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Super League Kerala | Dorielton sizzles as Forca Kochi downs Thiruvananthapuram Kombans




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Rampant Messi hits another hat-trick as Miami break MLS points record

Messi, who came off the bench in the 58th minute and led the late flurry of goals, has now scored 20 goals in 19 appearances in MLS with his former Barcelona team-mate Suarez also notching 20, from 27 games




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Serie A leader Napoli scores late to beat struggling Lecce and Atalanta routs Verona

Serie A leader Napoli has needed a late score from captain Giovanni Di Lorenzo to secure a 1-0 victory over struggling Lecce




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'Anti-Semitic' clashes erupt in Amsterdam after football match

The violence flared after the game between Maccabi Tel-Aviv and home team Ajax, which won 5-0.




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Gold prices anticipated to surpass $3,000 per ounce: Citi report

The report attributes this projection to the weakening US labour market, disinflation, and the Federal Reserve’s dovish pivot at the upcoming July FOMC meeting



  • Gold & Silver

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Jewellers woo Dhanteras buyers with attractive offers

Gold prices have been hovering above Rs ₹78,600 per 10 gm-level consistently despite weak demand due to ongoing global geopolitical turmoil in West Asia and Russia-Ukraine




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Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
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Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02467B, Paper
Open Access
Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank Vanhaecke
This study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02734E, Paper
Hui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang Tang
A biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites

Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper
Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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The highs and lows of plant parenthood

It helps one realise the value of soil and look at the sun with deep reverence




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Tie the knot on extravagant weddings

In conducting the feast and ceremonies, families spend as if there is no tommorow




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The happiness mantra

Giving care and being cared for are essential for human well-being




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Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra




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Activists demand that govt. grant land to landless, instead of encroachers on contract

They also urged the State government to recover the hundreds of acres of land encroached upon by private company estates in the Malnad region




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Don’t reduce quantum of advance, Minister Shivanand Patil tells NABARD




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Messi's Miami stunned by Atlanta in MLS

Miami were overwhelming favourites to win it all after producing a league record 74 points in the regular season but could not keep the momentum after Matias Rojas' close-range goal in the 17th minute and Messi's score in the 65th minute.




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Bruno Fernandes scores brilliant goal in landmark game for Man United against Leicester

Bruno Fernandes has scored 84 goals in all competitions since joining United from Sporting Lisbon in 2020




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U Mumba edge past UP Yoddhas in thrilling PKL match, Haryana Steelers beat Gujarat Giants




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Mumbai seeks another dominant show in contest against Services

The Rahane-led defending champion knowns that a victory will hold it in good stead for a quarterfinal berth




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Synergistic effect of the heterojunction g-C3N4/Bi2MoO6/clinoptilolite to enhance the photocatalytic degradation of antibiotics in water in the presence of persulfate

Environ. Sci.: Water Res. Technol., 2024, 10,2665-2687
DOI: 10.1039/D4EW00549J, Paper
Phuong Thu Le, Thu Phuong Nguyen, Thi Hai Do, Hong Nam Nguyen, Thi Mai Thanh Dinh, Thi Thuy Phan, Toshiki Tsubota, Trung Dung Nguyen
Proposed mechanism of OTC photocatalytic degradation by the CNBC-30/PDS/Vis system.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbon quantum dot (CQD)-dithizone-based thin-film chemical sensors for the specific detection of lead ions in water resources

Environ. Sci.: Water Res. Technol., 2024, 10,2858-2868
DOI: 10.1039/D4EW00452C, Paper
Tanmay Vyas, Hritik Kumar, Sandeep Choudhary, Abhijeet Joshi
Dithizone-CQD-based thin-film chemical sensors for the detection of lead ions in various water resources.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ultrafiltration behavior of CuO particles synthesized without and with different surfactants using PAN and PES membranes

Environ. Sci.: Water Res. Technol., 2024, 10,2981-2996
DOI: 10.1039/D4EW00462K, Paper
Olabimpe Genevieve Badru, Ime Akanyeti
Four different CuO particles were synthesized, with no surfactant (CuO/NS) and with three surfactants: Triton X-100 (CuO/TX100), cetyltrimethylammonium bromide (CuO/CTAB) and sodium dodecyl sulfate (CuO/SDS).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fe3+ and H2O2 assisted dopamine rapid polymerization on melamine foam to activate PMS for organic pollutant degradation

Environ. Sci.: Water Res. Technol., 2024, 10,2698-2708
DOI: 10.1039/D4EW00596A, Paper
Haoxiang Yan, Jianzheng Zhen, Yuyuan Yao
A bulk sponge catalytic material was prepared by rapid polymerization of DA and utilized for PMS activation to degrade BPA. The coexistence of HCO3 enhanced 1O2 generation, accelerating BPA degradation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A review of carbon recovery in sewage treatment and analysis of product options for a typical water recycling plant

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00160E, Critical Review
Arash Mohseni, Linhua Fan, Li Gao, Joel Segal, Felicity Roddick
Reviewed existing and emerging technologies for carbon recovery from WWTPs, best options investigated as case study for typical conventional plant.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Applicability of β-lactamase entrapped agarose discs for removal of doripenem antibiotic: reusability and scale-up studies

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00572D, Paper
Huma Fatima, Amrik Bhattacharya, Sunil Kumar Khare
Schematic diagram illustrating antibiotic removal via β-lactamase-entrapped agarose discs in a fixed-bed column bioreactor, highlighting the potential for scale-up.
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Sorption and biodegradation of stormwater trace organic contaminants via composite alginate bead geomedia with encapsulated microorganisms

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00600C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Debojit S. Tanmoy, Gregory H. LeFevre
We quantified sorption of stormwater relevant trace organic contaminants and dissolved phosphorus to a novel composite-alginate geomedia. We demonstrated coupled sorption and biodegradation of a representative tirewear compound via the geomedia.
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L&T bags 'significant' order for global nuclear fusion project

The company classifies a 'significant order' as orders valued between ₹1,000 crore and ₹2,500 crore




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Vedanta plans to invest $500 million in group firm AvanStrate Inc.

“This investment is aimed at driving innovation and expansion within ASI, strengthening its focus on R&D,” the company said




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Indigo launches daily flights from Thiruvananthapuram to Pune




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NoRKA warns public to be vigilant against fake recruitment ads




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Thiruvananthapuram to host major film preservation and restoration workshop

The dire state of film preservation in India led Dungarpur to set up the Film Heritage Foundation in 2014, for the conservation, preservation and restoration of films




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‘Vanitha Junction’ campaign launched in Thiruvananthapuram district




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Water supply disruption in Thiruvananthapuram city




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Meet Aswanth A, the visual designer behind the IFFK 2024 logo and brand identity concept

The IFFK film festival will take place in Thiruvananthapuram from December 13 onwards




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Water supply to 11 wards in Thiruvananthapuram to be disrupted till 10 a.m. on November 3




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Sufi Qawwali group Warsi Brothers from Rampur to perform in Thiruvananthapuram




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Rise in liver transplants in Kerala MCHs due to lower cost, better access

Liver transplant surgeries now available in government medical colleges in Kerala, offering affordable options for patients in need.