b MOF-derived Co–Mo bimetallic heterostructures for the selective trapping and conversion of polysulfides in lithium–sulfur batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01249F, Research ArticleRongmei Zhu, Yuxuan Jiang, Bingxin Sun, Wang Zhang, Huan PangHollow CoSx/MoO3 derived from ZIF-67 shows preferred selective trapping and conversion of LiPSs as a modified separator material for LSBs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A solvent-free neutral cobalt complex exhibiting macroscopic polarization switching induced by directional charge transfer By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01389A, Research ArticleZi-Qi Zhou, Shu-Qi Wu, Qi-Rui Shui, Wen-Wei Zheng, Akari Maeda, Xiao-Peng Zhang, Jing Chu, Shinji Kanegawa, Sheng-Qun Su, Osamu SatoA solvent-free neutral cobalt complex featuring a non-centrosymmetric polar structure exhibits macroscopic polarization switching induced by charge transfer.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b ZnIn2S4 nanosheets with tunable dual vacancies for efficient sacrificial-agent-free H2O2 photosynthesis By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02030H, Research ArticleChen Zhang, Gao Xu, Qifeng Liang, Li Liang, Zebo Fang, Rong Wu, Shunhang Wei, Lei Wang, Xiaoxiang XuZnIn2S4 nanosheets with tunable concentration of dual vacancies were prepared. Introducing dual vacancies effectively promotes photocarrier separation, facilitates O2 adsorption, and inhibits H2O2 decomposition by increasing hydrophilicity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Multifunctional core–shell CaSnO3@N-doped carbon coaxial nanocables with excellent lithium storage performance and efficient microwave absorption By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02264E, Research ArticleXiaoqiang Li, Guangguang Guan, Siyi Tong, Xin Chen, Kaiyin Zhang, Jun XiangIt is highly desirable but challenging to design multi-functional materials for energy storage and electromagnetic (EM) wave absorption.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Superior energy storage performance with a record high breakdown strength in bulk Ba0.85Ca0.15Zr0.1Ti0.9O3-based lead-free ceramics via multiple synergistic strategies By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02126F, Research ArticleChanghao Wang, Jiaxi Hao, Longxiao Duan, Jianfan Zhang, Wenfeng Yue, Zhenhao Fan, Dandan Han, Raz Muhammad, Fanxu Meng, Dawei WangA composition and structure optimization strategy combined with a two-step sintering (TSS) process is proposed to design and fabricate (1−x)Ba0.85Ca0.15Zr0.1Ti0.9O3−xBi(Mg1/2Sn1/2)O3 (BCZT-BMSx-TSS) lead-free ceramics.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Near-infrared-II photothermal conversion and magnetic dynamic regulation in [Ln3Rad2] aggregation by rigidity modification of nitronyl nitroxide By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01952K, Research ArticleHongdao Li, Chaoyi Jin, Jing Han, Jianke Tang, Xiaofeng Han, Zhenjun SongNitronyl nitroxide in Ln(III) multi-spin clusters has been utilized for realizing the regulation of NIR-II photothermal conversion and magnetic dynamics.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Water-stable zero-dimensional hybrid zinc halide modulated by π–π interactions: efficient blue light emission and third-order nonlinear optical response By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02194K, Research ArticleJia-Wei Li, Wenke Dong, Yanjie Liu, Yuhan Li, Lu-Yuan Qiao, Guang-Lu Liu, Hui Zhang, Chunjie Wang, Hui-Li Zheng, Jian-Qiang ZhaoWaterproof 0D hybrid Zn halide with highly efficient blue emission and third-order nonlinear optical response was constructed by the microregulating of π–π interactions, offering new insights for designing stable multifunctional halide materials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Amorphous MoaZr0.8Ox-500 catalyzed selective oxidation of sulfides to sulfoxides mediated by 1O2 from direct heterolytic cleavage of H2O2 By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02008A, Research ArticleTong Li, Jiaheng Qin, Xueyao Zhang, Xiaoqi Tang, Mingzhe Lv, Weiwen Mao, Linkun Dong, Tongtong Fan, Yu Long, Jiantai MaSulfoxides, a class of pharmaceuticals and fine chemicals of significant importance, are readily peroxidized to sulfones in the H2O2 system.