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From generation to collection – impact of deposition temperature on charge carrier dynamics of high-performance vacuum-processed organic solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03623A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Richard Adam Pacalaj, Yifan Dong, Ivan Ramirez, Roderick C. I. MacKenzie, Seyed Mehrdad Hosseini, Eva Bittrich, Julian Eliah Heger, Pascal Kaienburg, Subhrangsu Mukherjee, Jiaying Wu, Moritz Riede, Harald Ade, Peter Müller-Buschbaum, Martin Pfeiffer, James Robert Durrant
Substrate heating during co-evaporation of bulk heterojunction organic solar cells aids phase separation and improves performance. While recombination remains unaffected, hole transport improves due to more crystalline donor domains.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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Unveiling the role of structural vacancies in Mn-based Prussian blue analogues for energy storage applications

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE01618A, Paper
Chongwei Gao, Ming Chen, Jiantao Li, Xunan Wang, Guobin Zhang, Xi Tan, Shuhua Zhang, Guang Feng, Dengyun Zhai, Feiyu Kang
In this study, we explore two potential pathways for vacancy formation in Mn-based Prussian blue analogues, providing new insights for structural regulation.
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Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03156C, Review Article
Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue Dou
As a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.
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Stress regulation via surface micro-etching and reconstruction for enhancing triple-cation perovskite solar cells with an efficiency of 25.54%

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04248D, Paper
Yang Ding, Erming Feng, Siyuan Lu, Jianhui Chang, Caoyu Long, Sichao Tong, Hengyue Li, Junliang Yang
A surface micro-etching and reconstruction strategy is developed to regulate the stresses in a perovskite film, achieving a benign transition from tensile stress to compressive stress.
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Asymmetric evaporation for efficient and simultaneous extraction of freshwater, salt, and electrical energy from seawater

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04201H, Paper
Yitian Wu, Chaoliang Ma, Kangxin Zhu, Lizheng Jin, Lvfu Song, Lanze Li, Yingzhuo Lu, Yu Zheng, Yaoxin Zhang, Xin Zheng, Sai Wu, Yajun Pang, Zhehong Shen, Swee Ching Tan, Hao Chen
This study presents an asymmetric evaporation strategy that simultaneously achieves freshwater production, salt collection, and electrical energy generation.
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Quantitatively detecting and characterizing metallic lithium in lithium-based batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article
Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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Regulating local chemical softness of the collector to homogenize Li deposition for anode-free Li-metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03673E, Paper
Jiaming Zhu, Cong Kang, Xiangjun Xiao, Ya Mao, Ying Luo, Yuheng Wang, Quansheng Zhang, Yulin Ma, Chunyu Du, Shuaifeng Lou, Fanpeng Kong, Jingying Xie, Geping Yin
A heterogeneous collector featuring hard-base sites and soft-acid sites is proposed, which significantly reduces nucleation and growth barriers, with no dendrite formation. This finding offers a pathway to rationally design highly efficient collectors for AFLMBs.
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Customized structures of hydrogen-bonded organic frameworks towards photocatalysis

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03766A, Review Article
Chengdi Ma, Liyang Qin, Tianhua Zhou, Jian Zhang
This review provides a comprehensive analysis of the unique structural characteristics of HOFs and their diverse functional properties, while further exploring the potential of HOFs in the field of photocatalysis.
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Flexible spacer-block multi-component copolymerized donors enable resilient organic solar cells with over 40% crack-onset strain

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04208E, Paper
Congqi Lin, Zhenyu Chen, Ruixiang Peng, Wei Song, Jiangwei Gao, Xueliang Yu, Tingting Feng, Yongqi Bai, Ziyi Ge
A series of novel block donors were synthesized, achieving excellent PCE of 19.57% in rigid OSCs and 18.03% in f-OSCs, along with an outstanding crack-onset strain value of 40.29%.
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Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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A thermal evaporation–trapping strategy to synthesize flexible and robust oxygen electrocatalysts for rechargeable zinc–air batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03005B, Paper
Hong-Bo Zhang, Yu Meng, Lingzhe Fang, Fei Yang, Shangqian Zhu, Tao Li, Xiaohua Yu, Ju Rong, Weiwei Chen, Dong Su, Yi Mei, Peng-Xiang Hou, Chang Liu, Minhua Shao, Jin-Cheng Li
A thermal evaporation–trapping strategy is developed to fabricate a flexible N-doped carbon fiber cloth loaded with both CoFe-oxide nanoparticles and atomic Co/Fe–Nx sites, showing outstanding oxygen electrocatalytic performance.
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an

