an Smart snacking grows 1.2 times faster than traditional snacks in India By www.newkerala.com Published On :: Tue, 12 Nov 2024 18:06:02 +0530 Full Article
an Japan to push for biofuel-compatible new cars by 2030s By www.newkerala.com Published On :: Tue, 12 Nov 2024 20:20:03 +0530 Full Article
an Truly insightful: Gautam Adani hosts envoys from EU, Belgium, Denmark and Germany By www.newkerala.com Published On :: Tue, 12 Nov 2024 20:32:02 +0530 Full Article
an Bears on prowl! Sensex tanks 820 points, Nifty below 24,000 By www.newkerala.com Published On :: Tue, 12 Nov 2024 20:38:02 +0530 Full Article
an Donor-modified asymmetric N/B/O multi-resonance TADF emitters for high-performance deep-blue OLEDs with the BT.2020 color gamut By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18135-18145DOI: 10.1039/D4SC04896B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing Jin, Zhaolong He, Di Liu, Yongqiang Mei, Jiahui Wang, Huihui Wan, Jiuyan LiSpiro-acridine modified N/B/O type MR-TADF emitters realized deep blue fluorescence with an EQEmax of 20.5% and CIE (0.147, 0.048), which is state-of-the-art efficiency for N/B/O type deep-blue MR emitters with CIEy approaching the BT.2020 standard.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Visible-light-responsive hybrid photocatalysts for quantitative conversion of CO2 to highly concentrated formate solutions By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18146-18160DOI: 10.1039/D4SC05289G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ewan McQueen, Noritaka Sakakibara, Kei Kamogawa, Martijn A. Zwijnenburg, Yusuke Tamaki, Osamu Ishitani, Reiner Sebastian SprickThis highly efficient hybrid photocatalytic system can quantitatively convert CO2 to formate and produce 0.4 M of formate solution without additional concentration enrichment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Enhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18060-18066DOI: 10.1039/D4SC05442C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zheng-Xiao Tang, Bin Wang, Zhi-Rui Li, Zhuo Huang, Hai-Xia Zhao, La-Sheng Long, Lan-Sun ZhengA molecule-based ferroelectric [(CH3)3NCH2CH2Br][GaBr4] (1), with a d33 value of 331 pC N−1, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm−2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an NN bond cleavage in diazirines by a cyclic diborane(4) compound By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18048-18051DOI: 10.1039/D4SC04980B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Minling Zhong, Jie Zhang, Zuowei XieReactions of o-carborane-fused diborane(4) with 3H-diazirines lead to the complete cleavage of the NN bond, with one nitrogen atom being incorporated into the B–B bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Spotting d-band centers of single-atom catalysts by oxygen intermediate-boosted electrochemiluminescence By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18085-18092DOI: 10.1039/D4SC03763D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ruyu Xie, Kaitao Li, Rui Tian, Chao LuWe have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an A perspective on next-generation hyperfluorescent organic light-emitting diodes By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17739-17759DOI: 10.1039/D4SC05489J, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Upasana Deori, Gyana Prakash Nanda, Caroline Murawski, Pachaiyappan RajamalliThe evolution of next-generation HF-OLED technology and current challenges.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Chemoenzymatic multistep retrosynthesis with transformer loops By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18031-18047DOI: 10.1039/D4SC02408G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Kreutter, Jean-Louis ReymondIntegrating enzymatic reactions into computer-aided synthesis planning (CASP) should help devise more selective, economical, and greener synthetic routes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Recent advances in hydrogel-based flexible strain sensors for harsh environment applications By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17799-17822DOI: 10.1039/D4SC05295A, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Miaoyu Li, Jie Pu, Qinghe Cao, Wenbo Zhao, Yong Gao, Ting Meng, Jipeng Chen, Cao GuanThe application of hydrogel-based flexible strain sensors in harsh environments, including extreme temperatures, humidity, high mechanical strain, and strong corrosion, is investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an When microplastics/plastics meet metal–organic frameworks: turning threats into opportunities By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17781-17798DOI: 10.1039/D4SC05205F, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pengfei Wu, Mengting Guo, Ran-Wei Zhang, Qing Huang, Guibin Wang, Ya-Qian LanThe study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an A critical factor in reactive oxygen species (ROS) studies: the need to understand the chemistry of the solvent used: the case of DMSO By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17843-17851DOI: 10.1039/D4SC05038J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shubham Bansal, Binghe WangReactive oxygen species (ROS) play critical roles in normal physiological processes including cellular signaling and immune responses.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Is aromaticity loss necessary for transition-metal promoted arene–alkene cycloadditions? By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18093-18098DOI: 10.1039/D4SC05337K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.João V. Schober, Croix J. Laconsay, Judy I. WuDiene- and ene-like reactivity in transition metal coordinated arenes can be expected when there is a notable degree of aromaticity loss at the complexed arene.