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Significant adsorption enhancements driven by pore microenvironment tuning for efficient C2H2/C2H4 separation in a chemically stable Ni7-cluster-based framework By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01856G, Research ArticleYunli Wang, Rizhao Zhang, Jin-Peng Xue, Yuqiao Chai, Bao Li, Jia LiThis study presents a stable Ni7-cluster MOF with enhanced adsorption through pore microenvironment tuning. Two types of guest-free frameworks achieve C2H2/C2H4 separation, providing deep insights into separation mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Vibrational analysis of auranofin complexes with cysteine and selenocysteine unveils distinct binding motifs and specific unimolecular reactivity By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02023E, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Roberto Paciotti, Davide Corinti, Cecilia Coletti, Nazzareno Re, Giel Berden, Jos Oomens, Simonetta Fornarini, Maria Elisa CrestoniThe [(Et3P)AuCys]+ and [(Et3P)AuSec]+ ions and their deamination products were characterized using IRMPD spectroscopy backed by DFT calculations finding differences in binding motifs and reactivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Achieving high power density and stability in aqueous Mg–air batteries using taurine electrolyte additives By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01842G, Research ArticleSha Jianchun, Wang Qiang, Li Xue, Liu Zhoulin, Bao Jiaxin, Li Lianhui, Tian Jie, Chen Weilong, Liu Wenhong, Zhang ZhiqiangAqueous Mg–air batteries are promising candidates for large-scale energy storage, but their practical application is significantly hindered by water-induced parasitic reactions and the chunk effect.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02072C, Research ArticleXin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li ZhangA new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A narrowband ultraviolet-B-emitting LiCaPO4:Gd3+ phosphor with super-long persistent luminescence for over 100 h By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02407A, Research ArticleXihui Shan, Xulong Lv, Dongxun Chen, Yi Zhang, Lixin Ning, Yanjie LiangIntense NB-UVB emission at 312 nm and super-long persistent luminescence for >100 h have been realized in a LiCaPO4:Gd3+ phosphor after ceasing X-ray excitation, accompanied by a remarkable white-to-brown photochromism phenomenon.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Sulfonylcalix[4]arene-based Al4 clusters: three aluminum oxo clusters with different coordinated solvents for the CO2 cycloaddition reaction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02096K, Research ArticleXiao-Jie Liu, Long-Xue Guo, Wei Xu, Ya-Wen Wang, Yuan-Hang Tian, Li-Xing Zhao, Xiao-Yu Li, Jin-Hua Li, Guo-Ming WangBy using a macrocyclic H4BTC4A-SO2 ligand, we successfully synthesized three Al4 clusters with different solvents, which exhibit different potentials to expose metal active sites for the catalytic reaction. of cycloaddition of carbon dioxide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Chalcogen bond provided supramolecular association of beta-octamolybdate and chalconium cations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02258K, Research ArticleAnna A Mukhacheva, Vadim V. Yanshole, Mikhail V. Il’in, Alexander S. Novikov, Dmitrii Bolotin, Maksim Nailyevich Sokolov, Pavel A AbramovThe interactions of triple σ-(QIV)-hole donating chalconium cations ([Q(bPh)R]+, when Q = S, Se, Te) with nucleophilic beta-octamolybdate ([β-Mo8O26]4–) results in supramolecular association. The main focus of such assembling is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Heterointerface synergy between a 3 × 3 tunnel τ-MnO2 cathode and Mg2(OH)3Cl·4H2O for achieving long cycle-life aqueous zinc-ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02572E, Research ArticleFang Xu, Jialin Zheng, Dai-Huo Liu, Ao Wang, Zhenjiang Li, Chunyan Xu, Mengqin Song, Beinuo Zhang, Zhengyu Bai, Zhongwei ChenThe prepared of τ-MnO2–Mg2(OH)3Cl·4H2O heterostructure cathode material enhances Zn-ion diffusion, increases the proportion of Mn(IV) and suppresses structural instability, thereby improving the cycling stability of τ-MnO2.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Reversible on–off switching of a single-chain magnet via single-crystal-to- single-crystal transition- and light-induced metal-to-metal electron transfer By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01691B, Research ArticleMeng-Jia Shang, Han-Han Lu, Qiang Liu, Ren-He Zhou, Hui-Ying Sun, Zhen Shao, Liang Zhao, Yin-Shan Meng, Tao LiuThe development of single-chain magnets with reversible and adjustable properties is of great significance for achieving high-density information storage and switching devices with multi-stimuli responsiveness whilst remains a challenging task....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b The „chemical tug-of-war” in carborane clusters: distinct tuning on different sides of the cluster By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02566K, Research ArticleDalma Gál, Daniel Buzsaki, Balázs Szathmári, Tamas Holczbauer, Antal Udvardy, Júlia Kertész Szilágyiné, Denis Kargin, Clemens Bruhn, Rudolf Pietschnig, Zsolt KelemenThe special C-C bond in the icosahedral closo-dicarbadodecaboranes and its high plasticity have been highlighted several times, which is reflected in the ease of tuning the C-C bond distance with...