An electric double layer regulator empowers robust solid-electrolyte interphase for potassium metal batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03978E, Paper
Xueyu Lian, Liang Xu, Zhijing Ju, Ziang Chen, Xiaopeng Chen, Yuyang Yi, Zhengnan Tian, Tao Cheng, Shi Xue Dou, Xinyong Tao, Jingyu Sun
The electric double layer (EDL) plays a key role in constructing solid electrolyte interphase (SEI) for high-energy metal anodes. Nevertheless, the significance of EDL and its associated influence remain elusive...
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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an

A donor:hole-transport layer alloy for high-efficiency and stable binary organic solar cells with promoted hole collection and suppressed recombination

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04072D, Paper
Xianghui Zeng, Ting Xu, Hansheng Chen, Baoshen Deng, Qing Yan, Xuanlin Wen, Zijian Li, Haoxuan Zeng, Chuanlin Gao, Yaodong Xiao, Jiwei Liao, Hui Liu, Bin He, Peigang Han, Guangye Zhang, Shunpu Li, Yiwang Chen, Chen Xie
A donor-based nanoparticle (NPs)-incorporated hole-transport layer was synthesized for fine-tuning the energy level of anodes in organic solar cells. The conventional and inverted devices achieved record efficiencies of 19.9% and 17.2%, respectively.
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an

Removal of Residual Contaminants by Minute-level Washing Facilitates the Direct Regeneration of Spent Cathode from Retired EV Li-ion Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03021D, Paper
Yi Guo, Yang Li, Kai Qiu, Yan Li, Wei Jing Yuan, Chenxi Li, Xinyu Rui, Lewei Shi, Hou Yukun, Saiyue Liu, Dongsheng Ren, Tan Tiening, Gaolong Zhu, Languang Lu, Shengming Xu, Biao Deng, Xiang LIU, Minggao Ouyang
The direct regeneration of spent cathodes stands out as an environmentally and economically benign strategy within the battery ecosystem, eclipsing the cumbersome metallurgical approaches. Before addressing the lithium loss and...
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an

Cover matters: Enhanced performance of multistage solar evaporator with tuned optical and thermal cover properties

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02710H, Paper
Shiteng Li, Shang Liu, Qijun Yang, Shuai Deng, Meng Lin
To address global water scarcity and improve off-grid pure water production, this study focuses on enhancing the performance of inverted solar evaporators by optimizing the design of cover materials. By...
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an

Dual Promotion of Oxygen Reduction on Pt in Membrane Electrode Assembly by Hydroxyphenyl Metal Porphyrins

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04320K, Paper
Meihua Tang, Chunping Wang, Zhenying Zheng, Xiaoxiao Wang, Fulong Zhu, Shengli Chen
The oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs) is severely hindered by the strong adsorption of sulfonate groups in perfluorinated sulfonic acid (PFSA) ionomers on Pt,...
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an

Metastable interphase induced pre-strain compensation enables efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03801K, Paper
Hongyu Xu, Yun Xiao, Karim A Elmestekawy, Pietro Caprioglio, Qiuyang Li, Qixuan Zhong, Yongqiang Ji, Tianyu Huang, Haoming Yan, Yingguo Yang, Laura M Herz, Qihuang Gong, Henry Snaith, Rui Zhu, Lichen Zhao
High-efficiency metal halide perovskite solar cells (PSCs) include the rigid substrates with low thermal-expansion coefficients (TECs), resulting in a significant TEC mismatch with the perovskites with high TECs at the...
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an

Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
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an

A monolithic Co-FeCo8S8 electrode for stable anion exchange membrane water electrolyzer driven by fluctuating power supply

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04993D, Communication
Jahangir Khan, Heming Liu, Tianhao Zhang, Xin Kang, Zhiyuan Zhang, Yuxiao Dong, Shanlin Li, Jiarong Liu, Qiangmin Yu, Bilu Liu
Integrating water electrolysis and green electricity offers a promising approach towards sustainable and clean energy. However, such a system demands electrodes that can swiftly and stably adapt to fluctuating power...
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Market optimization and technoeconomic analysis of hydrogen-electricity coproduction systems

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02394C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel J. Laky, Nicole P. Cortes, John C. Eslick, Alexander A. Noring, Naresh Susarla, Chinedu Okoli, Miguel A. Zamarripa, Douglas A. Allan, John H. Brewer, Arun K. S. Iyengar, Maojian Wang, Anthony P. Burgard, David C. Miller, Alexander W. Dowling
We present an optimization framework to analyze emerging power systems technologies that coproduce power and alternative fuels. Emerging solid oxide-based systems have the potential to enable a reliable, efficient transition to cleaner energy.
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an

