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Shaheen Afridi reclaims top spot in ODI bowlers rankings

Pakistan's premier fast bowler Shaheen Afridi has reclaimed the No.1 position in the ICC Men's ODI Bowler Rankings, a spot he initially held during last year's Cricket World Cup in India.




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K'taka bypolls: 26.33 pc voting till 11 A.M. on three Assembly seats

The voting for the bye-elections held for three Assembly constituencies in Karnataka on Wednesday is witnessing a good turnout as 26.33 per cent of voting was recorded till 11 A.M.




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Bengal bypolls: Trinamool leader injured in shootout dies in hospital

The first casualty in the bypolls for six Assembly constituencies in West Bengal has been reported, as a Trinamool Congress leader who was severely injured in a shootout at Jagatdal adjacent to Naihati Assembly constituency in North 24 Parganas district, died on Wednesday.




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Jharkhand: Residents of Chuglu village in Gumla boycott voting over poor roads, civic amenities

The residents of Chuglu village in Gumla Assembly constituency boycotted the polling on Wednesday to protest against poor roads, streets and other civic amenities. They are frustrated over lack of basic and essential infrastructure in their villages.




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Trump appoints "The Great Elon Musk", Ramaswamy to head Dept of Government Efficiency

US President-elect Donald Trump appointedElon Musk and Vivek Ramaswamy to lead the new Department of Government Efficiency (DoGE).




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Celebrities including two Guvs cast their votes in Jharkhand, urge citizens to do their duty

As voting for the first phase of the Jharkhand Assembly elections covering 43 seats began at 7 A.M. on Wednesday, several prominent figures, political leaders, and candidates were among the early voters at their respective booths, stressing upon the importance of fulfilling one's duty.




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Supreme Court Sets 15-Day Notice Rule for Demolitions

The Supreme Court has laid down a series of pan-India directives, stating that no demolition will be carried out without serving at least a 15-day prior notice. The apex court's decision came in response to a series of petitions alleging that demolitions were carried out by several state authorities without sufficient notice.




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Trump names South Dakota governor to head Homeland Security with immigration mandate

US President-elect Donald Trump has nominated South Dakota Governor Kristi Noem as his secretary of the Department of Homeland Security, which controls immigration-related agencies.




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South Korea to double marine protection zone, address climate change

South Korea's oceans ministry plans to nearly double the size of its marine protected area by 2027 as part of efforts to proactively address climate change.




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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report

India accounts for per cent of the global total carbon dioxide (CO2) emissions, and it is expected to increase by 4.6 per cent in 2024, according to a new report released on Wednesday, ahead of the UN climate conference in Baku, Azerbaijan.




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Hyundai Motor India shares slip to Rs 1,745, down over 10 pc of IPO price

Shares of Hyundai Motor India, that were listed at Rs 1,931 apiece, have slipped more than 10 per cent from its IPO price.




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Navjot Singh Sidhu is back on Kapil Sharma's new show; netizens demand 'Justice for Archana Puran Singh'

Navjot Singh Sidhu's return on The Great Indian Kapil Show is expected to ruffle some feathers.




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Suriya reveals Jyothika made 3X more money than him: showers praises on wife [details]

Suriya revealed how Jyothika's career skyrocketed but it took a good couple of years to stabilize and reach that level.




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Reason behind Sai Pallavi's emotional breakdown on Shyam Singha Roy sets revealed [read now]

Sai Pallavi's portrayal of Rosie Maithreyi in the 2021 romantic period drama Shyam Singha Roy left a lasting impression among her fans. This was her second film appearance with Natural Star Nani, as they had previously worked on the film MCA, and the audiences love seeing them together on screen.




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Ayushmann gets nostaligic on his US music tour: "This is like homecoming for me"

Actor Ayushmann Khurrana, who is all set to enthrall fans with his music tour in the U.S., shared that the concert feels like a homecoming for him, as he used to perform in musicals during college.





