‘The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA)2KBiCl6 (MA = methylammonium)’

Mater. Horiz., 2024, 11,1832-1837
DOI: 10.1039/D4MH90029D, Commentary
Anthony K. Cheetham, Paul D. Bristowe, Satoshi Tominaka, Fengxia Wei
Cheetham et al. reflect on one of their first Materials Horizons papers (Mater. Horiz., 2016, https://doi.org/10.1039/C6MH00053C) published in the journal and discuss how their work may have influenced the research field.
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Materials Horizons Emerging Investigator Series: Professor Zhengbao Yang, Hong Kong University of Science and Technology

Mater. Horiz., 2024, 11,1830-1831
DOI: 10.1039/D4MH90031F, Editorial

Our Emerging Investigator Series features exceptional work by early-career researchers working in the field of materials science.
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Atomic-scale Ru anchored on chromium-shavings as a precursor for a pH-universal hydrogen evolution reaction electrocatalyst

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01951A, Communication
Qingxin Han, Qiangqiang Lu, Xuechuan Wang, Chao Wei, Xiaoyu Guan, Luming Chen, Xiao Wang, Ji Li
Chrome shavings produce electrocatalysts with atomically dispersed Ru sites. The CN/Cr2O3/Ru-1 catalyst has excellent HER catalytic performance under the synergistic effect of RuN4 and Cr2O3.
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Polycatechols inhibit ferroptosis and modulate tau liquid–liquid phase separation to mitigate Alzheimer's disease

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00023D, Communication
Hariharan Moorthy, Madhu Ramesh, Dikshaa Padhi, Prayasee Baruah, Thimmaiah Govindaraju
Polycatechols modulate amyloid-associated toxicities, arrest labile iron, inhibit lipid peroxidation, and regulate tau liquid–liquid phase separation (LLPS) to mitigate the pathological nexus between ferroptosis and AD.
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Construction of phase-separated Co/MnO synergistic catalysts and integration onto sponge for rapid removal of multiple contaminants

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00285G, Communication
Mengting Liu, Wanyu Zhang, Ruiting Ni, Zhenxiao Wang, Hongyao Zhao, Xiu Zhong, Yanyun Wang, Danhong Shang, Zengjing Guo, Edison Huixiang Ang, Fu Yang
Novel metallic Co integration onto MnO nanorods enhances catalyst efficiency for wastewater treatment.
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Running Our First Polishathon and Investing in UX Debt

We socialized the idea of a Polishathon at OneSignal — a set amount of days where we would pause from feature roadmap work in order to entirely focus on polish. The result was 5 days of executing on “polish” projects, where we shipped more than 20 UX improvements across our product.

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How we’re adding Lottie animations to our website and product ????

We’ve been rolling out a fresh wave of Lottie animations ???? to our website and product.

Here’s how we’re doing it ????✨…

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How we Organize Figma Projects and Files On Our Design Team

Organizing Figma projects & files differs from team to team, depends on size of your team, the make up of your team & products. Consistency & teaching people how to quickly navigate these files so they aren’t relearning each time is important.

This is how we organize Figma…

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How we Organize Design Files and Cover Pages in Figma

Not everyone on your team knows how to navigate Figma the way you do. Other designers have different methods. Engineers and PMs may not know where to start.

This is how we organize our project files and pages in Figma…

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How Product Design works with Product Managers and Engineers

When interviewing designers, PMs or engineers, I’ll usually get asked “how do you all work together?”. How does engineering work with PMs? PMs with design? Design with engineering?

My response goes something like this…

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Richard Hakluyt, a bibliography 1580-1588 : with essays on the suppression of the voyage to Cadiz in Hakluyt's 'Principal navigations' and Hakluyt and the East India Company / Anthony Payne

London : Published by the Boydell Press for the Hakluyt Society, 2024




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Advanced Python scripting for ArcGIS pro [electronic resource] / Paul A. Zandbergen

Redlands, California : Esri Press, 2024




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In rhythm and melody

A pleasing violin duet by B.V. Durgabhavani and Peravalli Nandakumar.




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Maharajapuram Srinivasan’s masterly rendition

The singer’s rendition was reminiscent of his illustrious father and grandfather’s concerts.




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Art for the sake of humanity

Kerala-based artists Sreekumar Mavoor and Jagadeesh Palayat use their work to raise their voice against social evils