Depressing charge recombination in hybrid perovskites by introducing a dynamic electron/energy relay couple towards enhanced photocatalytic hydrogen production

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03864A, Paper
Jiaqi Liu, Yuxin Xie, Yongxin Jiao, Hefeng Zhang, Junhui Wang, Yuying Gao, Xu Zong
Extraordinary photocatalytic hydrogen evolution is achieved on methylammonium lead iodide perovskites by introducing a dynamic Cu/(CuI2) couple as the electron/energy relay station and the Pt co-catalyst as the charge/energy-releasing promotor.
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an

Unveiling nanoscale fluid miscible behaviors with nanofluidic slim-tube

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02292K, Paper
Zengding Wang, Tianjiang Zhang, Shanchao Liu, Keli Ding, Tengyu Liu, Jun Yao, Hai Sun, Yongfei Yang, Lei Zhang, Wendong Wang, Cunqi Jia, Mojdeh Delshad, Kamy Sepehrnoori, Junjie Zhong
We developed a nanofluidic method to visualize fluid miscible behaviors in nanoscale and multiscale porous media. Nano-confinement reduces MMP, while multiscale structures increase MMP, unveiling distinct miscible stages.
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Reduction of bulk and interface defects via photo-annealing treatment for high-efficiency antimony selenide solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02877E, Paper
Xiaoyang Liang, Xinhua Wang, Qiwei Chang, Bingxin Yang, Wei Dang, Zheng Zhang, Yingnan Guo, Lin Yang, Zhiqiang Li
A novel interface engineering strategy with a photo-annealing treatment is proposed for regulating the interface of the Sb2Se3/CdS heterojunction.
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an

Decoupling light- and oxygen-induced degradation mechanisms of Sn–Pb perovskites in all perovskite tandem solar cells

Energy Environ. Sci., 2024, 17,8557-8569
DOI: 10.1039/D4EE02427C, Paper
Open Access
Yang Bai, Ruijia Tian, Kexuan Sun, Chang Liu, Xiting Lang, Ming Yang, Yuanyuan Meng, Chuanxiao Xiao, Yaohua Wang, Xiaoyi Lu, Jingnan Wang, Haibin Pan, Zhenhua Song, Shujing Zhou, Ziyi Ge
This study showed PEHCl-CN can enhance the strength of Sn–I, resulting in good light stability. The subsequent doping of MBI resulted in good air stability. This enables the integrated 2T all-perovskite device to achieve an efficiency of 27.9%.
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A novel high-performance all-liquid formic acid redox fuel cell: simultaneously generating electricity and restoring the capacity of flow batteries

Energy Environ. Sci., 2024, 17,8545-8556
DOI: 10.1039/D4EE02450H, Paper
Dongbo Wei, Lyuming Pan, Jing Sun, Meisheng Han, Manrong Song, Jincong Guo, Qing Zhang, Cailin Xiao, Zheng Li, Shuaibin Wan, Yubai Li, Lin Zeng, Lei Wei, Tianshou Zhao
This work presents an all-liquid formic acid redox fuel cell using degraded redox flow battery electrolyte as the cathode fuel. This approach efficiently generates power while regenerating the electrolyte, advancing energy conversion and storage.
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an

Trimming defective perovskite layer surfaces for high-performance solar cells

Energy Environ. Sci., 2024, 17,8582-8592
DOI: 10.1039/D4EE03585B, Paper
Chanhyeok Kim, Kihoon Kim, Youngmin Kim, Nikolai Tsvetkov, Nam Joong Jeon, Bong Joo Kang, Hanul Min
The defect density on the top surface of the perovskite thin film was significantly higher than that in the bulk. A trimming solvent treatment removed the defective top surface, substantially reducing the defect concentration and strain.
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Hydrogel electrolytes with an electron/ion dual regulation mechanism for highly reversible flexible zinc batteries

Energy Environ. Sci., 2024, 17,8570-8581
DOI: 10.1039/D4EE03067B, Paper
Fusheng Luo, Song Yang, Qing Wu, Yue Li, Jinlong Zhang, Yanhui Zhang, Jun Huang, Haibo Xie, Yiwang Chen
The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.
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Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency

Energy Environ. Sci., 2024, 17,8593-8608
DOI: 10.1039/D4EE02414A, Paper
Tao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei Huang
Fusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.
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A wearable DC tribovoltaic power textile woven by P/N-type organic semiconductor fibers

