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Ball milling-promoting difunctionalization of alkynyl sulfonium salts with sulfinic acids towards (Z)-1,2-disulfonylethenes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04895D, Paper
Li-Hua Yang, Bei Li, Lin Chen, Wen-Shi Yao, Han-Yue Peng, Sha Peng, Long-Yong Xie
A simple ball milling-mediated disulfonylation of alkynyl sulfonium salts with sulfinic acids for the stereoselective synthesis of various (Z)-1,2-disulfonylethenes has been developed under catalyst-, additive- and solvent-free conditions.
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1D/3D hierarchical carbon skeleton confined NiFe nanoparticles with optimized three-phase interfaces as tri-functional electrocatalysts

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04466E, Paper
Yuqing Chen, Binyang Liu, Xuesong Liu, Jiahui Ye, Kuan Deng, Chengjie Wu, Qiang Niu, Tao Yang, Wen Tian, Junyi Ji
Multilevel 1D/3D CNTs/carbon spheres with hydrophilicity can promote the infiltration of an electrolyte into the interior and guide bubble diffusion, thus constructing an optimal gas–solid–liquid interface to enhance the electrocatalytic process.
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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
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Comparison of microbial strains as candidate hosts and genetic reservoirs for the valorization of lignin streams

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03876B, Paper
Open Access
Rebecca A. Wilkes, Andrew J. Borchert, Valentina E. Garcia, Gina M. Geiselman, Sarah Liu, Adam M. Guss, Joshua K. Michener, Daniel R. Noguera, Eiji Masai, John M. Gladden, John Ralph, Gregg T. Beckham
Comparison of microbial strains for tolerance to and catabolism of lignin stream constituents toward evaluating microbial hosts for lignin bioconversion.
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CO2 switchable solvents for sustainable dissolution, modification, and processing of cellulose materials: a critical review

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04032E, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peter McNeice, Ben L. Feringa
CO2 switchable solvents provide a convenient and environmental method to dissolve and process cellulose.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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Mechanoenzymatic Hydrolysis of Cotton to Cellulose Nanocrystals

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05113K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sandra Kaabel, Inge Schlapp-Hackl, Eero Kontturi, Mauri A. Kostiainen
Solid-state mechanoenzymatic approaches for the production of cellulose nanocrystals from cotton were examined using three commercially available cellulase systems from Trichoderma reesei, Aspergillus niger and a Cellic CTec2 cellulase blend....
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Green Chemistry Startups: Some Lessons Learned

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3GC05187K, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jason P. Hallett
There has been an explosive growth in environmentally driven startups in recent years. Much of this has included university spin-outs aiming to translate academic research into commercial practice. This activity...
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Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05207B, Paper
Yao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming Zhang
The direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.
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Mirror, mirror on the wall...




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A job half done




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Education vs HRD

​The nomenclature ​has changed but has it made a difference big enough to change things?




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Hitman: Songs you must listen to this week




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Spotlight on the media

Satirical films about the media have always been entertaining




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Hitman: Songs you must listen to this week




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Hitman: Songs you must listen to this week




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Innovations... and collections

Only a professional approach can extend the careers of new-age directors and producers




on

Hitman: Songs you must listen to this week




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The Brexit conundrum

Now that the U.K. has voted to leave the EU, how will British cinema be affected?




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Hitman: Songs you must listen to this week




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MSV’s last song




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Hollywood’s Tamil conquest

The dubbed film market, once dominated by Telugu cinema, is now ruled by English films




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Kabali fever grips the nation

Press, TV, theatre owners, distributors and audiences prepare for the arrival of the biggest film of the year




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Hitman: Songs you must listen to this week




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Hitman: Songs you must listen to this week

Here are some songs you must listen to this week.




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Notes on a scandal

Political embarrsassment has always made for interesting cinema




on

The big promotion

Remo has shown that even an average film can be turned into a superhit if marketed aggressively enough




on

Royal Challengers ride on Kohli’s brilliance

Gayle and de Villiers too join the party in making Kolkata Knight Riders's challenging total seem small




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Raina returns as Lions hope to roar against Knight Riders

Half of Gujarat Lions worries will be taken care of if the dazzling opening combo of Dwayne Smith and Brendon McCullum fires.



  • Indian Premier League

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We have to work hard on our game: Raina



  • Indian Premier League

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Lions breeze through by 6 wickets

A Dwayne-Smith bowling special and a Suresh-Raina batting special takes Gujarat Lions up to the top of the table on points.



  • Indian Premier League

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Virat and AB are playing a different game: Watson




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Settled SRH takes on unpredictable DD



  • Indian Premier League

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Skipper Raina guides Lions ‘home’

Dwayne Smith’s stingy spell restricts Kolkata Knight Riders to its lowest score of this season.



  • Indian Premier League

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Nair's confidence earns Delhi 6-wicket win

And Delhi Daredevils stay afloat to fight another day, after Karun Nair held his own on a day of hot and cold fielding, after Sunrisers set them 158.



  • Indian Premier League

on

Pune vs Punjab: Cellar-dwellers battle to avoid wooden spoon



  • Indian Premier League

on

Pune vs Punjab: Amla says Kings keen to end on winning note



  • Indian Premier League

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Royal Challengers: Allan Donald happy bowling is finally clicking



  • Indian Premier League

on

Lions win will seal MI’s fate

Raina’s side could opt for a spinner-friendly track to counter the defending champion's strengths.



  • Indian Premier League

on

Lions pulverise MI, storm into playoffs

GL made short work of MI's 172/8, riding a rollicking 95-run partnership between Raina and McCullum to advance to the next stage with ease.



  • Indian Premier League

on

Raina, Smith confirm Lions’ top-two spot

Defeat leaves Mumbai Indians now praying for massive defeats for Knight Riders and Daredevils



  • Indian Premier League

on

DD takes on RCB in potential knockout



  • Indian Premier League

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Captain Dhoni at his belligerent best

Final-ball finish helps Supergiants consign Kings XI to last spot



  • Indian Premier League

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Kohli in the forefront again as RCB qualifies

Daredevils fail to put up a challenging score and pay the price; Mumbai Indians dethroned



  • Indian Premier League

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Lions stare down back-from-the-dead RCB

The victor goes straight to the final; the loser gets another shot, plays winner of Eliminator



  • Indian Premier League

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RCB pull off 4-wicket win on ABD's shoulders

GL struck early and big, reducing RCB to 29/5 in 5 overs, but ABD matched Dr Smith, carried his bat through with a 47-ball 79 to chase down 159.



  • Indian Premier League

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Royal Challengers’ spectacular comeback continues

de Villiers and Iqbal Abdulla help the team make the final from a precarious 68 for six; a rare failure from Kohli



  • Indian Premier League

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I don’t think too much, while Kohli is a thinker: de Villiers

He insists that there is a fine line between getting out to a bad shot and pulling off the incredible.



  • Indian Premier League

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Lions batsmen vs Sunrisers bowlers, the defining contest of Qualifier-2

With the tactical plans mapped out, the emphasis at the Kotla will be on execution under pressure



  • Indian Premier League

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Brett Lee's tips on fitness

Former Australian fast bowler Brett Lee, who was in Hyderabad recently, gave fitness tips to young cricketers at a training studio, first of its kind in India, at Hyderabad.