Apparatus for installing and removing road wheels from a motor vehicle, which may include a powered jack permanently mountable to the vehicle and a powered tool for tightening and loosening lug nuts and screws. The jack is an assembly incorporating two screw operated jacks, each for lifting one corner of the vehicle. The jack may include a manual controller having a power cord which is inserted into the cigarette lighter socket of the vehicle and which selectively operates any of up to four screw operated jacks. The powered tool may include plural sockets for engaging all lug nuts and screws simultaneously. The jack and powered tool may each have respective power cords which are insertable into the cigarette lighter socket or alternatively into a power port of the manual controller. The invention may comprise a kit including one or more jacks, the powered tool and optionally a jack stand.

A method of forming a material for reversible hydrogen storage within a storage tank includes charging a mixture of a metal amide and a metal hydride to the storage tank, and chemically reacting the mixture at a reaction condition within the storage tank to form a thermally conducting composite material situated in the storage tank and for reversibly storing hydrogen. The composite material includes a three-dimensional and interconnected framework including a conductive metal. A method for reversibly storing hydrogen includes providing a storage tank and in situ chemically forming a composite material by charging a mixture of a metal amide and a metal hydride to the storage tank and chemically reacting the mixture at a reaction condition to form a thermally conducting composite material including a metal hydride and a substantially unreactive elemental metal framework. Hydrogen is absorbed into the composite material and is desorbed from the composite material.

This tool, which is in particular a hammer, comprises a gripping handle, a striking head, and an intermediate shaft extending the handle and supporting the head, whereas the handle comprises a tube in which the shaft partially extends, this tube and this shaft being made from a rigid material presenting a first hardness. This shaft has a radial area bearing against the tube, with interposition of a link part, for absorbing vibrations, made from flexible material presenting a second hardness that is much lower than the first hardness, and a free terminal area, not covered by the link part, radially separated from the walls of the tube so as to be able to vibrate freely in an internal volume of the tube.

This invention includes embodiments which disclose a hand-held tool implement or apparatus which includes among other things, a handle attached to a head with a scraper and a hammering surface thereon.

A cutting device includes a first part and a second part which is pivotably connected to the first part. A first fixing portion is located in the top side of the first part. The second part has a second fixing portion defined in the underside side thereof and facing the top side of the first part. The second fixing portion is located corresponding to the first fixing portion. A reception slot is defined axially in the second part and communicates with the second fixing portion and the underside of the second part. A blade is inserted into the reception slot. A hole is defined through the first part for receiving a hydraulic hose. A pressing member is pivotably located in a recess in one side of the first part and is able to press the hydraulic hose passing through the hole and the recess.

A socket for driving a threaded fastener into a material has teeth spaced around a fastener opening. The teeth cut out a counterbore hole that receives the head of the fastener as the fastener threads into the material.

An angle measuring device or system can include a wrench and a digital angle meter. The wrench can include a head for engaging a fastening device, a central axis about which the wrench or bracket rotates during use, and a longitudinal axis perpendicular to the central axis. The digital angle meter can be attached to the wrench or bracket and include a housing, a processor, and at least one gyrometer. The at least one gyrometer including a first axis extending parallel to the longitudinal axis for determining the rotational orientation of the wrench or bracket relative to a reference position. A sensor of the digital angle meter allows for an automated and accurate calculation of a total angle of rotation of the nut or bolt about the central axis using a ratcheting wrench.

A method for controlling the effective heat transfer from a storage unit (1). During gas release from storage material (3) in the storage unit the storage material is heated by a heater (2). During re-saturation of the storage material (3) with gas the heater is off. Controlling of the effective heat transfer from the storage unit (1) is performed, during gas release, by ceasing convection of a convection gas and, during re-saturation, by performing or enabling convection of a convection gas to cool the storage unit (1).

A combination handle clamp, beverage bottle and can opener having a generally curved shaped body and integral attachment point to allow connection to other personal item such as a key ring. A secondary and tertiary integral curved section form a pair of loading points for fixing open a handle-trigger assembly and incorporate a gripping edge to facilitate opening a crimped or vacuum sealed bottle top. The tertiary curved section additionally functions as a second clamp position for the larger handles and also doubles as a pry mechanism to assist opening a pop-top can. The said gripping edge of the invention which contacts with said bottle top to be constructed of a durable material that won't abrade from its intended use.