Energy Environ. Sci., 2024, 17,8621-8632
DOI: 10.1039/D4EE02662D, Paper
Open Access
Beibei Fan, Guoxu Liu, Yiming Dai, Zefang Dong, Ruifei Luan, Likun Gong, Zhi Zhang, Zhong Lin Wang, Chi Zhang
A high-performance, wearable tribovoltaic DC power supply textile was prepared using a traditional weaving process. The WDPs have high flexibility, excellent environmental robustness, lower internal resistance, and washability.
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Superhalide structure and iodide-proof interphase via electrolyte regulation enable ultrastable zinc-iodine batteries

Energy Environ. Sci., 2024, 17,8643-8657
DOI: 10.1039/D4EE02192D, Paper
Wenjing Deng, Renfei Feng, Xiaolei Wang
A superhalide electrolyte structure and iodide-proof solid electrolyte interphase are introduced to simultaneously obtain efficient conversion activity and anode stability for reversible zinc–iodine batteries.
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Faster decarbonization of heavy industries in low-carbon power grids: using process flexibility for handling grid congestions

Energy Environ. Sci., 2024, 17,8838-8854
DOI: 10.1039/D4EE03888F, Paper
Sverre Stefanussen Foslie, Brage Rugstad Knudsen, Sigurd Bjarghov, Magnus Korpås
This work highlights the importance of process flexibility in industry decarbonization, showing it can enhance transmission grid capacity at costs comparable to other grid reinforcement measures, thereby enabling faster electrification of demand.
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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
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Reducing carrier recombination loss by suppressing Sn loss and defect formation via Ag doping in Cu2ZnSn(S,Se)4 solar cells

Energy Environ. Sci., 2024, 17,8609-8620
DOI: 10.1039/D4EE02485K, Paper
SeongYeon Kim, Jaebaek Lee, Dae-Ho Son, Wook Hyun Kim, Shi-Joon Sung, Dae-Kue Hwang, Tae Ei Hong, Namuundari Otgontamir, Enkhjargal Enkhbayar, Tae-Hee Lee, Min-Yeong Kim, Ji-Soo Choi, Sang-Mo Koo, JunHo Kim, Jin-Kyu Kang, Dae-Hwan Kim, Kee-Jeong Yang
The position of Ag of the CZTSSe precursor significantly impacts the carrier recombination loss and overall efficiency, offering crucial insights for optimizing the CZTSSe solar cell design.
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An energy-efficient tellurium electrode enabled by a Cs2TeI6 perovskite structure for durable aqueous Zn–Te batteries

Energy Environ. Sci., 2024, 17,8633-8642
DOI: 10.1039/D4EE02916J, Paper
Jinye Li, Chengjun Lei, Pengjie Jiang, Chen Xu, Tingting Liu, Xiao Liang
CsI in 2 M ZnSO4 aqueous electrolyte facilitates the formation of Cs2TeI6 perovskite phase for Te electrode, effectively suppressing Te4+ hydrolysis and sustaining fast redox kinetics in multi-electron transfer Zn–Te aqueous batteries.
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an

Hot carrier organic solar cells

Energy Environ. Sci., 2024, 17,8683-8690
DOI: 10.1039/D4EE02612H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priya Viji, Constantin Tormann, Clemens Göhler, Martijn Kemerink
Slow thermalization of photogenerated charge carriers in organic solar cells leads to an electronic temperature that is much larger than that of the lattice and to significantly enhanced open-circuit voltages.
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A techno-economic study of photovoltaic-solid oxide electrolysis cell coupled magnesium hydride-based hydrogen storage and transportation toward large-scale applications of green hydrogen

Energy Environ. Sci., 2024, 17,8429-8456
DOI: 10.1039/D4EE04224G, Analysis
Xusheng Wang, Longfei Shao, Shouyi Hu, Zi Li, Hangzuo Guo, Jiaqi Zhang, Yingyan Zhao, Xi Lin, Binjian Nie, Zhigang Hu, Jianxin Zou
Integrating PV-SOEC for hydrogen production with MgH2-based storage and transportation holds significant potential in advancing the hydrogen supply chain.
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Anti-dissolving Fe2N6 site-based carbon fiber membranes for binder-free Zn–air batteries with a 200-day lifespan

Energy Environ. Sci., 2024, 17,8722-8733
DOI: 10.1039/D4EE03148B, Paper
Open Access
Zian Xu, Jian Zhu, Jingze Shao, Yu Xia, Pengfei Liu, Guangshe Li, Rouxi Chen, Shaoqing Chen, Jiacheng Wang, Shi Chen, Fuqiang Huang, Hsing-Lin Wang
The anti-dissolving Fe2N6 structure enables ZABs to operate over 200 days (record-breaking 14 500 cycles).
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Interplay of intercalation dynamics and lithium plating in monolithic and architectured graphite anodes during fast charging