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Diverse quantum interference regimes in intramolecular singlet fission chromophores with thiophene-based linkers By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17823-17830DOI: 10.1039/D4SC03546A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jonghwan Lee, Sungsik Eom, Hyungjun KimThis work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18161-18169DOI: 10.1039/D4SC04318A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan LiA sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Automated electrosynthesis reaction mining with multimodal large language models (MLLMs) By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17881-17891DOI: 10.1039/D4SC04630G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shi Xuan Leong, Sergio Pablo-García, Zijian Zhang, Alán Aspuru-GuzikLeveraging multimodal large language models (MLLMs) to process multimodal data inputs and complex inter-modality data dependencies for automated (electro)chemical data mining from scientific literature.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an On-demand controlled bidirectional DNAzyme path for ultra-sensitive heavy metal ion detection By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18170-18178DOI: 10.1039/D4SC04404E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong TanA bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb2+ and Hg2+ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an MR-TADF liquid crystals: towards self assembling host–guest mixtures showing narrowband emission from the mesophase By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18022-18030DOI: 10.1039/D4SC04429K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julius A. Knöller, Franziska Müller, Tomas Matulaitis, John M. dos Santos, Abhishek Kumar Gupta, Eli Zysman-Colman, Sabine LaschatWe developed a MR-TADF based, columnar liquid crystalline host system and doped it with a MR-TADF guest. Efficient FRET allowed us to construct the first columnar liquid crystal with narrowband MR-TADF from the strongly aggregated mesophase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18111-18126DOI: 10.1039/D4SC04852K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. OfialCombined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2 By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18127-18134DOI: 10.1039/D4SC04874A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. ShaijumonThe synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Two in one: merging photoactivated chemotherapy and photodynamic therapy to fight cancer By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17760-17780DOI: 10.1039/D4SC04608K, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kirill M. Kuznetsov, Kevin Cariou, Gilles GasserCombining photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) into one single compound allows to achieve more efficient light-induced therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Porous liquids: an integrated platform for gas storage and catalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17720-17738DOI: 10.1039/D4SC04288C, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Errui Li, Kevin M. Siniard, Zhenzhen Yang, Sheng DaiIn this perspective, recent discoveries in the integration of gas storage and catalysis by leveraging PL platforms have been summarized, highlighting the unique features different from those of traditional homogeneous or heterogeneous procedures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Unified enantiospecific synthesis of drimane meroterpenoids enabled by enzyme catalysis and transition metal catalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06060A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen XuA unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Boronic ester-templated pre-rotaxanes as versatile intermediates for rotaxane endo-functionalisation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04879B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik SchaufelbergerDynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05998K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi GuanUtilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Dilute nanocomposites for capacitive energy storage: progress, challenges and prospects By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05437G, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Li Li, Wenhan Xu, Guanchun Rui, Shixian Zhang, Qiming Zhang, Qing WangElectrostatic capacitors (ECs) are critical components in advanced electronics and electric power systems due to their rapid charge-discharge rate and high power density. While polymers are ideal for ECs due...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an The Effect of gem-Difluorination on the Conformation and Properties of a Model Macrocyclic System By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05424E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Laurent Knerr, Thomas Cogswell, Marie. Ahlqvist, Richard James Lewis, Anneli Nordqvist, Christian SköldConformational control of drug candidates to engineer improved potency and ADME properties is an ongoing area of research. Macrocyclic rings tend to offer a greater degree of rigidity than non-cyclised...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04767B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lucie Pedussaut, Nolwenn Mahieu, Camille Chartier, Thayalan Rajeshkumar, Maxime Tricoire, Iskander Douair, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Grégory NoctonReversible light isomerization in organometallic complexes of lanthanides: the low-energy wavelengths favor the cis isomer, and the high-energy wavelengths favor the trans isomer.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05736H, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ritu Gupta, Anujit Balo, Rabia Garg, Amit Kumar Mondal, Koyel Banerjee Ghosh, Prakash Chandra MondalThis review highlights recent experimental findings related to the chirality-induced spin selectivity effect. This effect is demonstrated to explain asymmetric electron's spin transport in chiral molecules for various technological applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06820C, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seungwon Sun, Jisu Choe, Jaeheung ChoIn biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Pd(II)-Catalyzed Enantioselective C-H Olefination and Photoregulation of Sterically-Hindered Diarylethenes By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05375C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Guanlun Zhang, Xu Wu, Shiyu Mao, Mengqi Li, Honglong Hu, Bing-Feng Shi, Weihong ZhuSterically-hindered diarylethenes with intrinsic chirality have shown great potential in chiral signal regulation, light-controlled liquid crystals (LCs), etc. Their unique enantiospecific phototransformation between axial chirality of ring-open isomer and central...