Chem. Sci., 2024, 15,18135-18145
DOI: 10.1039/D4SC04896B, Edge Article

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Jing Jin, Zhaolong He, Di Liu, Yongqiang Mei, Jiahui Wang, Huihui Wan, Jiuyan Li
Spiro-acridine modified N/B/O type MR-TADF emitters realized deep blue fluorescence with an EQE_max of 20.5% and CIE (0.147, 0.048), which is state-of-the-art efficiency for N/B/O type deep-blue MR emitters with CIEy approaching the BT.2020 standard.
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Chem. Sci., 2024, 15,18146-18160
DOI: 10.1039/D4SC05289G, Edge Article

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Ewan McQueen, Noritaka Sakakibara, Kei Kamogawa, Martijn A. Zwijnenburg, Yusuke Tamaki, Osamu Ishitani, Reiner Sebastian Sprick
This highly efficient hybrid photocatalytic system can quantitatively convert CO₂ to formate and produce 0.4 M of formate solution without additional concentration enrichment.
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Chem. Sci., 2024, 15,18060-18066
DOI: 10.1039/D4SC05442C, Edge Article

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Zheng-Xiao Tang, Bin Wang, Zhi-Rui Li, Zhuo Huang, Hai-Xia Zhao, La-Sheng Long, Lan-Sun Zheng
A molecule-based ferroelectric [(CH₃)₃NCH₂CH₂Br][GaBr₄] (1), with a d₃₃ value of 331 pC N⁻¹, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm⁻².
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Chem. Sci., 2024, 15,18048-18051
DOI: 10.1039/D4SC04980B, Edge Article

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Minling Zhong, Jie Zhang, Zuowei Xie
Reactions of o-carborane-fused diborane(4) with 3H-diazirines lead to the complete cleavage of the NN bond, with one nitrogen atom being incorporated into the B–B bond.
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Chem. Sci., 2024, 15,18085-18092
DOI: 10.1039/D4SC03763D, Edge Article

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Ruyu Xie, Kaitao Li, Rui Tian, Chao Lu
We have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.
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Chem. Sci., 2024, 15,17799-17822
DOI: 10.1039/D4SC05295A, Review Article

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Miaoyu Li, Jie Pu, Qinghe Cao, Wenbo Zhao, Yong Gao, Ting Meng, Jipeng Chen, Cao Guan
The application of hydrogel-based flexible strain sensors in harsh environments, including extreme temperatures, humidity, high mechanical strain, and strong corrosion, is investigated.
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Chem. Sci., 2024, 15,17823-17830
DOI: 10.1039/D4SC03546A, Edge Article

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Jonghwan Lee, Sungsik Eom, Hyungjun Kim
This work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.
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Chem. Sci., 2024, 15,18161-18169
DOI: 10.1039/D4SC04318A, Edge Article

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Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan Li
A sterically demanding ortho-CF₃ substituent defines not only the arrangement of ligands on a Ag₉₈(2-CF₃PhCC)₄₈Cl₄ nanocluster (Ag₉₈) but also the inter-cluster interactions. Ag₉₈ shows excellent methanol tolerance in the oxygen reduction reaction.
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Chem. Sci., 2024, 15,17950-17961
DOI: 10.1039/D4SC05006A, Edge Article

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Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo Tanaka
The study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.
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Chem. Sci., 2024, 15,17971-17978
DOI: 10.1039/D4SC04685D, Edge Article

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Shuo Li, Guoli Zhang, Qianrui Li, Tianshun He, Xiaoqi Sun
A facile self-saturation strategy, realized by the introduction of a hydrophobic methyl group on naphthoquinone, is demonstrated to suppress the dissolution of small molecule cathode materials and achieve stable cycling in aqueous zinc cells.
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Chem. Sci., 2024, 15,18170-18178
DOI: 10.1039/D4SC04404E, Edge Article

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Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong Tan
A bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb²⁺ and Hg²⁺ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.
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Chem. Sci., 2024, 15,18022-18030
DOI: 10.1039/D4SC04429K, Edge Article

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Julius A. Knöller, Franziska Müller, Tomas Matulaitis, John M. dos Santos, Abhishek Kumar Gupta, Eli Zysman-Colman, Sabine Laschat
We developed a MR-TADF based, columnar liquid crystalline host system and doped it with a MR-TADF guest. Efficient FRET allowed us to construct the first columnar liquid crystal with narrowband MR-TADF from the strongly aggregated mesophase.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04620J, Edge Article

