Environ. Sci.: Nano, 2020, 7,1061-1067
DOI: 10.1039/C9EN01246J, Communication

Zhiyun Zhang, Ming Xia, Chuanxin Ma, Huiyuan Guo, Wenhao Wu, Jason C. White, Baoshan Xing, Lili He
An organic solvent-based extraction approach coupled with surface enhanced Raman spectroscopic mapping technique to quantify silver nanoparticles in spinach leaf.
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Environ. Sci.: Nano, 2020, 7,1102-1114
DOI: 10.1039/C9EN01104H, Paper

My Kieu Ha, Jang-Sik Choi, Sook Jin Kwon, Jaewoo Song, Yangsoon Lee, Young-Eun Kim, Tae Hyun Yoon
Between-population and within-population heterogeneity in the uptake and toxicity of silver nanoparticles in primary human immune cells revealed by mass cytometry.
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Environ. Sci.: Nano, 2020, 7,1068-1081
DOI: 10.1039/C9EN01382B, Paper

Quin R. S. Miller, John P. Kaszuba, Sebastien N. Kerisit, H. Todd Schaef, Mark E. Bowden, B. Peter McGrail, Kevin M. Rosso
Mineral carbonation reactivity trends and thresholds in nanoconfined water films delineated with in situ X-ray diffraction and molecular simulations.
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Environ. Sci.: Nano, 2020, 7,1041-1060
DOI: 10.1039/C9EN00938H, Critical Review

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Andrew J. Chetwynd, Iseult Lynch
Metabolites present in the corona may play a key role in biological recognition of nanomaterials yet remain a much-overlooked aspect of the corona.
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Environ. Sci.: Nano, 2020, 7,1008-1040
DOI: 10.1039/C9EN01341E, Critical Review

Xiaoyuan Zhang, Yu Liu
Nanomaterials have been demonstrated to be an effective adsorbent or an ion exchanger for selectively removing various radioactive species present in contaminated water while preventing radionuclides from entering and interacting with the biosphere.
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Environ. Sci.: Nano, 2020, 7,1214-1224
DOI: 10.1039/C9EN01279F, Paper

Xue Han, Peng Lv, Lu-Guang Wang, Fei Long, Xiao-Lin Ma, Chang Liu, Yu-Jie Feng, Ming-Feng Yang, Xiang Xiao
The spread of antibiotic resistance genes (ARGs) in the environment has aroused growing concern for human health and ecological safety.
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Environ. Sci.: Nano, 2020, 7,1194-1204
DOI: 10.1039/C9EN01453E, Paper

Zhuanxi Luo, Zhenhong Wang, Baoshan Xing
This study provides new insights into the “Trojan horse” effects of nano-TiO₂ on arsenite (As(III)) bioaccumulation in Daphnia magna.
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Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper

Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Environ. Sci.: Nano, 2020, 7,1136-1149
DOI: 10.1039/D0EN00049C, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Laura-Jayne A. Ellis, Eugenia Valsami-Jones, Iseult Lynch
Pristine engineered nanomaterials (NMs) entering the aquatic environment become ‘aged’ during their lifetime via chemical, physical and/or biological process.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00137F, Paper

Stuart S. Lichtenberg, Kanthi Nuti, Jason DeRouchey, Olga V. Tsyusko, Jason M. Unrine
Chitosan/dsRNA polyplex nanoparticles have shown great potential as insect biocontrol agents. Here, we show that polyplex nanoparticles have their gene silencing capacity altered by environmental variables.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00196A, Paper

Jiayi Zheng, Jiaxin Lv, Weizhen Liu, Zongren Dai, Huizhong Liao, Hong Deng, Zhang Lin
Amorphous nanosized particles in electroplating sludge are modified for selective extraction of heavy metals.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90018D, Retraction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Yubing Sun, Jianhui Lan, Mengxue Li, Wei Hu, Haibo Liu, Gang Song, Diyun Chen, Weiqun Shi, Xiangke Wang
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00131G, Paper

Jonghun Lim, Michael R. Hoffmann
The Co-TNT/PMS system enables the continuous degradation of organic pollutants under dark and solar light-irradiation conditions.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00023J, Paper

Joana Figueiredo, Susana Loureiro, Roberto Martins
Biocides encapsulation appears to be a promising solution to develop a new generation of efficient anti-fouling additives (e.g. SiNC–DCOIT; SiNC–DCOIT–Ag) for maritime coatings with lower environmental hazard than the current state-of-the-art biocides (e.g. DCOIT).
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00174K, Critical Review

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Meike van der Zande, Anita Jemec Kokalj, David Spurgeon, Susana Loureiro, Patricia Silva, Zahra Khodaparast, Damjana Drobne, Nathaniel J. Clark, Nico van den Brink, Marta Baccaro, Kees van Gestel, Hans Bouwmeester, Richard D. Handy
The structure of the gut barrier and luminal chemistry in non-mammalian vertebrates and invertebrates has been given little attention with respect to the dietary uptake of engineered nanomaterials (ENMs). This...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00163E, Paper

Yueyang Zhang, Greg G. Goss
The presence of microplastics in the environment and their potential effects on the health of organisms are a subject of great concern.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper

Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper

Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00091D, Paper

Yunyun Li, Nali Zhu, Xujun Liang, Xu Bai, Lirong Zheng, Jiating Zhao, Yu-Feng Li, Zhiyong Zhang, Yuxi Gao
Mercury (Hg) pollution is a worldwide concern. Silica nanoparticles (Nano-SiO2) can be released into ecosystems through natural and anthropogenic (engineered Nano-SiO2) processes. Here, the influence of two sizes (30 nm...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00008F, Paper

