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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

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Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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Gold nanoparticles cross cell-subcellular barriers for biological regulation

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Inorg. Chem. Front., 2024, 11,2205-2211
DOI: 10.1039/D4QI00316K, Chemistry Frontiers
Xiang Zheng, Guangchao Qing, Yaru Jia, Fangzhou Li, Lanju Xu, Xing-Jie Liang, Jinchao Zhang
Major biological barriers for nanomedicines to cross to reach target sites are the blood barrier, blood–tissue barrier, transmembrane barrier and cell-cellular barrier.
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Recent progress in aluminum anodes for high-performance rechargeable aqueous Al-ion batteries

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Inorg. Chem. Front., 2024, 11,2246-2259
DOI: 10.1039/D4QI00468J, Review Article
Le Li, Shaofeng Jia, Yue Shi, Conghui Wang, Hengwei Qiu, Yongqiang Ji, Minghui Cao, Dan Zhang
This review discusses the recent advances in the aluminum metal anodes, alloy anodes, and intercalated anodes used for rechargeable aqueous Al-ion batteries.
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor

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Inorg. Chem. Front., 2024, 11,2436-2441
DOI: 10.1039/D3QI02685J, Research Article
Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
D–J phase perovskite (BDA)MA2Pb3Br10 reveals excellent photo-responsivity antifatigue merits and remarkable switching stability.
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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

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Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
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Nanocarbon armor reinforced Ag particles to build a high-rate and long-lifespan aqueous Zn2+/Cl− dual-ion battery

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00499J, Research Article
Wenbo Guo, Tianyuan Zhang, Guangchang Shu, Leiyu Fan, Zhouxiang Wu, Lei Yan, Liyuan Zhang, Haoxiang Yu, Ting-Feng Yi, Jie Shu
A high-performance aqueous Zn2+/Cl− dual-ion battery is built by using nanocarbon armor reinforced Ag particles as the cathode, metallic Zn as the anode and ZnCl2 as the electrolyte.
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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
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New Ultraviolet Transparent Rare-Earth Borates with Enhanced Birefringence Induced by Cation Chemical Substitution

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00840E, Research Article
Guanglian Sun, xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu
Birefringence determined by optical anisotropy is one of the most pivotal and fundamental performance of optical materials. However, optimizing the birefringence remains a significant challenge. Herein, a simple and effective...
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Effect of -OH on the Thermal Enhancement Properties of NIR-II Lanthanide Doped Nanoparticles in Water

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00147H, Research Article
Yingping Huang, Jie Hu, Yongwei Guo, Zihao Wang, Fulin Lin, Haomiao Zhu
Thermal enhanced nanothermometry has attracted great attention due to its high thermal sensitivity, however, most of studies are focused on the upconversion nanoparticles (NPs) in forms of powder. In the...
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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00490F, Research Article
Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
β-Ga2O3 photodetectors achieve ultrahigh responsivity under low supply voltage and ultralow light intensity conditions via band engineering with polar Hf0.5Zr0.5O2 as an insert layer.
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Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00602J, Research Article
Fangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo Li
Photocatalytic hydrogen production using semiconductors is one of the most promising routes for sustainable energy production.
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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH−. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH−, and accelerated the kinetics of HMFOR.
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOH* creates favorable conditions for CO formation and desorption.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

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Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

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Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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Asian rice prices drop after India eases export curbs

By www.thehindubusinessline.com
Published On :: Fri, 04 Oct 2024 19:49:50 +0530

FAO says market down by $10-72 a tonne, Thai cuts rates by 10%


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Indian rice exports get delayed at ports as Customs officials hold up consignments

By www.thehindubusinessline.com
Published On :: Wed, 09 Oct 2024 18:52:39 +0530

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice


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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

By www.thehindubusinessline.com
Published On :: Thu, 10 Oct 2024 16:03:50 +0530

Subdued demand, struggling property sector may exert downward pressure on metals


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SEBI panel mulls new category of commodity funds

By www.thehindubusinessline.com
Published On :: Sun, 13 Oct 2024 18:51:20 +0530

MF investment in ETCDs is estimated to be under ₹10,000 crore


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Row over ISMA’s suggestion to regulate khandsari units

By www.thehindubusinessline.com
Published On :: Mon, 14 Oct 2024 18:32:27 +0530

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives


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Global Organic Textiles Standards bans 5 Indian cotton firms for faking documents

By www.thehindubusinessline.com
Published On :: Wed, 16 Oct 2024 16:54:34 +0530

Two firms used non-existent shipping firms to show transactions, the others submitted fake transaction certificates


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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

By www.thehindubusinessline.com
Published On :: Thu, 17 Oct 2024 18:10:31 +0530

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC


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Reservoirs with less than 50% storage down to single digit

By www.thehindubusinessline.com
Published On :: Thu, 17 Oct 2024 20:18:22 +0530

Key dams’ water level unchanged at 87% of capacity this week


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Global steel demand to drop a tad in 2024, rebound in 2025: worldsteel

By www.thehindubusinessline.com
Published On :: Fri, 18 Oct 2024 19:06:24 +0530

Ongoing weakness in housing construction, driven by tight financing conditions and high costs, cited as reason for the fall in demand


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Crude oil down due to concerns over slowing demand in China 

By www.thehindubusinessline.com
Published On :: Tue, 22 Oct 2024 11:14:32 +0530

Market is also cautious about a potential increase in global oil supply as the OPEC+ is planning to restore production output in December


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Not much relevance of windfall tax on crude now: Advisor to PM

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 15:15:22 +0530

Windfall Tax is to counterbalance the unusually high profits earned by oil and gas companies from high global crude oil prices


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India defers plan to hike minimum selling price of sugar, for now

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 19:59:36 +0530

The agri costs panel had recommended regular revision of the minimum price


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Diesel, petrol demand to grow 50,000-55,000 barrels per day Y-o-Y in Oct-Dec

By www.thehindubusinessline.com
Published On :: Thu, 24 Oct 2024 12:42:13 +0530

India’s appetite for oil products in October-December is set to get a boost from the upcoming festival season as well as the agricultural season


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Storage in key Indian reservoirs unchanged for 3rd week in a row

By www.thehindubusinessline.com
Published On :: Thu, 24 Oct 2024 19:20:01 +0530

They are higher than normal, filled to 87 per cent of the 180.852 BCM capacity


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Part of India’s sugar export quota to Maldives ‘diverted’ to Sri Lanka, Malaysia

By www.thehindubusinessline.com
Published On :: Fri, 25 Oct 2024 18:42:44 +0530

Though exports are banned, shipments of 64,000 tonnes were allowed under special bilateral pact


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Festivals, agriculture, elections set to boost India's oil demand: S&P Global Commodity Insights

By www.thehindubusinessline.com
Published On :: Sat, 26 Oct 2024 14:45:00 +0530

According to the commodities information services provider, India's oil demand decreased in September on a yearly basis, due to above normal rainfall, which affected road movement, construction, and mining activities


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