y

Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Tuneable Sulfonated Hypercrosslinked Polymers for Selective Esterification: Insights into Performance and Stability

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05208K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paul Schweng, Dorian Guerin-Faucheur, Freddy Kleitz, Robert Thomas Woodward
We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Axial oxygen-bridged FeN4O/NC produced by ultrafast joule heating for efficient oxygen reduction reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05604C, Communication
Feng Liu, Xinyu Guo, Yan Zhong, Shaqi Fu, Jingsha Li, Chunmei Zhang, Heng Zhang, Fenghui Ye, Shuai Yuan, Chuangang Hu, Chunxian Guo
Herein, we report an atomically dispersed Fe-N-C catalyst with axial oxygen ligands (FeN4O/NC) firstly synthesized by ultrafast joule heating. The formation of oxygen species between FeN4 and graphene, which offers...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Synthesis of Aryl Fluorocyclopropanes from Aryl Fluorodiazirines and Alkenes in Continuous Flow

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC01881H, Communication
Hoang-Minh To, Shima Mirakhorli, Thierry Ollevier
Photochemically induced generation of aryl fluorocarbene from arylfluorodiazirines and their subsequent [2 + 1] cycloaddition with alkenes was developed in continuous flow. The in situ generated electrophilic aryl fluorocarbene reacted...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Copper nanoclusters: emerging photoredox catalysts for organic bond formations

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




y

A liquid-infiltrated Al2O3 framework electrolyte enables aqueous zinc batteries

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04928D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rongyu Deng, Yi Yuan, Zixuan Li, Feixiang Wu, Alex W Robertson
Aqueous zinc-ion battery anodes face the twin challenges of dendrite growth and severe side reactions. Here a liquid-infiltrated Al2O3 framework electrolyte (LIAFE) is developed to address these issues and enables...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05503A, Communication
F Takeiri, Keiko KUSUMOTO, Kosuke Kawai, Hiroshi Yaguchi, Takashi Saito, Kazuhiro Mori, Saburo Hosokawa, Masashi Okubo, Genki Kobayashi
Transition-metal oxyhydrides are an emerging class of functional materials; however, the known compounds have mostly been limited to perovskite-type structures. Here, we successfully synthesized Li2NbHO2, the first example of a...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Laccase-catalyzed tyrosine click reaction with 1-methyl-4-arylurazole: rapid labeling on protein surfaces

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03802A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keita Nakane, Chizu Fujimura, Shogo Miyano, Zhengyi Liu, Tatsuya Niwa, Hafumi Nishi, Tetsuya Kadonosono, Hideki Taguchi, Shusuke Tomoshige, Minoru Ishikawa, Shinichi Sato
Our study shows efficient tyrosine labeling using 1-methyl-4-arylurazole (MAUra) with laccase under mild conditions. This method achieves a high efficiency (kcat/Km = 7.88 × 104 M−1 s−1), selectively targeting exposed tyrosine sites on proteins.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Iron-catalysed intramolecular C(sp3)–H amination of alkyl azides

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04169K, Feature Article
Open Access
Kai Wu, Chi-Ming Che
This review summarizes recent major advances in iron-catalysed C–H aminations of alkyl azides through iron–alkylnitrene/alkylimido intermediates to access various N-heterocycles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04451G, Communication
Dopil Kim, Jun Yeong Kim, Haein Kim, Eunjin Jeong, Minhyuk Lee, Dongwook Kim, JunWoo Kim, Myung Hwan Park, Min Kim
We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

Sustainable Production of Aromatic Chemicals from Lignin using Enzymes and Engineered Microbes

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05064A, Feature Article
Open Access
Timothy D.H. Bugg, Victoria Sodré
Lignin is an aromatic biopolymer found in plant cell walls, that is the must abundant source of renewable aromatic carbon in the biosphere. Hence there is considerable interest in the...
The content of this RSS Feed (c) The Royal Society of Chemistry




y

For the love of legiyam

SRINIVASA RAMANUJAM queues up to find out what goes into this Deepavali preparation at the iconic Dabba Chetty Shop in Mylapore




y

Home-grown luxury

This year, Chennai has seen two staunchly-local five-star hotels spring up. ELIZABETH MATHEW meets the men behind the ambitious projects




y

May you eat in M.I.P

For a dash of Punjabi cuisine and hospitality, head straight towards Made In Punjab




y

Pakoras on a cloudy day

Why do we eat what we eat when grey clouds appear on the horizon and that first rain drop hits the ground? SHONALI MUTHALALY has some answers. And hashtags.




y

Hot and spicy on the menu

Chef William Tong on revamping the menu of Chinapolis Chinese speciality restaurant, at Vivanta by Taj, Thycaud, with his signature Sichuan and Cantonese dishes.




y

Jingle all the way

City hotels hold traditional cake mixing ceremonies, ushering in the spirit of Christmas




y

The takeaway is taste

RAHUL VERMA finds a cold weather friend in Mayur Vihar!




y

Eating out? Leave your cash at home

From your local chaiwalla discovering digital wallets to restaurants setting up tabs for regulars, SHONALI MUTHALALY looks at how demonetisation has affected the food industry




y

Moringa honey: How Italian bees are helping farmers in sweet enterprise

Moringa honey is among the most popular varieties of floral nectar in the food sector. Farmer and beekeeper N Dhandayuthapani is one of those in the Cauvery delta reaping the benefit of combining apiary with agriculture




y

Reconsider decision to distribute fortified rice through PDS in Wayanad: Shreyams Kumar

Health issues, social impact not considered, says LJD State president




y

Paneer makhni burger, anyone?