Jeffrey M. Farner, Jacopo De Tommaso, Heather Mantel, Rachel S. Cheong, Nathalie Tufenkji
Research has focused on nanoparticle (NP) aggregation and transport behavior in saturated granular porous media, but few studies have looked at the effect that temperature variability associated with winter conditions will have on engineered NPs.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper

Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between Fe^III/Cr^I ion and Cu^II ion.
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CrystEngComm, 2020, 22,2705-2708
DOI: 10.1039/D0CE00440E, Communication

Keke Zhang, Noalle Fellah, Alexander G. Shtukenberg, Xiaoyan Fu, Chunhua Hu, Michael D. Ward
Two new metastable polymorphs of the tuberculosis drug isoniazid, considered monomorphic for sixty years, were discovered using melt crystallization and nanoscale confinement.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00113A, Paper

Mohd Nazri Abd Rahman, Yusnizam Yusuf, Afiq Anuar, Mohamad Raqif Mahat, Narong Chanlek, Noor Azrina Talik, Muhammad I. M. Abdul Khudus, Norzaini Zainal, Wan Haliza Abd Majid, Ahmad Shuhaimi
An atomically flat covering with a dense and crack-free surface of aluminium nitride films was successfully deposited on a sapphire-(0 0 0 1) substrate through a pulsed atomic-layer epitaxy technique via horizontal metalorganic chemical vapour deposition.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication

Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L²)₂] (M = Cu²⁺, Pd²⁺, Pt²⁺; L² = dinaphthoylmethanido⁻), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper

Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00084A, Paper

Yang Wang, Mengjia Luo, pei Zhao, Xiangli Che, Yunzhen Cao, Fu Qiang Huang
A new mid-infrared nonlinear optical oxyselenide, Sr₄Pb_1.5Sb₅O₅Se₈, was successfully synthesized by traditional solid-state reaction. It crystallizes in the noncentrosymmetric space group Cm (No. 8) of the monoclinic system. The crystal...
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CrystEngComm, 2020, 22,2904-2913
DOI: 10.1039/C9CE01157A, Paper

Edurne S. Larrea, Roberto Fernández de Luis, Arkaitz Fidalgo-Marijuan, Eva M. Maya, Marta Iglesias, Maria I. Arriortua
The versatility of CuBTC (HKUST-1) MOF materials to be functionalized to improve their catalytic activity performance was evaluated. CuBTC@IL catalysts are selective for the cycloaddition of CO₂ to epoxides, giving rise to value-added products.
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CrystEngComm, 2020, 22,3033-3041
DOI: 10.1039/D0CE00224K, Paper

Chunyan Dong, Yan Zhou, Na Ta, Wenjie Shen
Ceria nanocubes of 10–20 nm were hydrothermally synthesized, involving Ce(OH)₃ rods and small-sized CeO₂ polyhedra/cubes as building blocks.
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CrystEngComm, 2020, 22,2953-2963
DOI: 10.1039/D0CE00268B, Paper

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
2D porous nickel oxalate thin sheets constructed by ultrathin nanosheets were first synthesized by using a simple hydrothermal method. The resulting porous thin sheets exhibited superior supercapacitor performance.
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CrystEngComm, 2020, 22,3020-3032
DOI: 10.1039/D0CE00343C, Paper

Christian A. Juillerat, Vladislav V. Klepov, Mark D. Smith, Hans-Conrad zur Loye
The flux synthesis of a uranium gallophosphate and a uranium gallate, Cs₄[UO₂Ga₂(PO₄)₄] and Cs₂UO₂Ga₂O₅, and 4 uranium phosphates, [Rb₂Rb_3.93Cl_0.93][(UO₂)₅(PO₄)₅], Rb₁₁[(UO₂)₈(PO₄)₉], Rb_7.6[(UO₂)₈O_8.6F_0.4(PO₄)₂], and Rb₆[(UO₂)₅O₂(PO₄)₄], is reported.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00521E, Paper

Taka Narumi, Didier Chaussende, Takashi Yoshikawa
Solution growth of SiC is a promising process for producing high-quality SiC crystals; however, control over the morphology of the growth interface under rapid growth conditions is a critical issue....
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00334D, Paper

Angelo Gavezzotti, Leonardo Lo Presti, Silvia Rizzato
A novel, universal Lennard-Jones–Coulomb (LJC) atom–atom force field parametrization reproduces the experimental sublimation enthalpies of 377 molecular crystals drawn from the CSD.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00513D, Paper

Mengdie Wang, Jian Zhang, Yun-Kai Sun, Jing Wei, Chunhong Tan, Xiao-Feng Wang
Four layered coordination polymers, namely, [Cd2(fuma)2(phen)2] (1), [Cd2(BDC)2(phen)2]·2DMF (2), [Cd2(NDC)2(phen)2]·0.5H2O (3), [Cd2(NDC)2(bipy)2]·2DMF (4) have been synthesized under solvo-thermal conditions (fuma = fumaric acid, H2BDC = 1,4-benzenedicarboxylic acid, H2NDC =1,4-naphthalenedicarboxylic acid,...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00312C, Paper

Stefan Neumann, Cristina Menter, Ahmed Salaheldin Mahmoud, Doris Segets, David Rafaja
Although the concept of quantum confinement was introduced more than thirty years ago, a wide application of the quantum dots is still limited by the fact that monodisperse quantum dots...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00226G, Paper

Nida Tabassum, Panayiotis C. Varras, Fiza Arshad, Muhammad I. Choudhary, Sammer Yousuf
Urotropine (1) is a synthetic heterocyclic antibacterial agent.
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