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Pyridine tetrafluoro-λ6-sulfanyl chlorides: spontaneous addition to alkynes and alkenes in the presence or absence of photo-irradiation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00339E, Research Article
Kiyoteru Niina, Kazuhiro Tanagawa, Yuji Sumii, Norimichi Saito, Norio Shibata
A radical addition reaction of Py-SF4Cl to alkynes and alkenes provide pyridine-SF4-alkenes and pyridine-SF4-alkanes under blue LED light irradiation or absence of light irradiation in CPME or without solvent.
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Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00168F, Research Article
Simon Budde, Felix Goerdeler, Johannes Floß, Peter Kreitmeier, Elliot F. Hicks, Oren Moscovitz, Peter H. Seeberger, Huw M. L. Davies, Oliver Reiser
Hetero- and carbocyclic anellated cyclopropanes were converted in one step by a visible light induced photooxidation to their corresponding polycyclic endoperoxides, which show promising antimalarial activity.
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Roquefornine A, a sesterterpenoid with a 5/6/5/5/6-fused ring system from the fungus Penicillium roqueforti YJ-14

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00301H, Research Article
Jia-Peng Wang, Yan Shu, Jun-Tao Hu, Rui Liu, Xue-Yun Cai, Cheng-Tong Sun, Dong Gan, Di-Jiao Zhou, Rui-Feng Mei, Hao Ding, Xiao-Ran Zhang, Le Cai, Zhong-Tao Ding
Roquefornine A, a sesterterpenoid with an unprecedented 5/6/5/5/6-membered pentacyclic system, was characterized from Penicillium roqueforti YJ-14. Its structure was determined by extensive spectroscopic analyses, [Rh2(OCOCF3)4]-induced CD data and DP4+ calculations....
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Asymmetric Organocatalytic Double 1,6-Addition: Rapid Access to Chiral Chromans with Molecular Complexity

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00354A, Research Article
Indranil Chatterjee, Sourav Roy, Suman Pradhan, Krishan Kumar
An organocatalytic cascade vinylogous double 1,6-addition strategy for the synthesis of chiral chroman derivatives is reported. The cascade reaction follows oxa-Michael/1,6-addition reactions between ortho-hydroxyphenyl-substituted para-quinone methadies and 2,4-dienal derivatives to...
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Discrete boronate ester ladders from the dynamic covalent self-assembly of oligo(phenylene ethynylene) derivatives and phenylenebis(boronic acid)

Org. Chem. Front., 2020, 7,1082-1094
DOI: 10.1039/D0QO00083C, Research Article
Vasileios Drogkaris, Brian H. Northrop
Reversible boronate ester chemistry enables the controlled, dynamic self-assembly of olig(phenylene ethynylene)s into highly conjugated ladder frameworks.
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Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N,N'-(1,2-phenylene)bisamides and 2-amidophenols

Org. Chem. Front., 2020, 7,1095-1106
DOI: 10.1039/C9QO01508F, Research Article
Damoder Reddy Motati, Dilipkumar Uredi, Amarender Goud Burra, J. Phillip Bowen, Frank R. Fronczek, Clint R. Smith, E. Blake Watkins
A highly efficient, site-selective, visible light-accelerated, remote C–H halogenation of unsymmetrical aromatic bisamides/amidoesters has been developed.
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Topomeric aza/thia cryptands: synthesis and theoretical aspects of in/out isomerism using n-alkyl bridging

Org. Chem. Front., 2020, 7,1164-1176
DOI: 10.1039/D0QO00123F, Research Article
Ian S. Taschner, Tia L. Walker, Sharath Chandra M., Briana R. Schrage, Christopher J. Ziegler, Xinfeng Gao, Steven E. Wheeler
A series of heterobicyclic aza/thia-lactams and cryptands incorporating changes in n-alkyl bridging length have been synthesized, characterized, chelated to heavy metals and computationally assessed.
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Insights into N-heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of α,β-unsaturated aldehyde with 1,3-dicarbonyl compounds

Org. Chem. Front., 2020, 7,1113-1121
DOI: 10.1039/D0QO00091D, Research Article
Xinghua Wang, Yang Wang, Jinshuai Song, Donghui Wei
N-Heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of 1,3-dicarbonyl compounds have been systematically studied in theory.
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The origin of regioselectivity in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides

Org. Chem. Front., 2020, 7,1137-1148
DOI: 10.1039/D0QO00214C, Research Article
Shengnan Liu, Jianbiao Liu, Qiong Wang, Jin Wang, Fang Huang, Wenjuan Wang, Chuanzhi Sun, Dezhan Chen
Steric interactions mediate a switch between a ketone and allylic alcohol in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides.
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Rh(III)-Catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes

Org. Chem. Front., 2020, 7,1158-1163
DOI: 10.1039/D0QO00248H, Research Article
Shaonan Wu, Zhuo Wang, Dianxue Ma, Chen Chen, Bolin Zhu
We reported a Rh(III)-catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes, which provided diversiform functionalized N,N-bidentate chelating compounds.
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An Aspidosperma-type alkaloid dimer from Tabernaemontana bovina as a candidate for the inhibition of microglial activation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00296H, Research Article
Yang Yu, Si-Meng Zhao, Mei-Fen Bao, Xiang-Hai Cai
As a representative of twelve undescribed Aspidosperma-type alkaloid dimers, tabernaemontine F (6) inhibited microglial activation by blocking P38 MAPK activation, revealing a potential candidate for chronic neurodegenerative diseases.
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Chiral strong Brønsted acid-catalyzed enantioselective addition reaction of simple olefins with ethyl glyoxylate

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00448K, Research Article
Jun Kikuchi, Yuki Aizawa, Masahiro Terada
An enantioselective intermolecular addition reaction of 1,1,2-trisubstituted and 1,2- disubstituted simple olefins with ethyl glyoxylate was developed using F10BINOL-derived N-sulfonyl phosphoramide as a chiral strong Brønsted acid catalyst.
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An exocyclic π-system extension of the phenanthriporphyrin framework: towards azaaceneporphyrinoids

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00436G, Research Article
Bartosz Szyszko, Damian Dróżdż, Aleksandra Sarwa, Sebastian G. Mucha, Agata Białońska, Michał J. Białek, Katarzyna Matczyszyn, Lechosław Latos-Grażyński
An exocyclic π-extension of phenanthriporphyrin reduces the macrocyclic antiaromaticity of the formed expanded carbaporphyrinoids.
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Phosphine/Palladium Cooperative Catalysis: Enantioselective [5+4] Annulations of ortho-Quinone Methides and Vinylethylene Carbonates

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00128G, Research Article
Chao Xia, Dong-Chao Wang, Gui-Rong Qu, Hai-Ming Guo
Highly enantioselective [5+4] annulations of ortho-quinone methides with vinylethylene carbonates were enabled by phosphine/palladium asymmetric cooperative catalysis for the first time. Efficient synthesis of various nine-membered benzo-heterocycles was achieved in...
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A Vinylogous Michael Reaction of 2-Furanones Dimers to α, β-Unsaturated Nitroolefins for Constructing Chiral γ, γ-Disubstituted Butenolides

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00376J, Research Article
Zhushuang Bai, Cairong Zhang, Yongyi Chen, Aiqin Liu, Xinyu Wang, Chuna Yan, Xuechao Liu, Xiaoru Zhang, Ying Li, Ye Yuan, Zemei Ge, Jingxiang Pang, Yongshuai Chai, Xin Wang, Runtao Li
An efficient bifunctional thiourea catalyzed asymmetric vinylogous Michael addition of 2-furanones dimers to α, β-unsaturated nitroolefins has been developed to give the functional chiral γ,γ-disubstituted butenolides in good yields (up...
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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
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Targeted Isolation of Two Disesquiterpenoids Macrocephadiolides A and B from Ainsliaea macrocephala using Molecular Networking-based Dereplication Strategy

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00030B, Research Article
Yong-Mei Ren, Shuaizhen Zhou, Tian Zhang, Meijia Qian, Rui Zhang, Sheng Yao, Hong Zhu, Chunping Tang, Ligen Lin, Yang Ye
A molecular networking-based dereplication strategy was applied to the phytochemical investigation of Ainsliaea macrocephala, leading to the isolation of two novel disesquiterpenoids macrocephadiolides A (1) and B (2). Their structures,...
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id

Scientists must write : a guide to better writing for scientists, engineers and students / Robert Barrass

Barrass, Robert




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Writing scientific papers in English : an ELSE-Ciba Foundation guide for authors / Maeve O'Connor and F.Peter Woodford

