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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02781G, Paper
Ruopei Sun, Erwan Dupuis, Jean Aupiais, Pascal Reiller
The formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit

The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam.




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Are Coal Producers doing an OPEC?



  • Siddhartha P Saikia

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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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Anchored to beliefs




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Many facets of intolerance




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Android or Alangudi




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Of govt departments and RTI




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The highs and lows of plant parenthood

It helps one realise the value of soil and look at the sun with deep reverence




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Writing a requiem to handwriting

The decline started with the advent of photocopiers and word processors




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Tie the knot on extravagant weddings

In conducting the feast and ceremonies, families spend as if there is no tommorow




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Moving house and memories

When life’s imprints tumble out of closets and into oblivion




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A trip to Panchmarhi

A college tour to the picturesque destination breaks the ice




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The happiness mantra

Giving care and being cared for are essential for human well-being




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Thriving technology, waning memory

Too many digital nannies are robbing us of the power of memory




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The richness of Indian languages

The idioms in everyday usage display the creativity and punch of the tongues




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Celebrating Hanami

It’s a Japanese tradition of viewing flowers in spring




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Mode of transport

Bus lovers love their comfort zones, while those taking the train are more daring




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Man-dog ties

Pets are living beings requiring consistent care and attention




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Confessions of an impractical person

How one ignored the imperfection of life by finding solace in the perfection of art




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A shrinking Himalayan passage

A visit to Nagmithong Nala near Kargil, where the threat of a glacial lake outburst flood looms large and Botkol Pass is set to become inaccessible




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Doctors and handwriting

A running joke is that a student with sloppy handwriting will probably become a doctor




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Nothing has changed for women in India

From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country




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Learning languages

Are our practices and actions pushing children away from languages?




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A dictionary at hand

Consult it regularly to develop your own vocabulary




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Marks mania

A child may have great talent, but she is judged only by her marks




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Live life to the fullest at any age

Birthdays are not just a celebration of the years gone by, but a reminder to live fully, no matter what age one is




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An ode to teachers

Teachers must strike the right balance to foster inclusivity and bridge the cultural, linguistic and learning gaps




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The annual ‘whitewash’

Not glossing over defects, but making a building stand out




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Saying it with an emoji

The efficient and expressive symbols have led to a decline in the use of formal communication techniques




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United by food and festival

A Bengali raised in Jharkhand with a yen for celebrating Onam




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A lie and its deleterious effects

Lying often results in guilt, anxiety, or the fear of being caught




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Real is rational and rational is real

They may seem inextricably intertwined, but their relationship is a complex interplay of a myriad forces




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Navigating public spaces as a woman

When public transport is inadequate or absent, it can heighten risks of violence and restrict access




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Women and travel

Whether working or not working, during daytime or at night, indoors or outdoors, they have the right to life and dignity




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A case for public transport

Aspirational India likes to flaunt snazzy cars, unmindful of the cost to environment




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Rising stars: Chani Nava and Will Chen

Interview with early-career scientists in astronomy and quantitative ecology




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Rising stars: Anzar Abbas and Katie Wu

Interview with early-career scientists in immunology and neuroscience




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Rising stars: Sadie Witkowski and Michael Graw

Interview with early-career scientists in psychology and oceanography




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




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Enhancing radiotherapy with MRI

Bas Raaymakers describes how MRI can help target tumours with improved accuracy




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Developing the world's first full-body PET scanner

Simon Cherry explains why the EXPLORER project will revolutionize medical imaging




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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Channapatna bypolls: Micro-management of OBCs and MBCs might hold the key

BJP leaders from various backward class communities are entrusted with the task of micro-managing voters, since JD (S) lacks many such leaders in its ranks




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Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’

Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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Mysuru Sangeetha Sugandha concludes

Tourism Ministry to promote the event beyond State