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Mixed phase Ti3+-rich TiO2 thin films by oxide defect engineered crystallization

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03545C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika Valden
Amorphous TiO2 has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...
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Insights into the electrochemical catalytic mechanism of atomically dispersed metal on h-BCN monolayer

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02845G, Paper
Na Zhou, Yanning Wang, Jiao Wang, Panchao Zhao, Hang Zhang
Exploiting efficient and inexpensive electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of great significance for the rapid development of renewable energy technologies.
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DON encapsulated carbon dot–vesicle conjugate in therapeutic intervention of lung adenocarcinoma by dual targeting of CD44 and SLC1A5

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR00426D, Paper
Afreen Zaman, Aparajita Ghosh, Anup Kumar Ghosh, Prasanta Kumar Das
HACD–TMAV, a carbon dot–vesicle conjugate, selectively delivered glutamine inhibitor DON to CD44-enriched cancer cells, inducing ROS triggered apoptosis by dual targeting CD44 and SLC1A5 through downregulation of PI3K/AKT/mTOR signalling cascade.
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Current progress and frontiers in three-dimensional macroporous carbon-based aerogels for electromagnetic wave absorption: a review

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03738C, Review Article
Han Ding, Bo Hu, Yu Wang, Yunchen Du
This article provides a timely review on the construction of three-dimensional macroporous carbon-based aerogels and their application in the field of electromagnetic absorption.
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Photoemission spectroscopy and microscopy for Ta@Si16 superatoms and their assembled layers

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02778G, Paper
Open Access
Masahiro Shibuta, Tsutomu Ohta, Toshiaki Kamoshida, Kana Yamagiwa, Hironori Tsunoyama, Tomoya Inoue, Tsugunosuke Masubuchi, Atsushi Nakajima
An alkaline-like Ta-encapsulating Si16 superatom film was fabricated on a C60 substrate. Charge transfer between Ta@Si16 and C60 lowers the work function. In the multilayer film, the central Ta atom's positive charge is compensated by the Si16 cage.
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Design of a new process for the stabilization of FeS–Bi2S3 hybrid nanostructure and its application as a field emitter

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04138K, Paper
Arushi Arora, Anima Mahajan, Nausad Khan, Santanu Ghosh, Menaka Jha
Design of a new process for the fabrication of FeS–Bi2S3 anisotropic nanostructure for field emission application.
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Polylactic acid/chitosan-IKVAV Janus film serving as a dual functional platform for spinal cord injury repair

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02248C, Paper
Liyang Yu, Haoyong Jin, He Xia, Xiaoxiong Wang, Liang Wang, Dezheng Li, Jiangli Zhao, Yuanhua Sang, Jichuan Qiu, Ning Lu, Hong Liu, Ning Yang
Schematic showing the PLA/CS-IKVAV Janus film for promoting neuronal differentiation and SCI repair.
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The interaction of glycogen nanoparticles with human blood

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03034F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadiia Davydiuk, Vaidehi Londhe, Manfred F. Maitz, Carsten Werner, Andreas Fery, Quinn A. Besford
Glycogen nanoparticles are emerging biomaterials for theranostic applications. This study investigates the interactions of glycogen nanoparticles from different sources with human blood, finding that all are hemocompatible nanomaterials.
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Ultra-low noise measurements of ionic transport within individual single-walled carbon nanotubes

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02941K, Paper
Laure Bsawmaii, Clément Delacou, Valerii Kotok, Sébastien Méance, Koutayba Saada, M. Amine Kribeche, Saïd Tahir, Christophe Roblin, Antonin Louiset, Hanako Okuno, Manoel Manghi, John Palmeri, François Henn, Adrien Noury, Vincent Jourdain
Nanofluidic devices incorporating an individual single-walled carbon nanotube, which achieve a 1–3 orders of magnitude noise reduction over conventional devices, were fabricated using high dielectric constant materials.
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Contactless manufacturing of TERS-active AFM tips by bipolar electrodeposition

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03068K, Paper
Yuhan HUANG, David Talaga, Gerardo Salinas, Patrick Garrigue, Gary Sean Cooney, Stéphane Reculusa, Alexander Kuhn, Sébastien Bonhommeau, Laurent Bouffier
Tip-enhanced Raman spectroscopy (TERS) is a powerful technique for nanoscale chemical imaging. However, its worldwide expansion is still limited by the challenging fabrication of cheap, robust and efficient TERS tips...
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pH controlled synthesis of end to end linked Au nanorod dimer in an aqueous solution for plasmon enhanced spectroscopic applications