O'Connor, Maeve




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The ACS style guide : a manual for authors and editors / Janet S. Dodd, editor ; Marianne C. Brogan, advisory editor




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A guide to scientific writing : manual for students and research workers / David Lindsay

Lindsay, David




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A primer of mathematical writing : being a disquisition on having your ideas recorded, typeset, published, read and appreciated / Steven G. Krantz

Krantz, Steven G. (Steven George), 1951-




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The ACS style guide : a manual for authors and editors / Janet S. Dodd, editor




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A guide to scientific writing / David Lindsay

Lindsay, D. R




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Nanoscale devices : fundamentals and applications / edited by Rudolf Gross, Anatolie Sidorenko and Lenar Tagirov

NATO Advanced Research Workshop on Nanoscale Devices - Fundamentals and Applications (2004 : Kishinev, Moldova)




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Nanotechnology and occupational health / edited by Andrew D. Maynard, David Y.H. Pui

International Symposium on Nanotechnology and Occupational Health (2nd : 2005 : Minneapolis, Minn.)




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Nanotechnology / G. Schmid ... [et al.] (eds.)




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Advanced nanomaterials / edited by Kurt E. Geckeler and Hiroyuki Nishide




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Nanostructured titanium dioxide materials : properties, preparation and applications / Alireza Khataee, G. Ali Mansoori

Khataee, A. R. (Ali Reza), 1977-




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Nanotechnology intellectual property rights : research, design, and commercialization / Prabuddha Ganguli, Siddarth Jabade

Ganguli, Prabuddha




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New horizons in nanoscience and engineering / David L. Andrews, James G. Grote, editors




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Introduction to focused ion beam nanometrology / David C. Cox

Cox, David C. (David Christopher), 1965- author




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[ASAP] Ship-in-a-Bottle Preparation of Long Wavelength Molecular Antennae in Lanthanide Metal–Organic Frameworks for Biological Imaging

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c01426




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[ASAP] Kinetics of the <italic toggle="yes">Trans</italic> Effect in Ruthenium Complexes Provide Insight into the Factors That Control Activity and Stability in CO<sub>2</sub> Electroreduction

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c02912




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[ASAP] Stereodivergent Asymmetric Synthesis of a,ß-Disubstituted ß-Aminoalkylboronic Acid Derivatives via Group-Selective Protodeboronation Enabling Access to the Elusive Anti Isomer

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03207




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[ASAP] Measurement of the Proton Affinities of a Series of Mono- and Biradicals of Pyridine

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c00202




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[ASAP] Selective Modification of Tryptophan Residues in Peptides and Proteins Using a Biomimetic Electron Transfer Process

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03039




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[ASAP] Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03941




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[ASAP] Contrasting Efficiency of Electron-Induced Reaction at Cu(110) in Aliphatic and Aromatic Bromides

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c02851




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[ASAP] All-Inorganic Halide Perovskites as Potential Thermoelectric Materials: Dynamic Cation off-Centering Induces Ultralow Thermal Conductivity

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03427




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[ASAP] Copper-Catalyzed Asymmetric Radical 1,2-Carboalkynylation of Alkenes with Alkyl Halides and Terminal Alkynes

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03130




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[ASAP] Rapid Route-Finding for Bifurcating Organic Reactions

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b13449




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[ASAP] Amine-Reactive Activated Esters of <italic toggle="yes">meso</italic>-CarboxyBODIPY: Fluorogenic Assays and Labeling of Amines, Amino Acids, and Proteins

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b13982




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[ASAP] Extraordinary Acceleration of Cogwheel Helical Self-Organization of Dendronized Perylene Bisimides by the Dendron Sequence Encoding Their Tertiary Structure

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03353




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[ASAP] Sugar-Pirating as an Enabling Platform for the Synthesis of 4,6-Dideoxyhexoses

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b13766




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[ASAP] Controlling the Dynamics of Ionic Liquid Thin Films via Multilayer Surface Functionalization

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03044




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[ASAP] Iterative Catalysis in the Biosynthesis of Mitochondrial Complex II Inhibitors Harzianopyridone and Atpenin B

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03438




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[ASAP] Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c01895




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[ASAP] Discovery of Potent Cyclic Sulfopeptide Chemokine Inhibitors via Reprogrammed Genetic Code mRNA Display

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03152




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[ASAP] Chemical Equivalent of Arene Monooxygenases: Dearomative Synthesis of Arene Oxides and Oxepines

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c02724