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Odin Zhang, Yufei Huang, Shichen Cheng, Mengyao Yu, Xujun Zhang, Haitao Lin, Yundian Zeng, Mingyang Wang, Zhenxing Wu, Huifeng Zhao, Zaixi Zhang, Chenqing Hua, Yu Kang, Sunliang Cui, Peichen Pan, Chang-Yu Hsieh, Tingjun Hou
FragGen introduces a novel fragment-based AI-based molecular design method. It proposes the geometry handling protocol to improve the generation quality and has been applied to design highly bioactive type II kinase inhibitors.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06060A, Edge Article

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Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen Xu
A unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04879B, Edge Article

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Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik Schaufelberger
Dynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05998K, Edge Article

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Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S₁O₄G), which exhibits excellent ORR and zinc–air battery performances.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC90219J, Correction

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Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang Xu
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Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06820C, Review Article

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Seungwon Sun, Jisu Choe, Jaeheung Cho
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...
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Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04589K, Edge Article

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Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
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Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC03942D, Edge Article

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Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-Kostal
Cleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04174G, Edge Article

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Run-Zhou Liu, Zhihan Zhang, Min Li, Lihan Zhang
A metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.
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Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06660J, Edge Article

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Jasper Schuurmans, Tom Masson, Stefan Zondag, Simone Pilon, Nicola Bragato, Miguel Claros, Tim den Hartog, Fransesc Sastre Calabuig, Jonathan van den Ham, Pascal Buskens, Giulia Fiorani, Timothy Noel
Continuous-flow methodologies offer promising avenues for sustainable processing due to their precise process control, scalability, and efficient heat and mass transfer. The small dimensions of continuous-flow reactors render them highly...
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article

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Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04026K, Edge Article

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Jacob A. Iannuzzelli, Rachel Bonn, Andrew S. Hong, Abhijith Saseendran Anitha, Jermaine L. Jenkins, Joseph E. Wedekind, Rudi Fasan
Cyclopeptide agents targeted against the −1 programmed ribosomal frameshifting stimulatory sequence RNA pseudoknot of SARS-CoV-2 were discovered by screening a multiplexed phage display library of genetically encoded peptide macrocycles.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05014B, Edge Article

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Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei He
Modulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05935B, Edge Article

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Yanbin Xu, Huangsheng Yang, Anlian Huang, Linjing Tong, Wei Huang, Guosheng Chen, Wei Yi, Siming Huang, Gangfeng Ouyang
A biocompatible polymer deposition-mediated surface-charge reformation strategy is reported that enables the in-place MOF biomineralization onto different enzyme templates.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05493H, Edge Article

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Xin Li, Zhanfang Liu, Linsen Yang, Shengyang Zhou, Yongchao Qian, Yuge Wu, Zidi Yan, Zhehua Zhang, Tingyang Li, Qingchen Wang, Congcong Zhu, Xiang-Yu Kong, Liping Wen
Inspired by sniffer dog olfactory sensory neurons, an ultrasensitive TNP detection sensor was developed by in situ growing UiO-66-NH₂ layers on AAO. It exhibits a limit of detection with 6.5 × 10⁻¹⁶ g mL⁻¹, offering a new method for rapid detection.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05756B, Edge Article

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Danyang Dou, Bingbing Zhang, Daqing Yang, Ying Wang
By adopting an extended octupolar π-conjugation strategy, two excellent optical functional materials with a strong SHG response and large birefringence were prepared.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06389A, Edge Article

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Liam P. Griffin, Simon Aldridge
Zinc boryl and metal–metal bonded Zn(I) complexes can be accessed from a common Zn(II) iodide precursor and bis(pinacolaton)diboron(4).
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05873A, Edge Article

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Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou Zhai
A novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta₂O₅ nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06684G, Edge Article

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David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier Lorthioir
A synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC02262A, Edge Article

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Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. Zechel
The noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNA^UUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06190J, Edge Article

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Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi Liu
Incorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article

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Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06369D, Edge Article

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Xiao Jing Lv, Chun Zhi Ai, Li Rong Zhang, Xiu Xiu Ma, Juan Juan Zhang, Jia Peng Zhu, Ren Xiang Tan
BruN and BTG13 cleave chrysophanol hydroquinone into monodictyphenone and cephalanone F, respectively, with the regioselectivities found tunable via the key amino acid (AA) substitution strategy.
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