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03235G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Satyajit Patra, Shubhangi Sharma, Théo Minchella, Susmita Pradhan, Davy Gerard, Quanbo Jiang
End-to-end linked nanorod dimer nanogap antennas exhibit superior plasmonic enhancement compared to monomers due to the coupling of localized surface plasmon resonances (LSPR) of individual nanorods. However, controlling the assembly...
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Biomass-derived substrates hydrogenation over Rhodium Nanoparticles Supported on Functionalized Mesoporous Silica

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02579B, Paper
Open Access
Israel Tonatiuh Pulido-Díaz, Draco Martínez, Karla Patricia Salas-Martin, Benjamín Portales-Martínez, Dominique Agustin, Antonio Reina, Itzel Guerrero Ríos
The use of supported rhodium nanoparticles (RhNPs) is gaining attention due to the drive for better catalyst performance and sustainability. Silica-based supports are promising for RhNP immobilization because of their...
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Electrochemical chiral recognition of tryptophan enantiomers by using chiral polyaniline and β-CD-MOF

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02854F, Paper
Jiamin Liang, Yuxin Song, Huan Xing, Liang Ma, Fengxia Wang, Mingfang Zhang, Hongli Zhang, Gang Zou, Guang Yang
A electrochemical sensor for the chiral recognition of Trp based on chiral polyaniline (D-PANI) and β-CD-MOF was designed. It displayed higher affinity of L-Trp, and the oxidation peak current ratio (IL/ID) of DPV could be reached at 2.26.
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Conduction band photonic trapping via band gap reversal of brookite quantum dots using controlled graphitization for tuning a multi-exciton photoswitchable high-performance semiconductor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper
Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
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Nanoparticle’s shape is the game-changer for blood-brain barrier crossing and delivering through tunneling nanotubes among glioblastoma cells.

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03174A, Paper
Open Access
Giulia Sierri, Ines Saenz-de-Santa-Maria, Antonio Renda, Marcus Koch, Patrizia Sommi, Umberto Anselmi-Tamburini, Mario Mauri, Alessia D'Aloia, Michela Ceriani, Domenico Salerno, FRANCESCO MANTEGAZZA, Chiara Zurzolo, Francesca Re
Tunneling Nanotubes (TNTs) are thin, dynamic, long membrane protrusions that allow the intercellular exchanges of signal clues, molecules and organelles. The presence of TNTs and their involvement as drug delivery...
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Synthesis, Characterization, Genotoxicity Assessment and Antibacterial Applications of Zanthoxylum armatum Silver Nanoparticles (ZASNP) with Antibiotic Efficacy Enhancement Potential

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03608E, Paper
Open Access
Nikita Quadri, Manjunath M. Setty, Anshumali Awasthi, Usha Yogendra Nayak, Minakshi Singh, Sharad Sharma
The study aimed to develop alternative antibacterial treatments by combining traditional herbal knowledge with modern nanotechnology. This approach targets multiple bacterial strains, combats antibiotic resistance, and offers solutions for treating...
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Impact of catalyst support on water-assisted CO oxidation over PdO/MO2 (M = Sn, Ti, and Si) catalysts: experimental and theoretical investigation

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03963G, Paper
Kun Liu, Luliang Liao, Guangfu Liao
This study investigates the influence of different supports on PdO-based catalysts during CO oxidation, particularly under humid conditions.
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A liposome-based assay for cancer biomarker detection: exploring the correlation between platelet-derived microvesicles and NSCLC-associated miRNAs

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03704A, Paper
Mohamed Aimene Benariba, Kanza Hannachi, Sha Zhu, Yuting Zhang, Xiaoli Wang, Nandi Zhou
This research reveals a significant correlation between PMVs and their associated miRNA. Additionally, the liposome-based assay demonstrates enhanced sensitivity with calcium-induced platelet activation.
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Highly stable and ultra-fast vibration-responsive flexible iontronic sensors for accurate acoustic signal recognition

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03370A, Paper
Yan Wang, Weiqiang Liao, Xikai Yang, Kexin Wang, Shengpeng Yuan, Dan Liu, Cheng Liu, Shiman Yang, Li Wang
A wearable acoustic vibration pressure sensor was developed based on an interfacial-enhanced iontronic dielectric and integrated with an acoustic recognition system using a deep learning classifier.
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Particle Surface Engineering at Nano-Micro Scale Interfaces of Metal-Nonmetal Bonded Polymeric Coatings: Experimental and In-Silico Evaluations