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Insights into the photoinduced anion translocation of the Donor-π-Acceptor+(ion)- molecules By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04738A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hao-Ting Qu, Iida Partanen, Kai-Hsin Chang, Yan-Ding Lin, Igor O Koshevoy, Andrey Belyaev, Pi-Tai ChouBy strategic design and synthesis of a new series of phosphonium salts (compounds 1–7[OTf]), where [OTf]- stands for the trifluoromethanesulfonate anion, we performed comprehensive spectroscopic and dynamic studies on the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04589K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique PourpointThe stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03942D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-KostalCleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05788K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Utsav Dey Sarkar, Mahima Rana, Harinath ChakrapaniA new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Enhanced efficiency in plastic waste upcycling: the role of mesoporosity and acidity in zeolites By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05121A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Saideep Singh, Joaquín Martínez-Ortigosa, Nuria Ortuño, Vivek Polshettiwar, Javier García-MartínezBy optimizing zeolite pore confinement, polymer diffusion and up-cycling efficiency in hierarchical catalysts are significantly enhanced, reducing plastic degradation temperatures and providing a suitable route to sustainable plastic-to-fuel pathways.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Light-assisted carbon dioxide reduction in an automated photoreactor system coupled to carbonylation chemistry By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06660J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jasper Schuurmans, Tom Masson, Stefan Zondag, Simone Pilon, Nicola Bragato, Miguel Claros, Tim den Hartog, Fransesc Sastre Calabuig, Jonathan van den Ham, Pascal Buskens, Giulia Fiorani, Timothy NoelContinuous-flow methodologies offer promising avenues for sustainable processing due to their precise process control, scalability, and efficient heat and mass transfer. The small dimensions of continuous-flow reactors render them highly...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06334A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun FengWe present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06324D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. ReekControlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an An ultrasensitive 2,4,6-trinitrophenol nanofluidic sensor inspired by olfactory sensory neurons in sniffer dogs By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05493H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Li, Zhanfang Liu, Linsen Yang, Shengyang Zhou, Yongchao Qian, Yuge Wu, Zidi Yan, Zhehua Zhang, Tingyang Li, Qingchen Wang, Congcong Zhu, Xiang-Yu Kong, Liping WenInspired by sniffer dog olfactory sensory neurons, an ultrasensitive TNP detection sensor was developed by in situ growing UiO-66-NH2 layers on AAO. It exhibits a limit of detection with 6.5 × 10−16 g mL−1, offering a new method for rapid detection.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Large second harmonic generation and birefringence from extended octupolar π-conjugated structures By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05756B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Danyang Dou, Bingbing Zhang, Daqing Yang, Ying WangBy adopting an extended octupolar π-conjugation strategy, two excellent optical functional materials with a strong SHG response and large birefringence were prepared.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05482B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gongming Yang, Shangde Liu, Shujie Ji, Xingsen Wu, Jian WangThe unprecedented non-enzymatically atroposelective synthesis of planar-chiral macrocycles via a Pd/NHC sequential catalytic intermolecular macrocyclization is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05286B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lu-Lu Ma, Pavel N. Zolotarev, Kang Zhou, Xin Zhou, Jiaqi Liu, Jiafeng Miao, Shenfang Li, Guo-Ping Yang, Yao-Yu Wang, Davide M. Proserpio, Jing Li, Hao WangRegulated adsorptive separation of alkane/alkenes has been achieved through engineering the coordinated water arrays in MOF channels.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Zinc borylation and reduction by a diborane(4) species via B–O bond formation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06389A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Liam P. Griffin, Simon AldridgeZinc boryl and metal–metal bonded Zn(I) complexes can be accessed from a common Zn(II) iodide precursor and bis(pinacolaton)diboron(4).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Merging nucleophilic phosphine catalysis and photocatalysis for the rapid assembly of 2-oxabicyclo-[2.1.1]hexane scaffolds from feedstock allyl alcohols By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06684G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier LorthioirA synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC02262A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. ZechelThe noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06190J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi LiuIncorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06581F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lijun You, Daniel Roth, Lutz GrebA structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