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Boosted aluminum storage performance by d–p orbital modulation in zinc selenide with manganese element dopants By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02173H, Research ArticleHan Wang, Rongkai Kang, Boya Zhang, Xingchang Zhang, Guowen Chen, Yiqun Du, Jianxin ZhangBy modulating the band center, Mn-ion doping strategy enhances electronic conductivity and improves interaction with solvent groups, thereby achieving high capacity, enhanced kinetics, and long-term cycling in rechargeable aluminum batteries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02225D, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai YangPhenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01824A, Research ArticleQianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin YangA defect engineering strategy mediated by the structural cationic substitution is proposed and experimentally demonstrated for ultra-broadband emission in a garnet Y3Sc2Al3O12:B3+ phosphor.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Zero-dimensional cuprous halide scintillator with ultra-high anti-water stability for X-ray imaging By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02149E, Research ArticleJing-Ning Lv, Na Lin, Jia-Yi Zhang, Yu-Meng Liu, Li-Chuang Niu, Jie Shi, Xiao-Wu Lei, Zhi-Wei ChenA cuprous hybrid halide with high efficient photoluminescence and anti-water stability was prepared by reasonably selecting a hydrophobic organic cation, which allows this halide as a high-performance scintillator for X-ray imaging.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Strontium doping RuO2 electrocatalyst with abundant oxygen vacancies for boosting OER performance By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02070G, Research ArticleBei An, Xiaoqian Li, Yuan Lin, Fanfan Shang, Huijie He, Hairui Cai, Xiaoxiao Zeng, Weitong Wang, Shengchun Yang, Bin WangOxygen evolution reaction (OER) plays a crucial role as the anode reaction of electrolytic water in various applications. To date, it is still a great challenge to develop highly active...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02314E, Research ArticleXinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan FangEffects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Unprecedented aluminum molecular ring based-layer with tailorable optical limiting effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02507E, Research ArticleLin Geng, Di Wang, Ran-Qi Chen, San-Tai Wang, Chan Zheng, Wei-Hui Fang, Jian ZhangThis study achieved structural modulation from 0D aluminum rings to 2D MOF via a coordination-driven self-assembly strategy. Notably, the exfoliated nanosheets showed enhanced NLO properties, highlighting their potential in optical applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Three-dimensional porous rhodium–copper alloy nanoflowers stereoassembled on Ti3C2Tx MXene as highly-efficient methanol oxidation electrocatalysts By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02182G, Research ArticleHaiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie HuangAn in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti3C2Tx lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A highly active and durable NiMoCuCo catalyst with moderated hydroxide adsorption energy for efficient hydrogen evolution reaction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01947D, Research ArticleHyeonggeun Choi, Seunghwan Jo, Ki Hoon Shin, HeeYoung Lim, Liting Zhang, Keon Beom Lee, Young-Woo Lee, Jung Inn SohnA charge valence state and surface-electronegativity-modulated NiMoCuCo composite is proposed as an active and durable alkaline hydrogen evolution reaction electrocatalyst with moderated hydroxide adsorption energy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Toward highly efficient TADF-active Cu(I), Ag(I) and Au(I) carbene complexes using symmetry-based design strategy By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01996B, Research ArticleAlexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. GritsanTetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Reconstruction and immobilization of polymolybdate induced by metal-organic coordination units for enhanced electrocatalytic hydrogen generation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02311K, Research ArticleJingyi Ma, Zhihan Chang, Xue Xi, Juju Liang, Yuchun Lin, Yaling Zhu, Xiuli WangElectrocatalytic water cracking for hydrogen evolution has drawn the concern from researchers owing to its high efficiency. Polymolybdate has excellent redox behaviors and O-rich surface, becoming attractive electrocatalytic materials. In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Fe3O4-decorated MXene for the effective removal of 133Ba and 137Cs: synthesis, characterization, and optimization via response surface methodology (RSM) By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7860-7871DOI: 10.1039/D4QI00404C, Research ArticleShalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier MonfortThe potential activity of Fe3O4 decorated MXenes in the removal of highly toxic 133Ba and 137Cs using a radioactive indicator method.