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Won’t back off from ‘Pharma Village’, says Telangana CM’s brother - The Siasat Daily

  1. Won’t back off from ‘Pharma Village’, says Telangana CM’s brother  The Siasat Daily
  2. Lagcherla: KTR named in remand report  Deccan Chronicle
  3. Ex-BRS MLA held over mob attack on Vikarabad collector  Hindustan Times
  4. Video | Violence Over Land Row In Telangana Chief Minister's Constituency, 55 Detained  NDTV
  5. Govt. charges BRS with hatching conspiracies to stall development projects for political gains  The Hindu




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Wayanad, where Priyanka made poll debut, records lowest-ever voter turnout since constituency’s formation - The Indian Express

  1. Wayanad, where Priyanka made poll debut, records lowest-ever voter turnout since constituency’s formation  The Indian Express
  2. Wayanad, where Priyanka Gandhi made election debut, sees lowest-ever voter turnout  Hindustan Times
  3. Bypolls for one Lok Sabha, 31 Assembly seats keep 10 states busy  The Economic Times
  4. Rahul Gandhi Takes Kerala's Longest Zipline In Landslide-Hit Wayanad  NDTV
  5. You’re inspiration to keep fighting for ideals nation was built on: Priyanka to Wayanad voters  The Indian Express





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10 Negotiation Strategies Strong Leaders Use to Get Results

Effective negotiation for business leaders requires clear goals, understanding the other party's needs and utilizing strategies like preparation, flexible options, active listening and knowing when to stand firm or concede to build mutually beneficial relationships.




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Apple's Next Device Will Reportedly Be Mounted on Your Wall: 'They Feel Like They're Going to Sell a Lot of These Things'

The device will arrive by March at the earliest, according to reports.




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Spotify teases a ‘super premium’ tier for superfans and upcoming video expansion in Q3 earnings call

Spotify CEO Daniel Ek has once again teased the company’s long-delayed HiFi or “super premium” tier, a higher-qualify subscription offering the streaming service first announced in 2021 and then failed to roll out. In the company’s third-quarter earnings call with investors on Wednesday, the exec suggested that such a product was still on the way, […]

© 2024 TechCrunch. All rights reserved. For personal use only.




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Dr. Amiya Rajan Barik vs State Of Odisha & Others .... Opposite ... on 13 November, 2024

1. Since the issue involved in all these three (3) Writ Petitions are identical, all were heard analogously and disposed of by the present common order.

2. For the sake of brevity, pleadings made in W.P.(C ) No.36125 of 2023 was taken as the lead case for deciding the issue in question.

3. Writ petition in W.P.(C ) No.36125 of 2023 has been filed challenging the advertisement issued by the State Selection Board (in short, "the Board") on 11.09.2023 under Annexure-1.Vide the said advertisement, the Board invited applications to fill up the post of Lecturers in various discipline including Physics in non-Government Aided Colleges of Odisha and the last date for making such application was fixed to 13.10.2023.




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Haribhau S/O Rajaram Telgote And 2 ... vs The State Of Maharashtra Thr. Pso, Ps, ... on 13 November, 2024

Extreme penalty provided under the Indian Penal Code (IPC) i.e. Death Penalty imposed by the Sessions Judge is placed before us for scrutiny due to mandate of Section 366 of the Code, as well as by virtue of appeal preferred by the accused in terms of Section 374[2] of the Code of Criminal Procedure (Cr.P.C.)

2. Appellant Nos.1 to 3 were tried and convicted by the Additional Sessions Judge, Akot vide judgment and order dated 17.05.2024 in Sessions Case No.57/2015 for the offence punishable under Sections 302 read with Section 34 of the IPC and Section 506 [Part-II] read with Section 34 of the IPC. Though they have also been charged for the offence punishable under Section 323 of the Indian Rgd.