A multipurpose string line tool having an inner tube slideable within an outer tube provided with an attached bottom end cap and a removable upper end cap whereby a storage space for small construction implements can be stored within the inner tube. A line string is wrapped around the outer tube. The outer tube with the line string wrapped there-around is designed so that it can easily spin around the inner tube thereby providing a free release of the line string. The free end of the line string can be locked within an annular space between the outer tube and a cylindrical stopper by the upper end cap at the upper end of the multipurpose tool. A small opening can be provided in the upper end cap and a pencil sharpener fixed to an inner surface of said upper end cap in alignment with the small opening.

The device for tapping and inoculating trees includes an elongate, main arm having an actuating mechanism attached to one end and a housing attached to the opposite end. A cutting mechanism extends from one side of the housing and a spray system is disposed in a recess in the housing. A universal actuator operates both the cutting mechanism and the spray system upon activation by the actuating mechanism. The cutting mechanism taps or scrapes the bark off the target branch and the spray system sprays a solution that stimulates the tapped area into producing more sap and sap of higher quality.

A compact, folding tool permitting the exchange of implement sets, including one or more quick release mechanisms that are easily removed from a handle to release interchangeable implements; the tool further accommodating implement sets including different types and quantities of implements which are inhibited from rotating by an adjustable clamping force produced by the quick release mechanisms and optionally including over travel stops to obstruct implement rotation, or may rely solely on the clamping force provided by the quick release mechanisms to stabilize implements for use.

A forming and framing hammer comprises an elongate handle and a head fixed to the top end of the handle. The head has three striking surfaces: two on a striking body and one on the side of the head. The third striking surface is cushioned by a neoprene bushing to reduce vibration in the handle of the hammer. The head has two pulling tools for pulling nails. The bottom of the handle accepts interchangeable tools.

A tool for the removal of connectors from pipes is disclosed that, in one embodiment, enables the removal of connectors from large pipes and in another embodiment from a size range of pipes. Movable and stationary gripping and pushing elements are affixed to handles to enable a pipe to be firmly gripped between a movable gripping jaw and a stationary gripping jaw and the connector prevented from movement by the movable pusher jaw and the stationary pusher jaw. The handles can compress around a pivot point or slide on a bar. In another embodiment the movable and stationary gripping and pushing elements are removable from the body of the tool.

A hydrogen storage tank by absorption into a hydrogen storage material, the tank having a longitudinal axis and including an enclosure and an inner structure provided within the enclosure. The inner structure includes a plurality of stages and a heat exchange system within the inner structure, each stage including a plurality of compartments distributed into a plurality of rows directed along the longitudinal direction, each compartment having a semi-cylindrical shape, and each compartment containing a hydrogen storage material, wherein the material has been introduced through the opening.

A combination tool of the locknut wrench type, which includes a leveling device and a screwdriver blade on the opposite end. The locknut head and screwdriver ends may be interchanged depending on the size locknut wrench needed and the type of screwdriver needed.

The present invention relates to embodiments of a folding knife having a seat belt cutter on the blade tang. In one embodiment, a folding knife comprises a handle and a knife blade. The knife blade comprises a tang pivotably connected to the handle, and the blade is operable to pivot relative to the handle about a pivot axis extending through the tang between a closed position and an open position. The tang comprises an enlarged tang portion that extends outwardly from the handle when the blade is in the closed position, and the enlarged tang portion comprises a cutting portion.

The invention concerns barrier films comprising: (i) a substrate comprising at least first and second coatings on the substrate; (ii) the first coating comprising an inorganic oxide, metal oxide or metallic coating; and (iii) the second coating capable of adhering to the substrates, wherein the second coating is polymeric; wherein the degradation of oxygen transmission rate is reduced when compared to a barrier film without the second coating when the barrier film is subjected to Gelbo-type flexing as described in ASTM F392.