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03431G, Paper
Suman Yadav, Sarvesh Kumar Pandey, Shikha Awasthi
Polyvinyl alcohol (PVA) is a well-known cost-effective synthetic polymer that offers a variety of applications including medical, aerospace, automotive, and construction industries. However, weak bonding with low mechanical and tribological...
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Photo-Assisted Epitaxial Growth from Nanoparticles to Enhance Multi-Materialization for Advanced Surface Functionalization

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03112A, Paper
Masayuki Fukuda, Yuuki Kitanaka, Tomohiko Nakajima
To meet the requirements of freeform objects, a wide range of highly designable resin-based materials has been created, highlighting the need for low-temperature ceramic deposition methods for surface functionalization. Photo-assisted...
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Unraveling the Ammonia Sensing Behavior and Degradation Pathways of Novel Lead-Free MA2CuBr4 based Ammonia Sensor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02943G, Communication
Abinash Tiwari, Arjumand Mir, Aswani Yella
We report a lead-free copper-based halide perovskite gas sensor to detect ammonia gas at ambient temperature. The sensor uses methylammonium copper bromide as the active material and can trace ammonia...
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Recent Progress of Two-dimensional Bi2O2Se and its Heterostructures

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03769C, Review Article
Xiaoyu Hu, Wen He, Dongbo Wang, Lei Chen, Xiangqian Fan, Duoduo Ling, Yanghao Bi, Wei Wu, Shuai Ren, Ping Rong, Yinze Zhang, Yajie Han, Jinzhong Wang
Ever since the identification of graphene, the research on two-dimensional (2D) materials has garnered significant attention. As a typical layered bismuth oxyselenide, Bi2O2Se has attracted growing interest not only due...
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Exploring Graphene's Impact on Graphite/PANI Matrix Composites: High-Press Fabrication and Enhanced Thermal-Electrical Properties

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03171G, Paper
Murat OZLEK, Merve Sehnaz Akbulut, Engin Burgaz
This study investigates the effects of graphene content and applied press on electrical and thermal conductivities of graphite/polyaniline (GP) and graphite/graphene/polyaniline (GGP) composites which were produced by using direct mixing...
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High yield exfoliation of sub-micron hexagonal boron nitride using a solvent free method

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02850C, Paper
Diana Santiago, Maricela Lizcano, Sean P. McDarby, Ching-cheh Hung, Baochau N. Nguyen
Schematic of intercalation and exfoliation of submicron hBN.
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Low Volume Shrinkage Alkaline Degradable UV Nanoimprint Lithography Resists Based on Acrylic Anhydride

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03291H, Paper
Chuan Zhe Zhao, Ya-Juan Cai, Yi-Xing Sun, Ya-Ge Wu, Kexiao Sang, Ting Yue, Zihao Yang, Jinggang Gai
The shrinkage phenomenon of UV-NIL resist during photocuring is still regarded as an important problem hindering the wide application of UV-NIL technology. We designed four degradable UV-NIL resists with low...
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Electrode Informatics Accelerated Optimization for Catalyst Layer Key Parameters in Direct Methanol Fuel Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03026E, Paper
Lishou Ban, Danyang Huang, Yanyi Liu, Pengcheng Liu, Xihui Bian, Kaili Wang, Yifan Liu, Xijun Liu, Jia He
As the core component of direct methanol fuel cell, the catalyst layer plays the key role of material, proton and electron transport channels. However, due to the complexity of its...
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Shape-controlled, water-assisted synthesis of 2D luminescent CsPb2Br5 perovskite microcrystals for highly responsive UV detectors

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03021D, Paper
Dipayan Ray, Ankush Saini, Ankit Kumar, Sumit Kumar, Monojit Bag, Prasenjit Kar
Water-assisted, growth-controlled synthesis of CsPb2Br5 microcrystals for fast responsive UV-detectors.
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Emerging chiral sulfur-based nanomaterials for chiroptical applications

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03736G, Review Article
Hammad Hasan, Md Ifzal Azhar, Santosh Kumar Behera, Md Palashuddin Sk
This review covers fundamental principles and techniques for measuring chiral properties as well as the synthesis of chiral sulfur-based nanomaterials, their optical and chiroptical properties, and possible applications.
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Bifunctional electrocatalytic hybrid heterostructures for polysulfide anchoring/conversion for a stable lithium–sulfur battery

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03190C, Paper
Sakthivel Kaliyaperumal, Karthik Kiran Sarigamala, Padmini Moorthy, Balaji Ramachandran, Narendhar Chandrasekar, Tim Albrecht
In situ phase engineering of transition metal dichalcogenides (TMDs) based hybrid heterostructures with controlled sulfur vacancies offers a promising strategy for superior-performance lithium–sulfur (Li–S) batteries.
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Effect of number ratio and size ratio on the formation of binary superlattices assembled by two-sized polymer-tethered spherical nanoparticles

