b

A budget that chose to be on the side of the angels

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 20:33:00 +0530

Why the nixing of angel tax can prove a game changer for job creation in India


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b

It’s a lonely battle for brand aggregators 

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 20:47:00 +0530

Why e-commerce roll-up — banding together smaller online brands for growth — didn’t find strength in numbers 


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b

Drawing water from air on a sustainable, industrial scale

By www.thehindubusinessline.com
Published On :: Sun, 11 Aug 2024 20:18:00 +0530

Uravu Labs devises an affordable means of mimicking nature’s water cycle


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b

When talent becomes unaffordable for startups

By www.thehindubusinessline.com
Published On :: Sun, 11 Aug 2024 20:24:00 +0530

Why good leadership is increasingly beyond the means of startups looking to build great products


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b

Bond investment 101: Create a login ID

By www.thehindubusinessline.com
Published On :: Sun, 11 Aug 2024 20:32:00 +0530

Higher interest. Bond investment platforms buzz with users drawn by the user-friendly interface, zero cost, jargon-free guidance


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b

Scaling up from local to global market

By www.thehindubusinessline.com
Published On :: Sun, 11 Aug 2024 20:37:00 +0530

How Jungle Ventures scouts for local market opportunities with potential for cross-border expansion


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b

Principal focus is on debt access

By www.thehindubusinessline.com
Published On :: Sun, 25 Aug 2024 20:28:00 +0530

Why Stride Ventures focuses on VC-backed loss-making companies


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b

The unfortunate truth about ‘pedigree’ and the founder ecosystem

By www.thehindubusinessline.com
Published On :: Sun, 25 Aug 2024 21:03:00 +0530

How old school ties do matter in the Indian startup system, and why that’s a problem


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b

Flexi funding for unbanked needs

By www.thehindubusinessline.com
Published On :: Sun, 15 Sep 2024 20:54:00 +0530

Anicut Capital zeroes in on investment opportunities that banks overlook due to regulatory constraints


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b

Outer-surface adduct formation and selective separation of cis-type gallated and cis-type non-gallated catechins using cucurbit[7]uril

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05035E, Communication
Open Access
Hiroyuki Tsutsumi, An Miura, Asuka Hanada, Rino Sonoda, Rie Nakashima, Tomonori Ohata, Hirohito Ikeda
The selective separation of cis-type gallated and non-gallated catechins in solution was achieved by utilizing the formation of outer-surface adducts between cis-type catechins and cucurbit[7]uril.
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b

The synthesis of specifically isotope labelled fluorotryptophan and its use in mammalian cell-based protein expression for 19F-NMR applications

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04789C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giorgia Toscano, Martina Rosati, Letizia Barbieri, Katharina Maier, Lucia Banci, Enrico Luchinat, Robert Konrat, Roman J. Lichtenecker
Combining multistep organic synthesis with mammalian cell based protein overexpression leads to isolated 13C–19F spin systems in tryptophan side chains, which represent ideal sensors to probe protein interaction and dynamics using NMR spectroscopy.
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b

CO insertion enabled γ-C(sp3)–H heteroarylative carbonylation of tertiary alcohols via heteroaryl migration

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05361C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xin Qi, Yuanrui Wang, Xiao-Feng Wu
A carbonylative γ-C(sp3)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
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b

Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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b

Direct π-extension of a Conjugated Carbon Nanohoop Using a Zipper Method

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04976D, Communication
kang Wei, Zaitian Cheng, Xingyu Zhang, Qiang Huang, Pingwu Du
The π-extension of carbon nanorings towards ultrashort carbon nanotubes (CNTs) is a great challenge for synthetic chemists. Herein, we report the synthesis, characterization, and properties of a nanographene-embedded carbon nanoring...
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b

Mild boroxazolidone formation and dissociation: Application toward target identification of bioactive molecules

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication
Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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b

Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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b

ARCaDia: Single-round screening of a DNA-type targeted covalent binder possessing a latent warhead

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04594G, Communication
Open Access
Masumi Taki, Masayasu Kuwahara, Chaohui Li, Naoko Tomoda, Naoyuki Miyashita, Tetsuo Kan, Jay Yang
A covalent binder for a target protein was obtained by a direct single-round screening of a latent-warhead-modified DNA library via affinity/reactivity-based co-selection of aptameric deoxyribonucleic acid (ARCaDia), followed by a...
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b

Yolk-shelled MoS2/C@Void@C@MoS2 nanospheres as a stable and high-rate anode in sodium/potassium ion batteries

