b

Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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b

Crystal growth and cation order of Ni3-xCoxB2O6 oxyborates

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00091A, Paper
Svetlana Sofronova, Evgeniya Moshkina, Artem Chernyshev, Alexander D. Vasil’ev, Nikolai Maximov, A.S. Aleksandrovsky, Tatyana Andryushchenko, Alexander Shabanov
A series of single crystals of Ni3-xCoxB2O6 compounds with the kotoite structure and with different concentrations of transition metal ions (x = 0; 0,19; 0,6; 0,93; 2) were obtained. The...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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b

Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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b

High-performance (Al0.4Ga0.6)2O3/Al0.32Ga0.68N-based UVC/UVB tunable dual-band photodetector

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D3CE01297B, Paper
Siyu Wu, Zhengyuan Wu, Peng Fei Tian, Jason Hoo, Shiping Guo, Zhilai Fang
The detection of ultraviolet B (UVB) and UVC radiation is of paramount importance, and has been expanding applications in industrial, scientific, environmental and biomedical fields. In this work, high-Al-content β-(Al0.4Ga0.6)2O3/Al0.32Ga0.68N...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

High-quality β-(AlxGa1-x)2O3 thin films on sapphire substrate by face-to-face annealing

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00263F, Paper
Songhao Wu, Chicheng Ma, Han Yang, Zichun Liu, Yuanxiao Ma, Ran Yao, Yiyun Zhang, Hua Yang, Xiaoyan Yi, Junxi Wang, Yeliang Wang
High-quality β-(AlxGa1-x)2O3 thin film is fabricated through a face-to-face annealing on sapphire substrate covered by epitaxial Ga2O3. Al atoms during the high-temperature annealing are uniformly diffused from the sapphire substrate...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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b

Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility

CrystEngComm, 2024, 26,2112-2122
DOI: 10.1039/D4CE00039K, Paper
Yao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua Du
In this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Fabrication of BiVO4 submicron rods photoanodes through phase transition assisted by Mo doping

CrystEngComm, 2024, 26,2078-2086
DOI: 10.1039/D4CE00074A, Paper
Shuang Zhao, Haipeng Zhang, Zhaoqi Wang, Deifei Xiao, Xianbin Xu, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Ying Dai, Hefeng Cheng, Zeyan Wang, Baibiao Huang
Herein, Mo doping has been found to effectively lower the phase transition temperature from tetragonal zircon BiVO4 to monoclinic scheelite BiVO4. Our research introduces a novel method for the production of submicron rods BiVO4 photoanodes.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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b

A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
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b

Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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b

Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Evolution of fractal patterns in lead-free, zero-dimensional perovskite Cs2InBr5(H2O)

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00204K, Paper
Wanyin Ge, Yang Maohao, Masaki Saruyama, Kenshi Matsumoto, Ryota Sato, Haruka Takekuma , Ryo Takahata, Toshiharu Teranishi
The crystallization behavior of halide perovskites is of great significance. Fractal structures, featured by self-similarity between local morphology and global structures, have consistently captivated scientists’ interest across diverse disciplines. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Red-emitting Cs2NaScCl6:Sm flexible films for high-resolution X-ray imaging

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00018H, Paper
Yuxia Li, Qi Luo, Xin Huang, Hao Lu, Yazhou Yuan, Xieming Xu, Shuaihua Wang, Shaofan Wu
A study of the radiation detection properties of Cs2NaScCl6:Sm and imaging of flexible scintillation films.
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b

Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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b

Coordinatively unsaturated 5-nitroisophthalate based cobalt(II) coordination polymers: efficient catalytic CO2 fixation and Hantzsch condensation

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00102H, Paper
Subham Sahoo, Rajesh Patra, Debajit Sarma
Labile-coordinated water-based CPs have been synthesized. SSICG-6 serves as an excellent heterogeneous catalyst in CO2 cycloaddition and one-pot Hantzsch condensation reactions compared to other 1D-reported CPs due to the presence of OMSs.
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b

S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Highly efficient and durable P, Ru–CeO2 self-supporting electrodes toward industrial-level hydrogen production

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00143E, Paper
Wenguang Ma, Xiaodong Yang, Yanru Xu, Cuncheng Li, Yiqiang Sun, Qi Shen, Zhixin Sun
The electrolysis of seawater has become a preferred method for hydrogen production since the current shortage of freshwater resources, offering an effective strategy to address the energy crisis.
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b

Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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b

A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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b

Flux growth and characterization of gallium-rare earth borates

CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
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b

Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives

CrystEngComm, 2024, 26,2155-2165
DOI: 10.1039/D3CE01208E, Paper
Wenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu
A series of charge transfer cocrystals with fluorescence properties involving 1,2,4,5-tetracyanobenzene as acceptor, fluorene, 2-bromofluorene, carbazole and 2-bromocarbazole as donor were synthesized via cocrystal design strategies.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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b

Distribution of basal plane dislocations in 4-degree off-axis 4H-SiC single crystals

CrystEngComm, 2024, 26,2143-2154
DOI: 10.1039/D4CE00055B, Paper
Sheng'ou Lu, Binjie Xu, Yazhe Wang, Hongyu Chen, Wei Hang, Rong Wang, Julong Yuan, Xiaodong Pi, Deren Yang, Xuefeng Han
The basal plane slip model in 4H-SiC was developed to investigate the effects of off-axis angles on total resolved shear stress. The results showed that the TRSS changed from 6-fold to 4-fold symmetry with the increasing off-axis angles.
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b

Effects of B2S3 additive on diamond crystallization at HPHT conditions

CrystEngComm, 2024, 26,2190-2196
DOI: 10.1039/D4CE00147H, Paper
Yong Li, Shuai Wang, Hongyu Xiao, Qiang Wang, Zhengguo Xiao, Yanchao She, Ying Wang
The color of the diamond obtained with the B2S3 additive changes from yellow to light blue and the resistivity of the synthesized diamond drops from 3.89 × 10 Ω cm to 2.51 × 10−1 Ω cm with the introduction of Ti/Cu into the synthetic cavity.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Bilirubin and its crystal forms

CrystEngComm, 2024, 26,2136-2142
DOI: 10.1039/D4CE00123K, Paper
Open Access
Matthew L. Bracken, Manuel A. Fernandes, Sadhna Mathura
Bilirubin crystals in the gall bladder and urine are typical indicators of liver dysfunction. Examining the crystal structure of lipophilic bilirubin is thus of interest. We present crystal structures for three crystal forms of the bile pigment.
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b

Study on Raman scattering spectroscopy of Mn-doped GaN grown by the ammonothermal method

CrystEngComm, 2024, 26,2166-2171
DOI: 10.1039/D4CE00093E, Paper
Wenhao Lu, Tengkun Li, Guoqiang Ren, Zhenghui Xia, Kaihe Xie, Shaozhe Li, Liangkun Shen, Ke Xu
Mn-doped GaN crystals of a-plane and (11−22) plane were grown by the ammonothermal method.
The content of this RSS Feed (c) The Royal Society of Chemistry




b

Shortening CN⋯Br–Csp3 halogen bonds via π-stacking

CrystEngComm, 2024, 26,2131-2135
DOI: 10.1039/D4CE00307A, Communication
Open Access
Kamil Kupietz, Rosa M. Gomila, Thierry Roisnel, Antonio Frontera, Rafael Gramage-Doria
An extremely short N⋯Br distance between a nitrile group and a Csp3-linked bromine atom was encountered in the solid-state and rationalized by DFT calculations, which emphasized the role of π-stacking for bringing both partners at close proximity.
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b

Acoustic shock wave-induced phase transition in indium selenide: tuning band gap energy for solar cell applications

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00012A, Paper
S. Oviya, F. Irine Maria Bincy, S. Arumugam, K. Kamala Bharathi, Raju Suresh Kumar, P. Kannappan, Ikhyun Kim, S. A. Martin Britto Dhas
Acoustic shock wave loading experiment on indium selenide.
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b

A highly stable hydrogen-bonded organic framework for hydrogen storage

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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b

WhatsApp launches screen-sharing, tabs for navigation bar on Android

Meanwhile, WhatsApp is working on a username feature




b

WhatsApp releases status archive feature for businesses on Android

WhatsApp will roll out the functionality to more users in the coming weeks




b

WhatsApp to roll out redesigned keyboard

WhatsApp redesigned keyboard will include the emoji category bar




b

Meta Verified is now available in India at ₹699

Meta Verified is available for direct purchase on Instagram or Facebook.




b

Twitter Blue gives 60-minutes to edit tweets

Twitter has increased the window to edit tweets from 30 minutes to one hour for Blue subscribers.




b

Twitter is refusing to pay its Google Cloud bills: Report

Twitter hosts some services on its server and houses others on the cloud platforms of Amazon and Google.




b

Reddit protest: Why are thousands of subreddits going dark?

Starting next month, third-party app developers using Reddit's vast troves of data will have to pay a price and the changes could affect players across the spectrum




b

Twitter sued by music publishers for allowing copyrighted songs

Members of the National Music Publishers’ Association (NMPA) are seeking over $250 million in damages for alleged infringement of nearly 1,700 copyrights.




b

Instagram rolls out broadcast channel globally

Instagram started testing broadcast channels in February.




b

WhatsApp, Google fixes dashboard bug in Android

Android Developers put out a tweet confirming the issue and its fix




b

After Youtuber's arrest, Kerala govt warns stern legal action against misleading social media content

Kerala Police arrested controversial Youtuber 'Thoppi' who had been accused of making allegedly objectionable remarks and creating a traffic block in Malappuram district