Energy Environ. Sci., 2024, 17,8702-8721
DOI: 10.1039/D4EE02211D, Paper
Open Access
Aleksandar S. Mijailovic, Seth Waag-Swift, Guanyi Wang, Bingyao Zhou, Mei Luo, Wenquan Lu, Qingliu Wu, Brian W. Sheldon
Fast charging of high-capacity anodes is challenging due to lithium plating reactions, which lead to poor cycling performance and safety concerns.
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Promoted thermoelectric performance in cubic-phase GeTe via grain-boundary phase elimination under phase diagram guidance

Energy Environ. Sci., 2024, 17,8691-8701
DOI: 10.1039/D4EE03090G, Paper
Fudong Zhang, Baopeng Ma, Yiyuan Luo, Lujun Zhu, Weishuai Wang, Yalin Shi, Beiquan Jia, Zhen-Hua Ge, Zupei Yang, Di Wu, Jiaqing He
The Ag8GeTe6 grain boundary phase gets eliminated in cubic-phase δ-TAGS as guided by a quaternary phase diagram.
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Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article
Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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an

Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage

Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
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Post-deposition in situ passivation of AgBiS2 nanocrystal inks for high-efficiency ultra-thin solar cells

Energy Environ. Sci., 2024, 17,8885-8892
DOI: 10.1039/D4EE03266G, Paper
Jae Taek Oh, Yongjie Wang, Carmelita Rodà, Debranjan Mandal, Gaurav Kumar, Guy Luke Whitworth, Gerasimos Konstantatos
A post-deposition in situ passivation strategy using a multi-functional molecular agent is reported with enhanced colloidal dispersibility of an environmentally-friendly AgBiS2 nanocrystal ink, achieving a PCE over 10% in a solar cell.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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Deep ion mass transfer addressing the capacity shrink challenge of aqueous Zn‖MnO2 batteries during the cathode scaleup

Energy Environ. Sci., 2024, 17,8904-8914
DOI: 10.1039/D4EE02871F, Paper
Na Jiang, You Zeng, Qi Yang, Puda Lu, Keqi Qu, Lihang Ye, Xuejun Lu, Ziqiang Liu, Xixian Li, Yongchao Tang, Jinchao Cao, Shimou Chen, Chunyi Zhi, Jieshan Qiu
This work shows that the introduction of interstitial carbon into the MnO2 lattice could reduce the affinity toward SO42− and OH, thus suppressing the surface coverage of ZHS and improving the Zn||MnO2 battery performance under large loading mass.
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An octave box inspired energy regularization triboelectric nanogenerator for highly efficient wave energy harvesting

Energy Environ. Sci., 2024, 17,8829-8837
DOI: 10.1039/D4EE02969K, Paper
Yuanchao Ren, Zizhuo Wang, Jie Chen, Fei Wu, Hengyu Guo
Inspired by the mechanical transmission structure of octave boxes, this work proposes a novel energy regularization triboelectric nanogenerator to effectively convert chaotic wave energy into stable electric output.
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Enhancing inter-domain connectivity by reducing fractal dimensions: the key to passivating deep traps in organic photovoltaics

Energy Environ. Sci., 2024, 17,8893-8903
DOI: 10.1039/D4EE02961E, Paper
Yuang Fu, Luhang Xu, Yuhao Li, Emily J. Yang, Yu Guo, Guilong Cai, Pok Fung Chan, Yubin Ke, Chun-Jen Su, U-Ser Jeng, Philip C. Y. Chow, Ji-Seon Kim, Man-Chung Tang, Xinhui Lu
Researchers in CUHK identified isolated non-fullerene acceptor (NFA) domains as the morphological origin of deep electron traps in organic photovoltaics. They showcased effective trap passivation by reducing the fractal dimensions of NFA networks.
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Engineering ultrafast exciton dynamics to boost organic photovoltaic performance

Energy Environ. Sci., 2024, 17,8776-8786
DOI: 10.1039/D4EE03315A, Paper
Yu Guo, Guangchao Han, Jing Guo, Haotian Guo, Yuang Fu, Xiaodan Miao, Zhen Wang, Dongsheng Li, Shuixing Li, Xiaomin Xu, Xinhui Lu, Hongzheng Chen, Yuanping Yi, Philip C. Y. Chow
Y-type acceptors exhibiting faster migration (shorter τ) of local excitons (LEs) in disordered regions of aggregates to intermolecular charge-transfer (ICT) excitons in ordered regions can achieve higher efficiencies in organic solar cells.
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