an Bullion Cues: Prices can rally By www.thehindubusinessline.com Published On :: Sat, 03 Aug 2024 19:17:27 +0530 Gold can rise to ₹75,000 if the facing resistance at ₹71,300 is breached and silver at ₹85,000, with potential gains if these levels are breached Full Article Derivatives
an Gold prices climb amid US recession concerns and rate cut bets By www.thehindubusinessline.com Published On :: Mon, 05 Aug 2024 12:04:16 +0530 Spot gold rose 0.14% to $2,446.83 per ounce, while US gold futures increased by 0.8% to $2,488.50. Full Article Gold & Silver
an Gold industry forms self-regulatory body to ensure transparency, boost trust By www.thehindubusinessline.com Published On :: Tue, 06 Aug 2024 19:28:37 +0530 The Association for Gold Excellence and Standards will frame good practices to be followed by the entire value chain of the industry, including bullion, jewellery manufacturers and retailers Full Article Gold & Silver
an Domestic gold prices surge 10% amid global price rally, central bank buying: World Gold Council By www.thehindubusinessline.com Published On :: Sat, 24 Aug 2024 12:52:53 +0530 Manufacturers have noted that in some cases, orders have reached levels not seen in several years, underscoring the strong buying interest among jewellery retailers and consumers alike Full Article Gold & Silver
an Gold purification: Provide small and medium refineries licences, says industry association By www.thehindubusinessline.com Published On :: Tue, 03 Sep 2024 12:13:43 +0530 Merchants’ association urges Centre to review decision on mandatory hallmarking and HUIC certification for purifying old ornaments Full Article Gold & Silver
an Gold futures slip on low demand By www.thehindubusinessline.com Published On :: Wed, 04 Sep 2024 14:04:57 +0530 Analysts attribute the fall in gold prices to weak global cues Full Article Gold & Silver
an Gold hits all-time high in August as import duties drop and USD weakens By www.thehindubusinessline.com Published On :: Sat, 07 Sep 2024 19:48:32 +0530 The rise was primarily driven by a drop in the US dollar and lower 10-year Treasury yields due to potential Federal Reserve rate cuts. Full Article Gold & Silver
an Sovereign Gold Bonds: Secondary market thrives amidst drought in primary issuances By www.thehindubusinessline.com Published On :: Sat, 21 Sep 2024 18:58:05 +0530 Recent data reveals a significant increase in trading volume, with retail holdings growing 63 per cent year-on-year. Full Article Gold & Silver
an Gold steadies after Iran strikes spark surge of haven buying By www.thehindubusinessline.com Published On :: Wed, 02 Oct 2024 09:24:12 +0530 Gold has rallied nearly 30 per cent this year, hitting a series of record highs. Full Article Gold & Silver
an Gold may sustain its current rally to top $3,000/oz, say analysts By www.thehindubusinessline.com Published On :: Thu, 03 Oct 2024 09:00:00 +0530 US Fed rate cut, weak dollar and rising geopolitical tension to aid the precious metal’s surge Full Article Gold & Silver
an Gold hits near record levels, silver follows suit amidst rising demand By www.thehindubusinessline.com Published On :: Fri, 11 Oct 2024 19:41:01 +0530 Gold prices surged by ₹1,150 to ₹78,500 per 10 grams, while silver prices rose by ₹1,500 to reach ₹93,000 per kg Full Article Gold & Silver
an 65% of millennials prefer digital gold over traditional for its ease of access and convenience: Moneyview survey By www.thehindubusinessline.com Published On :: Wed, 16 Oct 2024 19:33:09 +0530 Digital gold can be easily converted to cash or physical gold, giving investors flexibility to trade without incurring heavy transaction costs or delays Full Article Gold & Silver
an Gold soars over $2,700 an ounce on additional boosters By www.thehindubusinessline.com Published On :: Fri, 18 Oct 2024 19:29:34 +0530 US presidential polls uncertainty, jobless claims and new Israeli attack on Hamas add more glitter Full Article Gold & Silver
an Gold prices hit record highs, affecting demand during festival season By www.thehindubusinessline.com Published On :: Sat, 19 Oct 2024 16:45:26 +0530 Gold jewellery demand this Dhanteras is expected to be subdued due to a 5% surge in bullion prices, now at ₹77,410 per 10 grams Full Article Gold & Silver
an Godrej & Boyce launches ISI-certified lockers for jewellers and pawnbrokers By www.thehindubusinessline.com Published On :: Tue, 22 Oct 2024 19:22:07 +0530 To improve security standards and ensure compliance with government regulations, all high-security safes are now mandated to carry an ISI mark Full Article Companies
an Jewellers woo Dhanteras buyers with attractive offers By www.thehindubusinessline.com Published On :: Tue, 29 Oct 2024 22:18:54 +0530 Gold prices have been hovering above Rs ₹78,600 per 10 gm-level consistently despite weak demand due to ongoing global geopolitical turmoil in West Asia and Russia-Ukraine Full Article News
an India’s Q3 gold demand surges 18% as prices fall post duty cut By www.thehindubusinessline.com Published On :: Wed, 30 Oct 2024 13:08:08 +0530 The value of gold demand also increased dramatically by 54% to ₹1.65 lakh crore. Full Article Gold & Silver
an Tibetan Cuisine By www.berkshirepublishing.com Published On :: Mon, 18 Jan 2021 02:55:08 +0000 Abstract: Variations in cuisine among the Tibetan minority of China are due in part to environmental diversity. Different ecologies yielded varied adaptive strategies of resource use (economies), and resulted in three main types of food production: pastoralism, agriculture, and a mixed economy with both kinds of production. These strategies in turn affect the type The post Tibetan Cuisine appeared first on Berkshire Publishing. Full Article Encyclopedia of Chinese Cuisines Advance Articles
an Milk and Dairy Products By www.berkshirepublishing.com Published On :: Fri, 22 Jan 2021 17:12:05 +0000 Abstract: China has a long history of dairy production and consumption. Milk was appreciated for its culinary and medicinal uses, with successive dynasties expanding production and acquisition of pastoral animals. Now China is one of the world’s great dairy nations. Dairy was first commercially available in cities, but advances in packing and shipping have The post Milk and Dairy Products appeared first on Berkshire Publishing. Full Article Encyclopedia of Chinese Cuisines Advance Articles