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04032E, Communication
Open Access
Jinlan Li, Xin Yu, Jianing Zhang, Jing Jin, Yanxiong Pan, Xiangling Ji, Wei Jiang
Binary superlattices (BNSLs) with unique configurations are of great interest, attributing to the interaction between two kinds of nanoparticles, providing potential applications in sensing, electronic and optical fields. Here, polystyrene...
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Quantifying the polar skyrmion motion barrier in an oxide heterostructure

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03686G, Paper
Lizhe Hu, Yuhui Huang, Yong Jun Wu, Zijian Hong
Exotic polar topologies such as polar skyrmions have been widely observed in the ferroelectric superlattice system. The dynamic motion of the polar skyrmion under external forces holds promise for applications...
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Aptamer-functionalized Nucleic Acid Nanotechnology for Biosensing, Bioimaging and Cancer Therapy

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04360J, Review Article
Xiaofang Zheng, Zhiyong Huang, Qiang Zhang, Guoli Li, Minghui Song, Ruizi Peng
Nucleic acids have enabled to fabricate self-assemblies and perform dynamic operations. Among different functional nucleic acids, aptamers can specifically bind to wide range of targets including proteins, viral antigens, living...
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Expression of concern: Iron oxide magnetic nanoparticles with versatile surface functions based on dopamine anchors

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR90209B, Expression of Concern
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mykola Mazur, Alexandre Barras, Victor Kuncser, Andrei Galatanu, Vladimir Zaitzev, Kostiantyn V. Turcheniuk, Patrice Woisel, Joel Lyskawa, William Laure, Aloysius Siriwardena, Rabah Boukherroub, Sabine Szunerits
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Electrical transport phenomena in two-dimensional metallic 2H-NbSe2: an experimental and theoretical study

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03369H, Paper
Jeongmin Kim, Seonhye Youn, Damin Lee, Chan Woong Kim, Hongjae Moon, Seok-Hwan Chung, Hoyoung Kim, Dong Hwan Kim, Sumin Kim, Jong Wook Roh, Joonho Bang, Wooyoung Lee
Two-dimensional (2D) metallic transition metal dichalcogenides (TMDCs) have attracted extensive interest in various fields owing to their unique electronic properties.
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Spontaneous switching and fine structure of donor-acceptor Stenhouse adducts on Au(111)

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03942D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anton Senenko, Alexander Anatolievich Marchenko, Oleksandr Kurochkin, Oleksiy Kapitanchuk, Mykola Kravets, Vassili Nazarenko, Volodymyr Sashuk
We present the spontaneous isomerization of donor-acceptor Stenhouse adducts anchored onto a gold surface, visualized using scanning tunneling spectroscopy. Our investigation reveals a palette of molecular arrangements, including those with...
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Theoretical Understanding of the In-plane Tensile Strain Effects on Enhancing the Ferroelectric Performance of Hf0.5Zr0.5O2 and ZrO2 Thin Films

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03333G, Paper
Kun Hee Ye, Taeyoung Jeong, Seungjae Yoon, Dohyun Kim, Cheol Seong Hwang, Jung-Hae Choi
The in-plane tensile strain was reported to enhance the ferroelectricity of Hf1-xZrxO2 thin films by promoting the formation of the polar orthorhombic (PO-) phase. However, its origin remains yet to...
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Hydrodynamic Slip in Nanoconfined Flows: A Review of Experimental, Computational, and Theoretical Progress

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03697B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Abdul Aziz Shuvo, Luis E. Paniagua-Guerra, Juseok Choi, Seong H. Kim, Bladimir Ramos Alvarado
Nanofluidics has made significant impacts and advancements in various fields, including ultrafiltration, water desalination, biomedical applications, and energy conversion. These advancements are driven by the distinct behavior of fluids at...
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Constructing Nickel Complex/Crystalline Carbon Nitride Hybrid with a Built-in Electric Field for Boosting CO2 Photoreduction

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03586K, Paper
Yanrui Li, Linda Wang, Bo Zhan, Liangqing Zhang, Xiaolin Zhu, Xiang Gao
Sluggish charge separation dynamics resulting from the amorphous structure and the lack of driving force for graphitic carbon nitride (GCN) limits its highly effective CO2 photoreduction performance. Herein, a built-in...
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Improving Dynamic Control of Toehold-Mediated Strand Displacement Reactions through Phosphorothioate Modifications

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper
Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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