An amino-containing silica particle is provided. The amino-containing silica particle is obtained by hydrolysis-condensation reaction of an alkoxy silane represented by formula (I), an alkoxy silane represented by formula (II) and a catalyst: Si(OR1)4 formula (I) (NH2—Y)m—Si(OR2)4-m formula (II) wherein in formula (I), R1 is a C1-C10 alkyl group, and in formula (II), Y is a C1-C10 alkyl group or a C2-C10 alkenyl group, R2 is a C1-C10 alkyl group, and m is an integer of 1 to 3.

Provided are a propylene homopolymer composition for a capacitor film, which can provide a film with excellent high-temperature voltage resistance and excellent thin-film stretchability, a method for producing the same, and a capacitor film. The propylene homopolymer composition for a capacitor film contains 50 to 99% by mass of a propylene homopolymer (A1) having predetermined characteristics and 1 to 50% by mass of a propylene homopolymer (B1) having predetermined characteristics, and has (i) a melt flow rate (MFR) of 1.0 to 10.0 g/10 min and (ii) a chlorine content of 2 ppm by mass or less.

Provided is a hardcoat film having a film thickness of 25 μm or less in which a polymerized substance of a compound having an energy ray-curable group and a resin are mixed across an entire region in a film thickness direction, in which a percentage of a mass concentration of the resin which is represented by the Expression (1) as defined herein has a distribution in which the percentage is maximized on at least one of two opposed surfaces, in the film thickness direction, of the hardcoat film or at a central part, in the film thickness direction, of the hardcoat film.

The invention relates to a method for obtaining a magnesium fluoride (MgF2) sol solution, comprising the steps of providing a magnesium alkoxide precursor in a non-aqueous solvent and adding 1.85 to 2.05 molar equivalents of non-aqueous hydrofluoric acid to said magnesium precursor, characterized in that the reaction proceeds in the presence of carbon dioxide. The invention further relates to sol solutions, method of applying the sol solutions of the invention to surfaces as a coating, and to antireflective coatings obtained thereby.

At least a two-layer protective coating system including: (a) a layer of a fusion bonded epoxy, and (b) a layer of a spray-dried protective powder coating disposed on at least a portion of the top surface of the fusion bonded epoxy layer (a), said powder coating being cured to form a protective coating on at least a portion of the fusion bonded epoxy layer; a process for preparing the above two-layer protective coating system; a substrate such as a metal pipe coated with the above two-layer protective coating system; and a process for producing a coated article such as a coated metal pipe using the above two-layer protective coating system.

A method for protecting a surface of an article from sulfate corrosion resulting from exposure to a sulfate containing material at an elevated temperature includes coating the surface with a nickel based material to form an anti-corrosion coating. The nickel based material includes NiO, a spinel of formulation AB2O4, or a combination thereof, wherein A includes nickel, and B includes iron or a combination of manganese and a B site dopant.

Provided is a conductive roller coating composition which can reduce degradation of toner during durable printing when used for a developing roller, and a developing roller and image formation device using the same. In a conductive roller coating composition containing a resin component including a polyol and an isocyanate, and microparticles, a Tg of the microparticles is −13° C. or less. In a developing roller including: a shaft 1; and an elastic layer 2 supported on an outer periphery of the shaft 1, an outer periphery of the elastic layer 2 is coated with the conductive roller coating composition.

Described herein are putty compositions comprising: an initiator component comprising a thermal initiator and a photo initiator; an acrylate-functional resin; and a filler composition comprising: calcium carbonate particles; and glidant particles; wherein the calcium carbonate particles and the glidant particles are present in a weight ratio ranging from about 4:1 to about 1:1.

Described herein are putty compositions having a first reactive component comprising a first acrylate oligomer and a second reactive component comprising a second acrylate oligomer that comprising a urethane acrylate oligomer, as well as an initiator component wherein the first acrylate oligomer and the second acrylate oligomer are present in a weight ratio that ranges from about 4:1 to about 1:2 and wherein the putty composition is self-leveling.

An interlayer composition including an epoxy resin; a polyvinyl phenol; a poly(melamine-co-formaldehyde) polymer; a solvent; an optional surfactant and an optional catalyst. A device including a substrate; an interlayer disposed thereon; and conductive features; wherein the interlayer is formed from a composition comprising an epoxy resin; a polyvinyl phenol; a poly(melamine-co-formaldehyde) polymer; an optional surfactant and an optional catalyst. A process for forming conductive features on a substrate including depositing an interlayer onto a substrate; thermally curing the interlayer; depositing a conductive composition onto the interlayer to form deposited features; and annealing the deposited features to form conductive features.

The present invention relates to a pressure sensitive adhesive sheet containing, laminated in this order, a supporting substrate, a pressure sensitive adhesive layer (X), a continuous void-containing layer including a composition containing silica particles, and a pressure sensitive adhesive layer (Y), the continuous void-containing layer having a mass concentration of the silica particles of more than 60% and 100% or less.

Provided is a high-strength cold-rolled steel sheet having excellent ductility and stretch-flangeability as well as weldability in a range in which a tensile strength is 980 MPa or higher and a 0.2% yield strength is less than 700 MPa (preferably 500 MPa or higher). In the high-strength cold-rolled steel sheet of the present invention, the chemical composition is adjusted as appropriate, and the area ratio of below-mentioned metal structures at a position of ¼ sheet thickness in the steel sheet satisfies following requirements: tempered martensite: 10 area % to less than 30 area %, bainite: more than 70 area %, total of tempered martensite and bainite: 90 area % or more, ferrite: 0 area % to 5 area %, and retained austenite: 0 area % to 4 area %. The high-strength cold-rolled steel sheet has excellent ductility, stretch-flangeability, and weldability, and has a tensile strength of 980 MPa or higher and a 0.2% yield strength of less than 700 MPa.

This invention relates to thermal spray coatings and processes onto non-smooth surfaces. The coating and processes can coat non-smooth surfaces without substantial degradation of the underlying surface texture or profile of the non-smooth surfaces so as to sufficiently preserve the underlying surface texture or profile. The ability for coating fractional coverage to maintain the surface profile while maintaining wear resistance is unprecedented by conventional thermal spray processes

A process for producing a layer or a body built up of layers. A process gas which has a pressure of >10 bar is accelerated in a convergent-divergent nozzle and a coating material which is formed by particles and is composed of Mo, W, an Mo-based alloy or a W-based alloy is injected into the process gas. The particles are at least partly present as aggregates and/or agglomerates. It is possible to produce dense layers and components in this way. We also describe layers and components having a microstructure with cold-deformed grains having a high aspect ratio.

An example composite material composed of a metal or multilayered metal substrate onto which an elastomer or elastomeric mixture is positioned by electrophoretic disposition. The elastomer or elastomeric mixture forms a flexible non-rigid elastomeric coating, which imparts a soft touch tactile feeling to the metal base substrate.

A coated substrate is provided that can include a substrate defining a surface, and an abradable coating on the surface of the substrate. The abradable coating can comprise La2-xAxMo2-y-y' WyBy'O9-δ forming a crystalline structure, where A comprises Li, Na, K, Rb, Cs, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, Be, Mg, Ca, Sr, Ba, Cu, Bi, Cd, Zn, Ag, Au, Pt, Ir, Rh, Ru, Pd, or combinations thereof; 0

A method for selective deposition of an organic solderability preservative coating on a copper surface of an article is disclosed. The method includes two steps of organic coatings by two solutions; the first step contains contacting the copper surface with a first solution including azole compound and the second step contains contacting the copper surface treated by the first solution with a second solution including a specific pyrazine derived compound.

Methods of producing a polyamide filaments and fibers are provided. The methods include providing a dual-terminated polyamide and spinning the dual-terminated polyamide at a speed of 3500 m/min to 8000 m/min to form a fiber. In one embodiment, the polyamide has an amine endgroup concentration of 25 mmol/kg to 40 mmol/kg and a carboxyl endgroup concentration of 18 mmol/kg to 50 mmol/kg. Fibers and yarns comprising polyamide filaments and fibers formed from the method are also disclosed.

A sheet material includes a fibrous substrate made of microfibers and a hydrophilic-group-containing resin applied to the fibrous substrate. The hydrophilic-group-containing resin has a microphase-separated structure that satisfies Condition I: In a phase image obtained by observing an area of 1 μm2 in a cross-section of the hydrophilic-group-containing resin applied to the fibrous substrate by phase imaging using an atomic force microscope (AFM), a standard deviation of a mode of brightness distribution of areas of 0.2 μm2 in the area of 1 μm2 is from 0 to 10. Provided are a sheet material that is produced through an eco-conscious production process and yet has such uniformity that is comparable to those of man-made leathers produced using organic-solvent-based polyurethanes, an elegant surface appearance, and a good touch, and a method for producing such a sheet material.

An object of the present invention is to provide a method for producing an ultrafine fiber-containing sheet with suppressed yellowing. Another object of the present invention is to provide an efficient method for eliminating an introduced substituent, and a composite sheet comprising an organic layer and/or an inorganic layer laminated on the obtained sheet. The present invention provides a method for producing an ultrafine fiber-containing sheet, comprising (a) introducing a substituent having electrostatic and/or steric functionality to a fiber raw material to obtain substituent-introduced fiber; (b) machine-processing the substituent-introduced fiber obtained in the step (a) to obtain substituent-introduced ultrafine fiber; (c) preparing a sheet from the substituent-introduced ultrafine fiber obtained in the step (b); and (d) eliminating at least a portion of introduced substituents from the sheet obtained in the step (c). In a preferred aspect, the substituent having electrostatic and/or steric functionality is a phosphoric acid-derived group, and the method may further comprise, after the step (a) and before the step (c), the step of (e) changing the degree of neutralization of the substituent-introduced fiber or the substituent-introduced ultrafine fiber.

The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.

A lightweight construction element (1) comprises at least one lightweight panel (2) and a layer of insulating material (4) associated with the lightweight panel (2), wherein the at least one lightweight panel (2) comprises boards (6), which, on at least one of the main surfaces (8) thereof, have a group of grooves (9) running parallel and which boards (6) are arranged in at least one layer (5) and are connected to one another via adhesive bonds. The layer of insulating material (4) comprises wood chips (19), which are removed from starting boards during the manufacture of boards (6) for the lightweight panels (2). These lightweight construction elements have good load and thermal insulation properties. The material used originates from one source and achieves a large overall volume after processing.

The invention provides a high strength stone plastic floor and manufacturing method thereof. The stone plastic floor comprises a PVC substrate and a surface layer on a surface of the PVC substrate. Compositions of PVC substrate comprise: PVC powder from 20 to 35 weight percent, calcium carbonate from 60 to 70 weight percent, stabilizer from 1 to 3 weight percent, flexibilizer from 1 to 3 weight percent, lubricants from 0.4 to 1 weight percent, and colorant from 0.4 to 1 weight percent. The high strength stone plastic floor does not contain plasticizer so environmental risks are completely avoided. The contractility is good. The high strength stone plastic floor is resistant to high temperature and direct sunlight. Compared with conventional stone plastic floor, lifespan of the present invention is prolonged. The PVC substrate of the floor can be combined with different layers and can integrate different advantages of other floors.

Air permeable core material is vacuum sealed in enveloping member. Further, core material is formed of at least two layers of heat insulating core materials having different heat conductivities. Further, at least two of the at least two layers of heat insulating core materials which form core material are formed of materials having change gradients in the heat conductivity changed in accordance with temperature, and the change gradients in the heat conductivity of the heat insulating core materials intersect with each other. Since two layers of heat insulating core materials having different heat conductivities are provided in a vacuum state, a heat insulating property becomes higher compared to a conventional configuration in which a single layer of the heat insulating core material formed of fiber material such as glass wool or rock wool is vacuum sealed and the high heat insulating property is shown in a wide temperature range.

A cover glass includes a glass substrate and an antireflection film disposed on at least one of main surfaces of the glass substrate, and the at least one of main surfaces of the glass substrate has one or more cracks formed therein, the crack(s) each having a length of 5 μm or less, and a difference Δa* in a* value between any two points within a surface of the cover glass on the side where the antireflection film has been disposed and a difference Δb* in b* value between any two points within the surface of the cover glass on the side where the antireflection film has been disposed satisfy the following expression: √{(Δa*)2+(Δb*)2}≦4.

In nanoimprinting processes, photo-cured products often separate from the substrate and stick to the mold due to insufficient adhesion between the photo-cured product and the substrate. This causes a defect of pattern separation. An adhesion layer composition used for forming an adhesion layer between a substrate and a photocurable composition includes a compound (A) having at least two functional groups, and a solvent (B). The functional groups include at least one functional group capable of being bound to the substrate, selected from the group consisting of hydroxy, carboxy, thiol, amino, epoxy, and (blocked) isocyanate, and at least one hydrogen donating group as a functional group capable of being bound to the photocurable composition.

The magnetic tape has a nonmagnetic layer containing nonmagnetic powder and binder on a nonmagnetic support and a magnetic layer containing ferromagnetic powder and binder on the nonmagnetic layer, wherein a fatty acid ester is contained in at least the magnetic layer, the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, the ferromagnetic hexagonal ferrite powder has a crystallite volume as determined by X-ray diffraction analysis ranges from 1,000 nm3 to 2,400 nm3, and a ratio of the crystallite size Dx(107) obtained from a diffraction peak of a (107) plane to a particle size in a direction of an easy axis of magnetization DTEM as determined by observation with a transmission electron microscope, Dx(107)/DTEM, is greater than or equal to 1.1, and ΔSFD in a longitudinal direction of the magnetic tape as calculated with Equation 1: ΔSFD=SFD25° C.−SFD−190° C., ranges from 0.50 to 1.60.

A base for a magnetic recording medium includes, a substrate made of an Al alloy, and a film made of a NiP-based alloy and provided on the substrate. The Al alloy of the substrate includes Mg in a range of 0.2 mass % to 6 mass %, Si in a range of 3 mass % to 17 mass %, Zn in a range of 0.05 mass % to 2 mass %, and Sr in a range of 0.001 mass % to 1 mass %. An average grain diameter of Si grains in an alloy structure of the substrate is 2 μm or less. The film has a thickness of 10 μm or greater. The substrate has an outer diameter of 53 mm or greater, a thickness of 0.9 mm or less, and a Young's modulus of 79 GPa or higher.

The present invention relates to an electrode having a multilayer nanomesh structure using single-crystalline copper and a method for manufacturing same, the electrode comprising: a substrate; a single-crystalline copper electrode layer formed on the substrate and having a hive-shaped pattern with a nano-sized line width; and a metal oxide layer formed on the single-crystalline copper electrode layer, this providing an electrode having excellent optical transmittance, low electrical sheet resistance, and excellent mechanical stability. The present invention is technically characterized by an electrode having a multilayer nanomesh structure using single-crystalline copper, the electrode comprising: a substrate; a single-crystalline copper electrode layer formed on the substrate and having a hive-shaped pattern with a nano-sized line width; and a metal oxide layer formed on the single-crystalline copper electrode layer.

A composite manufacture includes an extrudable thermoplastic matrix and a photochromic colorant, the photochromic colorant conferring to the composite a reversible strain-induced color change property. Methods include adding photochromic colorant to an extrudable thermoplastic polymer matrix to form a mixture, heating the mixture to form a composite, the photochromic colorant conferring to the composite a reversible strain-induced color change property. The composite manufactures can be used in cable coatings permitting visual detection of mechanical stresses in a wire based on the reversible strain-induced color change property.

Provided is a method for manufacturing magnetic particles, in which an oxidation treatment, a reduction treatment, and a nitriding treatment are performed in that order on raw material particles with a core-shell structure in which a silicon oxide layer is formed on the surfaces of iron microparticles, thereby nitriding the iron microparticles while maintaining the core-shell structure. Due to this configuration, granular magnetic particles with a core-shell structure in which a silicon oxide layer is formed on the surfaces of iron nitride microparticles can be obtained.

Disclosed herein is an electronic apparatus to allow a window to have an anti-scratch and anti-shock protection by allowing a coating unit including a coating layer having a high hardness and a coating layer having a low hardness, to be coated on an upper portion of the window. An electronic apparatus includes a display module, a window disposed on an upper portion of the display module to protect the display module, and a coating unit coated on an upper portion of the window to have a hardness to prevent the window from being damaged, wherein the coating unit comprises a first coating layer coated on the upper portion of the window and a second coating layer coated on an upper portion of the first coating layer to have a high hardness to prevent the window from being scratched, wherein the first coating layer is coated to have a relatively lower hardness than the second coating layer to absorb a shock applied to the window.