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Erik ten Hag fired as Manchester United fire manager after troubled start to season

Erik Ten Hag, who was hired in 2022, paid the price for leading United to just three wins in nine league games in the opening months of the campaign. Ruud van Nistelrooy was named interim coach.




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Cristiano Ronaldo misses late penalty as Al-Nassr eliminated from Saudi Cup

Ronaldo, who is yet to win a major trophy since signing for Al-Nassr, had converted all 18 of his previous penalties for the club but this time shot over the bar




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League Cup: Man United routs Leicester days after firing Ten Hag; Tottenham eliminates Manchester City

Liverpool continued its title defense with a 3-2 win over Brighton; Newcastle beat Chelsea 2-0




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Man United makes its worst league start in almost 40 years after 1-1 draw with Chelsea

Moises Caicedo’s stunning long-range volley has secured a 1-1 draw for Chelsea against Manchester United in the Premier League




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Real Madrid, Manchester City humiliated in Champions League; Liverpool enjoys Alonso’s return

Defending champion Madrid was humbled 3-1 at home by AC Milan; City lost 4-1 at Sporting Lisbon




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Gold prices anticipated to surpass $3,000 per ounce: Citi report

The report attributes this projection to the weakening US labour market, disinflation, and the Federal Reserve’s dovish pivot at the upcoming July FOMC meeting



  • Gold & Silver

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Silver poised to outperform gold, expected to hit ₹1.25 lakh/kg in 12-15 months: MOFSL

Silver has shown impressive growth in 2024, recording gains of over 40 per cent year-to-date and surpassing the ₹1,00,000 mark domestically



  • Gold & Silver

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LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02619E, Paper
Chunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao Nie
Lithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02603A, Paper
Takeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa Mehrkhodavandi
Alkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02848A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02871F, Paper
Yuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing Li
The reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02636E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard Gadermaier
Ionic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Multi-functional biotinylated platinum(IV)–SAHA conjugate for tumor-targeted chemotherapy

Dalton Trans., 2024, 53,17829-17840
DOI: 10.1039/D4DT01571A, Paper
Ajay Gupta, Pijus K. Sasmal
Herein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An insightful study on the reduction and extraction of neptunium assisted by molybdenum

Dalton Trans., 2024, 53,17909-17917
DOI: 10.1039/D4DT02547D, Paper
Huaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing Chen
Mo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications

Dalton Trans., 2024, 53,17852-17863
DOI: 10.1039/D4DT02538E, Paper
Kelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. Toledo
A structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks

Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper
Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction

Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication
Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Media invited but not welcomed!



  • Siddhartha P Saikia

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United by food and festival

A Bengali raised in Jharkhand with a yen for celebrating Onam




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




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Dalit family assaulted for entering temple in Arakalgud village




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Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra




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BMTC driver assaulted over alleged road rage




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Man arrested for Bagalur double murder




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D’Cunha report revealed ₹918 crore misappropriated in COVID equipment procurement: Sharan Prakash Patil




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Movement of suspected Maoists in Chikkamagaluru: Jayapura police register case, seize three rifles




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PIX: United log first Europa League win

The win leaves United in 15th place in the Europa League standings on six points from four games.




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EPL PIX: United thrash Leicester

IMAGES from the English Premier League matches played on Sunday.




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Fringe of the fringe : queering punk media history / edited by Kathrin Dreckmann, Elfi Vomberg, Linnea Semmerling.

Berlin : Hatje Cantz, [2023]




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Haight-Ashbury, psychedelics, and the birth of acid rock / Robert J. Campbell ; revised and edited by David P. Szatmary.

Albany, NY : State University of New York Press, [2023]




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Music resistance from 1900 to the present / edited by Igor Contreras Zubillaga, Helena Martín-Nieva.

Turnhout : Brepols, 2022.




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Handbook of art therapy [electronic resource] / edited by Cathy A. Malchiodi.

New York : Guilford Press, 2012.




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Schema-focused working methods for arts and body-based therapies [electronic resource] : a practical guide / edited by Suzanne Haeyen.

New York, NY : Routledge , 2024.




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Sacred cow, mad cow : a history of food fears / Madeleine Ferrières ; translated by Jody Gladding

New York : Columbia University Press, c2006




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Boozers beware: Maharashtra orders sophisticated surveillance of 'watering holes'




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Annual post-monsoon runway maintenance work successfully completed: Mumbai Airport




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Dharavi lights up Diwali with 1 million handcrafted diyas