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High-efficiency photocatalytic water splitting by a N-doped porous g-C3N4 nanosheet polymer photocatalyst derived from urea and N,N-dimethylformamide

Inorg. Chem. Front., 2020, 7,1770-1779
DOI: 10.1039/D0QI00117A, Research Article
Feng Guo, Lijing Wang, Haoran Sun, Mingyang Li, Weilong Shi
N-Doped porous g-C3N4 nanosheets for high-efficiency photocatalytic water splitting were prepared by mixing the precursor of N,N-dimethylformamide and urea through a simple one-step thermal copolymerization method.
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Unraveling the complexation mechanism of actinide(III) and lanthanide(III) with a new tetradentate phenanthroline-derived phosphonate ligand

Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article
Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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[NH2CHNH2]3Sb2I9: a lead-free and low-toxicity organic–inorganic hybrid ferroelectric based on antimony(III) as a potential semiconducting absorber

Inorg. Chem. Front., 2020, 7,1780-1789
DOI: 10.1039/D0QI00137F, Research Article
Przemysław Szklarz, Ryszard Jakubas, Anna Gągor, Grażyna Bator, Jakub Cichos, Mirosław Karbowiak
A novel room-temperature ferroelectric crystal with the complex sequence of phase transitions.
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Facile assembly of a graphitic carbon nitride film at an air/water interface for photoelectrochemical NADH regeneration

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00182A, Research Article
Open Access
Changchao Jia, Wenjuan Hu, Yuanyuan Zhang, Chao Teng, Zupeng Chen, Jian Liu
A graphitic carbon nitride film electrode could be assembled at an air/water interface from nanosheets which exhibits improved photoelectrochemical coenzyme regeneration by further coupling with graphene during the interfacial self-assembly.
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Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates(III) and halobismuthates(III)

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00265H, Review Article
R. Jakubas, M. Rok, K. Mencel, G. Bator, A. Piecha-Bisiorek
Halogenoantimonates(III) and halogenobismuthates(III) are a highly versatile class of organic–inorganic hybrid materials, applicable in optoelectronics and switchable dielectric devices.
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A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article
Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln60. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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Intermetallic borides: structures, synthesis and applications in electrocatalysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00146E, Review Article
Hui Chen, Xiaoxin Zou
This review summarizes structural features and recent synthesis methods of structurally ordered intermetallic borides, and the theoretical–experimental advances in the emerging boride-catalyzed reactions.
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Disentangling Site Occupancy, Cation Regulation, and Oxidation State Regulation of the Broadband Near Infrared Emission in Chromium Doped SrGa4O7 Phosphor

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article
Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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id

Controllable synthesis of a mesoporous NiO/Ni nanorod as an excellent catalyst for urea electro-oxidation

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00316F, Research Article
Qing Li, Nan Li, Jing An, Huan Pang
Mesoporous rod-like structured composites of NiO/Ni have been successfully prepared via a low temperature heat treatment of the precursor NiC2O4·2H2O in N2.
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Ag nanoparticle embedded Cu nanoporous hybrid arrays for the selective electrocatalytic reduction of CO2 towards ethylene

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article
Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO2 to C2H4, and exhibit a maximum Faraday Efficiency 41.3%.
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Surface-guided polymorphism control of titanyl phthalocyanine single crystals

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00228C, Research Article
Youngkwan Yoon, Jin Young Koo, Jongwon Oh, Soyoung Kim, Hee Cheul Choi, Seok Min Yoon
Polymorphism control of the titanyl-phthalocyanine (TiOPc) single crystals by molecule-surface interactions and their effects of crystallographic structural differences on photo-electronics.
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Ni-Doped magnesium manganese oxide as a cathode and its application in aqueous magnesium-ion batteries with high rate performance

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article
Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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id

Systematic Study of the Optical Properties of Mononuclear Hybrid Organo-Inorganic Lanthanoid Complexes.

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00232A, Research Article
Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Minguez Espallargas, Lauro J. Q. Maia, Gisane Gasparotto, Ricardo Costa de Santana, Walter Cañón-Mancisidor
A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu4]3[LnH(PW11O39)(phen)2]·H2O, denoted as LM4-1-Ln (Ln = DyIII, TbIII, EuIII, NdIII, ErIII, HoIII and GdIII), were synthesized via hydrothermal synthesis and were structurally...
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id

Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

Inorg. Chem. Front., 2020, 7,1845-1850
DOI: 10.1039/C9QI01431D, Research Article
Jonghoon Choi, Yunho Lee
Catalytic hydrogenation of CO2 occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.
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id

Enabling high performance n-type metal oxide semiconductors at low temperatures for thin film transistors

Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article
Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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id

A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system

Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article
Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)4]2− complexes within π-acidic cavities.
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id

Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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id

Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal–organic framework

Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article
Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO2-philic acylamide groups exhibits high performance for CO2 capture, separation and chemical conversion.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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id

Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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id

An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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id

Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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id

Aerobic Oxidation Catalyzed by Polyoxometalates Associated to an Artificial Reductase at Room Temperature and in Water

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article
Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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id

Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




id

Roxanne [videorecording] / Columbia Pictures presents a Daniel Melnick Indieprod & LA Films production ; screenplay by Steve Martin ; produced by Michael Rachmil & Daniel Melnick ; directed by Fred Schepisi

1 videodisc (approximately 107 min.) : sound, color ; 4 3/4 in




id

Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




id

Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




id

Wonder Woman [videorecording] / directed by Patty Jenkins ; screenplay by Allan Heinberg ; story by Zack Snyder & Allan Heinberg and Jason Fuchs ; produced by Charles Roven, Deborah Snyder, Zack Snyder, Richard Suckle ; a Warner Bros. Pictures present

2 videodiscs (141 min.) : sound, color ; 4 3/4 in




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We cannot run away to moon, need to develop herd immunity: Epidemiologist

Muliyil tells Somesh Jha that the days of eradicating the disease is over and the country should move towards developing 'herd immunity'




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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal




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Early lockdowns in India may flatten Covid-19 curve: Nimhans virologist

In a Q&A, V Ravi says at some later stage two-thirds of the population will have gotten Covid-19 but that stage many would have recovered without even knowing they had been infected




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Munch on the go: Dietary guide for jet-setters




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Try apple cider vinegar to cure digestive problems




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Tackling menopause’s side effects




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Steroid shots for back, leg pain has few benefits: Study




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Experts divided on best way to brush teeth




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‘Eating well could cut incidence of TB by half’




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Fake death: Charred body still unidentified, Sharma claims it was a beggar




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Sunny side up: Vitamin D deficiency can affect your well-being




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Treat food addiction to combat obesity epidemic




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Diet Diary: Festival cheer marred by nasty hangover? Tips to avoid it





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Diet Diary: Why grandma always washed those kidney beans




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Diet Diary: Food intolerance and thyroid disorders directly proportional




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[ASAP] Continuous Production of Metal Oxide Nanoparticles via Membrane Emulsification–Precipitation

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00603




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[ASAP] Nitroxide-Mediated Miniemulsion Polymerization of Bio-Based Methacrylates

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00840




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[ASAP] Effect of the Solid Inlet Design on the Continuous Drying of Fine and Ultrafine Sand in a Fountain Confined Conical Spouted Bed

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00575




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[ASAP] Preparation and Interfacial Properties of Ultralow Concentrations of Amphiphilic Molybdenum Disulfide Nanosheets

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00217