an Noodles, Lanzhou By www.berkshirepublishing.com Published On :: Sat, 23 Jan 2021 22:28:15 +0000 Abstract: Lanzhou, the capital of Gansu Province, is home to one of China’s best-known noodle dishes: Lanzhou lamian. Created over a century ago, these hand-pulled beef noodles are a simple yet delicious regional specialty emblematic of both the city itself and the Hui Muslim people of the northwest. Lanzhou lamian have steadily acquired popularity The post Noodles, Lanzhou appeared first on Berkshire Publishing. Full Article Encyclopedia of Chinese Cuisines Advance Articles
an Home Ecology Tips in English and Chinese By www.berkshirepublishing.com Published On :: Mon, 31 Jan 2022 16:55:22 +0000 Our friend and colleague Catherine ZHOU kindly translated some introductory sections from Karen Christensen's in-progress book Home Ecology. Versions of these tips were included in some of her previous books, and she is busy compiling and writing a new guide that will focus on preparing for climate change, but also deal with other issues close The post Home Ecology Tips in English and Chinese appeared first on Berkshire Publishing. Full Article Berkshire Blog Making a Difference Home Ecology
an Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Recent advances in discrete Cu complexes for enhanced chemodynamic therapy By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02380C, FrontierZhao-Guo Hong, Liangliang Zhang, Hong Liang, Fu-Ping HuangSince the concept of metal ion stimulation-mediated chemodynamic therapy was proposed by Bu and Shi 's group in 2016, increasing attention has been directed toward fabricate efficient, safe and stable...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02197E, PaperVandana Kardam, Vaibhav Bhatt, Kshatresh DubeyArylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02496F, PaperSergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena ShubinaOctahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02714K, PaperAna Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva MaiaThe diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02690J, CommunicationAlexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di SunFirst metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02303J, PaperTao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan WangNi/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02659D, PaperSunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua SunThe coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02469A, PaperZhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei QinHeteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02274B, PaperEmilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-ŻyrekHistatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an High-pressure synthesis and crystal structure analysis of PbTeO4, a UV transparent material By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02697G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael Hladik, Armin Penz, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Matthias WeilCrystal structure of PbTeO4 with presumed position of the PbII lone-pair electrons (turquoise spheres). The electron localization function was used to emphasize the presence of the electron lone pair E.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02467B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank VanhaeckeThis study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02310B, PaperCai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui WenThe automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Syntheses, structures and characterization of noncentrosymmetric MZnPO4 (M = K, NH4) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02530J, PaperJiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai AnTwo phosphates, KZnPO4 and NH4ZnPO4, were successfully synthesized, and both structures show a three-way skeleton of isolated PO4 and ZnO4 tetrahedra. And NCS KZnPO4 and NH4ZnPO4 can exhibit SHG responses of 0.4 × KDP and 1 × KDP.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02603A, PaperTakeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa MehrkhodavandiAlkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02734E, PaperHui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang TangA biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02606C, PaperIan DanceI describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Oxaphosphiranes: isolable phosphorus-containing epoxide rings By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02915A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer StreubelA new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02650K, CommunicationKatherine Merkel, Alyssa V. B. Santos, Scott SimpsonDFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02848A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi ShimojimaWell-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01765J, PaperRomain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim StorrThe synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02613F, PaperAlena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. DybtsevFour new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02696A, PerspectiveAnkita Sharma, Unnikrishnan Nair K, Subrata KunduCarbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02645D, PaperKetan Maru, Sarita Kalla, Ritambhara JangirThe study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02958E, PaperJanak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika KhullarThe development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02656J, PaperTomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał GrubbaThe reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02901A, PaperMaxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia SpitsynaThe hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02396J, PaperChuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo PengZinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
an A ratiometric luminescence thermometer based on lanthanide encapsulated complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02639J, PaperAribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju LaishramThis paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article