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The State Of Mah. Thr. Psops Hivarkhed ... vs Haribhau Rajaram Telgote And 2 Others on 13 November, 2024

Extreme penalty provided under the Indian Penal Code (IPC) i.e. Death Penalty imposed by the Sessions Judge is placed before us for scrutiny due to mandate of Section 366 of the Code, as well as by virtue of appeal preferred by the accused in terms of Section 374[2] of the Code of Criminal Procedure (Cr.P.C.)

2. Appellant Nos.1 to 3 were tried and convicted by the Additional Sessions Judge, Akot vide judgment and order dated 17.05.2024 in Sessions Case No.57/2015 for the offence punishable under Sections 302 read with Section 34 of the IPC and Section 506 [Part-II] read with Section 34 of the IPC. Though they have also been charged for the offence punishable under Section 323 of the Indian Rgd.




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Suo Motu vs State Of Kerala on 7 November, 2024

Dr. A.K.Jayasankaran Nambiar, J.

These writ petitions raise an interesting question as regards the scope, content and extent of the right to freedom of speech and expression enuring to the media when they report facts about ongoing criminal investigations or the proceedings in cases pending adjudication before the various adjudicatory forums in the country. The writ petitions were initially considered by a Full Bench of this Court. However, by an order dated 24.05.2018, the Full Bench took the view that in the light of an earlier decision of another Full Bench of this Court in S. Sudin v. Union of India and Others - [2015 (2) KLT 296 (FB)], these matters needed to be referred to a Larger Bench of five Judges for consideration. It is thus, and pursuant to an order dated 02.09.2024 of the Hon'ble the Acting Chief Justice, that these matters are now before us.




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Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment”

Moov Leasing, un start-up românesc lansat de Bogdan Speteanu și Mircea Dihel, propune o schimbare radicală în leasingul auto, transformând experiența de utilizare a unei mașini într-una simplă și accesibilă, la fel ca utilizarea unui telefon mobil. După 20 de ani de experiență la BCR, timp în care a ocupat mai multe funcții de conducere, printre care și ...

The post Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” appeared first on Forbes Romania.




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Kerala Lottery Result: ഏത് നമ്പരിനാണ് ഭാ​ഗ്യമടിച്ചത്? ഫിഫ്റ്റി ഫിഫ്റ്റി ഭാ​ഗ്യക്കുറി ഫലം വന്നു

Fifty Fifty Lottery Result: നിങ്ങളെടുത്ത ലോട്ടറിക്കാണോ ഒരു കോടി അടിച്ചത്? വിജയികളുടെ നമ്പറുകൾ അറിയാം...        




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This actor lived on a rooftop, starved for days, gatecrashed film sets for food; became one of India's biggest OTT stars

This actor, who once used to starve for days, gatecrash film sets for food, later became a superstar.




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Bigg Boss OTT-fame Bhojpuri actress Akshara Singh receives extortion threat

Bhojpuri actress Akshara Singh receives extortion threat, investigation underway.




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Kerala lottery TODAY November 14: Karunya Plus KN- 547 result to be OUT at 3 PM, know how to check full winners list

The Kerala Lottery Result for Karunya Plus KN 547 is set to be drawn today (November 14, 2024). The draw is scheduled to be held at Gorky Bhavan near Bakery Junction in Thiruvananthapuram. The public can view the Winning Number post at 2.55 pm during the Kerala Lottery Today live broadcast.




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Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00228H, Research Article
Ekaterina V. Malakhova, Vladislav S. Kostromitin, Vitalij V. Levin, Alexander D. Dilman
Commodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.
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Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00233D, Research Article
Fan Zhu, Zhi Qiao, Na He, Chunxiao Nong, Qiping He, Meilan Xi, Xizhong Song, Jun Lin, Jingbo Chen, Yi Jin
A general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is reported. These reactions proceed via a phosphoranyl radical, followed by radical coupling of the resulting azole radical to the alkene radical.
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Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00311J, Research Article
Pei-Ting Li, Zi-Fa Shi, Wei Yu
Two triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00310A, Research Article
Jiaxi Fang, Ziheng Jian, Huan Liu, Yuting Wang, Xianbo Yu, Zehuai Mou, Huifei Wang
A novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.
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Correction: Stereodivergent and enantioselective total syntheses of isochaetominines A–C and four pairs of isochaetominine C enantiomers: a six-step approach