Everything from tofu to mutton ghee roast is fair game now 




y

Coimbatore’s Kaapi 2.0 offers healthy snacks with strong filter coffee

Kaapi 2.0, a new chain of minimalist cafes in the city, offers healthy snack options to munch on along with filter coffee



  • Life & Style

y

The 2022 sadya fix: what Chennai’s restaurants have in store

Festive fundraisers, takeaway menus, and payasam gift boxes. There’s a lot to choose from for this year’s Onam sadya




y

With pop-up restaurants, chefs discover the joys of cooking flexible, seasonal menus

A pandemic-prompted wave of pop-up kitchens has now become a creative way for independent chefs and edgy restaurants to travel, experiment and connect with diners



  • Life & Style

y

Watch | Payasam cakes and Mahabali cookies for Onam

Bakers and chefs are innovating with the traditional flavours of Onam




y

Pesticide residues above limits detected in curry powders sold in Kerala

Eight samples had no manufacturer details, while the rest were from leading brands




y

Dawat-e-Hyderabadi with ladies of Luqma kitchen studio

Traditional Hyderabadi dishes include much more than dum biryani, proves a team of women at Luqma kitchen studio



  • Life & Style

y

Currently trending in Hyderabad’s food scene: Apricot delight

Hyderabadis’ love affair with apricot continues to delight with many modern variations



  • Life & Style

y

Cloud kitchens make a mark in Thiruvananthapuram with pocket-friendly food and a wide range of cuisines

Still ordering in, though lockdowns are over? You are not alone. As cloud kitchens juggle cuisines and experiment with new dishes from a single space, takeaway in Thiruvananthapuram gets more interesting every day




y

In Auroville, try a mac and ‘sheeze’ as vegan chefs set up cafes and create healthy alternatives to meat

We sample inventive menus across the lush, experimental township, which draws visitors from across the world



  • Life & Style

y

Korean jjigae and scallops from Hokkaido: Pa Pa Ya opens its doors to Chennai

Pa Pa Ya finally opens its doors in the city. We try its signature mix of playful experiments with Asian cuisine, from tuna tataki pizza to Korean jjigae




y

Guardians of the galaxy, with fries

Ciclo Café’s new venture, Big Burger Theory, introduces hampers of hefty space-themed burgers with unexpected frills from guacamole to Japanese curry




y

Visiting Abu Dhabi this holiday season? Get a sense of the city’s growing luxury dining scene

Abu Dhabi is rising as a culinary destination with an emphasis on luxury dining offering cuisine from across the globe




y

Artisanal craft chocolates made in Rajahmundry

An artisanal craft chocolate named Bon Fiction is made from cacao beans grown here



  • Life & Style

y

Farmlore in Bengaluru sets out to prove that luxury dining can be local, ethical and even fun

Set on 37 acres of farmland, the restaurant seats just 18 guests, serving multi-course menus starring ethically sourced seafood and meat, as well as freshly harvested vegetables and foraged wild greens




y

Predictions for 2023: AI, VR boom in hospitality, wellness and gaming, and Balenciaga in India

This is the time of year when that we draw up the Best Of 2022 lists, and trend forecasts for 2023. And But how do you predict the unpredictable? We start with gains from the past.



  • Life & Style

y

The story behind Goila butter chicken

Saransh Goila tells how Goila Butter Chicken was born and why it is less sweet




y

Vizhinjam in Thiruvananthapuram has become the city’s seafood hub

Restaurants on Vizhinjam Harbour Road are making waves for dishing up the best seafood in town




y

Chances of infection: food safety squad continues aggressive checking in eateries

Nearly 70 shops dealing with food-based business inspected; flash inspections conducted considering the crowd turnout for Kerala State School Kalolsavam




y

Six millet-based recipes to try this Pongal

This pongal, help yourself to healthy servings of Foxtail Poli and Little Millet pepper pongal While Pongal meals have traditionally been a rice-dominant affair, give Foxtail Poli and Little Millet pepper pongal a try




y

A four-day Wild Food Festival in the Nilgiris puts the spotlight on sustainability

Climate crisis is real. It’s time to switch the narrative towards seasonal, locally available produce for sustainability, say speakers at the recently-concluded four-day Nilgiris Wild Food Festival