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05088F, Communication
Mang Niu, Zongfan Zhu, Zhenkai Mou, Wenpei Kang
Yolk-shelled MoS2/C@Void@C@MoS2 exhibits superior high-rate sodium/potassium sodium storage capability, owing to the large inner void and ingenious shell.
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b

Supramolecular self-sorting predicted by a simple harmonic oscillator model

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05336B, Communication
Open Access
Adriana Sacristán-Martín, Nerea Álvarez-Llorente, Eric Masson, Alberto Diez-Varga, Héctor Barbero
The self-sorting process of homobimetallic Pt(II) terpyridyl acetylide dimers secured by a pair of Cucurbit[8]uril macrocycles with recognition motif mismatch can be quantified using a model comprising two coupled harmonic oscillators.
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b

Extended polyene formation by a cryptic iterative polyketide synthase from Rhodococcus

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04963B, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Panward Prasongpholchai, Sam Tucker, Charles Burgess, Robert Jenkins, Ina Wilkening, Christophe Corre, Lijiang Song, Manuela Tosin
Investigations of the workings of a newly identified iterative polyketide synthase from Rhodococcus erythropolis PR4 reveal its ability to synthesise extended polyenes.
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b

Ti3C2Tx MXene bonded perylene diimide as a robust charge host for seawater electrolytes

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05059B, Communication
Sreelakshmi P., Soujanya H. Goudar, Soumyaranjan Behera, Kotagiri Venkata Rao, Ambika S., Narendra Kurra
MXene bonded perylene diimide redox electrode as a robust host for seawater electrolytes.
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b

Composition tunable and stable spontaneous emission and lasing in Cd-alloyed perovskite microdisks

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04488F, Communication
Dmitry A. Tatarinov, Elizaveta V. Sapozhnikova, Daria Khmelevskaia, Yangyang Ju, Dmitriy M. Dolgintsev, Elena V. Bodyago, Alexandr A. Marunchenko, Alexey E. Zhukov, Haizheng Zhong, Ivan G. Scheblykin, Anatoly P. Pushkarev
All-inorganic Cd-alloyed perovskite microdisks were synthesized by pressure-assisted high temperature recrystallization. The microdisks showed composition tunable and temporally stable photoluminescence.
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b

What could be the low-temperature limit of atomic layer deposition of platinum using MeCpPtMe3 and oxygen?

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04679J, Communication
Hao Van Bui, Anh Phan Nguyen, Manh Duc Dang, Truong Duc Dinh, Patricia J. Kooyman, J. Ruud Van Ommen
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO2 nanopowder.
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b

Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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b

Alkenylation of unactivated alkanes: synthesis of Z-alkenes via dual Co-TBADT catalysis

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04651J, Communication
Vetrivelan Murugesan, Anagha Syam, Guru Vigknesh Anantharaj, Ramesh Rasappan
Hydroalkylation of terminal alkynes using unactivated alkanes under dual Co-TBADT catalysts is reported. Our cobalt-HAT catalysis achieves the desired Z alkene with excellent regio- and diastereoselectivity via C–H activation.
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b

Carboxylative cyclization of atmospheric CO2 with alkynol catalyzed by a 1-methylhydantoin anion-functionalized ionic liquid via chelative interactions

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication
Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]− acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P4442][1-MHy]-catalyzed reaction of atmospheric pressure CO2 with MBY under metal- and solvent-free conditions.
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b

Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05125D, Communication
Open Access
Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Javier García-Ben, Angel Ferradanes-Martínez, María Gelpi, Julian Walker, Charles James McMonagle, Socorro Castro-García, María Antonia Señarís-Rodríguez, Juan Manuel Bermúdez-García, Manuel Sánchez-Andújar
The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K.
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b

Helical aromatic foldamers with tubular cavities capable of accommodating multiple halide ions

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05474A, Communication
Seungwon Lee, Byeung Ju Lee, Geunmoo Song, Kyu-Sung Jeong
A series of pyridinium–indolocarbazole oligomers has been synthesized, which fold into helical structures with tubular cavities capable of accommodating up to four iodide ions in a linear arrangement.
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b

Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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b

Directed nucleophilic aromatic substitution reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication
Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
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b

Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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b

Radical anions of 1,1-azoliumdithiocarboxylates

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05486E, Communication
Martin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo Radius
The 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...
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b