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO90034K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang Huang
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Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis

Org. Chem. Front., 2024, 11,2344-2350
DOI: 10.1039/D3QO01955A, Research Article
Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang
N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.
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Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles

Org. Chem. Front., 2024, 11,2208-2214
DOI: 10.1039/D4QO00121D, Research Article
Lei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo Peng
A facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.
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Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst

Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
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Photo-induced catalyst-free formal carbon insertion of acylsilanes into B–B and B–Si bonds

Org. Chem. Front., 2024, 11,2339-2343
DOI: 10.1039/D4QO00139G, Research Article
Xiongxiong Lu, Qingbin Zhao, Hao Zhang, Pan Xu, Xuenian Chen, Zhenxing Liu
A formal carbon insertion of acylsilanes into B–B and B–Si bonds has been developed. The in situ formed siloxycarbene under blue LED irradiation worked as the intermediate for the reaction. When 2-furyl and 2-thiophenyl acylsilanes were used, the B(pin) ring was enlarged to a six-membered ring.
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Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis

Org. Chem. Front., 2024, 11,2269-2276
DOI: 10.1039/D4QO00073K, Research Article
Yujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang Lu
Two major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.
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Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study

Org. Chem. Front., 2024, 11,2231-2240
DOI: 10.1039/D4QO00177J, Research Article
Romain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas Poisson
Herein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.
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Electrochemical remote C(sp3)–H thiocyanation

Org. Chem. Front., 2024, 11,2283-2288
DOI: 10.1039/D4QO00032C, Research Article
Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li, Weisi Guo
An electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.
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Photoinduced alkylation of pyrazolones via β-scission of unstrained aliphatic alcohol derivatives

Org. Chem. Front., 2024, 11,2289-2296
DOI: 10.1039/D4QO00077C, Research Article
Xinxin Geng, Pan Tao, Yujun Li, Ke Zheng
An efficient radical approach was reported for the transformation of unstrained aliphatic alcohols through the β-scission of alkoxyl radicals.
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Nickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides

Org. Chem. Front., 2024, 11,2297-2305
DOI: 10.1039/D4QO00167B, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Le-Cheng Wang, Xiao-Feng Wu
A novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.
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NHC and photoredox catalysis dual-catalyzed 1,4-mono-/di-fluoromethylative acylation of 1,3-enynes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00372A, Research Article
Jiuli Xia, Ruiyang Ma, Lihong Wang, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC and photocatalysis dual-catalyzed mono/difluoromethylative acylation of 1,3-enynes was realized, providing fluormethyl-substituted allenyl ketones. SO2 might play a critical role in achieving high reactivity and selectivity.
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Cr-mediated Photocatalytic Decarboxylative Coupling of alpha-Oxo Acids with Benzylic Pyridinium Salts

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00475B, Research Article
Jia Cao, Yan Liu, Zhixiang Wang, Le Liu
Herein, we report the chromium/photoredox dual catalytic synthesis of ketones using α-oxo acids with benzylic pyridinium salts. This reaction proceeded by photocatalytic generation of acyl radical from α-oxo acids and...
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Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00280F, Research Article
Hui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan Zhang
A metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.
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Development of a photoenzymatic one-pot hybrid system for the direct synthesis of 3,3-disubstituted indole-2-ketones from N-methyl indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00371C, Research Article
Yao Yao, Yuan Yu, Ming-Liang Shi, Xin-Yue Fan, Ru-De Lin, Kun Li, Wen-Dian Li, Fei-Yan Tao, Na Wang
The effective combination of photocatalysis and enzyme catalysis has been widely utilized for the synthesis of high-value-added products.
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Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00552J, Research Article
Open Access
Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier Bourissou
Cycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...
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