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Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry




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π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01592D, Research Article
Bin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao He
The development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01734J, Research Article
Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing Li
Transition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens




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Telangana CID arrests two involved in pan-India job fraud racket




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At Via Milano in Hyderabad, the pizza can wait, go for the chops




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Usha Rk on the visual splendour of Adi Shankaracharya’s Ashtakams

Usha Rk, former director of Jawaharlal Nehru Cultural Center (JNCC) of the Embassy of India in Moscow, shares her vision of bringing Adi Shankaracharya’s Ashtakams to life through a dance form




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Woman arrested after kidnap attempt in Koti Government Maternity Hospital

The accused was a habitual offender and had made a vain bid on Tuesday night, before being caught by the hospital staff and police on Wednesday




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Six awarded life imprisonment for trafficking Bangladeshi girls




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Cong. govt cheating paddy farmers on procurement: Kishan Reddy




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Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy

The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said




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Thousands gather for Chhath Puja at Bathukamma ghats

In addition to Hussainsagar, Chhath Puja is being celebrated at 49 other locations across the twin cities of Hyderabad and Secunderabad.




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Moneylenders push family to end life, man his daughter die, wife survives

Head of the family was being harassed and intimidated by two Nizamabad-based moneylenders




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₹4.8 crore loan fraud scheme unearthed at SBI Sanathnagar, eight more arrested




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HYDRAA created fear among encroachers and big builders and not common people: Telangana CM




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75th anniversary of Bharat Scouts and Guides celebrated




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Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district




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Nampally court takes cognisance of ED’s prosecution complaint against AgriGold




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When hope meets hurdles: stark reality of Telangana’s job market

The State’s job crisis has come back to haunt the Congress party, which rode to power last year on promises of employment. While local youth wait, worry, and exchange dreams about securing government jobs, short-term opportunities are drawing people from other States. This dynamic has transformed Telangana into a job magnet for outsiders but a desert for its own aspirants, reports Serish Nanisetti




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Cyberabad | Four arrested for vandalising Gandhi statue




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Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad

Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika




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Telangana set to unveil new industrial sectoral policies 

Electric Mobility and Storage, Electronics, Life Sciences, Defence and Aerospace sectors to get new growth guiding documents as some existing policies have become outdated and those in other States are superior, senior official 




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Congress shedding ‘çrocodile tears’ over BCs welfare: BJP leader Laxman




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Raid on hospitals in Hyderabad and Secunderabad leads to seizure of controlled drugs

The raiding teams found substances which are are classified as controlled drugs and their sale and possession are strictly regulated under the Narcotic Drugs and Psychotropic Substances (NDPS) Act




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Ugandan woman sentenced to 13 years RI for smuggling drugs to Hyderabad

The woman was caught attempting to smuggle 3,900 grams of heroin, worth ₹25 crore, to Hyderabad




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Hyderabad man loses ₹1.73 lakh trying to get 0% interest loan on insurance policy worth ₹10 lakh




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No more parties without permission: Telangana Excise Dept. to farmhouse owners




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Telangana Deputy CM seeks proposals for retaining wall to prevent monsoon flooding in Madhira




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Eleven transgenders arrested for public nuisance in Cyberabad




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Man arrested for sexually assaulting mother-in-law in Balapur




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Home guard injured after engineering student attempts to flee vehicle checking in Panjagutta




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Cockroach infestation found at CCMB canteen; hygiene violations flagged at Nacharam restaurants




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Kishan Reddy slams Revanth government for failing farmers, challenges Rahul Gandhi to tour villages in Telangana




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32 STPs taken up by BRS govt. to cleanse Musi: MLAs

₹3.8k crore STP project was to protect Nalgonda ryots’ farm fields from sewage water




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Ponnam criticises BJP leader Laxman’s comments on caste census




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Telangana govt. urged to release caste survey forms in English and Urdu




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Man, accused of murdering ‘friend’ in Sept., arrested




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Mental health and resilience in higher education institutions as a mission 

A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing




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Man arrested for kidnapping, marrying, sexually assaulting minor




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Trust deficit exists between citizens and healthcare system: former IAS officer




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Man, friend killed in car-bus collision after attending sister’s wedding reception




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Telangana delegation to embark on 3-day study tour in Karnataka for fisheries development




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Guru Nanak’s 555th birth anniversary celebrations to begin in Hyderabad on November 11




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Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months

45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data




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Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe

Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice




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Explosion at restaurant injures four in Hyderabad’s Jubilee Hills




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CM Revanth Reddy announces resolve to complete pending projects of Palamuru district

Criticises opposition parties for trying to create obstacles in district development  




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Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana




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Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief

He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore