re

Research progress on photocatalytic, electrocatalytic and photoelectrocatalytic selective oxidation of 5-hydroxymethylfurfural

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10739-10773
DOI: 10.1039/D4GC03597F, Critical Review
Yang An, Tao Lei, Weiyi Jiang, Huan Pang
This paper summarizes the latest research progress in selective photocatalytic, electrocatalytic, and photoelectrocatalytic oxidation of HMF, along with the reaction mechanisms, advantages, and challenges faced during selective HMF oxidation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Synthesis of axially chiral thiourea by NHC-catalyzed desymmetrizative amidation

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10940-10949
DOI: 10.1039/D4GC03113J, Paper
Yingtao Wu, Xin Guan, Kehan Jiao, Huaqiu Zhao, Mingrui Li, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC-catalyzed desymmetrization amidation of biaryl dialdehydes has been developed for NH-free axially chiral thiourea. Sequential kinetic resolution enhances the chirality induction of the desymmetrization strategy, expanding the applicable scope.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Lipase-entrapped colloidosomes with light-responsive wettability for efficient and recyclable Pickering interfacial biocatalysis

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10824-10828
DOI: 10.1039/D4GC03982C, Communication
Dingyi Yang, Qi Zeng, Kaiwen Tan, Haoyue Hou, Xingyuan Fang, Chenlong Guo, Hao Yuan, Tao Meng
We prepared lipase-entrapped TiO2 colloidosomes with excellent recyclability for light-responsive Pickering interfacial biocatalysis, providing a green, recyclable and efficient Pickering interfacial biocatalysis platform.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Metal-free photoinduced-radical hydrocyclization of 2-isocyanides: a unified synthetic approach to facilely assemble diverse N-heteroarenes

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10804-10810
DOI: 10.1039/D4GC03774J, Communication
Ziyi Wang, Haonan Wei, Jinrong Du, Zhijun Zuo
We present an efficient and sustainable protocol for the photoinduced-radical hydrocyclization of isocyanides, providing a united route to assemble diverse α-unsubstituted N-heteroarenes.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Electroreductive deoxygenative carboxylation of alkyl oxalates with CO2

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10811-10817
DOI: 10.1039/D4GC03452J, Communication
Yong Yuan, Hangfei Jiang, Ya-Nan Zhang, Yuyan Tao, Xincong Liu, Congde Huo
An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Electrochemistry-enabled Rh-catalyzed regioselective [4 + 1] and [4 + 2] cycloaddition of benzoic acid with alkynyl esters/amides

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10996-11002
DOI: 10.1039/D4GC03753G, Paper
Wei-Jung Chiu, Chung-Ming Sun
The reaction of benzoic acids with alkynyl esters/amides in the presence of a Rh-catalyst and AcOH as an additive to give phthalides by [4 + 1] annulation. In contrast, the additive NaOAc exclusively affords isocoumarins through the [4 + 2] pathway.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Electroreductive deuteration of N-propynylamides to enamides

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10975-10981
DOI: 10.1039/D4GC03790A, Paper
Qiansong Gao, Mingchun Wang, Lianyou Zheng, Lingling Shi, Cheng Wu, He Li, Jinbao Xiang
A migratory reductive deuteration of terminal alkynes to access enamides with more than 3 deuteriums incorporated per molecule was realized.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Postliminary treatment of food-waste digestate via combined hydrothermal carbonization and microbial fuel cell for bio-energy recovery: a comparative life cycle impact assessment

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04081C, Paper
Shraddha Yadav, Manikanta M. Doki, Makarand M. Ghangrekar, Brajesh K. Dubey
Multiple resource recovery from food-waste digestate by deploying hydrothermal carbonisation and microbial fuel cells. A green route for environmental sustainability and economic gains.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04502E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiajun Zhang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng Wu
This paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

A solvent-free, self-emulsified and heat-responsive polyester coating enables chemically-recyclable and fire-safe PET foam

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04531A, Paper
Bei-Bei Zhang, Li-Xia Fan, Lin Chen, Xiu-Li Wang, Yu-Zhong Wang
This work implements a state-of-the-art strategy to simultaneously achieve use performance and future recycling, which will greatly benefit the green sustainable circular economy for wind turbine blades.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Does enzymatic catalysis lead to more sustainable chemicals production? A life cycle sustainability assessment of isopropyl palmitate

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04514A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pieter Nachtergaele, Ozan Kocak, Yblin Roman Escobar, Jordy Motte, Dries Gabriels, Leopold Mottet, Jo Dewulf
A methodology is presented for assessing the life cycle sustainability of enzymatic catalysis for chemicals production. For IPP, lower environmental impacts, but higher costs and social risks were found for switching to enzymatic catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Valorization of pomegranate waste through green solvent extraction and biochar production: a zero-waste biorefinery approach

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03707C, Paper
Leonardo M. de Souza Mesquita, Letícia S. Contieri, Bárbara M. C. Vaz, Vitor Sencadas, Filipe H. B. Sosa, João A. P. Coutinho, Maurício A. Rostagno, Sónia P. M. Ventura
This study presents a zero-waste biorefinery for pomegranate waste, extracting anthocyanins and ellagic acid with green solvents and converting leftovers to biochar.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

The Effects of Polyolefin Structure and Source on Pyrolysis-Derived Plastic Oil Composition

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04029E, Paper
Jiayang Wu, Zhen Jiang, Victor S Cecon, Greg W. Curtzwiler, George W. Huber, Keith L. Vorst, Manos Mavrikakis
Seven types of plastics were pyrolyzed in a fluidized bed reactor: post-consumer recycled (PCR) high-density polyethylene (HDPE), PCR polypropylene (PP), virgin resins of varying molecular weights of HDPE, virgin resins...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Catalytic hydrodeoxygenation and C–C coupling of lignin and its derivatives into renewable jet-fuel-range cycloalkanes

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC02051K, Critical Review
Xinyong Diao, Ying Xiong, Yawen Shi, Longlong Ma, Chenglong Dong, Shengbo Zhang, Na Ji
This review provides an in-depth understanding of the synthesis pathways and corresponding catalytic systems for the production of jet-fuel-range cycloalkanes from lignin and its derivatives via catalytic hydrodeoxygenation and C–C coupling.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Advances in catalytic chemical recycling of synthetic textiles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04768K, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carmen Moreno-Marrodan, Francesco Brandi, Pierluigi Barbaro, FRANCESCA LIGUORI
Synthetic fibres cover most of textile market, but their value chain is almost entirely linear. Common raw materials are non-renewable and oil-derived, while requiring large amounts of (toxic) chemicals and...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Engineering high-valence nickel sites in Ni3S2/Ni3Se2 architectures enabling urea-assisted hydrogen evolution reactions

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04318A, Paper
Taotao Ai, Miaomiao Bai, Weiwei Bao, Jie Han, Xueling Wei, Xiangyu Zou, Jungang Hou, Lizhai Zhang, Zhifeng Deng, Yuxin Zhang
Bifunctional Ni3S2@Ni3Se2 electrocatalysts were constructed for urea-assisted hydrogen evolution. In the HER/UOR two-electrode system, the heterogeneous interface modulates the electronic structure and thus improves the catalytic performance.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

In silico modeling enables greener analytical and preparative chromatographic methods

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04300F, Paper
Troy T. Handlovic, Daipayan Roy, Muhammad Qamar Farooq, Gabriel Mazzi Leme, Kevin Crossley, Imad A. Haidar Ahmad
Environmental impact of chromatographic separation at both analytical and preparative scale can be significantly reduced using In Silico Modeling.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

CO2 catalyzed recycling of polyester and polycarbonate plastics

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04782F, Paper
Open Access
Qiao Zhang, Nan Wang, Chenyang Hu, Peng-Yuan Li, Fu-Quan Bai, Xuan Pang, Xuesi Chen, Xianhong Wang
CO2 was found to be an efficient catalyst for depolymerizing common waste polyesters and polycarbonates via alcoholysis, yielding valuable organic molecules. CO2 was considered a Lewis acid–base pair, activating both polymers and alcohol.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Photo-Induced FeCl3-catalysed direct denitrative chlorination of (hetero)nitroarenes at room temperature

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04210G, Communication
Mingjing Deng, Ke Liu, Zhaolun Ma, Guanzhong Luo, Longyang Dian
We present herein an iron-catalyzed denitrative chlorination of (hetero)nitroarenes at room temperature under visible light irradiation. In this study, FeCl3 catalyzed direct chlorination was achieved through denitrative chlorination under light...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Biological production and simulated moving bed purification of streptothricin F from food waste digestate

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04026K, Paper
Xiaofang Zhou, Peiyi Li, Yuchen Sun, Zeyang Zhang, Chuanyi Yao, Qingbiao Li, Yuanpeng Wang
Globally, a significant amount of food waste is generated annually, representing a considerable potential resource.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Green dipolar aprotic solvents for the dynamic polycondensation of high-performance polyimide membranes

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04279D, Paper
Open Access
E. San José, M. R. de la Viuda, F. J. Carmona, C. Soto, L. Palacio, P. Prádanos, A. Hernández, A. Tena
Guidelines for the evaluation of green solvents were revisited and integrated into a decision diagram. GVL, Cyrene™, DMC, NOP, DEC, DMI, GBL, NBP, Rhodiasolv® PolarClean, and DMSO showed the potential to substitute hazardous polar aprotic solvents.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05156D, Paper
Hongjiao Chen, Kewei Zhang, Yanzhi Xia, Jian Li, Bin Hui
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Crystalline/amorphous c-NiMo/a-NiMoOx nanoarrays for urea-assisted energy-saving H2 production in alkaline seawater

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05042H, Paper
Dongxue Guo, Yi Ping, Chuanjiao Wang, Changan Hou, Danhong Wang
Electrocatalytic seawater splitting is regarded as the most effective method for producing green hydrogen (H2), but it faces issues of high energy consumption and harmful chlorine evolution side reactions. Replacing...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

N–N atropisomer synthesis via electrolyte- and base-free electrochemical cobalt-catalysed C–H annulation

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04390A, Communication
Jiating Cai, Linzai Li, Chuitian Wang, Shi Qin, Yuanyuan Li, Si-Yan Liao, Shengdong Wang, Hui Gao, Zhi Zhou, Yugang Huang, Wei Yi, Zhongyi Zeng
An exogenous electrolyte- and base-free electrochemical cobalt-catalysed atroposelective C–H annulation has been established to construct N–N axially chiral isoquinolinones in excellent enantioselectivities and good yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Photo-driven reduction/cyclization of nitroarenes via electron donor–acceptor complexes: a novel method for the acquisition of N-heterocycles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04082A, Communication
Bin Sun, Chun Lv, Xiaohui Zhuang, Yan Xu, Haijing Song, Jiayin Wang, Zhaokang Zhang, Jiayang Wang, Can Jin
An EDA complex-based method for the reduction/cyclization of nitroarenes to obtain N-heterocycles with H2O as a clean by-product is presented.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

High Efficiency Leaching of Valuable Metals from Waste Lithium-ion ternary Batteries under Mild Conditions Using Green Deep Eutectic Solvents

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04373A, Paper
Bo Li, Zhengfu Zhang, Chengping Li, Jinsong Wang, Rundong Wan, Jiangzhao Chen, Ying Liu, Yuejing Bin, xiaoping yang, Chongjun Bao, Shaohua Ju
Recently, the production and demand for lithium-ion batteries (LIBs) has increased owing to increasing number of electric vehicles and products. This surge has considerably increased spent LIBs, leading to environmental...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

The Chemistry of Oleates and Related Compounds in 2020s

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04862H, Tutorial Review
Pavel V. Ivchenko, Ilya E. Nifant'ev
The use of renewable resources as an alternative to fossil raw materials is one of the topical directions of modern science. Consistent efforts are being taken to find the most...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Catalyst free PET and PEF polyesters using a new traceless oxalate chain extender

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11182-11195
DOI: 10.1039/D4GC02791D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin van der Maas, Daniel H. Weinland, Robert-Jan van Putten, Bing Wang, Gert-Jan M. Gruter
When producing PET the metal catalyst (typically Sb) remains in the polymer. This raises concerns as our food and the air we breathe is contaminated with PET microplastics. Here we report the production of metal-free PET using a small amount of DGO.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Toward safer and more sustainable by design biocatalytic amide-bond coupling

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11147-11163
DOI: 10.1039/D4GC03665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Elisabeth Söderberg, Kerstin von Borries, Ulf Norinder, Mark Petchey, Ganapathy Ranjani, Swapnil Chavan, Hanna Holmquist, Magnus Johansson, Ian Cotgreave, Martin A. Hayes, Peter Fantke, Per-Olof Syrén
We describe an exploratory approach to a concept of safer and more sustainable by design in biocatalytic amide bond synthesis.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11061-11082
DOI: 10.1039/D4GC03829K, Tutorial Review
Zulfiqar Ali, Jiliang Ma, Runcang Sun
Biomass-derived organic acid for green and sustainable future.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

A spatially integrated electrochemical–thermal tandem reaction for continuous mild synthesis of propylene oxide

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11206-11215
DOI: 10.1039/D4GC03455D, Paper
Yuefeng Qiu, Peng Jiang, Wenkai Ye, Jiahao Hu, Bin Zhang, Tuo Ji, Liwen Mu, Xin Feng, Xiaohua Lu, Jiahua Zhu
A spatially integrated electrochemical–thermal tandem reaction generates propylene oxide at 1 atm using hydrogen, oxygen, and propylene as feedstock.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Regulatable selective synthesis of benzofurans and coumarins from aryl propargyl ethers via an electrochemical tandem cyclization reaction

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11216-11221
DOI: 10.1039/D4GC03842H, Paper
Zhaoyue Feng, Xueyi Guan, Haiyang Ma, Yingsibing Fan, Ping Liu, Peipei Sun
A divergent protocol for the selective synthesis of benzofuran-2-carboxaldehydes and 3-organoselenyl-2H-coumarins from propargylic aryl ethers in the presence of dialkyl(aryl) diselenides under electrochemical reaction conditions was established.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Photocatalytic acylation of lysine screened using a microfluidic-based chemical robotic system

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11238-11248
DOI: 10.1039/D4GC03562C, Paper
Zhanfeng Hou, Chuan Wan, Heming Jiang, Yuena Wang, Yun Xing, Jinpeng Wang, Zhihong Liu, Xiaochun Guo, Yuhao An, Wei Han, Rui Wang, Xinhao Zhang, Feng Yin, Zigang Li
In our work, we contribute to the photoredox catalytic lysine acylation in proteins and peptides. The optimal reaction conditions were obtained using a high-throughput microfluidic-based chemical robotic system and GPR model.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Catalytic synthesis of renewable lubricant base oils with methyl oleate and aromatics

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11249-11258
DOI: 10.1039/D4GC03448A, Paper
Binbin Zhou, Nan Wang, Sibao Liu, Guozhu Liu
Aromatic-ester and cyclo-branched alkane renewable lubricant base oils were produced from methyl oleate and biomass-derived aromatics by alkylation and alkylation followed by hydrodeoxygenation (HDO).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Shell biorefineries: mixed biofuel production from chitin

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11280-11289
DOI: 10.1039/D4GC03761H, Paper
Hao Huang, Guangping Zhou, Xiaolan Cai, Min Zhuang, Shaoqu Xie
Bioenergy is a key strategy for sustainability, yet the potential for biofuel production from chitin is under-exploited.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Visible light-induced strain-release transformations of bicyclo[1.1.0]butanes