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b High-efficiency tunable self-trapped exciton emission in one-dimensional β-Cs3Cu2Br5via Ag alloying for optoelectronic applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7793-7802DOI: 10.1039/D4QI00970C, Research ArticleXin Xu, Zhongyi Wang, Qingkun Kong, Siping Liu, Ruiling Zhang, Xiaojing Liu, Keli HanMetastable 1D β-Cs3Cu2Br5 synthesized by rapid cooling could be stabilized by Ag+. Ag-alloyed samples exhibit tunable emission from blue-greenish to yellow, which is attributed to different degrees of lattice distortion regulated by Ag+.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Effects of metal–metal bonding in photosensitizers: red-shifted absorption and oscillator strength enhancement By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7812-7821DOI: 10.1039/D4QI02131B, Research ArticleOshan J. Jinarathne, Malkanthi K. KarunanandaMetal–metal bonds facilitate a red-shift in the maximum absorption wavelength and an enhancement of the oscillator strength in photosensitizers.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Exchange of equatorial ligands in protein-bound paddlewheel Ru25+ complexes: new insights from X-ray crystallography and quantum chemistry By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7803-7811DOI: 10.1039/D4QI01846J, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello MerlinoThe reactivity of [Ru2Cl(D-p-CNPhF)(O2CCH3)3]n (D-p-CNPhF− = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7872-7885DOI: 10.1039/D4QI01874E, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo BusicoThe stability and reactivity of {[iBu2(L)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Scalable complete conversion of MgCo2O4 by mechanochemistry for high-performance supercapacitors By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7886-7897DOI: 10.1039/D4QI02020K, Research ArticleZhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping ZhaoComplete conversion of MgCo2O4 with excellent electrochemical performance has been successfully achieved.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Atomically precise Ag25(SR)18 nanoclusters: a stable photosensitizer for photocatalysis By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7991-8002DOI: 10.1039/D4QI01976H, Research ArticleLinjian Zhan, Junyi Zhang, Boyuan Ning, Yunhui He, Guangcan Xiao, Zhixin Chen, Fang-Xing XiaoAg25(SR)18 nanocluster is utilized to couple with transition metal chalcogenides for constructing TMC/Ag25(SR)18 heterostructures, which demonstrate boosted photoactivities toward selective organic transformation and heavy metal reduction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C2H6/C2H4 separation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7947-7954DOI: 10.1039/D4QI01685H, Research ArticleMeng Feng, Jiantang Li, Xirong Wang, Jingyu Wang, Dongmei Wang, Banglin ChenBenefitting from reticular chemistry, the newly developed MOF material ZJNU-400 establishes a low-polarity environment that enables reversed ethane adsorption and facilitates the efficient separation of C2H6/C2H4.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Design of DyIII single-molecule magnets with molecularly installed luminescent thermometers based on bridging [PtII(CN)2(C^N)]− complexes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7966-7978DOI: 10.1039/D4QI02373K, Research ArticlePawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon ChorazyDysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Copper-doped Bi2MoO6 with concurrent oxygen vacancies for enhanced CO2 photoreduction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,8003-8015DOI: 10.1039/D4QI02005G, Research ArticleJiawei Liu, Xin Liu, Chunhui Dai, Chao Zeng, Sajjad Ali, Mohamed Bououdina, Yushuai JiaBi2MoO6 catalysts doped by monovalence Cu with self-adapting O vacancies (Ov) are prepared. The optimal Bi2MoO6–10% Cu exhibits an outstanding CO evolution rate of 11.40 μmol g−1 h−1, about 6 times higher than that of Bi2MoO6 (1.94 μmol g−1 h−1).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Realizing efficient broadband near-infrared emission under blue light excitation in Sb3+-doped zero-dimensional organic tin(IV)-based metal halides via coordination structure modulation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7979-7990DOI: 10.1039/D4QI01904K, Research ArticleBao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo ZouHere, we report a new NIR emitter of Sb3+-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b In situ growth of δ-MnO2/C fibers as a binder-free and free-standing cathode for advanced aqueous Zn-ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,8016-8024DOI: 10.1039/D4QI01661K, Research ArticleYan Li, Fei Zhang, Miaomiao Wu, Yong Guo, Yuanyuan Liang, Reyihanguli Ababaikeri, Luyang Wang, Qiao Liu, Xingchao Wangδ-MnO2 anchored in N-doped carbon fibers, derived from coal, was prepared using an electrospinning method, demonstrating enhanced performance in AZIBs.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Rationally reconstructing the surface microstructure of a chemical bath deposited electron transport layer for efficient and stable perovskite solar cells By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7910-7920DOI: 10.1039/D4QI01808G, Research ArticleXinxuan Yang, Lexin Wang, Meihan Liu, Jiahui Jin, Lili Yang, Lin Fan, Maobin Wei, Huilian Liu, Haoran Chen, Jinghai Yang, Yulei Chang, Fengyou WangA reconstruction strategy is designed to manipulate the surface microstructure of a CBD SnO2 ETL, yielding PSCs with a high PCE >24%.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Tuning the phototherapeutic activity of Pt(IV) complexes for bladder cancer via modification of trans N-heterocyclic ligands By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7898-7909DOI: 10.1039/D4QI01765J, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Huayun Shi, Guy J. Clarkson, Peter J. SadlerThe photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H2O2 photosynthesis By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,8037-8046DOI: 10.1039/D4QI01580K, Research ArticleLiang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu LinTwo-dimensional chiral bismuth–porphyrin metal–organic frameworks featuring mesoscopic square spiral terrace morphology significantly enhance H2O2 photosynthesis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Governing efficiency and thermoresponsivity of luminescence in dirhenium(V) molecules by a highly tunable emission mechanism By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,8047-8069DOI: 10.1039/D4QI01943A, Research ArticleMichal Liberka, Mikolaj Zychowicz, Laurine Vasseur, James Hooper, Szymon ChorazyModification of an organic linker bonding two cyanido-nitrido Re(V) complexes enables the tuning of the emission mechanism that non-trivially modulates the photoluminescence and its applicability for temperature sensing.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Pyridyl–triazole ligands enable in situ generation of a highly active dihydride iridium(III) complex for formic acid dehydrogenation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7921-7929DOI: 10.1039/D4QI01818D, Research ArticleMiriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra[CpIr(CO)H2] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k2-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h−1.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Towards ultra-sensitive multimodal luminescent thermometers enabled by high crystal field strength of Lu2CaMg2Ge3O12:Yb3+,Nd3+,Er3+ phosphors By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7955-7965DOI: 10.1039/D4QI01767F, Research ArticleZhijiao Zhao, Mengmeng Dai, Kejie Li, Guiying Liang, Yanling Wei, Zuoling FuAn effective full-spectrum thermometer covering from the visible to NIR-II band was designed based on garnet Lu2CaMg2Ge3O12:Yb3+,Er3+/Nd3+ phosphors; meanwhile, Er3+ (4I13/2) split into four Stark sublevels due to high crystal field strength.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7756-7774DOI: 10.1039/D4QI02232G, Review ArticleHangwei Jia, Xueling Hou, Shilie PanThe calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A long-range synergistic effect between Ptn clusters and Zn1 single atoms for efficient selective hydrogenations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7822-7830DOI: 10.1039/D4QI02027H, Research ArticleHaisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing RenBenefiting from the long-range synergistic effect between Ptn clusters and Zn1 single atoms, Ptn@Zn1-N–C displays superior catalytic performance in selective hydrogenations.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Photochromism-induced multi-mode optical modulations and fluorescent temperature sensing in Sr/Er-codoped (K0.5Na0.5)NbO3 ceramics By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,8025-8036DOI: 10.1039/D4QI01804D, Research ArticleFangyuan Yu, Qifa Lin, Xiangfu Zeng, Ping Zhou, Xiao Wu, Cong Lin, Chunlin Zhao, Min Gao, Tengfei Lin, Xingan Jiang, Laihui Luo, Qiwei ZhangSr/Er was codoped in KNN ceramics to induce the coexistence of O and T phases, resulting in improving optical transparency, maintaining moderate ferroelectricity, inducing excellent PC behavior and fluorescence temperature sensing performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article