Endosomolytic Peptides Enable the Cellular Delivery of Peptide Nucleic Acids

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05214E, Communication
Open Access
JoLynn B. Giancola, Ronald T. Raines
Precision genetic medicine enlists antisense oligonucleotides (ASOs) to bind to nucleic acid targets important for human disease. Peptide nucleic acids (PNAs) have many desirable attributes as ASOs but lack cellular...
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b

Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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b

Boosting the electrochemical performance of Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04275A, Communication
Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O...
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b

Electrocatalytic reduction of N2 to NH3 by MIL-88 derived pod-like Fe7Se8/C nanomaterials under ambient conditions

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04683H, Communication
Gongyao Nie, Huanhuan Zhang, Lanhua Yi, Xiao Ma, Wei Yi, Jiawei Wan, Yebo Lu, Xingzhu Wang
In this paper, pod-like Fe7Se8/C nanocomposite catalyst materials were prepared by MIL-88 selenide annealing and the as-prepared Fe7Se8/C nanocatalyst exhibited excellent electrocatalytic performance in neutral electrolyte for electrocatalytic nitrogen reduction...
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b

Recent Advances in Photochemical Strain-Release Reactions of Bicyclo[1.1.0]butanes

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05108D, Highlight
Xiang Zhou, Ye Hu, Yao Huang, Yang Xiong
Bicyclo[1.1.0]butanes (BCBs) are attractive compounds for their beautiful “butterfly” conformations, distinctive properties, and novel reactivities. As soon as the first example had been synthesized, a wide range of strain-release reactions...
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b

Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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b

Lipidic biomass as a renewable chemical building block for polymeric materials

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Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04993D, Feature Article
Rafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert Bannach
Polymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...
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b

Crystal-Facet Modulated Pathway of CO2 Photoreduction on Bi4NbO8Cl Nanosheets Boosting Production of Value-Added Solar Fuels

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05581K, Communication
Yong Zhou, Haoqiang Chi, Zhengdao Li, Yong Cai Zhang, Zhigang Zou, Yong Yang, Xinxin Lu, Peiting Hao
Two ultrathin nanosheets of Bi4NbO8Cl were successfully synthesized for photocatalytic conversion of CO2 into solar fuel. featuring differently exposed (001) and (201) facets. In contrast to bulk Bi4NbO8Cl, which produced...
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b

Tunable synthesis of magnetoelectric CoFe2O4–BaTiO3 core–shell nanowires

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03701D, Communication
Noah D. Ferson, John R. Ganiban, David P. Arnold, Jennifer S. Andrew
CoFe2O4–BaTiO3 core–shell nanowires with tunable magnetic anisotropy and magnetoelectric coupling are generated using a template-assisted synthetic procedure providing composition control.
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Engineering biotin anchored-MWCNTs as a superb carrier for facile delivery of the potent Ru(II)-N^N scaffold in breast cancer cells

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13376-13379
DOI: 10.1039/D4CC04276J, Communication
Lavanya Thilak Babu, Nilmadhab Roy, Tiasha Dasgupta, Sreejani Ghosh, Ramasamy Tamizhselvi, Priyankar Paira
This article portrays the construction of biotinylated-MWCNTs for SMVT-guided delivery of a potent Ru(II)-scaffold into MCF7 cells.
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b

Polymeric antibubbles with strong ultrasound imaging capabilities

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Published On ::

Chem. Commun., 2024, 60,13340-13343
DOI: 10.1039/D4CC03572K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roman A. Barmin, Jens Köhler, Michael Pohl, Bea Becker, Fabian Kiessling, Twan Lammers, Albert T. Poortinga, Roger M. Pallares
Antibubbles are liquid droplets encapsulated by a gas film and are proposed for ultrasound-triggered drug release. Here, we develop polymeric microbubbles with greater ultrasound imaging response than conventional Pickering-stabilized antibubbles.
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b

Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

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Published On ::

Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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b

Catalytic applications of organic–inorganic hybrid porous materials

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Published On ::

Chem. Commun., 2024, 60,13325-13335
DOI: 10.1039/D4CC04284K, Feature Article
Maodi Wang, Huicong Dai, Qihua Yang
Insights into the synergistic effects of different active sites of organic–inorganic hybrid porous materials for thermal- and photo-catalysis were discussed.
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b

Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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b

Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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b

Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

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Published On ::

Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
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b

A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
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PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density

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Chem. Commun., 2024, 60,13344-13347
DOI: 10.1039/D4CC04430D, Communication
Dajun Hou, Jingjing Zhou, Wen Chen, Jing Zhou, Pengchao Zhang
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy.
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