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11083-11105
DOI: 10.1039/D4GC03193H, Tutorial Review
Qing-Bao Zhang, Feng Li, Bin Pan, Shanshan Zhang, Xiang-Guo Yue, Qiang Liu
This review aims to provide an overview on the recent visible light-mediated strain-release transformations of bicyclo[1.1.0]butanes. Prospects for future development of (aza)bicyclo[1.1.0]butanes in this fascinating field are outlined.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Selective electrosynthesis of aldehydes at industrially relevant current densities via tandem electrochemical–chemical catalysis

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11290-11302
DOI: 10.1039/D4GC04536J, Paper
Ting Lin, Menglu Cai, Huijie Chen, Yiming Mo
A closed-loop tandem electrochemical–chemical catalysis system for aldehyde synthesis was developed, demonstrating a viable approach for the electrosynthesis of valuable intermediates under practical current densities with minimal waste electrolyte.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Catalytic C–N bond formation strategies for green amination of biomass-derived molecules

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11019-11060
DOI: 10.1039/D4GC03182B, Critical Review
Yan Zhong, Feng Liu, Jingsha Li, Chunxian Guo
Recent advances in the amination of biomass-derived molecules to generate valuable nitrogenous chemicals by employing thermocatalysis, electrocatalysis and photocatalysis strategies are reviewed.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Production of nanochitins via a shell biorefinery process for self-assembly applications as photonic films and Pickering emulsions

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11222-11237
DOI: 10.1039/D4GC02680B, Paper
Open Access
Xuhai Zhu, Fuyan Peng, Hui Li, Rongjun Lin, Rui Lu, Fang Lu
A simple, environmentally friendly, and flexible shell biorefinery process for integrated utilization of all NCh products in high-value applications, such as photonic films and Pickering emulsions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Substrate-controlled regioselective hydrophosphorylation of allenes to enable photocatalytic synthesis of alkenylphosphoryl compounds

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11272-11279
DOI: 10.1039/D4GC03588G, Paper
Tian-Ming Yang, Xin-Lu Fan, Wei Shi, Xuefei Zhao, Xu-Hong Hu
A visible-light-induced hydrophosphorylation of allenes with H-phosphine oxides is demonstrated to give a diverse range of alkenylphosphoryl compounds in a highly stereoselective and regioselective manner.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Iron/photoredox dual-catalyzed redox-neutral double decarboxylative C(sp3)–C(sp3) cross-coupling

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11334-11339
DOI: 10.1039/D4GC04523H, Paper
Qi Zhang, Shanghui Wu, Xuesong Wu
An efficient iron porphyrin/photoredox dual catalytic system for the double decarboxylative radical C(sp3)–C(sp3) cross-coupling under redox-neutral and mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11351-11363
DOI: 10.1039/D4GC04447A, Paper
Open Access
Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen Li
A paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11125-11131
DOI: 10.1039/D4GC05070C, Communication
Open Access
Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin, Stephen J. Connon
The evaluation of a library of phase transfer catalysts in the alkaline hydrolysis of polyethylene terephthalate revealed the key interplay between catalyst structure/properties and the reaction conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Biomass-derived polyol esters as sustainable phase change materials for renewable energy storage

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11259-11271
DOI: 10.1039/D4GC03460K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Magdalena Gwóźdź, Marta Markiewicz, Stefan Stolte, Anna Chrobok, David R. Turner, Karolina Matuszek, Alina Brzęczek-Szafran
Innovative thermal battery technology has the capability to revolutionize the renewable energy storage market.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11106-11124
DOI: 10.1039/D4GC04094E, Tutorial Review
Qiang Yuan, Xiao Cai, Weiping Ding, Yan Zhu
The homogeneous and heterogeneous catalyst systems applied in N-formylation reaction of amines and CO2 reaction from both homogeneous and heterogeneous systems are summarized.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

re

Correction: Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11364-11364
DOI: 10.1039/D4GC90117G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu Hwang
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article